Which of the following factors has no effect on the rate of SN1 reactions? (a) the nature of the alkyl halide (b) the nature of the leaving group (c) the concentration of the alkyl halide (d) the concentration of the nucleophile

Which of the following factors has no effect on the rate of SN1 reactions?
(a) the nature of the alkyl halide
(b) the nature of the leaving group
(c) the concentration of the alkyl halide
(d) the concentration of the nucleophile
by

1 Answer

Answer :

the concentration of the nucleophile
by

Related questions

Which of the following factors influence whether a reaction will proceed by an SN1, SN2, E1, or E2 mechanism? (a) Structure of the alkyl halide (b) Solvent (c) Concentration of reagents (d) Nature of the nucleophile (e) All of these

Description : Which of the following factors influence whether a reaction will proceed by an SN1, SN2, E1, or E2 mechanism? (a) Structure of the alkyl halide (b) Solvent (c) Concentration of reagents (d) Nature of the nucleophile (e) All of these

Last Answer : All of these

Which of the following is the rate law for SN1 mechanisms? (a) Rate = k[Alkyl Halide] [Nucleophile] (b) Rate = k[Nucleophile] (c) Rate = k[Alkyl Halide](d) Rate = k1[Alkyl Halide] + k2[Nucleophile]

Description : Which of the following is the rate law for SN1 mechanisms? (a) Rate = k[Alkyl Halide] [Nucleophile] (b) Rate = k[Nucleophile] (c) Rate = k[Alkyl Halide] (d) Rate = k1[Alkyl Halide] + k2[Nucleophile]

Last Answer : Rate = k[Alkyl Halide]

Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the concentration of the alkyl halide. (c) The rate of reaction of a particular alkyl bromide depends on the steric accessibility of the carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides

Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides

Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides

Which is the most reactive alkyl halide in a SN1 reaction? (a) CH3F (b) CH3Br (c) CH3I (d) CH3Cl

Description : Which is the most reactive alkyl halide in a SN1 reaction? (a) CH3F (b) CH3Br (c) CH3I (d) CH3Cl

Last Answer : CH3I

Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an sp3 hybridized carbon undergo substitution and elimination reactions. (c) The electronegative atom is replaced by another atom or group in substitution reactions. (d) (a) and (b)

Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)

Last Answer : (a) and (b)

In an alkyl halide substitution of hydrogen by deuterium results in slow formation of ion pair. This is known as? a. Ortho effect b. Mesomeric effect c. Secondary kinetic isotope effect d. Primary kinetic isotope effect

Description : In an alkyl halide substitution of hydrogen by deuterium results in slow formation of ion pair. This is known as? a. Ortho effect b. Mesomeric effect c. Secondary kinetic isotope effect d. Primary kinetic isotope effect

Last Answer : c. Secondary kinetic isotope effect

In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the carbon chain, the reagent used as sou

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When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form

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Last Answer : primary amines form

Which reaction does not yield an ester as one of the products?(a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid

Description : Which reaction does not yield an ester as one of the products? (a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid

Last Answer : A Grignard reagent is added to a carboxylic acid

The reaction of a sodium alkoxide with an alkyl halide is called (a) Wurtz-Fittig reaction (b) Perkin reaction (c) Williamson's synthesis (d) Aldol condensation

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How should CH3CHClCH2CH3 be classified? (a) primary alkyl halide (b) secondary alkyl halide (c) tertiary alkyl halide (d) quarternary alkyl halide

Description : How should CH3CHClCH2CH3 be classified? (a) primary alkyl halide (b) secondary alkyl halide (c) tertiary alkyl halide (d) quarternary alkyl halide

Last Answer : secondary alkyl halide

Which of the following is a secondary alkyl halide? (a) CH3Br(b) (CH3)3CBr (c) (CH3)2CHBr (d) (CH3)2CHCH2Br

Description : Which of the following is a secondary alkyl halide? (a) CH3Br (b) (CH3)3CBr (c) (CH3)2CHBr (d) (CH3)2CHCH2Br

Last Answer : (CH3)2CHBr

Which of the following statements is correct for a saturated alkyl halide? (a) the C–X bond results from overlap of the s orbital of carbon and the p orbital of the halogen (X) (b) the C–X bond results from overlap of the p orbital of carbon and the p orbital of the halogen (X) (c) the C–X bond results from overlap of the sp3 orbital of carbon and the p orbital of the halogen (X) (d) the C–X bond results from overlap of the sp2 orbital of carbon and the p orbital of the halogen (X)

Description : Which of the following statements is correct for a saturated alkyl halide? (a) the C-X bond results from overlap of the s orbital of carbon and the p orbital of the halogen (X) (b) the C-X bond ... the C-X bond results from overlap of the sp2 orbital of carbon and the p orbital of the halogen (X)

Last Answer : the C–X bond results from overlap of the sp3 orbital of carbon and the p orbital of the halogen (X)

Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:-

Description : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:-

Last Answer : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:- A. B. C. D.

`S_(N^(1))` mechanism for the hydrolysis of an alkyl halide involves the formation of intermediate:

Description : `S_(N^(1))` mechanism for the hydrolysis of an alkyl halide involves the formation of intermediate:

Last Answer : `S_(N^(1))` mechanism for the hydrolysis of an alkyl halide involves the formation of intermediate: ... B. carbocation C. carbanion D. none of these

Statement-1: In protic solvents phenoxide ion is alkylated primarily at C-alkylation whereas in polar aprotic solvents O-alkylation with alkyl halide.

Description : Statement-1: In protic solvents phenoxide ion is alkylated primarily at C-alkylation whereas in polar aprotic solvents O-alkylation with alkyl halide.

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Which alkyl halide would be preferred for the synthesis of the following ether by Williamson synthesis ? `H_(5)C_(2)-O-overset(CH_(3))overset(|)unders

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Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

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Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds of alkynes are higher in energy than the bonds and are thus more reactive. (c) Unlike alkenes, alkynes fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.

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Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

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Last Answer : Nucleophilic substitution reactions

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The acid-catalyzed dehydration mechanism for alcohols is best described as a(n) : (a) E1 . (b) E2 . (c) SN1 (d) SN2

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Last Answer : E1 .

Predict the two most likely mechanisms which occur when 2-iodohexane is heated in ethanol. (a) SN2 and SN1 (b) E1 and E2 (c) SN2 and E2 (d) E1 and SN1

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Last Answer : E1 and SN1

Predict the two most likely mechanisms for the reaction of 2-iodohexane with sodium ethoxide. (a) SN2 and SN1 (b) E1 and E2 (c) SN2 and E2 (d) E1 and SN1

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Dehydrohalogenation of 2-bromobutane in the presence of a strong base proceeds via which of the following mechanistic pathways? (a) SN1 (b) SN2 (c) E1 (d) E2

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Which compound reacts most rapidly by an SN1 mechanism? (a) Methyl chloride(b) Isopropyl chloride(c) Ethyl chloride(d) tert-Butyl chloride

Description : Which compound reacts most rapidly by an SN1 mechanism? (a) Methyl chloride (b) Isopropyl chloride (c) Ethyl chloride (d) tert-Butyl chloride

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SN1 reaction is having ......order. a. Zero b. First c. Second d. Third

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Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism

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Last Answer : Resonance stabilization

Which of the following is not a correct statement concerning the FriedelCrafts acylation of benzene? (a) An alkyl group substitutes for a hydrogen. (b) The benzene ring attacks an acylium ion. (c) The acylium ion is resonance stabilized. (d) The acylium ion is often produced from an acyl chloride.

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What type of an alkyl group is an isobutyl group? (a) primary (b) secondary (c) tertiary (d) none of these

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What class of organic compounds is characterized by an -OH group bonded to an alkyl group?

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(3) Detergents give lather even with hard water Explanation: Soaps are made of materials found in nature. Detergents are synthetic a big drawback of washing with soap is that the minerals in water react with those in soap, leaving an insoluble film. Detergents react less to minerals in water and for all practical purposes are the product of choice for laundry, unless you have very soft water. On the other hand, soap will combine with the magnesium and calcium ions in hard water to create an insoluble residue that can clog drains and stick to clothing.

Description : (3) Detergents give lather even with hard water Explanation: Soaps are made of materials found in nature. Detergents are synthetic a big drawback of washing with soap is that the minerals in water ... ions in hard water to create an insoluble residue that can clog drains and stick to clothing.

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Last Answer : Cement is usually a mixture of – (1) Calcium silicate and calcium alurninate (2) Calcium silicate and calcium ferrate (3) Calcium aluminate and calcium ferrate (4) Lime stone and silicon dioxide

What is mechanism of sn1 explain?

Description : What is mechanism of sn1 explain?

Last Answer : What is the answer ?

Why cyanide ion act as ambident nucleophile ?

Description : Why cyanide ion act as ambident nucleophile ?

Last Answer : Ans.---- Cyanide ion can link through either carbon or nitrogen, therefore it is an ambident nuclophile.

Which of the following is the best nucleophile in water? (a) I– (b) CH3SCH3 (c) CH3OCH3 (d) Cl–

Description : Which of the following is the best nucleophile in water? (a) I– (b) CH3SCH3 (c) CH3OCH3 (d) Cl–

Last Answer : I–

Which of the following is the strongest nucleophile in an aqueous solution? (a) HO– (b) Cl– (c) Br– (d) I

Description : Which of the following is the strongest nucleophile in an aqueous solution? (a) HO– (b) Cl– (c) Br– (d) I

Last Answer : I–

Which of the following is not a possible reaction of a carbocation? (a) addition of a nucleophile (b) rearrangement to a more stable carbocation (c) addition of a proton to form an alkane (d) loss of a β-hydrogen to form an alkene

Description : Which of the following is not a possible reaction of a carbocation? (a) addition of a nucleophile (b) rearrangement to a more stable carbocation (c) addition of a proton to form an alkane (d) loss of a β-hydrogen to form an alkene

Last Answer : addition of a proton to form an alkane

Why does a H+ ion attacking a carbon-carbon double bond add to the carbon with the least number of substituents? (a) the reaction is resonance stabilized. (b) the hybrid geometry favors this process. (c) nucleophile tends to attack stable centers of negative charge. (d) a more stable carbonium ion is generated.

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Last Answer : a more stable carbonium ion is generated.

In the reaction of propene with HCl, H+ ion acts as the : (a) electrophile (b) carbonium ion (c) nucleophile (d) carbanion

Description : In the reaction of propene with HCl, H+ ion acts as the : (a) electrophile (b) carbonium ion (c) nucleophile (d) carbanion

Last Answer : electrophile

Which of the following statements is incorrect? (a) Electrons move toward positively charged locations. (b) An electron-rich atom is called an electrophile. (c) An electrophile is electron loving. (d) A nucleophile has a a pair of electrons it can share

Description : Which of the following statements is incorrect? (a) Electrons move toward positively charged locations. (b) An electron-rich atom is called an electrophile. (c) An electrophile is electron loving. (d) A nucleophile has a a pair of electrons it can share

Last Answer : An electron-rich atom is called an electrophile.

Which of the following is not a nucleophile? (a) FeBr3 (b) Br– (c) NH3 (d) CH3OCH3

Description : Which of the following is not a nucleophile? (a) FeBr3 (b) Br– (c) NH3 (d) CH3OCH3

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Which of the following is not normally considered to be a nucleophile? (a) NH3 (b) CH3NH2 (c) HC≡C:– (d) CH3CH2+

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Last Answer : CH3CH2+

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Last Answer : Lewis base