Description : Which molecule has the greatest dipole moment (a) CH3Cl (b) CH3Br (c) CH3F (d) CH3I
Last Answer : CH3F
Description : Which of the following factors influence whether a reaction will proceed by an SN1, SN2, E1, or E2 mechanism? (a) Structure of the alkyl halide (b) Solvent (c) Concentration of reagents (d) Nature of the nucleophile (e) All of these
Last Answer : All of these
Description : Which of the following is a secondary alkyl halide? (a) CH3Br (b) (CH3)3CBr (c) (CH3)2CHBr (d) (CH3)2CHCH2Br
Last Answer : (CH3)2CHBr
Description : Which of the following factors has no effect on the rate of SN1 reactions? (a) the nature of the alkyl halide (b) the nature of the leaving group (c) the concentration of the alkyl halide (d) the concentration of the nucleophile
Last Answer : the concentration of the nucleophile
Description : Which of the following is the rate law for SN1 mechanisms? (a) Rate = k[Alkyl Halide] [Nucleophile] (b) Rate = k[Nucleophile] (c) Rate = k[Alkyl Halide] (d) Rate = k1[Alkyl Halide] + k2[Nucleophile]
Last Answer : Rate = k[Alkyl Halide]
Description : Which reaction does not yield an ester as one of the products? (a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid
Last Answer : A Grignard reagent is added to a carboxylic acid
Description : The reaction of a sodium alkoxide with an alkyl halide is called (a) Wurtz-Fittig reaction (b) Perkin reaction (c) Williamson's synthesis (d) Aldol condensation
Last Answer : Williamson's synthesis
Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides
Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides
Description : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:-
Last Answer : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:- A. B. C. D.
Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form
Last Answer : primary amines form
Description : How should CH3CHClCH2CH3 be classified? (a) primary alkyl halide (b) secondary alkyl halide (c) tertiary alkyl halide (d) quarternary alkyl halide
Last Answer : secondary alkyl halide
Description : Which of the following statements is correct for a saturated alkyl halide? (a) the C-X bond results from overlap of the s orbital of carbon and the p orbital of the halogen (X) (b) the C-X bond ... the C-X bond results from overlap of the sp2 orbital of carbon and the p orbital of the halogen (X)
Last Answer : the C–X bond results from overlap of the sp3 orbital of carbon and the p orbital of the halogen (X)
Description : In an alkyl halide substitution of hydrogen by deuterium results in slow formation of ion pair. This is known as? a. Ortho effect b. Mesomeric effect c. Secondary kinetic isotope effect d. Primary kinetic isotope effect
Last Answer : c. Secondary kinetic isotope effect
Description : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the carbon chain, the reagent used as sou
Last Answer : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the ... C_(6)H_(4)(CO)_(2)N^(-)K^(+)`
Description : `S_(N^(1))` mechanism for the hydrolysis of an alkyl halide involves the formation of intermediate:
Last Answer : `S_(N^(1))` mechanism for the hydrolysis of an alkyl halide involves the formation of intermediate: ... B. carbocation C. carbanion D. none of these
Description : Statement-1: In protic solvents phenoxide ion is alkylated primarily at C-alkylation whereas in polar aprotic solvents O-alkylation with alkyl halide.
Last Answer : Statement-1: In protic solvents phenoxide ion is alkylated primarily at C-alkylation whereas in polar ... Statement-1 is false, Statement-2 is true
Description : Which alkyl halide would be preferred for the synthesis of the following ether by Williamson synthesis ? `H_(5)C_(2)-O-overset(CH_(3))overset(|)unders
Last Answer : Which alkyl halide would be preferred for the synthesis of the following ether by Williamson ... chloride C. Ethyl chloride D. Methyl chloride
Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism
Last Answer : Resonance stabilization
Description : Predict the two most likely mechanisms for the reaction of 2-iodohexane with sodium ethoxide. (a) SN2 and SN1 (b) E1 and E2 (c) SN2 and E2 (d) E1 and SN1
Last Answer : SN2 and E2
Description : SN1 reaction is having ......order. a. Zero b. First c. Second d. Third
Last Answer : b. First
Description : Anisole on heating with concentrated HI gives (a) Iodobenzene (b) Phenol + CH3I (c) Iodobenzene + CH3OH (d) Phenol + CH3OH
Last Answer : Phenol + CH3I
Description : Anisole is formed when phenol is treated with (a) CH3I/NaOH (b) CH3CH2I/NaOH (c) CHCl3/NaOH (d) Acetic anhydride
Last Answer : CH3I/NaOH
Description : Iodobenzene can be prepared by (a) treating chlorobenzene with I2 using FeCl3 catalyst. (b) treating phenol with I2 in NaOH solution. (c) treating benzenediazonium chloride with KI (d) treating benzene with CH3I using AlCl3 catalyst
Last Answer : treating benzenediazonium chloride with KI
Description : Which of the following is the best method for preparing CH3Br? (a) CH3OH + Br– (b) CH3OH + HBr (c) CH3OH + Br2 (d) CH3OH + NaBr
Last Answer : CH3OH + HBr
Description : Which one of the following statements about the mass spectrum of CH3Br is correct? a. the last two peaks are of equal size and occur at m/z values of 94 and 96 b. the last two peaks have abundances in the ... m/z value of 95 d. there is just one peak for the molecular ion with an m/z value of 44
Last Answer : a. the last two peaks are of equal size and occur at m/z values of 94 and 96
Description : Which of the following can be made by the action of CH3Cl on benzene in the presence of aluminium chloride? (a) Ethylbenzene (b) o-Xylene (c) Chlorobenzene (d) m-Xylene
Last Answer : o-Xylene
Description : Which of the following reagents will react with methyl group rather than the benzene ring in methylbenzene? (a) Chlorine in the presence of uv light (b) CH3Cl in the presence of AlCl3 (c) CH3COCl in the presence of AlCl3 (d) Hydrogen in the presence of nickel
Last Answer : Chlorine in the presence of uv light
Description : Which of the following will have the lowest boiling point? (a) CH3Cl (b) CH4 (c) CH2Cl2 (d) CHCl3
Last Answer : CH4
Description : Which of the following is a nonpolar molecule? (a) HCl (b) CH3Cl (c) H2 (d) NH3
Last Answer : H2
Description : When dipentyl ether is treated with excess HI, through what type of mechanism(s) does the major product result? (a) SN2 (b) SN1 (c) E1 (d) E2
Last Answer : SN2
Description : The acid-catalyzed dehydration mechanism for alcohols is best described as a(n) : (a) E1 . (b) E2 . (c) SN1 (d) SN2
Last Answer : E1 .
Description : Predict the two most likely mechanisms which occur when 2-iodohexane is heated in ethanol. (a) SN2 and SN1 (b) E1 and E2 (c) SN2 and E2 (d) E1 and SN1
Last Answer : E1 and SN1
Description : Dehydrohalogenation of 2-bromobutane in the presence of a strong base proceeds via which of the following mechanistic pathways? (a) SN1 (b) SN2 (c) E1 (d) E2
Last Answer : E2
Description : Which compound reacts most rapidly by an SN1 mechanism? (a) Methyl chloride (b) Isopropyl chloride (c) Ethyl chloride (d) tert-Butyl chloride
Last Answer : tert-Butyl chloride
Description : . Hunsdiecker reaction is used for the preparation of (a) Alkyl chlorides and bromides (b) Alkyl nitrates and nitrites (c) Ketenes (d) Alcohols
Last Answer : Alkyl chlorides and bromides
Description : Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides
Last Answer : Alkoxyalkanes
Description : Fatty liver is also caused by (A) CH3Cl (B) CCl4 (C) Na2SO4 (D) Riboflavin
Last Answer : Answer : B
Description : What is mechanism of sn1 explain?
Last Answer : What is the answer ?
Description : Give an example of oxidation of halide by another halogen. Explain the feasibility of the reaction.
Last Answer : Give an example of oxidation of halide by another halogen. Explain the feasibility of the reaction.
Description : Phenol on heating with NaOH followed by reaction with alky1 halide gives
Last Answer : Phenol on heating with NaOH followed by reaction with alky1 halide gives A. Acetone B. Ether C. Ethonal D. Acetic acid
Description : Compound P on treatement with `CH_(2)N_(2)` (diazomethane) produces compound Q. compound Q on reaction with Hl produces two alkyl iodides R and S . Al
Last Answer : Compound P on treatement with `CH_(2)N_(2)` (diazomethane) produces compound Q. compound Q on reaction ... 2-methyl-2-propanol D. 2-methyl-1-propanol
Description : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is :
Last Answer : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is : A. RF > RCl > RBr > ... RBr > RF > RI D. RI > RBr > RCl > RF
Description : Assertion (A): Alkyl aryl ethers on reaction with HI give alkyl iodide phenols Reason (R): Aryl - oxygen bond is weaker than alkyl oxygen bond
Last Answer : Assertion (A): Alkyl aryl ethers on reaction with HI give alkyl iodide phenols Reason (R): Aryl - oxygen ... is false D. A is false but R is true
Description : Name the reducing agent in the following reaction: 3MnO2 + 4Al———— > 3Mn + 2Al2O3 State which is more reactive, Mn or A1 and why? -Chemistry
Last Answer : ‘Al’ is reducing agent. ‘AT is more reactive than Mn v ‘Al’ displaces Mn from its oxide.
Description : Would you expect benzaldehyde to be more reactive or less reactive in nucleophlic addition reaction than propanal ? Explain.
Last Answer : C-atom of carbonyl group of benzaldehyde is less electrophilic than C-atom of carbonyl group in propanal. Polarity of carbonyl group is in benzaldehyde reduced due to resonance making it less ... group in it is more than in benzaldehyde. This makes propanal more reactive than benzaldehyde.
Description : Which of the following halides is least reactive in an E2 reaction with sodium methoxide? (a) (CH3)3CCH2I (b) (CH3)2CHCHICH3 (c) (CH3)2CHCH2Br (d) (CH3)2CHCH2Cl
Last Answer : (CH3)3CCH2I
Description : Which of the following halides is most reactive in an E2 reaction with sodium methoxide? (a) (CH3)3CCH2I (b) (CH3)2CHCHICH3 (c) (CH3)2CHCH2Br (d) (CH3)2CHCH2C
Last Answer : (CH3)2CHCHICH3
Description : Which of the following species is most reactive in a SN2 reaction? (a) CH3CH2Cl (b) CH3CH2Br (c) CH3CH2I (d) CH3CH2F
Last Answer : CH3CH2I
Description : Why is the halogenation of alkanes considered a chain reaction? (a) it occurs quickly. (b) it occurs without the generation of intermediates. (c) each step generates the reactive intermediate that causes the next step to occur. (d) the reaction allows long chains of halogenated alkanes to be formed
Last Answer : each step generates the reactive intermediate that causes the next step to occur
Description : Which halide is used in making sensitive emulsion on photographic film? (1) Sodium chloride (2) Silver bromide (3) Silver iodide (4) Silver chloride
Last Answer : (2) Silver bromide Explanation: Silver bromide, a soft, paleyellow, water insoluble salt well known for its unusual sensitivity to light. This property has allowed silver halides to become the basis of modern photographic materials.