Nitration of nitrobenzene with HNO3/H2SO4 gives : (a) m-dinitrobenzene (b) o-dinitrobenzene (c) p-dinitrobenzene (d) m-nitrobenzenesulfonic acid

Nitration of nitrobenzene with HNO3/H2SO4 gives :
(a) m-dinitrobenzene
(b) o-dinitrobenzene
(c) p-dinitrobenzene
(d) m-nitrobenzenesulfonic acid
by

1 Answer

Answer :

m-dinitrobenzene
by

Related questions

Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Description : Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Last Answer : can be oxidized with KMnO4 to give benzoic acid

Naphthalene undergoes nitration with HNO3/H2SO4 at 60°C to give mainly (a) 1-Nitronaphthalene (b) 1,2-Dinitronaphthalene (c) 2-Nitronaphthalene (d) 1,5-Dinitronaphthalene

Description : Naphthalene undergoes nitration with HNO3/H2SO4 at 60°C to give mainly (a) 1-Nitronaphthalene (b) 1,2-Dinitronaphthalene (c) 2-Nitronaphthalene (d) 1,5-Dinitronaphthalene

Last Answer : 1-Nitronaphthalene

Which of the following compounds reacts most rapidly with HNO3/H2SO4? (a) toluene (b) anisole (c) nitrobenzene(d) benzonitrile

Description : Which of the following compounds reacts most rapidly with HNO3/H2SO4? (a) toluene (b) anisole (c) nitrobenzene (d) benzonitrile

Last Answer : anisole

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?

Description : Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?

Last Answer : Ans. -CH3 group is electron donating while –NO2 group is electron withdrawing. Therefore, maximum electron density will be in toluene , followed by benzene and at least in m-dinitrobenzene. Therefore, the ease of nitration decreases in the order: Toluene> benzene> m-dinitrobenzene

Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?

Description : Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?

Last Answer : Ans. -CH3 group is electron donating while –NO2 group is electron withdrawing. Therefore, maximum electron density will be in toluene, followed by benzene and at least in m-dinitrobenzene. Therefore, the ease of nitration decreases in the order: Toluene> benzene> m-dinitrobenzene

Which of the following compounds undergoes nitration most readily? (a) Benzene (b) Toluene (c) Nitrobenzene (d) Benzoic acid

Description : Which of the following compounds undergoes nitration most readily? (a) Benzene (b) Toluene (c) Nitrobenzene (d) Benzoic acid

Last Answer : Toluene

40. Among the fo the one that is most reactive towards electrophilic nitration is: (1) Benzene (2) Benzoic acid (3) Nitrobenzene (4) Toluene

Description : 40. Among the following compounds the one that is most reactive towards electrophilic nitration is: (1) Benzene (2) Benzoic acid (3) Nitrobenzene (4) Toluene

Last Answer : Toluene

Which of the following agents is used in order to make benzene react with concentrated nitric acid to give nitrobenzene? (a) Concentrated H2SO4 (b) FeCl3 catalyst (c) Lindlar's catalyst (d) Ultraviolet light

Description : Which of the following agents is used in order to make benzene react with concentrated nitric acid to give nitrobenzene? (a) Concentrated H2SO4 (b) FeCl3 catalyst (c) Lindlar's catalyst (d) Ultraviolet light

Last Answer : Concentrated H2SO4

Trinitrotoluene (TNT), an explosive, is made by the nitration of (A) Nitrobenzene (B) Toluene (C) Nitrotoluene (D) Benzene

Description : Trinitrotoluene (TNT), an explosive, is made by the nitration of (A) Nitrobenzene (B) Toluene (C) Nitrotoluene (D) Benzene

Last Answer : (B) Toluene

Which of the following statements is correct about aniline? (a) is weak acid. (b) diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid. (c) can be nitrated with concentrated HNO3 to form p-nitroaniline. (d) gives an intense green color with a suspension of bleaching powder in water

Description : Which of the following statements is correct about aniline? (a) is weak acid. (b) diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid. (c) can be nitrated with ... p-nitroaniline. (d) gives an intense green color with a suspension of bleaching powder in water

Last Answer : diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid.

Glass lined vessels are not used for handling (A) Dilute H2SO4 (B) Dilute HNO3 (C) Dilute HCI (D) Hydrofluoric acid

Description : Glass lined vessels are not used for handling (A) Dilute H2SO4 (B) Dilute HNO3 (C) Dilute HCI (D) Hydrofluoric acid

Last Answer : (D) Hydrofluoric acid

Glass lined vessels are not used for handling/storing (A) Dilute H2SO4 (B) Dilute HNO3 (C) Dilute HCl (D) Hydrofluoric acid

Description : Glass lined vessels are not used for handling/storing (A) Dilute H2SO4 (B) Dilute HNO3 (C) Dilute HCl (D) Hydrofluoric acid

Last Answer : (D) Hydrofluoric acid

The electrolyte in a lead-acid battery is a) H2SO4 b) HNO3 c) HCl d) NaCl Ans. a

Description : The electrolyte in a lead-acid battery is a) H2SO4 b) HNO3 c) HCl d) NaCl Ans. a

Last Answer : ans a

For conduct of forced degradation studies under acidic conditions, which of the following substance is used? A. HCl B. H2SO4 C. HNO3 D. Citric acid

Description : For conduct of forced degradation studies under acidic conditions, which of the following substance is used? A. HCl B. H2SO4 C. HNO3 D. Citric acid

Last Answer : A. HCl

Which among the following is used as a catalyst in the production of high octane fuels? (1) HNO3 (2) H2SO4 (3) HCl (4) HF

Description : Which among the following is used as a catalyst in the production of high octane fuels? (1) HNO3 (2) H2SO4 (3) HCl (4) HF

Last Answer : (2) H2SO4 Explanation: Sulfuric acid is used as a catalyst for refining and for producing alkylate, an essential component of highoctane fuel. The hydrocarbon molecules are reformed into more complex molecules with a higher octane rating value.

Glass is soluble in - (1) H2SO4 (2) HCIO4 (3) HNO3 (4) HF

Description : Glass is soluble in - (1) H2SO4 (2) HCIO4 (3) HNO3 (4) HF

Last Answer : (4) HF Explanation: Hydrofluoric acid is a highly corrosive acid, capable of dissolving many materials, especially oxides. Its ability to dissolving lass has been known since the 17th century. It is a solution of hydrogen fluoride in water and is represented by HF.

Aquaregia is a mixture of the following in the ratio 1 : 3 by volume– (1) cone. HNO3 and cone. HCL (2) conc. HNO3 and conc. H2SO4 (3) dil. HCl and dil. HNO3 (4) cone. HCl and cone. HNO3

Description : Aquaregia is a mixture of the following in the ratio 1 : 3 by volume– (1) cone. HNO3 and cone. HCL (2) conc. HNO3 and conc. H2SO4 (3) dil. HCl and dil. HNO3 (4) cone. HCl and cone. HNO3

Last Answer : (3) dil. HCl and dil. HNO3 Explanation: Aqua regia or nitro-hydrochloric acid is a highly corrosive mixture of acids which is formed by freshly mixing concentrated Nitric acid (HNO3) and Hydrochloric acid (HCl), optimally in a volume ratio of 1:3. It is used in dissolving gold.

When glycerol is treated with a mixture of concentrated HNO3 + H2SO4, it forms (a) Nitroethane (b) 1-Nitropropane (c) Nitroglycerine (d) 2-Nitropropane

Description : When glycerol is treated with a mixture of concentrated HNO3 + H2SO4, it forms (a) Nitroethane (b) 1-Nitropropane (c) Nitroglycerine (d) 2-Nitropropane

Last Answer : Nitroglycerine

Diazotization is carried out by… a. HNO3 b. H2SO4 c. HNO2 d. NO

Description : Diazotization is carried out by… a. HNO3 b. H2SO4 c. HNO2 d. NO

Last Answer : c. HNO2

When aniline is heated with glycerol in the presence of sulfuric acid and nitrobenzene, it gives quinoline. This reaction in called (a) Fischer synthesis (b) Skraup synthesis (c) Diazotization (d) Corey-House synthesis

Description : When aniline is heated with glycerol in the presence of sulfuric acid and nitrobenzene, it gives quinoline. This reaction in called (a) Fischer synthesis (b) Skraup synthesis (c) Diazotization (d) Corey-House synthesis

Last Answer : Skraup synthesis

Nitrobenzene reacts with Br2 in the presence of FeCl3 to give(a) o-chloronitrobenzene(b) o-bromonitrobenzene(c) m-chloronitrobenzene(d) m-bromonitrobenzene

Description : Nitrobenzene reacts with Br2 in the presence of FeCl3 to give (a) o-chloronitrobenzene (b) o-bromonitrobenzene (c) m-chloronitrobenzene (d) m-bromonitrobenzene

Last Answer : m-bromonitrobenzene

Sulphur containing amino acids after catabolism produces a substance which is excreted: (A) SO2 (B) HNO3 (C) H2SO4 (D) H3PO4

Description : Sulphur containing amino acids after catabolism produces a substance which is excreted: (A) SO2 (B) HNO3 (C) H2SO4 (D) H3PO4

Last Answer : Answer : C

For the COD test of sewage, organic matter is oxidised by K2Cr2O7 in the presence of A. H2SO4 B. HNO3 C. HCl D. None of these

Description : For the COD test of sewage, organic matter is oxidised by K2Cr2O7 in the presence of A. H2SO4 B. HNO3 C. HCl D. None of these

Last Answer : ANS: A

Raw materials required for the production of CAN (Calcium ammonium nitrate) is NH3 (A) HNO3 & limestone (B) CO2 & H2SO4 (C) HNO3 & NH4Cl (D) CO2 & KNO3

Description : Raw materials required for the production of CAN (Calcium ammonium nitrate) is NH3 (A) HNO3 & limestone (B) CO2 & H2SO4 (C) HNO3 & NH4Cl (D) CO2 & KNO3

Last Answer : (A) HNO3 & limestone

Although — NH2 gp is an ortho and para directing gp, nitration of aniline gives along with ortho and para, meta derivatives also.

Description : Although — NH2 gp is an ortho and para directing gp, nitration of aniline gives along with ortho and para, meta derivatives also.

Last Answer : Nitration is carried out with a mixture of Conc. NO3 + Conc. H2 SO4 (nitrating mix). In the presence of these acids, most of aniline gets protonated to form anilinium ion. Therefore, in the ... is m-directing and deactivating hence a mixture of all three-ortho, para and meta derivatives is formed.

Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with acidic KMnO4 solution. (c) on refluxing with concentrated H2SO4 gives a mixture of ortho and para toluenesulfonic acid. (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene

Ascorbic acid can reduce (A) 2, 6-Dibromobenzene (B) 2, 6-Diiodoxypyridine (C) 2, 6-Dichlorophenol indophenol (D) 2, 4-Dinitrobenzene

Description : Ascorbic acid can reduce (A) 2, 6-Dibromobenzene (B) 2, 6-Diiodoxypyridine (C) 2, 6-Dichlorophenol indophenol (D) 2, 4-Dinitrobenzene

Last Answer : Answer : C

Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid

Which of the following will undergo substitution in the ortho and para positions rather than in the meta position? (a) Nitrobenzene (b) Benzoic acid (c) Acetanilide (d) Benzaldehyde

Description : Which of the following will undergo substitution in the ortho and para positions rather than in the meta position? (a) Nitrobenzene (b) Benzoic acid (c) Acetanilide (d) Benzaldehyde

Last Answer : Acetanilide

Aniline undergoes oxidation with Na2Cr2O7/H2SO4 to give (a) Schiff's base (b) p-Benzoquinone (c) Phenol (d) Benzoic acid

Description : Aniline undergoes oxidation with Na2Cr2O7/H2SO4 to give (a) Schiff's base (b) p-Benzoquinone (c) Phenol (d) Benzoic acid

Last Answer : p-Benzoquinone

Ethanol on heating with concentrated H2SO4 at 170°C gives (a) ethylene (b) ethyl hydrogen sulfate (c) diethyl ether (d) diethyl sulfate

Description : Ethanol on heating with concentrated H2SO4 at 170°C gives (a) ethylene (b) ethyl hydrogen sulfate (c) diethyl ether (d) diethyl sulfate

Last Answer : ethylene

Hydration of 2-methyl-1-propene (with H2O/H2SO4) gives : (a) CH3CH2CH2OH (b) (CH3)3COH (c) CH3CH2CH2CH2OH (d) (CH3)2CHOH

Description : Hydration of 2-methyl-1-propene (with H2O/H2SO4) gives : (a) CH3CH2CH2OH (b) (CH3)3COH (c) CH3CH2CH2CH2OH (d) (CH3)2CHOH

Last Answer : (CH3)3COH

When ethylene glycol is heated with concentrated HNO3, it forms (a) Oxalic acid (b) Ethylene oxide (c) Dioxane (d) Diethylene glycol

Description : When ethylene glycol is heated with concentrated HNO3, it forms (a) Oxalic acid (b) Ethylene oxide (c) Dioxane (d) Diethylene glycol

Last Answer : Oxalic acid

Edman’s reagent contains (A) Phenylisothiocyanate (B) 1-Fluoro-2, 4-dinitrobenzene (C) Dansyl Chloride (D) tBOC azide

Description : Edman’s reagent contains (A) Phenylisothiocyanate (B) 1-Fluoro-2, 4-dinitrobenzene (C) Dansyl Chloride (D) tBOC azide

Last Answer : Answer : A

Sanger’s reagent contains (A) Phenylisothiocyanate (B) Dansyl chloride (C) 1-Fluoro-2, 4-dinitrobenzene (D) Ninhydrin

Description : Sanger’s reagent contains (A) Phenylisothiocyanate (B) Dansyl chloride (C) 1-Fluoro-2, 4-dinitrobenzene (D) Ninhydrin

Last Answer : Answer : C

Compared to benzene, nitration of toluene takes place at (a) Same rate (b) Faster rate (c) Slower rate(d) Can not predict

Description : Compared to benzene, nitration of toluene takes place at (a) Same rate (b) Faster rate (c) Slower rate (d) Can not predict

Last Answer : Faster rate

Which of the following will give a precipitate with excess bromine water? (a) Bromobenzene (b) Aniline (c) Nitrobenzene (d) Toluene

Description : Which of the following will give a precipitate with excess bromine water? (a) Bromobenzene (b) Aniline (c) Nitrobenzene (d) Toluene

Last Answer : Aniline

Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Description : Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Last Answer : the reduction of nitrobenzene with Sn/HCl

Nitrobenzene undergoes reduction with zinc and KOH to give (a) Aniline (b) Hydrazobenzene (c) Azobenzene (d) None of these

Description : Nitrobenzene undergoes reduction with zinc and KOH to give (a) Aniline (b) Hydrazobenzene (c) Azobenzene (d) None of these

Last Answer : Hydrazobenzene

Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Description : Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Last Answer : Nitrobenzene

Which of the following compounds is most readily sulfonated? (a) Benzene (b) Chlorobenzene (c) Toluene (d) Nitrobenzene

Description : Which of the following compounds is most readily sulfonated? (a) Benzene (b) Chlorobenzene (c) Toluene (d) Nitrobenzene

Last Answer : Toluene

Benzaldehyde reacts with a mixture of concentrated sulfuric acid and nitric acid to give (a) p-Nitrobenzaldehyde (b) o-Nitrobenzaldehyde (c) p-Nitrobenzoic acid (d) m-Nitrobenzaldehyde

Description : Benzaldehyde reacts with a mixture of concentrated sulfuric acid and nitric acid to give (a) p-Nitrobenzaldehyde (b) o-Nitrobenzaldehyde (c) p-Nitrobenzoic acid (d) m-Nitrobenzaldehyde

Last Answer : m-Nitrobenzaldehyde

Cresols on distillation with zinc dust gives (a) o-Xylene(b) Benzene(c) o- plus p-Xylene(d) Toluene

Description : Cresols on distillation with zinc dust gives (a) o-Xylene (b) Benzene (c) o- plus p-Xylene (d) Toluene

Last Answer : Toluene

Pick out the correct statement about catalytic polymerisation. (A) H2SO4 polymerisation process gives gasoline rich in unsaturates (B) In H2SO4 polymerisation, H3PO4 is always used with 2% steam to prevent meta & ortho H3PO4 formation, which are inactive (C) Both (A) and (B) (D) Neither (A) nor (B

Description : Pick out the correct statement about catalytic polymerisation. (A) H2SO4 polymerisation process gives gasoline rich in unsaturates (B) In H2SO4 polymerisation, H3PO4 is always used with 2% steam to prevent meta & ortho H3PO4 formation, which are inactive (C) Both (A) and (B) (D) Neither (A) nor (B

Last Answer : (B) In H2SO4 polymerisation, H3PO4 is always used with 2% steam to prevent meta & ortho H3PO4 formation, which are inactive

In the manufacture of H2SO4 , vanadium catalyst as compared to platinum catalyst (A) Gives higher conversion efficiency (B) Has a longer life and is not poisoned by arsenic (C) Handles lower SO2 content gas (7 -10% SO2 ), thus increasing the capital cost of the plant (D) All (A), (B) and (C)

Description : In the manufacture of H2SO4 , vanadium catalyst as compared to platinum catalyst (A) Gives higher conversion efficiency (B) Has a longer life and is not poisoned by arsenic (C) Handles lower SO2 content gas (7 -10% SO2 ), thus increasing the capital cost of the plant (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Which of the following is a base (APEX)HI (hydroiodic acid)Ca(OH)2 (calcium hydroxide)H2CO3 (carbonic acid)HNO3 (nitric acid)?

Description : Which of the following is a base (APEX)HI (hydroiodic acid)Ca(OH)2 (calcium hydroxide)H2CO3 (carbonic acid)HNO3 (nitric acid)?

Last Answer : Ca(OH)2 (calcium hydroxide) (Apex)

Galactose on oxidation with conc. HNO3 produces (A) Gluconic acid (B) Saccharic acid (C) Saccharo Lactone (D) Mucic acid

Description : Galactose on oxidation with conc. HNO3 produces (A) Gluconic acid (B) Saccharic acid (C) Saccharo Lactone (D) Mucic acid

Last Answer : D

Oxidation of galactose with conc HNO3 yields (A) Mucic acid (B) Glucuronic acid (C) Saccharic acid (D) Gluconic acid

Description : Oxidation of galactose with conc HNO3 yields (A) Mucic acid (B) Glucuronic acid (C) Saccharic acid (D) Gluconic acid

Last Answer : A