Description : What is the number of degree of freedom for a system of two miscible non-reacting species in vapor-liquid equilibrium forming an azeotrope? (A) 0 (B) 2 (C) 1 (D) 3
Last Answer : (C) 1
Description : If the solubilities of different components (in a liquid-liquid extraction system) increase with rise in temperature, then the temperature above which they dissolve completely is known as the critical solution ... On heating, a vapor phase will appear; while on cooling, a solid phase will appear
Last Answer : (D) On heating, a vapor phase will appear; while on cooling, a solid phase will appear
Description : Number of degrees of freedom for a three phase system in equilibrium comprising of three non-reacting chemical species is (A) 2 (B) 0 (C) 1 (D) 3
Last Answer : (A) 2
Description : The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are: (A) 1 (B) 2 (C) 3 (D) 0
Last Answer : (B) 2
Description : What is the number of degrees of freedom for liquid water in equilibrium with a mixture of nitrogen and water vapor? (A) 2 (B) 0 (C) 3 (D) 1
Description : The number of degree of freedom for an Azeotropic mixture of ethanol and water in vapour-liquid equilibrium, is (A) 3 (B) 1 (C) 2 (D) 0
Last Answer : B) 1
Description : What is the degree of freedom for a system comprising liquid water equilibrium with its vapour? (A) 0 (B) 1 (C) 2 (D) 3
Description : A vessel with a volume of cubic meter contains liquid water and water vapor ion equilibrium at 600 kPa. The liquid water has mass of1kg. Using the steam table, calculate the mass of the water vapor. A. 0.99kg B. 1.57 kg C ... / kg vg = 0.3157 m^3 / kg Vtot = mƒ vƒ + mg vg mg = (tot-mƒ vƒ) / vg
Last Answer : 3.16 kg
Description : If a two phase system is in physical equilibrium; then it means that, the (A) Escaping tendency of each component from the liquid phase to the vapor phase is exactly equal to that from vapor phase to liquid phase ... liquid phase is equal to that throughout the vapor phase (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : The equilibrium liquid composition compared to the vapor composition in case of Azeotropic mixture is (A) More (B) Less (C) Same (D) Either more or less; depends on the system
Last Answer : (C) Same
Description : Bound moisture is that liquid which exerts an equilibrium vapor pressure __________ that of the pure liquid at the given temperature. (A) Less than (B) More than (C) Equal to (D) Either (A) or (B); depends on the solid
Last Answer : (A) Less than
Description : Clausius-Clapeyron equation is applicable to __________ equilibrium processes. (A) Solid-vapor (B) Solid-liquid (C) Liquid-vapor (D) All (A), (B) and (C)
Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi
Last Answer : (C) Temperature, pressure and liquid composition xi only
Description : A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. mxylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture? (A) The mixture exhibits ... : o-xylene 30, p-xylene 60 and m-xyoene 10 (D) The mixture contain optical isomers
Last Answer : (A) The mixture exhibits an azeotrope at 101.3 kPa
Description : In an exothermic reaction, the energy of the reacting substances as compared to that of products is (A) More (B) Less (C) Same (D) Either (A) or (B), depends on order of reaction
Last Answer : (A) More
Description : "The rate at which a substance reacts is proportional to its active mass and the rate of a chemical reaction is proportional to the product of active masses of the reacting substances". This is the (A) Lewis- ... (B) Statement of Van't Hoff Equation (C) Le-Chatelier's principle (D) None of these
Last Answer : (D) None of these
Description : __________________ represents the highest pressure and highest temperature at which liquid and vapor can coexist in equilibrium. a) Critical Point b) Boiling Point c) Quality Point d) None of the above
Last Answer : Critical Point
Description : The pressure of the vapor phase of a substance that is in equilibrium with the liquid or solid phase. a. Phase Pressure b. Equilibrium Vapor Pressure c. Specific Pressure d. Equilibrium Phase Pressure
Last Answer : Equilibrium Vapor Pressure
Description : Liquid "X" is at equilibrium with its vapor in a cylinder and piston apparatus. When the volume of the space above the liquid is 50 ml and the temperature 25!, the vapor pressure of "X" is 120 torr. What will the ... 25!C? Some liquid is always present. w) 30 torr x) 60 torr y) 120 torr z) 240 torr
Last Answer : ANSWER: Y -- 120 TORR
Description : The critical temperature is the temperature: w) above which a substance cannot be vaporized x) at which the density is a minimum y) at which solid, liquid, and vapor are in equilibrium z) above which the substance cannot be liquified.
Last Answer : ANSWER: Z -- ABOVE WHICH THE SUBSTANCE CANNOT BE LIQUIFIED.
Description : Pick out the wrong statement. (A) Minimum number of degree of freedom of a system is zero (B) Degree of freedom of a system containing a gaseous mixture of helium, carbon ... ) Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation
Last Answer : (D) Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation
Description : Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by ... occurs when the energy of the reacting molecule is less than the activation energy of the reaction
Last Answer : (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state
Description : Sooty and sulphurous smog formed due to combustion of fossil fuels particularly in winter, continues throughout the day and night. When the moist atmospheric air's water vapor condenses on the solid particles of smoke thereby ... B) Irritation in eyes (C) Respiratory trouble (D) All (A), (B) and (C)
Description : Sides of equilateral-triangular co-ordinates (on which ternary liquid system is plotted) represent (A) A pure component (B) A binary mixture (C) A ternary mixture (D) Partially miscible ternary system
Last Answer : (B) A binary mixture
Description : On moving the feed line (q-line) from saturated liquid feed (vertical position) to saturated vapor feed (horizontal feed), if the slope of both the operating lines are to be increased, then it will result in (A) Greater degree of separation with a fixed number of trays (B) Increased reboiler load
Last Answer : (C) Increased reflux ratio
Description : An exothermic reaction is one in which the reacting substances :
Last Answer : An exothermic reaction is one in which the reacting substances : A. Have same energy as products ... D. Are at higher temperature than the products
Description : A system of reacting substances from which neither the reactants nor the products are taken away or added to is called?
Last Answer : Closed system
Description : A solute distributes itself between two non-miscible solvents in contact with each other in such a way that, at a constant temperature, the ratio of its concentrations in two layers is constant, irrespective of ... B) Followed from Margules equation (C) A corollary of Henry's law (D) None of these
Last Answer : (A) The distribution law
Description : Ribbon blenders are exclusively meant for (A) Blending miscible liquids (B) Non-flowing powder and thin pastes (C) Bath mixing (D) Continuous mixing
Last Answer : (B) Non-flowing powder and thin pastes
Description : The purpose of providing a 'catchall' in the vapor line of an evaporator is to (A) Create vacuum (B) Regulate the vapor flow (C) Vent the non-condensable gases (D) Arrest the entrained liquid
Last Answer : (D) Arrest the entrained liquid
Description : The preferred reacting system for oxidation of o-xylene to phthalic anhydride is (A) Jacketed liquid phase CSTR (B) Jacketed steam heated multitubular reactor (C) Multitubular reactor with cooling (D) Multistage multitubular reactor with interstage cooling
Last Answer : (A) Jacketed liquid phase CSTR
Description : A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume ... 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V
Last Answer : (D) d(VCA )/dt = FCAF - kCA 2V
Description : Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium ... (D) The solubility of a particular gas in ideal solution in any solvent is always the same
Last Answer : (C) The operating pressure in solvent extraction system should be below vapor pressures of all components
Description : A plait point is the point on the solubility curve, where the tie line reduces to a point. What is the number of plait point for a ternary system containing two pairs of partially miscible liquids? (A) 0 (B) 1 (C) 2 (D) 3
Last Answer : (A) 0
Description : In distillation column design, the McCabe-Thiele procedure is inadequate and a Ponchan-Savarit procedure is needed, when (A) Saturated feed is not used (B) An azeotrope forms (C) The latent ... vaporisation of the more and less volatile components are greatly different (D) A total condenser is used
Last Answer : (D) A total condenser is used
Description : Solvent used in extractive distillation (A) Is of low volatility (B) Forms a low boiling azeotrope (C) Forms a high boiling azeotrope (D) Does not alter the relative volatility of the original components
Last Answer : (B) Forms a low boiling azeotrope
Description : Entrainer used in Azeotropic distillation should (A) Form a low boiling azeotrope with one of the constituents of the mixture (B) Form a new azeotrope of low relative volatility with one of the ... (C) Have high latent heat of vaporisation (D) Have high viscosity to provide high tray efficiency
Last Answer : (A) Form a low boiling azeotrope with one of the constituents of the mixture
Description : Which of the following mixtures does not form an azeotrope at atmospheric pressure? (A) Water-alcohol (B) Methyl alcohol-acetone (C) Butyl acetate-water (D) None of these
Description : A minimum boiling azeotrope is exemplified by (A) Toluene-benzene (B) Acetone-carbon disulphide (C) Water-isobutyl alcohol (D) None of these
Last Answer : (B) Acetone-carbon disulphide
Description : Pick out the system with minimum boiling azeotrope at 1 atm. (A) Benzene-toluene (B) Ethyl alcohol-water (C) Hydrochloric acid-water (D) All (A), (B) and (C)
Last Answer : (B) Ethyl alcohol-water
Description : Which of the following binary systems is an example of a maximum boiling azeotrope? (A) Water-hydrochloric acid (B) Acetone-carbon disulphide (C) Water-ethyl alcohol (D) n-heptane-n-octane
Last Answer : (A) Water-hydrochloric acid
Description : Flash distillation is suitable for separating the constituents of a binary system, which (A) Form minimum boiling azeotrope (B) Have very wide boiling points (C) Have very close boiling points (D) Form constant boiling azeotrope
Last Answer : (B) Have very wide boiling points
Description : Flash distillation is suitable for the separation of components (A) Having very close boiling points (B) Which form maximum boiling azeotrope (C) Having very wide boiling points (D) Which form minimum boiling azeotrope
Last Answer : (C) Having very wide boiling points
Description : For a binary mixture with low relative volatility, (A) Use steam distillation (B) Use molecular distillation (C) Use high pressure distillation (D) An azeotrope may be formed during distillation
Last Answer : (D) An azeotrope may be formed during distillation
Description : Which of the following would be construed as a reasonable restriction of the right to freedom'? (1) When the state disallows a candidate from securing votes in the name of religion (2) When ... of Nagaland disallows temporary residents to buy immovable property in Nagaland. (4) All of the above
Last Answer : (4) All of the above
Description : Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial ... at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1
Last Answer : (C) Azeotropes obey Raoult's law at all temperature
Description : Pick out the correct statement. (A) Higher hold up of the solid in the rotary dryer results in better exposure of the solids to the gas (B) The 'Hatta number' is ... reflux in case of distillation operation requires infinite number of plates for a binary system separation
Last Answer : (C) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion
Description : What is the temperature when water and vapor are in equilibrium with the atmospheric pressure? a. Ice point b. Steam point c. Critical point d. Freezing point
Last Answer : Steam point
Description : At steam point, the temperature of water and its vapor at standard pressure are: a. Extremes or maximum b. unity c. in equilibrium d. undefined
Last Answer : in equilibrium