Description : For a reaction `CH_(3)OCH_(3) (g) rarr CH_(4) (g)+H_(2) (g)+CO(g)` at 750K, the rate constant is `3.52xx10^(-3)" min"^(-1)`. Starting with a pressure
Last Answer : For a reaction `CH_(3)OCH_(3) (g) rarr CH_(4) (g)+H_(2) (g)+CO(g)` at 750K, the rate constant ... to become 760 mm Hg ? (Take log 2.25 = 0.352)
Description : A compound 'X' of the formula `C_(3)H_(8)O` gives iodoform test. On oxidation with acidified `K_(2)Cr_(2)O_(7)X` gave Y. Y also gives iodogorm test. T
Last Answer : A compound 'X' of the formula `C_(3)H_(8)O` gives iodoform test. On oxidation with acidified `K_(2)Cr_(2) ... ` D. `CH_(3)COCH_(3), CH_(3)CHOHCH_(3)`
Description : Arragne basicity of the following compounds in decreasing order: `CH_(3)CH_(2)NH_(2)(I)," "H_(2)C=CH-NH_(2)(II),` `HC-=C-NH_(2)(III)," "C_(6)H_(5)NH_(
Last Answer : Arragne basicity of the following compounds in decreasing order: `CH_(3)CH_(2)NH_(2)(I), ... `IVgtIIIgtIIgtI` C. `IIIgtIIgtIgtIV` D. `IgtIIIgtIIgtIV`
Description : 0.01 mole of iodoform `(CHI_(3))` reacts with Ag to produce a gas whose volume at NTP is `2CHI_(3)+6Ag to6Agl(s)+C_(2)H_(2)(g)`
Last Answer : 0.01 mole of iodoform `(CHI_(3))` reacts with Ag to produce a gas whose volume at NTP is `2CHI_(3)+6Ag ... mL B. 112 mL C. 336 mL D. None of these
Description : Which of the following compounds is produced when this reaction rakes place ? `CH_(3)-underset(CH_(3))underset(|)CH-OCH_(3)overset(HI)underset(cold)ra
Last Answer : Which of the following compounds is produced when this reaction rakes place ? `CH_(3)-underset(CH_(3)) ... OH` C. Both of these D. None of these
Description : Consider the given compounds : (a) `CH_(3)-CH_(2)-NH_(2)` (b) `CH_(3)-CH=NH` (c ) `CH_(3)-C=N` (d) `C_(2)H_(5)-NH-C_(2)H_(5)` Arrange basicity of thes
Last Answer : Consider the given compounds : (a) `CH_(3)-CH_(2)-NH_(2)` (b) `CH_(3)-CH=NH` (c ) `CH_(3)-C=N` (d) `C_(2 ... `a gt d gt b gt c` D. `d gt a gt c gt b`
Description : Write down the IUPAC names of the following compounds :- (A) `CH_(3)-underset(C_(2)H_(5))underset(|)(CH)-overset(CH_(3))overset(|)(CH)-underset(OH)und
Last Answer : Write down the IUPAC names of the following compounds :- (A) `CH_(3)-underset(C_(2)H_(5))underset(|)( ... )=CH-underset(CH_(3))underset(|)(CH)-C-=CH`
Description : Among the complex ions, `[Co(NH_(2) - CH_(2) - CH_(2) - NH_(2))_(2) Cl_(2)]^(+), [CrCl_(2) (C_(2)O_(4))_(2)]^(3-)` `[Fe(H_(2)O)_(4) (OH)_(2)]^(+), [Fe
Last Answer : Among the complex ions, `[Co(NH_(2) - CH_(2) - CH_(2) - NH_(2))_(2) Cl_(2)]^(+), [CrCl_(2) ... (3)) Cl]^(2+)` and that show(s) cis-trans isomerism is
Description : `HBr` reacts with `CH_(2)=CH-OCH_(3)` under anhydrous conditions at room temperature to give:
Last Answer : `HBr` reacts with `CH_(2)=CH-OCH_(3)` under anhydrous conditions at room temperature to give: A. `H_(3)C-CHBr- ... (3)OH` D. `BrCH_(2)-CH_(2)-OCH_(3)`
Description : What is the product when `C_(6)H_(5)CH_(2)NH_(2)` reacts with `HNO_(3)`?
Last Answer : What is the product when `C_(6)H_(5)CH_(2)NH_(2)` reacts with `HNO_(3)`?
Description : In the given reaction which one of the following statement is correct - `C_(6)H_(5)-underset(CH_(3))underset(|)(C)=O+NH_(2)-OH to "Oxime" overset(PCl_
Last Answer : In the given reaction which one of the following statement is correct - `C_(6)H_(5)- ... elimination reaction. D. oxime and amides are isomers.
Description : Arrange the carbanions, `(CH_(3))_(3)bar(C),bar(C)Cl_(3),(CH_(3))_(2)bar(C)H,C_(6)H_(5)bar(C)H_(2)`, in order of their decreasing stability
Last Answer : Arrange the carbanions, `(CH_(3))_(3)bar(C),bar(C)Cl_(3),(CH_(3))_(2)bar(C)H,C_(6)H_(5)bar(C)H_(2 ... (2)bar(C)HgtC_(6)H_(5)bar(C)H_(2)gtbar(C)Cl_(3)`
Description : The `S_(N^(1))` reactivity of the following halides will be in the order: (i) `(CH_(3))_(3)C-Br` (ii) `(C_(6)H_(5))CHBr` (iii) `(C_(6)H_(5))_(2)C(CH_(
Last Answer : The `S_(N^(1))` reactivity of the following halides will be in the order: (i) `(CH_(3))_(3)C-Br` (ii) `(C_ ... D. (iii) gt (ii) gt (i) gt (iv) gt (v)
Description : Consider the following carbocations : (I) `C_(6)H_(5)overset(+)(C )H_(2)` (II) `C_(6)H_(5)CH_(2)overset(+)(C )H_(2)` (III) `C_(6)H_(5)overset(+)(C )HC
Last Answer : Consider the following carbocations : (I) `C_(6)H_(5)overset(+)(C )H_(2)` (II) `C_(6)H_(5)CH_(2)overset(+ ... lt I lt II lt IV D. IV lt III lt I lt II
Description : Which is decreasing order of acidity in, `HCOOH(I), CH_(3)COOH(II), CH_(3)CH_(2)COOH(III) and C_(6)H_(5)COOH(IV)`?
Last Answer : Which is decreasing order of acidity in, `HCOOH(I), CH_(3)COOH(II), CH_(3)CH_(2)COOH( ... B. `IVgtIIIgtIIgtI` C. `IVgtIgtIIgtIII` D. `IgtIVgtIIgtIII`
Description : `C_(6)H_(5)-CH_(2)-I overset(NaN_(3))underset(Delta)rarr` Products Reaction is assumed to involve nitrene as intermediate, then various possible produ
Last Answer : `C_(6)H_(5)-CH_(2)-I overset(NaN_(3))underset(Delta)rarr` Products Reaction is assumed to involve nitrene as ... (2)` C. `C_(6)H_(5)CN=NH` D.
Description : In the given reaction sequence `C_(6)H_(5)-CH_(2)-NH_(2) overset(CHCl_(3)//Alc.KOH)underset(Delta)rarr [X] overset(H_(2)O //NaOH)rarr [Y],[Y]` will be
Last Answer : In the given reaction sequence `C_(6)H_(5)-CH_(2)-NH_(2) overset(CHCl_(3)//Alc.KOH)underset(Delta)rarr [X] ... -NH_(2)` D. `C_(6)H_(5)-CH_(2)OH`
Description : `C_(6)H_(5)Ohoverset(CH_(3)COCl)underset(NaOH(aq))(rarr)C_(6)H_(5)OCOCH_(3)` the above reaction is an example of
Last Answer : `C_(6)H_(5)Ohoverset(CH_(3)COCl)underset(NaOH(aq))(rarr)C_(6)H_(5)OCOCH_(3)` ... reaction B. Schotten-Baumann reaction C. Acetylation D. Benzoylation
Description : `C_(6)H_(5)-O-CH_(2)CH_(3)overset(HI)rarr` which of the following is not formed in this reaction ?
Last Answer : `C_(6)H_(5)-O-CH_(2)CH_(3)overset(HI)rarr` which of the following is not formed in this reaction ? A. ... )H_(5)-OH` C. Both of these D. None of these
Description : `C_(6)H_(5)-O-CH_(3)+HI_((excess))rarr`
Last Answer : `C_(6)H_(5)-O-CH_(3)+HI_((excess))rarr` A. `CH_(3)OH and C_(6)H_(5)I` B. `CH_(3)I and C_(6)H_(5)OH` ... )I and C_(6)H_(5)I` D. `C_(6)H_(6) and CH_(4)`
Description : The reaction of compounf P with `CH_(3)MgBr` (excess) in `(C_(2)H_(5)_(2)O` followed by addition of `H_(2)O` give Q the compound Q on treatment with `
Last Answer : The reaction of compounf P with `CH_(3)MgBr` (excess) in `(C_(2)H_(5)_(2) ... and Friedel-Crafts acylation D. Dehydration and Friedel-Crafts acylation
Last Answer : The reaction of compounf P with `CH_(3)MgBr` (excess) in `(C_(2)H_(5)_(2)O` followed by addition of `H_ ... product S is The product S is A. B. C. D.
Description : Which of the following structures correspond to the product expected, when excess of `C_(6)H_(6)` reacts with `CH_(2)Cl_(2)` in presence of anhydrous
Last Answer : Which of the following structures correspond to the product expected, when excess of `C_(6)H_(6)` reacts with ` ... anhydrous `AlCl_(3)`? A. B. C. D.
Description : Predict the product from claisen condensation of the following pair of esters. `Ph-CH_(2)-underset(O)underset(||)(C)-OCH_(3)+Ph-underset(O)underset(||
Last Answer : Predict the product from claisen condensation of the following pair of esters. `Ph-CH_(2)-underset(O)underset( ... )(C)-OCH_(3)overset(EtO^(Theta))to`
Description : `CH_(3)-underset(CH_(3))underset(|)CH-OCH_(3)overset(HI)underset(excess Delta)rarr` Which of the following is not formed in the above reaction ?
Last Answer : `CH_(3)-underset(CH_(3))underset(|)CH-OCH_(3)overset(HI)underset(excess Delta)rarr` Which of ... Isopropyl iodine C. Isopropyl alcohol D. All of these
Description : Given that standard heat enthalpy of `CH_(4), C_(2)H_(4)` and `C_(3)H_(8)` are -17.9, 12.5, -24.8 Kcal/mol. The `Delta H` for `CH_(4)+C_(2)Hrarr C_(3)
Last Answer : Given that standard heat enthalpy of `CH_(4), C_(2)H_(4)` and `C_(3)H_(8)` are -17.9, 12.5, -24.8 Kcal ... . `-30.2` Kcal C. 55.2 Kcal D. `-19.4` Kcal
Description : An organic compound A,`C_(5)H_(8)O` reacts with `H_(2)O, NH_(3)` and `CH_(3)COOH` as described below A is
Last Answer : An organic compound A,`C_(5)H_(8)O` reacts with `H_(2)O, NH_(3)` and `CH_(3)COOH` as described ... 2))underset(||)(C)-underset(H)underset(|)(C)=O`
Description : Condiser the reactions, (i) `(CH_(3))_(2)CH-CH_(2)Broverset(C_(2)H_(5)OH)rarr(CH_(3))_(2)CH-CH_(2)OC_(2)H_(5)+HBr` (ii) `(CH_(3))_(2)CH-CH_(2)Broverse
Last Answer : Condiser the reactions, (i) `(CH_(3))_(2)CH-CH_(2)Broverset(C_(2)H_(5)OH)rarr(CH_(3))_(2)CH-CH_(2)OC_(2)H_(5) ... N^(1))` D. `S_(N^(2)) and S_(N^(2))`
Description : The end product (B) of the reaction sequence: `C_(2)H_(5)-underset(H)underset(|)(N)-CH_(3) overset(Ph-overset(O)overset(||)(C)-Cl)underset(NaOH)rarrA
Last Answer : The end product (B) of the reaction sequence: `C_(2)H_(5)-underset(H)underset(|)(N)-CH_(3) overset(Ph-overset ... )underset(H_(2)O)rarr B` A. B. C. D.
Description : Assertion: (A) Ethers are relatively inert when compared to `C_(2)H_(5)OH` Reason (R): The hybridization of C and O in `CH_(3)-O-CH_(3) is SP^(3)`
Last Answer : Assertion: (A) Ethers are relatively inert when compared to `C_(2)H_(5)OH` Reason (R): The hybridization of ... R is false D. A is false but R is true
Description : Which alkyl halide would be preferred for the synthesis of the following ether by Williamson synthesis ? `H_(5)C_(2)-O-overset(CH_(3))overset(|)unders
Last Answer : Which alkyl halide would be preferred for the synthesis of the following ether by Williamson ... chloride C. Ethyl chloride D. Methyl chloride
Description : The IUPAC name of `C_(2)H_(5)-O-CH(CH_(3))_(2)`
Last Answer : The IUPAC name of `C_(2)H_(5)-O-CH(CH_(3))_(2)` A. Ethoxy propane B. 1,1-dimenthyl ether C. 2- Ethoxy isopropane D. 2-Ethoxy propane
Description : `C_(2)H_(5)OH overset(KMnO_(4)//H^(oplus))rarrX underset(H_(2)SO_(4))overset(Y)rarr CH_(3)COOC_(2)H_(5)`, X and Y respectively are
Last Answer : `C_(2)H_(5)OH overset(KMnO_(4)//H^(oplus))rarrX underset(H_(2)SO_(4))overset(Y)rarr CH_(3)COOC_(2)H_(5)` ... CH_(3)COOH` D. `CH_(3)COOH, C_(2)H_(5)OH`
Description : Which of the following compounds will give a positive iodoform test? (a) Benzaldehyde (b) 2-Pentanone (c) 3-Hexanone (d) 3-Pentanone
Last Answer : 2-Pentanone
Description : Which of the following compounds does not give iodoform test on treatment with I2/NaOH? (a) Ethanol (b) Propanone (c) 2-Propanol (d) Butanone
Last Answer : Butanone
Description : Which of the following compounds does not give a positive iodoform test : (a) Ethanol (b) Ethanal (c) Methanol (d) Propanone
Last Answer : Methanol
Description : Which of the following compounds will give an iodoform test? (a) Benzoic acid (b) Ethanol (c) Benzyl chloride (d) Methanol
Last Answer : Ethanol
Description : The heat of combustion of `CH_(4(g)), C_((g))` and `H_(2(g))` at `25^(@)C` are `-212.4` K cal, -94.0 K cal and -68.4 K cal respectively, the heat of f
Last Answer : The heat of combustion of `CH_(4(g)), C_((g))` and `H_(2(g))` at `25^(@)C` are `-212.4` K cal, -94.0 ... .4` K cal C. `-375.2` K cal D. `+212.8` K cal
Description : Three isometic compounds M,N and P `(C_(5)H_(10)O)` give the following tests (i) M and P react with sodium bisulfite to form an adduct J (ii) N Comsum
Last Answer : Three isometic compounds M,N and P `(C_(5)H_(10)O)` give the following tests (i) M and P react with ... M,N and P, respectively are A. B. C. D.
Description : Compounds P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Q and S is `C_(8)H_(8)O`. Q undergoes cannizzaro reactions b
Last Answer : Compounds P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Q and S is `C_(8) ... R , respectively is (are) A. B. C. D.
Description : How many isomeric compounds are possible for `C_(4)H_(10)O` ?
Last Answer : How many isomeric compounds are possible for `C_(4)H_(10)O` ? A. 4 B. 5 C. 6 D. 7
Description : Which is the increasing order of acidic strength in the following compounds ? `CH_(3)CH_(2)CH_(2)COOH(I), "NCCH"_(2)COOH(II), H_(2)C=CHCH_(2)COOH(III)
Last Answer : Which is the increasing order of acidic strength in the following compounds ? `CH_(3)CH_(2)CH_(2) ... B. `IltIIIltII` C. `IIIltIIltI` D. `IIltIltIII`
Description : Which of the following compounds is prduced when this reaction takes place ? `H_(3)C-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-O-CH_(3)ove
Last Answer : Which of the following compounds is prduced when this reaction takes place ? `H_(3)C-overset(CH_(3))overset ... -OH` C. Both of these D. None of these
Description : What is the structure of `(C_(4)H_(10)O)` which can give positive haloform test and evolves hydrogen gas with `LiAlH_(4)`
Last Answer : What is the structure of `(C_(4)H_(10)O)` which can give positive haloform test and evolves hydrogen gas ... (|)overset(CH_(3))overset(|)(C) - OH`
Description : An alkene (A) `C_(16)H_(16)` on ozonolysis gives only one product (B) `C_8H_8O`. Compound (B) on reaction with NaOH/`I_(2)` yeilds sodium benzoate. Co
Last Answer : An alkene (A) `C_(16)H_(16)` on ozonolysis gives only one product (B) `C_8H_8O`. Compound (B) ... `(H_(2)//Pd-C)` gives a racemic mixture
Description : The oxidation number and co-ordination number of chromium in complex ion `[Cr(C_(2)O_(4))_(2)(H_(2)O)_(2)]^(-)` are
Last Answer : The oxidation number and co-ordination number of chromium in complex ion `[Cr(C_(2)O_(4))_(2)(H_(2)O)_(2)]^(-)` are A. 3,6 B. 2,6 C. 2,8 D. 3,8
Description : The major product H in the given reaction sequence is `CH_(3)-CH_(2)-CO-CH_(3) overset(._(Theta)CN)toG overset(95% H_(2)SO_(4)) underset("Heat")toH`
Last Answer : The major product H in the given reaction sequence is `CH_(3)-CH_(2)-CO-CH_(3) overset(._(Theta)CN) ... CH=underset(CH_(3))underset(|)(C)-CO-NH_(2)`