Which of the following complexes can exists as enantiomers ? Draw their structures `(a) cis-[Co(NH_(3))_(4)Br_(2)]^(+) " " (b) cis-[Cr(H_(2)O)_(2)(en)

1 Answer

Answer :

Which of the following complexes can exists as enantiomers ? Draw their structures `(a) cis-[Co(NH_(3))_(4)Br_(2)]^ ... [Co(NH_(3))_(2)(en)_(2)]^(2+)`

Related questions

Description : Find the sum of number of geometrical isomers for following complexes. `(a) [CoCl_(2)Br_(2)]^(2-) " " (b) [Rh(en)_(3)]^(3+) " " ( c) [Cr(en)_(2)Br_(2)

Last Answer : Find the sum of number of geometrical isomers for following complexes. `(a) [CoCl_(2)Br_(2)]^(2-) " " (b) [Rh(en ... e) [Co(NH_(3))_(3)(NO_(2))_(3)]`

Description : Among the following complexes : `K_(3)[Fe(CN)_(6)],[Co(NH_(3))_(6)]Cl_(3)` , `Na_(3)[Co ( o x )_(3)],[Ni(H_(2)O)_(6)]Cl_(2)`, `K_(2)[Pt(CN)_(4)]` and

Last Answer : Among the following complexes : `K_(3)[Fe(CN)_(6)],[Co(NH_(3))_(6)]Cl_(3)` , `Na_(3)[Co ( o x )_(3)],[Ni(H_( ... ,M,N B. K,N,O,P C. L,M,O,P D. L,M,N,O

Description : Total number of paramagnetic complexes which are inner orbital complexes : `(i) [Cr(NH_(3))_(6)]Cl_(3) " " (ii)[Co(NH_(3))_(6)](NO_(3))_(2)" " (iii)[N

Last Answer : Total number of paramagnetic complexes which are inner orbital complexes : `(i) [Cr(NH_(3))_(6)]Cl_(3) " " (ii)[ ... (4)]" " Na_(4)[Fe(CN)_(5)(NOS)]`

Description : Calculate the EAN of central atom in the following complexes `(a) [Cr(CO)_(6)]" "(b) [Fe(CN)_(6)]^(4-)" " (c ) [Fe(CO)_(5)] " " (d) [Co(NH_(3))_(6)]^(

Last Answer : Calculate the EAN of central atom in the following complexes `(a) [Cr(CO)_(6)]" "(b) [Fe(CN)_(6)]^(4-)" " (c ... ))_(6)]^(4+)" " (h) [PtCl_(6)]^(2-)`

Description : The complex `[Cr(H_(2)O)_(4)Br_(2)]Cl` gives the test for :

Last Answer : The complex `[Cr(H_(2)O)_(4)Br_(2)]Cl` gives the test for : A. `Br^(-)` B. `Cl^(-)` C. `Cr^(3+)` D. `Br^(-) and Cl^(-)` both

Description : How many geomatrical isomers are possible for each of the following complexes ? `(a) [Pt(NH_(3))_(2)(SCN)_(2)] " " (b) [CoCl_(2)Br_(2)]^(2-)("tetrahed

Last Answer : How many geomatrical isomers are possible for each of the following complexes ? `(a) [Pt(NH_(3))_(2)(SCN)_(2)] " " ... (+) " " (f) [Rh(en)_(3)]^(3+)`

Description : The oxidation state of Cr in `[Cr(H_(2)O)_(6)]Cl_(3), [Cr(C_(6)H_(6))_(2)], and K_(2)[Cr(CN)_(2)(O)_(2)(O_(2))(NH_(3))]` respectively are :

Last Answer : The oxidation state of Cr in `[Cr(H_(2)O)_(6)]Cl_(3), [Cr(C_(6)H_(6))_(2)], and K_(2)[Cr(CN)_(2)(O)_(2 ... and +4` C. `+3,+4 and +6` D. `+3,+2 and +4`

Description : A `C_(6)H_(12)O` compound does not react with `Br_(2)` in `C Cl_(4)`, produces a flammable gas on treatment with `LiAlH_(4)`, and reacts with `H_(2)Cr

Last Answer : A `C_(6)H_(12)O` compound does not react with `Br_(2)` in `C Cl_(4)`, ... B. methoxycyclopentane C. 2-cyclopropyl-2-propanol D. 2-cyclobutylethanol

Description : `Ph-overset(O)overset(||)(C)-NH_(2)+Ph-CH_(2)-overset(O)overset(||)(C)-overset(15)(N)H_(2) overset(overset(Theta)(OH)+Br_(2))rarr A+B` Products A and

Last Answer : `Ph-overset(O)overset(||)(C)-NH_(2)+Ph-CH_(2)-overset(O)overset(||)(C)-overset(15)(N)H_(2) overset(overset ... (2)-NH_(2)` D. `Ph-overset(15)(N)H_(2)`

Description : The oxidation number and co-ordination number of chromium in complex ion `[Cr(C_(2)O_(4))_(2)(H_(2)O)_(2)]^(-)` are

Last Answer : The oxidation number and co-ordination number of chromium in complex ion `[Cr(C_(2)O_(4))_(2)(H_(2)O)_(2)]^(-)` are A. 3,6 B. 2,6 C. 2,8 D. 3,8

Description : The type of isomerism that `Co(NH_(3))_(4)Br_(2)Cl_(2)` can exhibit is/are

Last Answer : The type of isomerism that `Co(NH_(3))_(4)Br_(2)Cl_(2)` can exhibit is/are A. ... C. Optical and ionisation D. Optical, ionisation and geometric

Description : Consider the following reaction and statements: `[Co(NH_(3))_(4)Br_(2)]^(+)+Br^(-) to [Co(NH_(3))_(3)Br_(3)]+NH_(3)` Two isomers are produced if the r

Last Answer : Consider the following reaction and statements: `[Co(NH_(3))_(4)Br_(2)]^(+)+Br^(-) to [Co(NH_(3))_(3) ... II B. III and IV C. I and IV D. II and III

Description : Which kind of isomerism is shown by `Co (NH_(3))_(4) Br_(2) Cl` ?

Last Answer : Which kind of isomerism is shown by `Co (NH_(3))_(4) Br_(2) Cl` ? A. ... Optical and ionization C. Gometrical and optical D. Geometrical only

Description : Which kind of isomerism is exhibited by octahedral `[Co(NH_(3))_(4)Br_(2)]Cl` ?

Last Answer : Which kind of isomerism is exhibited by octahedral `[Co(NH_(3))_(4)Br_(2)]Cl` ? A. ... and optical C. Optical and ionization D. Geometrical only

Description : What type of isomers are the following : `(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]` `(ii) [Co(en)_(3)[Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)]` `(iii)

Last Answer : What type of isomers are the following : `(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]` `(ii) [Co(en)_(3)[Cr( ... ]Cl and [Co(H_(2)O)Cl_(3)(py)_(2)]H_(2)O`

Description : Oxidation state of cobalt in `[Co(NH_(3))_(4)(H_(2)O)Cl]SO_(4)` is

Last Answer : Oxidation state of cobalt in `[Co(NH_(3))_(4)(H_(2)O)Cl]SO_(4)` is

Description : Among the complex ions, `[Co(NH_(2) - CH_(2) - CH_(2) - NH_(2))_(2) Cl_(2)]^(+), [CrCl_(2) (C_(2)O_(4))_(2)]^(3-)` `[Fe(H_(2)O)_(4) (OH)_(2)]^(+), [Fe

Last Answer : Among the complex ions, `[Co(NH_(2) - CH_(2) - CH_(2) - NH_(2))_(2) Cl_(2)]^(+), [CrCl_(2) ... (3)) Cl]^(2+)` and that show(s) cis-trans isomerism is

Description : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) (NH_(3))_(2)] Cl_(3)` is

Last Answer : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) ( ... (III) chloride D. Diamminetetraaquacobalt (III) chloride

Description : Three arrangements are shown for the complex `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)` pick up the wrong statement.

Last Answer : Three arrangements are shown for the complex `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)` pick up ... are optical isomers D. II and III are geometrical isomers.

Description : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and 2.84 BM respectively. The second complex i

Last Answer : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2 ... . D. It produces three-fold freezing point depression.

Description : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and 2.84 BM respectively. The second complex i

Last Answer : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and ... (H_(2)O)_(2)](NO_(3))_(2)`, octahedral

Description : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and 2.84 BM respectively. The second complex i

Last Answer : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero ... two B. zero, zero C. two, zero D. two ,two

Description : Which isomerism is exhibited by `[Co(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(6)][Co(CN)_(6)]`?

Last Answer : Which isomerism is exhibited by `[Co(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(6) ... )]`? A. Ionization B. Linkage C. Coordination D. Polymerization.

Description : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is :

Last Answer : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is : A. ... (II) tris(oxalato)chromium(III) D. Hexaamminecobalt(III)trioxalatechromium(III)

Description : Arrange the following compounds in order of increasing molar conductivity . `(i) K[Co(NH_(3))_(2)(NO_(2))_(4)]" " (ii) [Cr(NH_(3))_(3)(NO_(2))_(3)]` `

Last Answer : Arrange the following compounds in order of increasing molar conductivity . `(i) K[Co(NH_(3))_(2)(NO_(2))_(4)]" ... )" " (iv) [Cr(NH_(3))_(6)]Cl_(3)`

Description : The IUPAC name of `K_(2)[Cr(CN)_(2)O_(2)(O)_(2)(NH_(3))]` is :

Last Answer : The IUPAC name of `K_(2)[Cr(CN)_(2)O_(2)(O)_(2)( ... Potassium amminedicyanoperoxooxochromate(VI) D. Potassium amminecyanodiperoxodioxochromate(VI)

Description : Consider the follwing complexes ion `P,Q` and `R` `P =[FeF_(6)]^(3-), Q=[V(H_(2)O)_(6)]^(2+)` and `R=[Fe(H_(2)O)_(6)]^(2+)` The correct order of the c

Last Answer : Consider the follwing complexes ion `P,Q` and `R` `P =[FeF_(6)]^(3-), Q=[V(H_(2)O)_(6)]^(2+)` and `R=[Fe( ... lt P` C. `R lt P lt Q` D. `Q lt P lt R`

Description : The IUPAC name of complex `[Cu(en)_(2)(H_(2)O)_(2)]^(22+)`

Last Answer : The IUPAC name of complex `[Cu(en)_(2)(H_(2)O)_(2)]^(22+)` A. ethylene ... C. diaquobisdietyleamineCU(II)ion D. diaquobis(ethylenediamine)cuprate(II)

Description : What is the value of n in the following equation : `Cr(OH)_(4)^(-)+OH^(-) rarr CrO_(4)^(2-)+H_(2)O+n e`?

Last Answer : What is the value of n in the following equation : `Cr(OH)_(4)^(-)+OH^(-) rarr CrO_(4)^(2-)+H_(2)O+n e`? A. 3 B. 6 C. 5 D. 2

Description : The volume (in `mL`) of `0.1M Ag NO_(3)` required for complete precipitation of chloride ions present in `30 mL` of `0.01M` solution of `[Cr(H_(2)O)_(

Last Answer : The volume (in `mL`) of `0.1M Ag NO_(3)` required for complete precipitation of chloride ions present ... Cl]Cl_(2)`, as silver chloride is close to:

Description : The ionisation isomer of `[Cr(H_(2)O)_(4) Cl (NO_(2))]Cl`

Last Answer : The ionisation isomer of `[Cr(H_(2)O)_(4) Cl (NO_(2))]Cl` A. `[Cr(H_(2)O)_(4)(O_(2)N)]Cl_(2)` B. `[Cr( ... D. `[Cr(H_(2)O)_(4)Cl_(2)(NO_(2))].H_(2)O`

Description : What is the charge on the complex `[Cr(C_(2)O_(4))_(2)(H_(2)O)_(2)]` formed by Cr(III) ?

Last Answer : What is the charge on the complex `[Cr(C_(2)O_(4))_(2)(H_(2)O)_(2)]` formed by Cr(III) ? A. `+3` B. `+1` C. `+2` D. `-1`

Description : 1 g of complex `[Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O` was passed through a cation exchanger to produce HCl. The acid liberated was diluted to 1 litre. What

Last Answer : 1 g of complex `[Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O` was passed through a cation ... molarity of acid solution [Molecular weight of complex=266.5]?

Description : Compare the following complexes with respect to their shape, magnetic behaviour and the hybrid orbitals involved : (i) [CoF4]2- (ii) [Cr(H2O)2(C2O4)2]– (iii) [Ni(CO)4] (Atomic number : Co = 27, Cr = 24, Ni = 28) -Chemistry

Last Answer : (i) [COF4]2_ : Tetrafluorido cobalt (III) ion Coordination number = 4 Shape = Tetrahedral Hybridisation = sp3 Important Questions for Class 12 Chemistry Chapter 9 Coordination Compounds Class 12 Important Questions 7

Description : The complexes `[Pt(NH_(3))_(4)][PtCl_(6)] and [Pt(NH_(3))_(4)Cl_(2)][PtCl_(4)]` are :

Last Answer : The complexes `[Pt(NH_(3))_(4)][PtCl_(6)] and [Pt(NH_(3))_(4)Cl_(2)][PtCl_( ... B. optical isomers C. co-ordination isomers D. ionisation isomers

Description : A `[M(H_(2)O)_(6)]^(2+)` complex typically absorbs at around 600 nm. It is allowed to react with ammonia to form a new complex `[M(NH_(3))_(6)]^(2+)`

Last Answer : A `[M(H_(2)O)_(6)]^(2+)` complex typically absorbs at around 600 nm. It is allowed to react with ammonia ... A. 800 nm B. 580 nm C. 620 nm D. 320 nm

Description : The correct statement on the isomerism associated with the following complex ions , `(a) [Ni(H_(2)O)_(5)NH_(3)]^(2+), (b) [Ni(H_(2)O)_(4)(NH_(3))_(2)]

Last Answer : The correct statement on the isomerism associated with the following complex ions , `(a) [Ni(H_( ... a) and (b) show geometrical and optical isomerism

Description : Which of the following isomerism is/are shown by the complex `[CoCl_(2)(H_(2)O)_(2)(NH_(3))_(2)]` Br ?

Last Answer : Which of the following isomerism is/are shown by the complex `[CoCl_(2)(H_(2)O)_(2)(NH_(3)) ... ? A. Ionization B. Linkage C. Geometrical D. optical

Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry

Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.

Description : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2)]` is :

Last Answer : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2 ... (ethane-1,2-diammine) nitritioplatinum(IV) dicyanoargentate (I)

Description : The number of geometrical isomers for octahedral `[CoCl_(4)(NH_(3))_(2)]^(-)`, square planar `[AuBr_(2)Cl_(2)]^(-)` and `[PtCl_(2)(en)]` are

Last Answer : The number of geometrical isomers for octahedral `[CoCl_(4)(NH_(3))_(2)]^(-)`, square planar `[AuBr_(2)Cl_(2)]^(-) ... are A. 4,2 B. 2,2 C. 3,2 D. 2,3

Description : Which of the following facts about the complex `[Cr(NH_(3))_(6)]Cl_(3)` is wrong ?

Last Answer : Which of the following facts about the complex `[Cr(NH_(3))_(6)]Cl_(3)` is wrong ... The complex gives white precipitate with siver nitrate solution.

Description : The oxidation state of `Cr` in `[Cr(NH_(3))_(4)Cl_(2)]^(+)` is:

Last Answer : The oxidation state of `Cr` in `[Cr(NH_(3))_(4)Cl_(2)]^(+)` is:

Description : Matching the information given in the three columns of the following table. [Note: Atomic Number of Cr=24,V=23,Pt=78)] About `(CrCl_(3)(NH_(3))_(3))`

Last Answer : Matching the information given in the three columns of the following table. [Note: Atomic Number of Cr=24,V=23,Pt=78)] ... (IV),(i), R D. (I),(ii),S

Description : The number of coordination isomers possible for `[Fe(NH_(3))_(6)]^(3+)[Cr(C_(2)O_(4))_(3)]^(3-)` is __________

Last Answer : The number of coordination isomers possible for `[Fe(NH_(3))_(6)]^(3+)[Cr(C_(2)O_(4))_(3)]^(3-)` is __________

Description : For the complex `K_(2)[Cr(NO)(NH_(3))(CN)_(4)],mu=1.73 BM`. (i) Write IUPAC name. (ii) What will be structure ? (iii) How many unpaired electrons are

Last Answer : For the complex `K_(2)[Cr(NO)(NH_(3))(CN)_(4)],mu=1.73 BM`. (i) Write IUPAC name. ... the complex. (vi) What will be the hybridisation of the complex.

Description : Reaction I `Ph-overset(O)overset(||)(C)-NH_(2) overset(overset(Theta)(OD),Br_(2))rarrA` Reaction II `Ph-overset(O)overset(||)(C)-ND_(2) overset(overse

Last Answer : Reaction I `Ph-overset(O)overset(||)(C)-NH_(2) overset(overset(Theta)(OD),Br_(2))rarrA` Reaction II `Ph- ... Both `Ph-NH_(2)` D. Both `Ph-ND_(2)`

Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry

Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+

Description : . A and B are stereoisomers. They are nonsuperimposable and are mirror images of one another. Which of the following best describes the relationship between A and B? (a) structural isomers (b) enantiomers (c) cis-trans isomers (d) diastereomers

Last Answer : enantiomers

Description : Which of the statements is false regarding chiral compounds? (a) rotate the plane of polarized light (b) have cis and trans isomers (c) exist as enantiomers (d) can be detected with a polarimeter

Last Answer : have cis and trans isomers