Mention the anomalous behaviour of beryllium

1 Answer

Answer :

Beryllium, the first member of the Group 2 metals, shows anomalous behaviour as compared to magnesium and rest of the members. Further, it shows diagonal relationship to aluminium

(i) Beryllium has exceptionally small atomic and ionic sizes and thus does not compare well with other  members of the group. Because of high ionisation enthalpy and small size it forms compounds which are

 largely covalent and get easily hydrolysed.

(ii) Beryllium does not exhibit coordination number more than four as in its valence shell there are only four orbitals. The remaining members of the group can have a coordination number of six by making use of  d-orbitals.

(iii) The oxide and hydroxide of beryllium, unlike the hydroxides of other elements in the group, are  amphoteric in nature. 

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