Description : Arrange the following in order of decreasing tendency towards `S_(N^(2))` reaction : `{:(underset("(I)")(CH_(3)CH_(2)CH_(2)CH_(2)Cl)", "underset("(II)
Last Answer : Arrange the following in order of decreasing tendency towards `S_(N^(2))` reaction : `{: ... `IIIgtIVgtIIgtI` C. `IgtIIIgtIIgtIV` D. `IIgtIgtIIIgtIV`
Description : The end product (B) of the reaction sequence: `C_(2)H_(5)-underset(H)underset(|)(N)-CH_(3) overset(Ph-overset(O)overset(||)(C)-Cl)underset(NaOH)rarrA
Last Answer : The end product (B) of the reaction sequence: `C_(2)H_(5)-underset(H)underset(|)(N)-CH_(3) overset(Ph-overset ... )underset(H_(2)O)rarr B` A. B. C. D.
Description : Asseration: Number of `S-S` bonds in `H_(2)S_(n)O_(6)` is (n-1). Reason: `H_(2)S_(n)O_(6)` shows `HO_(3)S-underset((n-2))(S)-SO_(3)H`
Last Answer : Asseration: Number of `S-S` bonds in `H_(2)S_(n)O_(6)` is (n-1). Reason: `H_(2)S_(n)O_(6)` shows `HO_(3)S-underset((n-2))(S)-SO_(3)H`
Description : Compounds P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Q and S is `C_(8)H_(8)O`. Q undergoes cannizzaro reactions b
Last Answer : Compounds P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Q and S is `C_(8) ... R , respectively is (are) A. B. C. D.
Description : In a `S_(N^(2))` substitution reaction of the type `R-Br+Cl^(-)overset("DMF")rarrR-Cl+Br^(-)` Which one of the following has the highest relative rate
Last Answer : In a `S_(N^(2))` substitution reaction of the type `R-Br+Cl^(-)overset("DMF")rarrR-Cl+Br^(-)` Which one of ... CH_(2)Br` D. `(CH_(3))_(2)CH-CH_(2)Br`
Description : `underset("Brown")([(NH_(3))_(5)Co-O-O-Co(NH_(3))_(5)]^(4+)) underset("oxidise")overset([S_(2)O_(8)]^(2-))tounderset("Green")([(NH_(3))_(5)Co-O-O-Co(N
Last Answer : `underset("Brown")([(NH_(3))_(5)Co-O-O-Co(NH_(3))_(5)]^(4+)) underset("oxidise")overset([S_(2)O_(8) ... III " "IV" & "III" "III),("brown "" green"):}`
Description : `n(CF_(2)=CF_(2))overset((NH_(4))_(2)S_(2)O_(8))underset(Heat)toX` Here , X is:
Last Answer : `n(CF_(2)=CF_(2))overset((NH_(4))_(2)S_(2)O_(8))underset(Heat)toX` Here , X is: A. PVC B. PMMA C. PAN D. none of these
Description : A mixture of potassium chlorate, oxalic acid and sulphuric acid is heated. During the reaction which element undergoes maximum change in the oxidation number? (1) C (2) S (3) H (4) Cl
Last Answer : Cl
Description : The major product formed in the reaction: `overset(p-TsOH("Trace"))underset(C_(6)H_(6).Delta)rarr`
Last Answer : The major product formed in the reaction: `overset(p-TsOH("Trace"))underset(C_(6)H_(6).Delta)rarr` A. B. C. D.
Description : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` mechanism?
Last Answer : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` ... Isopropyl chloride C. Chlorobenzene D. Benzyl chloride
Description : The number of S - S bonds in polythionic acid `(H_(2)S_(n)O_(6))`
Last Answer : The number of S - S bonds in polythionic acid `(H_(2)S_(n)O_(6))` A. n B. n - 1 C. n -2 D. None of these
Description : Acetone undergoes reduction with zinc amalgam in HCl to form propane. This reaction is known as (a) Clemmensen reduction (b) Wolf-Kishner reduction (c) Rosenmund reduction (d) Aldol condensation
Last Answer : Clemmensen reduction
Description : Acetone undergoes reduction with hydrazine in the presence of NaOH to form propane. This reaction is known as (a) Clemmensen reduction (b) Wolf-Kishner reduction (c) Rosenmund reduction (d) Reformatsky reaction
Last Answer : Wolf-Kishner reduction
Description : The eq. wt. of `Na_(2)S_(2)O_(3)` as reductant in the reaction, `Na_(2)S_(2)O_(3)+H_(2)O+Cl_(2)rarrNa_(2)SO_(4)+2HCl+S` is :
Last Answer : The eq. wt. of `Na_(2)S_(2)O_(3)` as reductant in the reaction, `Na_(2)S_(2)O_(3)+H_(2)O+Cl_(2)rarrNa_(2) ... wt.)/2 C. (Mol. wt.)/6 D. (Mol. wt.)/8
Description : Assertion : A white turbidity is obtained by passing `H_(2)S` through aq solution of `SO_(2)` Reason: Aq solution of `SO_(2)` and `H_(2)S` undergoes r
Last Answer : Assertion : A white turbidity is obtained by passing `H_(2)S` through aq solution of `SO_(2 ... Statement-I is not correct and Statement-II is correct
Description : Aniline reacts with mixed acid (conc. `HNO_(3)` and conc. `H_(2)SO_(4)`) at 288 K to give P (51%), Q (47%) and R(2%). The major product (s) of the fol
Last Answer : Aniline reacts with mixed acid (conc. `HNO_(3)` and conc. `H_(2)SO_(4)`) at 288 K to give P ... of the following reaction sequence is (are) B. C. D.
Description : The correct statement(s) about the following reaction sequence is (are) Cumene `(C_(9)H_(12))underset((ii)H_(3)O^(+))overset((i)O_(2))rarrPoverset(CHC
Last Answer : The correct statement(s) about the following reaction sequence is (are) Cumene `(C_(9)H_(12) ... violet coloration with 1% aqueous `FeCl_(3)` solution
Description : Which is a mutual reduction reaction ? A) `KMnO_(4)+O_(3)` B) `H_(2)O_(2)+O_(3)` C) `Ag_(2)O+O_(3)` D) `KI+H_(2)O+O_(3)`
Last Answer : Which is a mutual reduction reaction ? A) `KMnO_(4)+O_(3)` B) `H_(2)O_(2)+O_(3)` C) `Ag_(2)O+O_(3)` D) `KI+H_(2)O+O_(3)` A. A,B B. A,C C. A,D D. B,C
Description : Assertion :- `H_(2)S+Cl_(2)rarr2HCl+S` In the above reaction, Cl has been oxidised to `Cl^(-)` while `S^(-2)` has been reduced to S Reason :- In a rea
Last Answer : Assertion :- `H_(2)S+Cl_(2)rarr2HCl+S` In the above reaction, Cl has been oxidised to `Cl^(-)` ... is False. D. If both Assertion & Reason are False.
Description : For the reaction : `I^(-)+ClO_(3)^(-)+H_(2)SO_(4) to Cl^(-)+HSO_(4)^(-)+I_(2)` The correct statement(s) in the balanced equation is/are:
Last Answer : For the reaction : `I^(-)+ClO_(3)^(-)+H_(2)SO_(4) to Cl^(-)+HSO_(4)^(-)+I_(2)` The ... Sulphur is reduced. D. `H_(2)O` is one of the products.
Description : A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin (Q). Ozonolysis o
Last Answer : A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give ... (S) is: A. B. C. D.
Last Answer : A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration ... respectively, are: A. B. C. D.
Last Answer : A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give ... (P) is: A. B. C. D.
Description : (A) `S_(N^(2))` reactioin takes place in single step. (R) `S_(N^(2))` reaction involves transition state intermediate.
Last Answer : (A) `S_(N^(2))` reactioin takes place in single step. (R) `S_(N^(2))` reaction involves transition ... . D. IF (A) is incorrect but (R) is correct.
Description : Some amount of "20V" `H_(2)O_(2)` is mixed with excess of acidified solution of Kl. The iodine so liberated required 200 mL of 0.1 N `Na_(2)S_(2)O_(3)
Last Answer : Some amount of "20V" `H_(2)O_(2)` is mixed with excess of acidified solution of Kl. The iodine so liberated ... 56 mL B. 112 mL C. 168 mL D. 224 mL
Last Answer : Some amount of "20V" `H_(2)O_(2)` is mixed with excess of acidified solution of Kl. The iodine so liberated required ... . 0.8 g C. 4.2 g D. 0.98 g
Last Answer : Some amount of "20V" `H_(2)O_(2)` is mixed with excess of acidified solution of Kl. The iodine so liberated required ... 37.2 mL C. 5.6 mL D. 22.4 mL
Description : The `S_(N^(1))` reactivity of the following halides will be in the order: (i) `(CH_(3))_(3)C-Br` (ii) `(C_(6)H_(5))CHBr` (iii) `(C_(6)H_(5))_(2)C(CH_(
Last Answer : The `S_(N^(1))` reactivity of the following halides will be in the order: (i) `(CH_(3))_(3)C-Br` (ii) `(C_ ... D. (iii) gt (ii) gt (i) gt (iv) gt (v)
Description : The product of the chemical reaction between `Na_(2)S_(2)O_(3)`, `Cl_(2)` and `H_(2)O` are
Last Answer : The product of the chemical reaction between `Na_(2)S_(2)O_(3)`, `Cl_(2)` and `H_(2)O` are A. `HCl + Na_( ... + Na_(2)SO_(3)` D. `NaHClO_(3) + H_(2)O`
Description : Arrange the following resonating structures in order of increasing stability `underset((I))(CH_(2)=overset(+)(N)=overset(-)(N))" "underset((II))(H_(2)
Last Answer : Arrange the following resonating structures in order of increasing stability `underset((I))(CH_(2)=overset(+)(N)= ... gt IV D. III gt I gt IV gt II
Description : Which of the following observations is / are not correct about the given equation: Pb(NO 3 ) 2 (aq) + 2 KI (aq) PbI 2 (s) + 2KNO 3 (aq) (a) PbI 2 is yellow precipitate insoluble in water (b) It is precipitation reaction (c) It is single displacement reaction (d) It is very fast reaction
Last Answer : (c) It is single displacement reaction
Description : Consider the follwing complexes ion `P,Q` and `R` `P =[FeF_(6)]^(3-), Q=[V(H_(2)O)_(6)]^(2+)` and `R=[Fe(H_(2)O)_(6)]^(2+)` The correct order of the c
Last Answer : Consider the follwing complexes ion `P,Q` and `R` `P =[FeF_(6)]^(3-), Q=[V(H_(2)O)_(6)]^(2+)` and `R=[Fe( ... lt P` C. `R lt P lt Q` D. `Q lt P lt R`
Description : Among the electrolytes `Na_(2),SO_(4),CaCl_(2),Al_(2)(SO_(4))_(3) and NH_(4)Cl`, the most effective coagulating agent for `Sb_(2)S_(3)` sol is
Last Answer : Among the electrolytes `Na_(2),SO_(4),CaCl_(2),Al_(2)(SO_(4))_(3) and NH_(4)Cl`, the most effective coagulating ... `Al_(2)(SO_(4))_(3)` D. `NH_(4)Cl`
Description : Statement-I: Optically active 2-idoibutane on treatment with `NaI` in acetone undergoes racemisation. Because Statement-II: Repeated Walden inversions
Last Answer : Statement-I: Optically active 2-idoibutane on treatment with `NaI` in acetone undergoes racemisation. ... Statement-1 is false, Statement-2 is true
Description : `{:("column I","column II"),("(A)"4.1gH_(2)SO_(3),"(p) 200 mL of 0.5 N base is used for complete neutralization"),("(B)" 4.9 g H_(3)PO_(4),"(q) 200 mi
Last Answer : `{:("column I","column II"),("(A)"4.1gH_(2)SO_(3),"(p) 200 mL of 0.5 N base is used for ... Na_(2)CO_(3),"(s)May react with an oxidising agent"):}`
Description : `underset("Calcium carbide")(CaC_(2))overset(H_(2)O)(to)(A)overset("Red hot Cu tube")(to)(B)`, Product (B) of the reaction is:
Last Answer : `underset("Calcium carbide")(CaC_(2))overset(H_(2)O)(to)(A)overset("Red hot Cu tube")(to)(B)`, Product (B) of the reaction is: A. B. C. D.
Description : In the reaction, `C_(6)H_(5)NH_(2)underset(0-5^(@)C)overset(NaNO_(2)+HCl)rarr(A)underset(KCN)overset(CuCN)rarr(B)overset(H^(+)//H_(2)O)rarr(C)` the pr
Last Answer : In the reaction, `C_(6)H_(5)NH_(2)underset(0-5^(@)C)overset(NaNO_(2)+HCl)rarr(A)underset(KCN)overset(CuCN ... COOH` C. `C_(6)H_(5)OH` D. none of these
Description : The major product H in the given reaction sequence is `CH_(3)-CH_(2)-CO-CH_(3) overset(._(Theta)CN)toG overset(95% H_(2)SO_(4)) underset("Heat")toH`
Last Answer : The major product H in the given reaction sequence is `CH_(3)-CH_(2)-CO-CH_(3) overset(._(Theta)CN) ... CH=underset(CH_(3))underset(|)(C)-CO-NH_(2)`
Description : In the given reaction which one of the following statement is correct - `C_(6)H_(5)-underset(CH_(3))underset(|)(C)=O+NH_(2)-OH to "Oxime" overset(PCl_
Last Answer : In the given reaction which one of the following statement is correct - `C_(6)H_(5)- ... elimination reaction. D. oxime and amides are isomers.
Description : Observe the following reaction `CH_(3)-underset(O)underset(||)(C)-CH_(2)-underset(O)underset(||)(C) -CH_3 overset(HCN "(excess)")to overset(H_(3)overs
Last Answer : Observe the following reaction `CH_(3)-underset(O)underset(||)(C)-CH_(2)-underset(O)underset(| ... D. The product is a mixture of three stereoisomers.
Description : In the given reaction `{:(" "CH_(3)),(" |"),(H_(3)C-C-C-CHO),(" | ||"),(" "H_(3)C " "O):} overset("(i)Conc. NaOH")underset((ii)H^(+)) to` product is
Last Answer : In the given reaction `{:(" "CH_(3)),(" |"),(H_(3)C-C-C-CHO),(" | ||"),(" "H_(3)C " "O):} overset("(i) ... )C-C-C-CH_2),(" | ||"),(" "H_(3)C " "OH):}`
Description : `C_(6)H_(5)-CH_(2)-I overset(NaN_(3))underset(Delta)rarr` Products Reaction is assumed to involve nitrene as intermediate, then various possible produ
Last Answer : `C_(6)H_(5)-CH_(2)-I overset(NaN_(3))underset(Delta)rarr` Products Reaction is assumed to involve nitrene as ... (2)` C. `C_(6)H_(5)CN=NH` D.
Description : `overset(1.Br_(2)^(-)+KOH, Delta)underset(2.H_(3)O^(o+))rarr` The product of above reaction is:
Last Answer : `overset(1.Br_(2)^(-)+KOH, Delta)underset(2.H_(3)O^(o+))rarr` The product of above reaction is: A. B. C. D.
Description : The major end product (B) of the reaction: `overset(HCI)underset(ZnCl_(2))rarr A overset(1.NaCN("excess"))underset(2.H_(2),Ni)rarr B`
Last Answer : The major end product (B) of the reaction: `overset(HCI)underset(ZnCl_(2))rarr A overset(1.NaCN("excess"))underset(2.H_(2),Ni)rarr B` A. B. C. D.
Description : The product formed in the reaction is: `overset(1.LiAlH_(4))underset(2.H_(2)O)rarr`
Last Answer : The product formed in the reaction is: `overset(1.LiAlH_(4))underset(2.H_(2)O)rarr` A. B. C. `H_(3)C- ... )underset(|)(N)-(CH_(2))_(3) -CH_(2)OH`
Description : The major product (X) of the reaction is: `overset(H_(2),Ni)underset(Delta)rarr X`
Last Answer : The major product (X) of the reaction is: `overset(H_(2),Ni)underset(Delta)rarr X` A. B. C. D.