Description : KI in acetone, undergoes `S_(N)2` reaction with each of `P,Q ,R` and S The rates of the reaction very as `underset(P)(H_(3)C-Cl)` .
Last Answer : KI in acetone, undergoes `S_(N)2` reaction with each of `P,Q ,R` and S The rates of the reaction very as ` ... R gt Q gt S D. R gt P gt S gt Q
Description : `P+Q rarr Anisol e overset(HI)rarrR+S` Correct statement among the following is
Last Answer : `P+Q rarr Anisol e overset(HI)rarrR+S` Correct statement among the following is A. P and Q are `C_(6)H_(5)` ... Q are `C_(6)H_(5)C1` and `CH_(3)` Ona
Description : Arrange the following in order of decreasing tendency towards `S_(N^(2))` reaction : `{:(underset("(I)")(CH_(3)CH_(2)CH_(2)CH_(2)Cl)", "underset("(II)
Last Answer : Arrange the following in order of decreasing tendency towards `S_(N^(2))` reaction : `{: ... `IIIgtIVgtIIgtI` C. `IgtIIIgtIIgtIV` D. `IIgtIgtIIIgtIV`
Description : The end product (B) of the reaction sequence: `C_(2)H_(5)-underset(H)underset(|)(N)-CH_(3) overset(Ph-overset(O)overset(||)(C)-Cl)underset(NaOH)rarrA
Last Answer : The end product (B) of the reaction sequence: `C_(2)H_(5)-underset(H)underset(|)(N)-CH_(3) overset(Ph-overset ... )underset(H_(2)O)rarr B` A. B. C. D.
Description : The `S_(N^(1))` reactivity of the following halides will be in the order: (i) `(CH_(3))_(3)C-Br` (ii) `(C_(6)H_(5))CHBr` (iii) `(C_(6)H_(5))_(2)C(CH_(
Last Answer : The `S_(N^(1))` reactivity of the following halides will be in the order: (i) `(CH_(3))_(3)C-Br` (ii) `(C_ ... D. (iii) gt (ii) gt (i) gt (iv) gt (v)
Description : From the elements: Cl, Br, F, O, Al, C, Li, Cs and Xe; choose the following: (a) The element with highest negative electron gain enthalpy. (b) The element with lowest ionization enthalpy. ( ... . (f)The element which belongs to zero group. (g) The elements which forms largest number of compounds.
Last Answer : Ans. (a). The element chlorine (Cl) has the highest negative electron gain enthalpy. (b). The element cesium (Cs) has lowest ionization enthalpy. (c). The element fluorine F has lowest atomic radius. (d ... zero group (or group 18). (g). The element carbon (C) forms the largest number of compounds.
Description : (A) Cation carriers, e.g., `H-Br,Cl-OH` and `Br-Br` and oxidising agents such as `O_(3)` and `R-O-O-R`, etc. act as electrophilic reagents. (R) Electr
Last Answer : (A) Cation carriers, e.g., `H-Br,Cl-OH` and `Br-Br` and oxidising agents such as `O_(3)` and ... incorrect. D. IF (A) is incorrect but (R) is correct.
Description : Arrange the following order of the property indicated: (a). F, Cl, Br and I (negative electron gain enthalpy) (b). Mg, Al, Si and Na (ionization enthalpy) (c). C, N, O and F (second ionization enthalpy)
Last Answer : Ans. (a). I
Description : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` mechanism?
Last Answer : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` ... Isopropyl chloride C. Chlorobenzene D. Benzyl chloride
Description : `underset("Brown")([(NH_(3))_(5)Co-O-O-Co(NH_(3))_(5)]^(4+)) underset("oxidise")overset([S_(2)O_(8)]^(2-))tounderset("Green")([(NH_(3))_(5)Co-O-O-Co(N
Last Answer : `underset("Brown")([(NH_(3))_(5)Co-O-O-Co(NH_(3))_(5)]^(4+)) underset("oxidise")overset([S_(2)O_(8) ... III " "IV" & "III" "III),("brown "" green"):}`
Description : `n(CF_(2)=CF_(2))overset((NH_(4))_(2)S_(2)O_(8))underset(Heat)toX` Here , X is:
Last Answer : `n(CF_(2)=CF_(2))overset((NH_(4))_(2)S_(2)O_(8))underset(Heat)toX` Here , X is: A. PVC B. PMMA C. PAN D. none of these
Description : The reaction `RCH_(2)CH_(2)COOH overset(Red P)underset(Br_(2))toRCH_(2)-underset(Br)underset(|)(C)HCOOH` is called as
Last Answer : The reaction `RCH_(2)CH_(2)COOH overset(Red P)underset(Br_(2))toRCH_(2)-underset(Br) ... reaction C. Reimer Teimann reaction D. Sandmeyer reaction
Description : `CH_(3)CH_(2)-CH_(2)-COOH overset("Red + P" +Br_(2))toCH_(3)-CH_(2)-underset(Br)underset(|)(CH)-COOH` This reaction is called
Last Answer : `CH_(3)CH_(2)-CH_(2)-COOH overset("Red + P" +Br_(2))toCH_(3)-CH_(2)-underset(Br)underset(|)(CH)-COOH` This reaction is called
Description : Identify A and B in the following reaction `C_(2)H_(5) - Cl overset(A)rarr C_(2)H_(5) OH overset(B)leftarrow C_(2)H_(5)Cl`
Last Answer : Identify A and B in the following reaction `C_(2)H_(5) - Cl overset(A)rarr C_(2)H_(5) OH overset(B)leftarrow C_ ... 2)` D. `A = AgNO_(2), B = KNO_(2)`
Description : (A) `S_(N^(2))` reactioin takes place in single step. (R) `S_(N^(2))` reaction involves transition state intermediate.
Last Answer : (A) `S_(N^(2))` reactioin takes place in single step. (R) `S_(N^(2))` reaction involves transition ... . D. IF (A) is incorrect but (R) is correct.
Description : `K_2S_2O_8` , acidic `K_2S_2O_8` and acidic `MnO_2` oxidise `I^(-), Br^(-) , Cl^(-)` to `I_2 , Br_2 and Cl_2` , respectively. From the given data the
Last Answer : `K_2S_2O_8` , acidic `K_2S_2O_8` and acidic `MnO_2` oxidise `I^(-), Br^(-) , Cl^(-)` to `I_2 , ... gt I_2 gt Br_2` D. `Cl_2 gt K_2 S_2O_8 gt Br_2`
Description : How many orders are correct: (a) H—F lt H-Cl lt H—Br lt H—I (Bond length) (b) H—F lt H—I ltH—Br ltH—I (Acidic strength) (C) H—I H—Br lt H—Cl ltH—F (Bo
Last Answer : How many orders are correct: (a) H-F lt H-Cl lt H-Br lt H-I (Bond length) (b) H-F lt H-I ltH- ... power) (f) H-Fgt H-Igt H-Brgt H-Cl (Boiling point)
Description : For the following `(i) I^(-) (ii) Cl^(-) (iii) Br^(-)` the increasing order of nucleophilicity would be:
Last Answer : For the following `(i) I^(-) (ii) Cl^(-) (iii) Br^(-)` the increasing order of nucleophilicity would be: A. ... )ltCl^(-)` D. `Cl^(-)ltBr^(-)ltI^(-)`
Description : Which has the smallest bond angle `X-S-X` in the given molecules ? (X=F, Cl, Br, I)
Last Answer : Which has the smallest bond angle `X-S-X` in the given molecules ? (X=F, Cl, Br, I) A. `SOF_(2)` B. `SOC1_(2)` C. `SOBr_(2)` D. `SOI_(2)`
Description : The increasing order of reactivity among group 1 elements is Li
Last Answer : Ans. In group 1 elements (alkali metals) the reactivity of the metals is mainly due to the electron releasing tendency of their atoms, which is related to ionization enthalpy, Since ... electron gain enthalpy. Since both of them decrease down the group, the reactivity therefore decreases.
Description : Which of the following is the strongest nucleophile in an aqueous solution? (a) HO– (b) Cl– (c) Br– (d) I
Last Answer : I–
Description : Which of the following is the best leaving group? (a) F– (b) Cl– (c) Br– (d) I–
Description : The halogen with the largest atomic radius is: w) Cl x) I y) Br z) At
Last Answer : ANSWER: Z -- At
Description : Among the electrolytes `Na_(2),SO_(4),CaCl_(2),Al_(2)(SO_(4))_(3) and NH_(4)Cl`, the most effective coagulating agent for `Sb_(2)S_(3)` sol is
Last Answer : Among the electrolytes `Na_(2),SO_(4),CaCl_(2),Al_(2)(SO_(4))_(3) and NH_(4)Cl`, the most effective coagulating ... `Al_(2)(SO_(4))_(3)` D. `NH_(4)Cl`
Description : Of the following reactions, how many reaction, are used for the preparation of amines? (a) `R-C-=N overset(LiAIh_(4))rarr` (b) `R-overset(O)overset(||
Last Answer : Of the following reactions, how many reaction, are used for the preparation of amines? (a) `R-C-=N overset( ... R-CH_(2)-NO_(2) overset(H_(2),Ni)rarr`
Description : The acid D obtained through the following sequence of reactions is: `C_(2)H_(5)Br overset(Alc. KOH)rarrA overset(Br_(2))underset(C Cl_(4))rarrBoverset
Last Answer : The acid D obtained through the following sequence of reactions is: `C_(2)H_(5)Br overset(Alc. KOH) ... B. Malonic acid C. Maleic acid D. Oxalic acid
Description : How many sterioisomers does the following compound have ? `CH_(3)-CH_(2)-underset(overset(|)(Br))(C)H-CH_(2)-CH=CH-CH_(3)`
Last Answer : How many sterioisomers does the following compound have ? `CH_(3)-CH_(2)-underset(overset(|)(Br))(C)H-CH_(2)-CH=CH-CH_(3)` A. None B. 2 C. 4 D. 6
Description : Total number of stereoisomers of compound is: `CH_(3)-underset(overset(|)(OH))(C)H-underset(overset(|)(Br))(C)H-CH_(3)`
Last Answer : Total number of stereoisomers of compound is: `CH_(3)-underset(overset(|)(OH))(C)H-underset(overset(|)(Br))(C)H-CH_(3)` A. 2 B. 4 C. 6 D. 8
Description : Number of chiral carbon persent in the following compound: `CH_(3)-underset(overset(|)(OH))(C)H-CH_(2)-underset(overset(|)(Br))(C)H-underset(overset(|
Last Answer : Number of chiral carbon persent in the following compound: `CH_(3)-underset(overset(|)(OH))(C)H-CH_(2)-underset(overset( ... (3)` A. 2 B. 3 C. 4 D. 5
Description : Consider the following sequence of reactions: `overset(C CI_(4))underset(Delta)rarr A overset(1.CH_(2)=CH-CH_(2)Br)underset(2.H_(3)O^(o+),Delta)rarrB`
Last Answer : Consider the following sequence of reactions: `overset(C CI_(4))underset(Delta)rarr A overset(1.CH_(2)=CH-CH_(2) ... end product (B) is: A. B. C. D.
Description : `CH_(3)CH_(2)Br overset(AgCN)rarr A overset(NaOH, Delta)underset(overset(o+)(H_(3)O))rarrB,(B)` is:
Last Answer : `CH_(3)CH_(2)Br overset(AgCN)rarr A overset(NaOH, Delta)underset(overset(o+)(H_(3)O))rarrB,(B)` is: A. `CH_( ... (2)NH_(2)` C. `CH_(3)CH_(2)NH_(2)` D.
Description : What is the chemical solvent DMF called?
Last Answer : ANSWER: -- DIMETHYLFORMAMIDE (pron: die-meth-il-FOR-ma-mide)
Description : Which of the following statement is correct regarding following process ? `(i) Cl overset(E.A)to Cl^(-) " " (ii) Cl^(-) overset(I.E.)to Cl` `(iii) Cl
Last Answer : Which of the following statement is correct regarding following process ? `(i) Cl overset(E.A)to Cl^(-) " ... of process (iv)|=|E.A of process (iii)|
Description : Ammonium salts decompose quite readily on heating : (i) Ammonium salt of weak oxidizing anion (e.g. `Cl^(-), CO_(3)^(2-), SO_(4)^(2-)`) `overset("heat
Last Answer : Ammonium salts decompose quite readily on heating : (i) Ammonium salt of weak oxidizing anion (e.g. `Cl^(-), CO_(3) ... N_(2)` D. `NO, NH_(3), N_(2)O`
Description : (A) In `S_(N^(2))` reactions, complete inversion of configuration takes place. (R) In `S_(N^(1))` reactions, retention but not the inversion takes pla
Last Answer : (A) In `S_(N^(2))` reactions, complete inversion of configuration takes place. (R) In `S_(N^(1))` ... . D. IF (A) is incorrect but (R) is correct.
Description : Consider the following reaction and statements: `[Co(NH_(3))_(4)Br_(2)]^(+)+Br^(-) to [Co(NH_(3))_(3)Br_(3)]+NH_(3)` Two isomers are produced if the r
Last Answer : Consider the following reaction and statements: `[Co(NH_(3))_(4)Br_(2)]^(+)+Br^(-) to [Co(NH_(3))_(3) ... II B. III and IV C. I and IV D. II and III
Description : Which of the following are correct for `S_(N^(2))` reaction?
Last Answer : Which of the following are correct for `S_(N^(2))` reaction? A. The reaction intermediate ... solvents D. It is favoured by stability of carbocation
Description : Which of the following halides will be most reactive towards `S_(N^(2))` reaction?
Last Answer : Which of the following halides will be most reactive towards `S_(N^(2))` reaction? A. `C_(6)H_(5)CH_(2 ... (2)-underset(Br)underset("| ")"CH"-CH_(3)`
Description : The correct increasing order of the reactivity of halides for `S_(N^(1))` reaction is:
Last Answer : The correct increasing order of the reactivity of halides for `S_(N^(1))` reaction is: A. `CH_(3)CH_(2)-Xlt( ... -Xlt(CH_(3))_(2)CH-XltCH_(3)CH_(2)-X`
Description : Which one is most reactive towards `S_(N^(1))` reaction?
Last Answer : Which one is most reactive towards `S_(N^(1))` reaction? A. `C_(6)H_(5)CH(C_(6)H_(5))Br` B. `C_(6)H_(5) ... H_(5)CH(CH_(3))Br` D. `C_(6)H_(5)CH_(2)Br`
Description : In the `S_(N^(1))` reaction on chiral centres there is :
Last Answer : In the `S_(N^(1))` reaction on chiral centres there is : A. `100%` racemization B. ... partial racemization C. `100%` retention D. `100%` inversion
Description : As `S_(N^(2))` reaction at an asymmetric carbon of a compound always gives:
Last Answer : As `S_(N^(2))` reaction at an asymmetric carbon of a compound always gives: A. an ... C. a mixture of diastereomers D. a single stereoisomer
Description : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is :
Last Answer : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is : A. RF > RCl > RBr > ... RBr > RF > RI D. RI > RBr > RCl > RF
Description : Which of the following reactions is an example of `S_(N^(2))` reaction?
Last Answer : Which of the following reactions is an example of `S_(N^(2))` reaction? A. `(CH_(3))_(3)C-Br+OH^(-) ... )CH_(2)OHunderset((-H_(2)O))rarrH_(2)C=CH_(2)`
Description : Which one of the following statements wrong about `S_(N^(2))` reaction?
Last Answer : Which one of the following statements wrong about `S_(N^(2))` reaction? A. The rate of ... The rate of reaction `prop` [substrate] [nucleophile]
Description : Conjugation of electron withdrawing groups, e.g., `-CHO`, `-overset(O)overset("|")C-R", "-overset(O)overset(||)C-OR", "-C-=N", "-NO_(2)` activates nuc
Last Answer : Conjugation of electron withdrawing groups, e.g., `-CHO`, `-overset(O)overset("|")C-R", "-overset(O) ... O)overset(||)C-ORgt-overset(O)overset(||)C-R`