Which complex of the following pairs has the larger value of `Delta_(0)` (i) `[Co(CN)_(6)]^(3-)` and `[Co(NH_(3))_(6)]^(3+)` (ii) `[Co(NH_(3))_(6)]^(3

1 Answer

Answer :

Which complex of the following pairs has the larger value of `Delta_(0)` (i) `[Co(CN)_(6)]^(3-)` and `[Co(NH_( ... (3))_(6)]^(3+) lt [CoF_(6)]^(3-)`

Related questions

Description : For the complex `K_(2)[Cr(NO)(NH_(3))(CN)_(4)],mu=1.73 BM`. (i) Write IUPAC name. (ii) What will be structure ? (iii) How many unpaired electrons are

Last Answer : For the complex `K_(2)[Cr(NO)(NH_(3))(CN)_(4)],mu=1.73 BM`. (i) Write IUPAC name. ... the complex. (vi) What will be the hybridisation of the complex.

Description : The value of `Delta_(0) " for " [Ti(H_(2)O)_(6)]^(3+)` is found to be 240 kJ `mol^(-1)` then predict the colour of the complex using the following tab

Last Answer : The value of `Delta_(0) " for " [Ti(H_(2)O)_(6)]^(3+)` is found to be 240 kJ `mol^(-1)` then ... -34)J-sec,N_(A)=6xx10^(23)c=3xx10^(8) m//sec)`

Description : Which isomerism is exhibited by `[Co(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(6)][Co(CN)_(6)]`?

Last Answer : Which isomerism is exhibited by `[Co(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(6) ... )]`? A. Ionization B. Linkage C. Coordination D. Polymerization.

Description : Among the following complexes : `K_(3)[Fe(CN)_(6)],[Co(NH_(3))_(6)]Cl_(3)` , `Na_(3)[Co ( o x )_(3)],[Ni(H_(2)O)_(6)]Cl_(2)`, `K_(2)[Pt(CN)_(4)]` and

Last Answer : Among the following complexes : `K_(3)[Fe(CN)_(6)],[Co(NH_(3))_(6)]Cl_(3)` , `Na_(3)[Co ( o x )_(3)],[Ni(H_( ... ,M,N B. K,N,O,P C. L,M,O,P D. L,M,N,O

Description : Calculate the EAN of central atom in the following complexes `(a) [Cr(CO)_(6)]" "(b) [Fe(CN)_(6)]^(4-)" " (c ) [Fe(CO)_(5)] " " (d) [Co(NH_(3))_(6)]^(

Last Answer : Calculate the EAN of central atom in the following complexes `(a) [Cr(CO)_(6)]" "(b) [Fe(CN)_(6)]^(4-)" " (c ... ))_(6)]^(4+)" " (h) [PtCl_(6)]^(2-)`

Description : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2)]` is :

Last Answer : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2 ... (ethane-1,2-diammine) nitritioplatinum(IV) dicyanoargentate (I)

Description : The oxidation state of Cr in `[Cr(H_(2)O)_(6)]Cl_(3), [Cr(C_(6)H_(6))_(2)], and K_(2)[Cr(CN)_(2)(O)_(2)(O_(2))(NH_(3))]` respectively are :

Last Answer : The oxidation state of Cr in `[Cr(H_(2)O)_(6)]Cl_(3), [Cr(C_(6)H_(6))_(2)], and K_(2)[Cr(CN)_(2)(O)_(2 ... and +4` C. `+3,+4 and +6` D. `+3,+2 and +4`

Description : Consider the coordination compound , `[Co(NH_(3))_(6)]Cl_(3)`. In the formation of the complex, the species which acts as the Lewis acid is :

Last Answer : Consider the coordination compound , `[Co(NH_(3))_(6)]Cl_(3)`. In the formation of the complex, the species which ... -)` C. `Co^(3+)` D. `NH_(3)`

Description : The IUPAC name of `K_(2)[Cr(CN)_(2)O_(2)(O)_(2)(NH_(3))]` is :

Last Answer : The IUPAC name of `K_(2)[Cr(CN)_(2)O_(2)(O)_(2)( ... Potassium amminedicyanoperoxooxochromate(VI) D. Potassium amminecyanodiperoxodioxochromate(VI)

Description : What type of isomers are the following : `(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]` `(ii) [Co(en)_(3)[Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)]` `(iii)

Last Answer : What type of isomers are the following : `(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]` `(ii) [Co(en)_(3)[Cr( ... ]Cl and [Co(H_(2)O)Cl_(3)(py)_(2)]H_(2)O`

Description : Which kind of isomerism is shown by the complex `[Co(NH_(3))_(5)(ONO)]SO_(4)` ? 1. Ionisation isomerism 2.Linkage isomerism 3. Geometrical isomerism 4

Last Answer : Which kind of isomerism is shown by the complex `[Co(NH_(3))_(5)(ONO)]SO_(4)` ? 1. Ionisation ... are correct only D. Q, R and S are correct only

Description : Among the complex ions, `[Co(NH_(2) - CH_(2) - CH_(2) - NH_(2))_(2) Cl_(2)]^(+), [CrCl_(2) (C_(2)O_(4))_(2)]^(3-)` `[Fe(H_(2)O)_(4) (OH)_(2)]^(+), [Fe

Last Answer : Among the complex ions, `[Co(NH_(2) - CH_(2) - CH_(2) - NH_(2))_(2) Cl_(2)]^(+), [CrCl_(2) ... (3)) Cl]^(2+)` and that show(s) cis-trans isomerism is

Description : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) (NH_(3))_(2)] Cl_(3)` is

Last Answer : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) ( ... (III) chloride D. Diamminetetraaquacobalt (III) chloride

Description : Three arrangements are shown for the complex `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)` pick up the wrong statement.

Last Answer : Three arrangements are shown for the complex `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)` pick up ... are optical isomers D. II and III are geometrical isomers.

Description : Statement-I : In the extraction of Ag, the complex `Na[Ag(CN)_(2)]` is reacted with `Zn` Statement-II : `Zn` is transition metal according to electron

Last Answer : Statement-I : In the extraction of Ag, the complex `Na[Ag(CN)_(2)]` is reacted with `Zn` ... . Statement-1 : is false , statement-2 : is true

Description : Total number of paramagnetic complexes which are inner orbital complexes : `(i) [Cr(NH_(3))_(6)]Cl_(3) " " (ii)[Co(NH_(3))_(6)](NO_(3))_(2)" " (iii)[N

Last Answer : Total number of paramagnetic complexes which are inner orbital complexes : `(i) [Cr(NH_(3))_(6)]Cl_(3) " " (ii)[ ... (4)]" " Na_(4)[Fe(CN)_(5)(NOS)]`

Description : Arrange the following in increasing order as directed. `(a) (i) [CoCl_(3)(NH_(3))_(3)]," "(ii)[CoCl(NH_(3))_(5)]Cl_(2)," "(iii)[Co(NH_(3))_(6)]Cl_(3),

Last Answer : Arrange the following in increasing order as directed. `(a) (i) [CoCl_(3)(NH_(3))_(3)]," "(ii)[CoCl(NH_ ... -),NH^(3),NO^(3)^(-)`-strength of ligands.

Description : A blue colour complex is obtained in the analysis of `Fe^(+3)` having formula `Fe_(4)[Fe(CN)_(6)]_(3)` Let a= oxidation number of Iron in the corrdina

Last Answer : A blue colour complex is obtained in the analysis of `Fe^(+3)` having formula `Fe_(4)[Fe(CN)_ ... coordination sphere. Then find the value of (c+a-2b)

Description : A complex compound in which the oxidation number of a metal is zero is - (1) K4 [Fe (CN)6] (2) K3 [Fe (CN)6] (3) [Ni (CO)4] (4) [Pl (NH3)4]Cl2

Last Answer : (3) [Ni (CO)4]

Description : A `[M(H_(2)O)_(6)]^(2+)` complex typically absorbs at around 600 nm. It is allowed to react with ammonia to form a new complex `[M(NH_(3))_(6)]^(2+)`

Last Answer : A `[M(H_(2)O)_(6)]^(2+)` complex typically absorbs at around 600 nm. It is allowed to react with ammonia ... A. 800 nm B. 580 nm C. 620 nm D. 320 nm

Description : Which of the following facts about the complex `[Cr(NH_(3))_(6)]Cl_(3)` is wrong ?

Last Answer : Which of the following facts about the complex `[Cr(NH_(3))_(6)]Cl_(3)` is wrong ... The complex gives white precipitate with siver nitrate solution.

Description : Arrange the following compounds in order of increasing molar conductivity . `(i) K[Co(NH_(3))_(2)(NO_(2))_(4)]" " (ii) [Cr(NH_(3))_(3)(NO_(2))_(3)]` `

Last Answer : Arrange the following compounds in order of increasing molar conductivity . `(i) K[Co(NH_(3))_(2)(NO_(2))_(4)]" ... )" " (iv) [Cr(NH_(3))_(6)]Cl_(3)`

Description : The complex `K_(4)[Zn(CN)_(4)(O_(2))_(2)]` is oxidised into `K_(2)[Zn(CN)_(4)(O_(2))_(2)]`, then which of the following is correct ?

Last Answer : The complex `K_(4)[Zn(CN)_(4)(O_(2))_(2)]` is oxidised into `K_(2)[Zn(CN)_(4) ... C. `O-O` bond length increases D. Paramagnetic moment increases.

Description : `Na_(2)S + Na_(2)[Fe(CN)_(5)NO]to " X"` (Violet colour) The total number of possible isomers for complex " X" is , provided the ambident behaviour of

Last Answer : `Na_(2)S + Na_(2)[Fe(CN)_(5)NO]to " X"` (Violet colour) The total number of possible ... the ambident behaviour of `CN^(-)` is not considered.

Description : Statement-1: Zn displaces Ag from the complex `Na[Ag(CN)_(2)]` to give `Na_(2)[Zn(CN)_(4)]` Statement-2:Zn is more electro positive than silver

Last Answer : Statement-1: Zn displaces Ag from the complex `Na[Ag(CN)_(2)]` to give `Na_(2)[Zn(CN)_(4) ... false D. Statement-1 is false but Statement -2 is true

Description : The crystl field splitting energy for octahedral complex `(Delta_(0))` and that for tetrahedral complex `(Delta_(1))` rae related as :

Last Answer : The crystl field splitting energy for octahedral complex `(Delta_(0))` and that for tetrahedral complex `(Delta_(1) ... ` D. `Deltat=(9)/(4)Delta_(0)`

Description : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is :

Last Answer : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is : A. ... (II) tris(oxalato)chromium(III) D. Hexaamminecobalt(III)trioxalatechromium(III)

Description : Among `[Ni(CO)_(4)], [NiCl_(4)]^(2-), [Co (NH_(3))_(4) Cl_(2)] Cl, Na_(3) [CoF_(6)], Na_(2)O_(2)` and `CsO_(2)`, the total number of paramagnetic comp

Last Answer : Among `[Ni(CO)_(4)], [NiCl_(4)]^(2-), [Co (NH_(3))_(4) Cl_(2)] Cl, Na_(3) [CoF_(6)], ... total number of paramagnetic compounds is A. 2 B. 3 C. 4 D. 5

Description : The major product H in the given reaction sequence is `CH_(3)-CH_(2)-CO-CH_(3) overset(._(Theta)CN)toG overset(95% H_(2)SO_(4)) underset("Heat")toH`

Last Answer : The major product H in the given reaction sequence is `CH_(3)-CH_(2)-CO-CH_(3) overset(._(Theta)CN) ... CH=underset(CH_(3))underset(|)(C)-CO-NH_(2)`

Description : Both `[Ni(CO)_(4)] and [Ni(CN)_(4)]^(2-)` are diamagnetic. The hybridisation of nickel in these complexes, respectively are :

Last Answer : Both `[Ni(CO)_(4)] and [Ni(CN)_(4)]^(2-)` are diamagnetic. The hybridisation of nickel in these complexes, ... (2),sp^(3)` D. `dsp^(2),sp^(2)`

Description : Amongst `Ni(CO)_(4),[Ni(CN)_(4)]^(2-) and NiCl_(4)^(2-)`:

Last Answer : Amongst `Ni(CO)_(4),[Ni(CN)_(4)]^(2-) and NiCl_(4)^(2-)`: A. `Ni(CO)_(4) and NiCl_(4)^(2-)` ... NiCl_(4)^(2-) and [Ni(CN)_(4)]^(2-)` are paramagnetic.

Description : `{:(,"Compounds",,"O.N."),((A),KMn^(**)O_(4),(1),+4),((B),Ni^(**)(CO)_(4),(2),+7),((C),[Pt^(**)(NH_(3))Cl_(2)]Cl_(2),(3),0),((D),Na_(2)O_(2)^(**),(4),

Last Answer : `{:(,"Compounds",,"O.N."),((A),KMn^(**)O_(4),(1),+4),((B),Ni^(**)(CO)_(4),(2),+7),((C),[Pt^(**)(NH_(3) ... ),(2,3,1,4):}` D. `{:(A,B,C,D),(4,1,2,3):}`

Description : How many are redox reaction- `{:((i),K_(4)[Fe (CN)_(6)] + "conc."H_(2)SO_(4) overset(Delta)rarr,(ii),"conc." H_(2)SO_(4) + KCl rarr),((iii),"conc." H_

Last Answer : How many are redox reaction- `{:((i),K_(4)[Fe (CN)_(6)] + "conc."H_(2)SO_(4) overset(Delta)rarr,(ii)," ... ,((ix),"conc." H_(2)SO_(4) + Cu rarr,,):}`

Description : How many are redox reaction- `{:((i),K_(4)[Fe (CN)_(6)] + "conc."H_(2)SO_(4) overset(Delta)rarr,(ii),"conc." H_(2)SO_(4) + KCl rarr),((iii),"conc." H_

Last Answer : How many are redox reaction- `{:((i),K_(4)[Fe (CN)_(6)] + "conc."H_(2)SO_(4) overset(Delta)rarr,(ii)," ... ,((ix),"conc." H_(2)SO_(4) + Cu rarr,,):}`

Description : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and 2.84 BM respectively. The second complex i

Last Answer : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2 ... . D. It produces three-fold freezing point depression.

Description : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and 2.84 BM respectively. The second complex i

Last Answer : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and ... (H_(2)O)_(2)](NO_(3))_(2)`, octahedral

Description : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and 2.84 BM respectively. The second complex i

Last Answer : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero ... two B. zero, zero C. two, zero D. two ,two

Description : The correct statement on the isomerism associated with the following complex ions , `(a) [Ni(H_(2)O)_(5)NH_(3)]^(2+), (b) [Ni(H_(2)O)_(4)(NH_(3))_(2)]

Last Answer : The correct statement on the isomerism associated with the following complex ions , `(a) [Ni(H_( ... a) and (b) show geometrical and optical isomerism

Description : Statement-1: The geometrical isomers of the complex `[M(NH_(4))_(4)Cl_(2)]` are optically inactive, and Statement-2: Both geometrical isomers of the c

Last Answer : Statement-1: The geometrical isomers of the complex `[M(NH_(4))_(4)Cl_(2)]` are optically inactive, ... D. Statement-1 is false, statement-2 is true.

Description : Which of the following isomerism is/are shown by the complex `[CoCl_(2)(H_(2)O)_(2)(NH_(3))_(2)]` Br ?

Last Answer : Which of the following isomerism is/are shown by the complex `[CoCl_(2)(H_(2)O)_(2)(NH_(3)) ... ? A. Ionization B. Linkage C. Geometrical D. optical

Description : The complex `[Pt(NH_(3))_(4)]^(2+)` has ………. Structure :

Last Answer : The complex `[Pt(NH_(3))_(4)]^(2+)` has ………. Structure : A. square planar B. tetrahedral C. pyramidal D. pentagonal

Description : Describe the shape and magnetic behaviour of following complexes : (i) [CO(NH3)6]3+ (ii) [Ni(CN)4]2- (At. No. Co = 27, Ni = 28) -Chemistry

Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-

Description : Oxidation state of cobalt in `[Co(NH_(3))_(4)(H_(2)O)Cl]SO_(4)` is

Last Answer : Oxidation state of cobalt in `[Co(NH_(3))_(4)(H_(2)O)Cl]SO_(4)` is

Description : `underset("Brown")([(NH_(3))_(5)Co-O-O-Co(NH_(3))_(5)]^(4+)) underset("oxidise")overset([S_(2)O_(8)]^(2-))tounderset("Green")([(NH_(3))_(5)Co-O-O-Co(N

Last Answer : `underset("Brown")([(NH_(3))_(5)Co-O-O-Co(NH_(3))_(5)]^(4+)) underset("oxidise")overset([S_(2)O_(8) ... III " "IV" & "III" "III),("brown "" green"):}`

Description : IUPAC name of `|Co(ONO)(NH_(3))_(5)Cl_(2)|` is

Last Answer : IUPAC name of `|Co(ONO)(NH_(3))_(5)Cl_(2)|` is A. ... pentamminenitritocobalt(III)chloride D. pentammineoxo-nitrocobalt(III)chloride

Description : The type of isomerism that `Co(NH_(3))_(4)Br_(2)Cl_(2)` can exhibit is/are

Last Answer : The type of isomerism that `Co(NH_(3))_(4)Br_(2)Cl_(2)` can exhibit is/are A. ... C. Optical and ionisation D. Optical, ionisation and geometric

Description : Consider the following reaction and statements: `[Co(NH_(3))_(4)Br_(2)]^(+)+Br^(-) to [Co(NH_(3))_(3)Br_(3)]+NH_(3)` Two isomers are produced if the r

Last Answer : Consider the following reaction and statements: `[Co(NH_(3))_(4)Br_(2)]^(+)+Br^(-) to [Co(NH_(3))_(3) ... II B. III and IV C. I and IV D. II and III

Description : Which kind of isomerism is shown by `Co (NH_(3))_(4) Br_(2) Cl` ?

Last Answer : Which kind of isomerism is shown by `Co (NH_(3))_(4) Br_(2) Cl` ? A. ... Optical and ionization C. Gometrical and optical D. Geometrical only

Description : Co-ordination compounds `[Pt(NH_(3))_(3)(NCS)]` and `[Pt(NH_(3))_(2) Cl_(2)]Cl` are example of ........ Isomerism

Last Answer : Co-ordination compounds `[Pt(NH_(3))_(3)(NCS)]` and `[Pt(NH_(3))_(2) Cl_(2) ... isomerism B. linkage isomers C. optical isomerism D. hydrate isomerism

Description : Cosider the following reaction and statements: `[Co(NH_(3))_(4)Br]^(+)+Br^(-) to [Co(NH_(3))_(3)Br]+NH_(3)` (I) Two isomers are produced if the reacta

Last Answer : Cosider the following reaction and statements: `[Co(NH_(3))_(4)Br]^(+)+Br^(-) to [Co(NH_(3))_(3)Br]+NH_(3) ... (IV) C. (I) and (III) D. (I) and (III)