Description : Pi bonds are formed by the overlap of: w) unhybridized p orbitals x) sp2 hybridized orbitals y) sp hybridized orbitals z) unhybridized s orbitals
Last Answer : ANSWER: W -- UNHYBRIDIZED P ORBITALS
Description : Which of the following is not characteristic of a p bond? (a) A p bond results from lateral overlap of atomic orbitals (b) A p bond may be formed by the overlap of p - or d - orbitals (c) p bonds are obtained from hybrid orbitals (d) p bonds is formed when a bond already exists
Last Answer : Ans:(c)
Description : The delocalized π system in benzene is formed by a cyclic overlap of 6 orbitals. (a) s (b) p (c) sp (d) sp2
Last Answer : p
Description : The N–H bond in the ammonium ion, NH4+, is formed by the overlap of what two orbitals? (a) sp3–sp3 (b) sp3–sp2 (c) sp2–sp2 (d) sp3–s
Last Answer : sp3–s
Description : What two atomic orbitals or hybrid atomic orbitals overlap to form the carbon-carbon σ bond in ethyne? (a) sp3–sp3 (b) sp2–sp2 (c) s–s (d) sp–sp
Last Answer : sp–sp
Description : What orbitals overlap to create the H–C bond in CH3+? (a) sp3–sp3 (b) sp2–sp3 (c) s–p (d) s–sp2
Last Answer : s–sp2
Description : Hyperconjugation involves overlap of which of the following orbitals?
Last Answer : Hyperconjugation involves overlap of which of the following orbitals? A. `sigma-sigma` B. `sigma-p` C. `p-p` D. `pi-pi`
Description : The number of `pi` molecular orbitals completely filled in the ground state of benzene is :
Last Answer : The number of `pi` molecular orbitals completely filled in the ground state of benzene is : A. three B. one C. six D. none
Description : How many p orbitals result when delocalized and pi orbitals form?
Last Answer : Need answer
Description : An inert element has electron shells that a. Overlap The Shells Of Other Atoms. b. Are Completely Filled With Electrons. c. Yield Hydrogen Ions. d. Form Covalent Bonds.
Last Answer : b. Are Completely Filled With Electrons.
Description : The higher reactivity of an alkene or alkyne, as compared to an alkane, is due to (a) sigma bonds (b) pi bonds (c) hydrogen bonds (d) None of these
Last Answer : pi bonds
Description : Which of the following statements is not true about propyne, HC–C≡CH3? (a) It contains six sigma bonds. (b) It contains three pi bonds. (c) The H–C–H bond angle is about 109.5°. (d) The C–C–C bond angle is 180°.
Last Answer : It contains three pi bonds
Description : Which of the following describes a triple bond? (a) two sigma bonds and two pi bonds (b) one sigma bond and one pi bond (c) two sigma bonds and one pi bond (d) one sigma bond and two pi bonds
Last Answer : one sigma bond and two pi bonds
Description : A triple bond consists of (a) 2 sigma bonds and 1 pi bond (b) 3 sigma bonds (c) 1 sigma bond and 2 pi bonds (d) 3 pi bonds
Last Answer : 1 sigma bond and 2 pi bonds
Description : A triple bond consists of how many pi bonds and how many sigma bonds?
Last Answer : ANSWER: ONE SIGMA BOND AND TWO PI BONDS
Description : A triple bond consists of: w) three sigma bonds x) three pi bonds y) two sigma bonds and one pi bond z) one sigma bond and two pi bonds
Last Answer : ANSWER: Z -- ONE SIGMA BOND AND TWO PI BONDS
Description : Which of the following molecules has both `p_(pi)-p_(pi) and p_(pi)-d_(pi)` bonds
Last Answer : Which of the following molecules has both `p_(pi)-p_(pi) and p_(pi)-d_(pi)` bonds A. `XeO_(2)F_(2)` B. `SO_(2)Cl_(2)` C. `SO_(3)` D. `XeO_(3)`
Description : The number of `pi` bonds in perxenate ion is :
Last Answer : The number of `pi` bonds in perxenate ion is :
Description : The compound in which the number of `d pi - p pi` bonds are equal to those present in `ClO_(4)` -
Last Answer : The compound in which the number of `d pi - p pi` bonds are equal to those present in `ClO_(4)` - A. `XeF_(4)` B. `XeO_(3)` C. `XeO_(4)` D. `XeF_(6)`
Description : The nature of `pi` - bonds in `XeO_(3)` :
Last Answer : The nature of `pi` - bonds in `XeO_(3)` : A. two `(p pi- p pi)` and one `(p pi- d pi)` B. one `(p ... C. three `(p pi- d pi)` D. three `(p pi- p pi)`
Description : Identify the correct sequence of increasing of `pi-` bonds in the structure of the following molecules `:` `(I)H_(2)S_(2)O_(6)" "(II)H_(2)S_(2)O_(3)"
Last Answer : Identify the correct sequence of increasing of `pi-` bonds in the structure of the following molecules `:` `(I)H_(2) ... I C. II, I, III D. I, III,II
Description : Which of the following has more number of `p pi-dpi` bonds?(all central atoms are in excited states)
Last Answer : Which of the following has more number of `p pi-dpi` bonds?(all central atoms are in excited states) A. `SO_(2)` B ... `SO_(3)^(2-)` D. `CO_(3)^(2-)`
Description : What is the number of sigma `(sigma)` and pi `(pi)` bonds present in sulphuric acid molecule ?
Last Answer : What is the number of sigma `(sigma)` and pi `(pi)` bonds present in sulphuric acid molecule ? A. 6 `sigma` ... ` and 4 `pi` D. 2 `sigma` and 2 `pi`
Description : In `SO_(2)` two oxygen atoms are linked to the sulpher atom through double bonds. The two `pi` bonds are
Last Answer : In `SO_(2)` two oxygen atoms are linked to the sulpher atom through double bonds. The two `pi` bonds are A. ... (pi)-p_(pi)` and one `p_(pi)-p_(pi)`
Description : Statement-I : Elements of oxygen family are not capable of forming `p pi-p pi` bonds with other elements of smaller size like C, N ets Statement-II :
Last Answer : Statement-I : Elements of oxygen family are not capable of forming `p pi-p pi` bonds with ... Statement-I is not correct and Statement-II is correct
Last Answer : Identify the correct sequence of increasing of `pi-` bonds in the structure of the following molecules `:` `(I)H_(2) ... i C. ii, I, iii D. I, iii, ii
Description : Which of the following contains `p pi-dpi` bonds
Last Answer : Which of the following contains `p pi-dpi` bonds A. `NO_(2)` B. `SO_(3)` C. `SO_(2)` D. Both 2 and 3
Description : How many sigma and pi bonds are there in a triple bond?
Last Answer : 1 sigma, 2 pi bonds in a triple bond.
Description : How many sigma and pi bonds are present in nitrogen formula ?
Last Answer : Each nitrogen molecule contain one sigma and 2 Pi bonds
Description : In double bond, how many sigma and Pi bonds are present in it ?
Last Answer : Double bond = 1 Sigma bond and one Pi bond Among sigma and Pi bonds which is the stronger one Sigma bond is Stronger than pi bond
Description : How does covalent bond form in terms of orbital overlap concept?
Last Answer : Ans. When two half filled orbitals overlap ,covalent bond forms .
Description : Which of the following statements is correct for a saturated alkyl halide? (a) the C-X bond results from overlap of the s orbital of carbon and the p orbital of the halogen (X) (b) the C-X bond ... the C-X bond results from overlap of the sp2 orbital of carbon and the p orbital of the halogen (X)
Last Answer : the C–X bond results from overlap of the sp3 orbital of carbon and the p orbital of the halogen (X)
Description : Compare the following complexes’ with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : (i) [Ni(CN)4]2- (ii) [NiCl4]2- (iii) [CoF6]3- [At. Nos. : Ni = 28; Co = 27] -Chemistry
Last Answer : (i) [Ni(CN)4]2- Shape : Octahedral outer orbital complex Hybridisation : sp3d2 Magnetic behaviour : Paramagnetic (4 unpaired electrons)
Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.
Description : Compare the following complexes with respect to their shape, magnetic behaviour and the hybrid orbitals involved : (i) [CoF4]2- (ii) [Cr(H2O)2(C2O4)2]– (iii) [Ni(CO)4] (Atomic number : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [COF4]2_ : Tetrafluorido cobalt (III) ion Coordination number = 4 Shape = Tetrahedral Hybridisation = sp3 Important Questions for Class 12 Chemistry Chapter 9 Coordination Compounds Class 12 Important Questions 7
Description : For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify (i) the oxidation number of iron, (ii) the hybrid orbitals and the shape of the complex, (iii) the magnetic behaviour of the complex, (iv) ... an optical isomer also, and (vi) name of the complex. (At. no. of Fe = 26) \ -Chemistry
Last Answer : i) [Fe(en)2Cl2] Cl or x + 0 + 2 (-1) + (-1) = 0 x + (- 3) = 0 or x = + 3 ∴ Oxidation number of iron, x = + 3 (ii) The complex has two bidentate ligands and two ... )2Cl2] Cl, only cis-isomer shows optical isomerism. (vi) Name of complex: Dichloridobis (ethane-1, 2- diamine) Iron (III) chloride
Description : The high reactivity of fluorine is due to (1) small size of fluorine atom (2) its high electro negativity (3) availability of d-orbitals (4) strong F - F bond
Last Answer : (2) its high electro negativity Explanation: The high reactivity of fluorine is due to its high electro negativity.
Description : Give conditions for the combination of Atomic Orbitals
Last Answer : Ans i).The combining atomic orbitals must have the same or nearly the same energy ii).The combining atomic orbitals must have the same symmetry about the molecular axis iii) The combining atomic orbitals must overlap to the maximum extent
Description : What is Aufbau’s principle? How it helps to fill electrons in an atom in different orbitals?
Last Answer : Ans Electrons are filled in orbitals of an atom according to increasing energies which is in accordance to (n+l) values of electrons. If (n+l )values are same the electron goes to orbital having lower value of n.
Description : Explain why half-filled orbitals have extra stability.
Last Answer : Ans. It has symmetrical electron density as well as greater exchange energy.
Description : “In reality all the s-orbitals are spherically symmetric.” What does this represent?
Last Answer : Ans. The probable density of an electron in s-orbital is equally distributed at all coordinates in space.
Description : Where are the two lone pairs of electrons of the oxygen atom in an alcohol molecule located? (a) in two p orbitals (b) in two sp orbitals (c) in two sp2 orbitals (d) in two sp3 orbitals
Last Answer : in two sp3 orbitals
Description : The bond angles associated with the hybrid orbitals of a carbon involved in a triple bond is (a) 180° (b) 120° (c) 109° (d) 45
Last Answer : 180
Description : Which of the following statements is correct regarding nucleophiles? (a) They have an overall positive charge (b) They have a lone-pair of electrons (c) They have an unpaired electron (d) They have empty orbitals
Last Answer : (b) They have a lone-pair of electrons
Description : What is bond angle between the hybrid orbitals in methane? (a) 180° (b) 120° (c) 109.5° (d) 115.5°
Last Answer : 109.5°
Description : Compound in which carbons use only sp3 hybrid orbitals for bond formation is (a) CH3CH2CH3 (b) CH3C≡CH (c) CH3CH=CH2 (d) CH2=CH—CH=CH2
Last Answer : CH3CH2CH3
Description : The catalytic activity of transition metals and their compounds is ascribed mainly to (1) their chemical reactivity (2) their magnetic behaviour (3) their unfilled d-orbitals (4) their ability to adopt variable oxidation states
Last Answer : (4) their ability to adopt variable oxidation states
Description : The order of energy level of molecular orbitals in H3 species in a. 1σ < 2σ = 3σ b. 1σ >2σ = 3σ c. 1σ =2σ < 3σ d. 1σ < 2σ < 3σ
Last Answer : d. 1σ < 2σ < 3σ
Description : The nuclei of heavy atoms generally contain: w) more electrons than neutrons x) more protons than electrons y) more neutrons than electrons z) more orbitals than electrons
Last Answer : ANSWER: Y -- MORE NEUTRONS THAN ELECTRONS