For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify (i) the oxidation number of iron, (ii) the hybrid orbitals and the shape of the complex, (iii) the magnetic behaviour of the complex, (iv) the number of geometrical isomers, (v) whether there is an optical isomer also, and (vi) name of the complex. (At. no. of Fe = 26) \ -Chemistry

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Answer :

i) [Fe(en)2Cl2] Cl or x + 0 + 2 (-1) + (-1) = 0 x + (- 3) = 0 or x = + 3 ∴ Oxidation number of iron, x = + 3 (ii) The complex has two bidentate ligands and two monodentate ligands. Therefore, the coordination number is 6 and hybridization will be d2sp3 and shape will be octahedral. (iii) In the complex 26Fe3+ = 3d5 4s0 4p0 Due to presence of one unpaired electrons in d orbitals the complex is paramagnetic. The number of geometrical isomers are two. (v) In coordination complex of [Fe(en)2Cl2] Cl, only cis-isomer shows optical isomerism. (vi) Name of complex: Dichloridobis (ethane-1, 2- diamine) Iron (III) chloride

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