Description : Which of the following compounds will react most readily with bromine in CCl4? (a) CH3CH2CH3 (b) (CH3)3CH (c) CH3CH=CH2 (d) (CH3)4C
Last Answer : CH3CH=CH2
Description : What two atomic orbitals or hybrid atomic orbitals overlap to form the carbon-carbon σ bond in ethyne? (a) sp3–sp3 (b) sp2–sp2 (c) s–s (d) sp–sp
Last Answer : sp–sp
Description : What bond angle is associated with sp3 (read: S - P - hybrid orbitals?
Last Answer : ANSWER: 109.5 DEGREES
Description : Which of the following statements about propene, CH3CH=CH2, is correct? (a) All nine atoms lie in the same plane. (b) The compound has a cis and trans isomer. (c) There is a total of eight sigma bonds. (d) All the carbon atoms are sp2 hybridized
Last Answer : There is a total of eight sigma bonds.
Description : For which molecule can the bonding be described in terms of sp3 hybrid orbitals of the central atom? w) CH4 x) SF6 y) BF3 z) PCL5
Last Answer : ANSWER: B -- CH4
Description : The N–H bond in the ammonium ion, NH4+, is formed by the overlap of what two orbitals? (a) sp3–sp3 (b) sp3–sp2 (c) sp2–sp2 (d) sp3–s
Last Answer : sp3–s
Description : What orbitals overlap to create the H–C bond in CH3+? (a) sp3–sp3 (b) sp2–sp3 (c) s–p (d) s–sp2
Last Answer : s–sp2
Description : Which of the following compounds show geometrical isomerism (a) (CH3)3N (b) CH3CH=CH2 (c) (CH3)2NH (d) CH3CH=CHCH
Last Answer : CH3CH=CHCH
Description : sp3 Why is the angle between hybrid orbitals 109 degrees 26 ' ?
Last Answer : : A s orbital and three p orbitals of the conjugate layer overlap and form a sp3 hybrid orbital. The balanced sp3 orbital is directed along the four angles of any regular tetrahedron. And between the orbitals the angle 109 ৮ 26 ' is present and the structure is quadratic.
Description : Which of the following terms best describes the compound below? CH3(CH2)7CH=CH(CH2)7CO2H (a) an unsaturated fatty acid (b) a triglyceride (c) a synthetic detergent (d) a micelle
Last Answer : an unsaturated fatty acid
Description : Compound (A) reacts with sodium metal to form one mole of H2. The compound (A) can be (a) CH3CH2CH=CH2 (b) HOCH2CH2CH2CH2OH (c) CH=CH–CH=CH2 (d) CH3CH2CH2CH2OH
Last Answer : HOCH2CH2CH2CH2OH
Description : The compound having the formula H2N—CO—NH—CH2—CH2—CH2—CH— COOH is | NH2 (A) Lysine (B) Glutamine (C) Serine (D) Citrulline
Last Answer : Answer : D
Description : The bond angles associated with the hybrid orbitals of a carbon involved in a triple bond is (a) 180° (b) 120° (c) 109° (d) 45
Last Answer : 180
Description : What is bond angle between the hybrid orbitals in methane? (a) 180° (b) 120° (c) 109.5° (d) 115.5°
Last Answer : 109.5°
Description : What bond angle is associated with sp hybrid orbitals
Last Answer : ANSWER: 180 DEGREES
Description : Where are the two lone pairs of electrons of the oxygen atom in an alcohol molecule located? (a) in two p orbitals (b) in two sp orbitals (c) in two sp2 orbitals (d) in two sp3 orbitals
Last Answer : in two sp3 orbitals
Description : Which of following statements is false about propane? (a) all bond angles are 109.5° (b) each carbon is sp3 hybridized (c) the compound is combustible (d) the compound undergoes polymerization to give polypropylene.
Last Answer : the compound undergoes polymerization to give polypropylene.
Description : Is (CH2 — CH — C6H5 ) n a homo polymer or a copolymer.
Last Answer : Ans. It is a homo polymer and the monomer from which it is obtained in styrene C6H5 CH = CH2 .
Description : Which of the following compounds would react most rapidly in an SN2 reaction? (a) CH3CH2I (b) CH2=CH–I (c) (CH3)2CHI (d) (CH3)3CI
Last Answer : CH3CH2I
Description : How many σ (sigma) bonds are there in CH2=CH—CH=CH2? (a) 3 (b) 6 (c) 9 (d) 12
Last Answer : 9
Description : Two hybrid orbitals have a bond angle of `120^(@)`. The percentage of p character in the hybrid orbital is nearly :-
Last Answer : Two hybrid orbitals have a bond angle of `120^(@)`. The percentage of p character in the hybrid orbital is nearly ... 25%` B. `33%` C. `50%` D. `66%`
Description : Which of the following is not characteristic of a p bond? (a) A p bond results from lateral overlap of atomic orbitals (b) A p bond may be formed by the overlap of p - or d - orbitals (c) p bonds are obtained from hybrid orbitals (d) p bonds is formed when a bond already exists
Last Answer : Ans:(c)
Description : Which compound has the highest boiling point? 1. CH3CH2CH3 2. CH3CH2OH 3. CH3CH2NH2 (a) 1 (b) 2 (c) 3 (d) 2 and 3 have similar boiling points
Last Answer : 2
Description : The compound with the lowest boiling point is (a) H2O (b) CH3CH2OH (c) CH3OCH3 (d) CH3CH2CH3
Last Answer : CH3CH2CH3
Description : Cysteine has the formula: (A) CH3SH (B) H2N—CH2—COOH (C) HS—CH2—CH(NH2)—COOH (D) S—CH2—CH(NH2)—COOH | S—CH2—CH(NH2)—COOH
Last Answer : Answer : C
Description : The figure shows a hypothetical tetrapeptide portion of a protein with parts labelled A-D. Which one of the following options is correct? - HN - CH - CO - NH - CH - CO - NH - CH - CO - ... -terminal amino acid and D is N-terminal amino acid. (d) A is a sulphur containing amino acid methionine.
Last Answer : (a) D is the acidic amino acid-glutamic acid.
Description : Vinyl chloride (CH2 = CH.Cl) is produced by the thermal pyrolysis of ethylene dichloride at a pressure & temperature of (A) 4 kgf/cm2 & 500°C (B) 10 kgf/cm2 & 1000°C (C) 40 kg/cm2 & 200°C (D) 100 kgf/cm2 & 500°C
Last Answer : (A) 4 kgf/cm2 & 500°C
Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane
Last Answer : Benzene
Description : What is the name given to a compound containing only carbons and hydrogens and having the maximum number of hydrogens in the molecule? (a) alkene (b) unsaturated hydrocarbon (c) saturated hydrocarbon (d) alkyne
Last Answer : saturated hydrocarbon
Description : Pyridine is less basic than trimethylamine because the lone-pair of electrons on N-atom in pyridine resides in (a) sp2 hybrid orbital (b) sp hybrid orbital (c) sp3 hybrid orbital (d) p-orbital
Last Answer : sp2 hybrid orbita
Description : Which of the following hydrocarbons has the shortest C–C bond length? (a) CH2=CH2 (b) CH3CH3 (c) HC≡CH
Last Answer : HC≡CH
Description : The decreasing order of bond dissociation energy of C-H bond in given compound is :- (A) `CH_(3)-H` (B) `CH_(3)-CH_(2)-H` `CH_(2)=CH-CH_(2)-H` (D)
Last Answer : The decreasing order of bond dissociation energy of C-H bond in given compound is :- (A) `CH_(3)-H` (B) `CH_(3)- ... gt B gt A` D. `C gt B gt A gt D`
Description : Which of the following statements about benzene is correct? (a) All of the carbon atoms are sp3 hybridized. (b) It has no delocalized electrons. (c) The carbon-carbon bond length is longer than that of ethane. (d) It is a planar molecule.
Last Answer : It is a planar molecule.
Description : Triethylamine [(CH3CH2)3N] is a molecule in which the nitrogen atom is __________ hybridized and the CNC bond angle is __________. (a) sp2; >109.5° (b) sp2; 109.5° (d) sp3;
Last Answer : sp3;
Description : Which of the following statements is correct for a saturated alkyl halide? (a) the C-X bond results from overlap of the s orbital of carbon and the p orbital of the halogen (X) (b) the C-X bond ... the C-X bond results from overlap of the sp2 orbital of carbon and the p orbital of the halogen (X)
Last Answer : the C–X bond results from overlap of the sp3 orbital of carbon and the p orbital of the halogen (X)
Description : The carbon atoms involved in the double bond of an alkene are (a) sp hybridized (b) sp2 hybridized (c) sp3 hybridized (d) None of these
Last Answer : sp2 hybridized
Description : What is the predicted shape, bond angle, and hybridization for CH3+? (a) trigonal planar, 120°, sp2 (b) trigonal planar, 120°, sp3 (c) trigonal planar, 109.5°, sp2 (d) trigonal pyramidal, 120°, sp2
Last Answer : trigonal planar, 120°, sp2
Description : A meso compound : (a) is an achiral molecule which contains chiral carbons (b) contains a plane of symmetry or a centre of symmetry (c) is optically inactive (d) is characterized by all of the above
Last Answer : ) is characterized by all of the above
Description : An optically active compound (a) must contain atleast four carbons (b) when in solution rotate the plane of polarized light (c) must always contain an asymmetric carbon atom (d) in solution always give a negative reading in polarimeter
Last Answer : when in solution rotate the plane of polarized light
Description : Compare the following complexes’ with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : (i) [Ni(CN)4]2- (ii) [NiCl4]2- (iii) [CoF6]3- [At. Nos. : Ni = 28; Co = 27] -Chemistry
Last Answer : (i) [Ni(CN)4]2- Shape : Octahedral outer orbital complex Hybridisation : sp3d2 Magnetic behaviour : Paramagnetic (4 unpaired electrons)
Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.
Description : Compare the following complexes with respect to their shape, magnetic behaviour and the hybrid orbitals involved : (i) [CoF4]2- (ii) [Cr(H2O)2(C2O4)2]– (iii) [Ni(CO)4] (Atomic number : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [COF4]2_ : Tetrafluorido cobalt (III) ion Coordination number = 4 Shape = Tetrahedral Hybridisation = sp3 Important Questions for Class 12 Chemistry Chapter 9 Coordination Compounds Class 12 Important Questions 7
Description : For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify (i) the oxidation number of iron, (ii) the hybrid orbitals and the shape of the complex, (iii) the magnetic behaviour of the complex, (iv) ... an optical isomer also, and (vi) name of the complex. (At. no. of Fe = 26) \ -Chemistry
Last Answer : i) [Fe(en)2Cl2] Cl or x + 0 + 2 (-1) + (-1) = 0 x + (- 3) = 0 or x = + 3 ∴ Oxidation number of iron, x = + 3 (ii) The complex has two bidentate ligands and two ... )2Cl2] Cl, only cis-isomer shows optical isomerism. (vi) Name of complex: Dichloridobis (ethane-1, 2- diamine) Iron (III) chloride
Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.
Last Answer : The addition product is a frequently observed minor product.
Description : Which of the following terms best describes the compound below? CH3(CH2)26CO2CH2(CH2)32CH3 (a) a fat (b) a wax (c) a terpene (d) an unsaturated triglyceride
Last Answer : a wax
Description : Which of the following terms best describes the compound below? CH3(CH2)12CO2H (a) a fatty acid (b) an oil (c) a wax (d) a soap
Last Answer : a fatty acid
Description : Propadiene, CH2=C=CH2, is (a) a planar compound (b) a cumulated diene (c) an isolated diene (d) a conjugated diene
Last Answer : a cumulated diene
Description : Which of the following is the best description of propane, CH3CH2CH3, at room temperature? (a) liquid, soluble in H2O (b) gas, soluble in gasoline (c) liquid, soluble in gasoline (d) gas, soluble in water
Last Answer : gas, soluble in gasoline
Description : The high reactivity of fluorine is due to (1) small size of fluorine atom (2) its high electro negativity (3) availability of d-orbitals (4) strong F - F bond
Last Answer : (2) its high electro negativity Explanation: The high reactivity of fluorine is due to its high electro negativity.