Description : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism?
Last Answer : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism? A. `CH_(3)Cl` B. `CH_(3)CH_(2)Cl` ... (2)CH_(2)Cl` D. `(CH_(3))_(3)"CCl"`
Description : The correct increasing order of the reactivity of halides for `S_(N^(1))` reaction is:
Last Answer : The correct increasing order of the reactivity of halides for `S_(N^(1))` reaction is: A. `CH_(3)CH_(2)-Xlt( ... -Xlt(CH_(3))_(2)CH-XltCH_(3)CH_(2)-X`
Description : Which of the following halides will be most reactive towards `S_(N^(2))` reaction?
Last Answer : Which of the following halides will be most reactive towards `S_(N^(2))` reaction? A. `C_(6)H_(5)CH_(2 ... (2)-underset(Br)underset("| ")"CH"-CH_(3)`
Description : The `S_(N^(1))` reactivity of the following halides will be in the order: (i) `(CH_(3))_(3)C-Br` (ii) `(C_(6)H_(5))CHBr` (iii) `(C_(6)H_(5))_(2)C(CH_(
Last Answer : The `S_(N^(1))` reactivity of the following halides will be in the order: (i) `(CH_(3))_(3)C-Br` (ii) `(C_ ... D. (iii) gt (ii) gt (i) gt (iv) gt (v)
Description : Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides
Last Answer : Alkoxyalkanes
Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides
Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides
Description : `S_(N^(1))` mechanism for the hydrolysis of an alkyl halide involves the formation of intermediate:
Last Answer : `S_(N^(1))` mechanism for the hydrolysis of an alkyl halide involves the formation of intermediate: ... B. carbocation C. carbanion D. none of these
Description : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is
Last Answer : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in ... reaction D. Reaction with `NH_(3)`
Description : Why the presence of a base is essential in the ammonolysis of alkyl halides ?
Last Answer : During ammonolysis of alkyl halides, the acid liberated during the reaction combines with the amine formed to form amine salt. To liberate free amine from the amine salt, a base is needed.
Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form
Last Answer : primary amines form
Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism
Last Answer : Resonance stabilization
Description : Alkyl halides react with ammonia in the presence of base to form : (a) primary amines (b) nitrated alkyl halides (c) amides (d) quaternary ammonium salts
Last Answer : primary amines
Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)
Last Answer : (a) and (b)
Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F
Last Answer : CH3CH2I
Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions
Last Answer : Nucleophilic substitution reactions
Description : Arrange the following in order of decreasing tendency towards `S_(N^(2))` reaction : `{:(underset("(I)")(CH_(3)CH_(2)CH_(2)CH_(2)Cl)", "underset("(II)
Last Answer : Arrange the following in order of decreasing tendency towards `S_(N^(2))` reaction : `{: ... `IIIgtIVgtIIgtI` C. `IgtIIIgtIIgtIV` D. `IIgtIgtIIIgtIV`
Description : (A) `S_(N^(2))` reactioin takes place in single step. (R) `S_(N^(2))` reaction involves transition state intermediate.
Last Answer : (A) `S_(N^(2))` reactioin takes place in single step. (R) `S_(N^(2))` reaction involves transition ... . D. IF (A) is incorrect but (R) is correct.
Description : Which of the following are correct for `S_(N^(2))` reaction?
Last Answer : Which of the following are correct for `S_(N^(2))` reaction? A. The reaction intermediate ... solvents D. It is favoured by stability of carbocation
Description : KI in acetone, undergoes `S_(N)2` reaction with each of `P,Q ,R` and S The rates of the reaction very as `underset(P)(H_(3)C-Cl)` .
Last Answer : KI in acetone, undergoes `S_(N)2` reaction with each of `P,Q ,R` and S The rates of the reaction very as ` ... R gt Q gt S D. R gt P gt S gt Q
Description : In a `S_(N^(2))` substitution reaction of the type `R-Br+Cl^(-)overset("DMF")rarrR-Cl+Br^(-)` Which one of the following has the highest relative rate
Last Answer : In a `S_(N^(2))` substitution reaction of the type `R-Br+Cl^(-)overset("DMF")rarrR-Cl+Br^(-)` Which one of ... CH_(2)Br` D. `(CH_(3))_(2)CH-CH_(2)Br`
Description : Which one is most reactive towards `S_(N^(1))` reaction?
Last Answer : Which one is most reactive towards `S_(N^(1))` reaction? A. `C_(6)H_(5)CH(C_(6)H_(5))Br` B. `C_(6)H_(5) ... H_(5)CH(CH_(3))Br` D. `C_(6)H_(5)CH_(2)Br`
Description : In the `S_(N^(1))` reaction on chiral centres there is :
Last Answer : In the `S_(N^(1))` reaction on chiral centres there is : A. `100%` racemization B. ... partial racemization C. `100%` retention D. `100%` inversion
Description : As `S_(N^(2))` reaction at an asymmetric carbon of a compound always gives:
Last Answer : As `S_(N^(2))` reaction at an asymmetric carbon of a compound always gives: A. an ... C. a mixture of diastereomers D. a single stereoisomer
Description : Which of the following reactions is an example of `S_(N^(2))` reaction?
Last Answer : Which of the following reactions is an example of `S_(N^(2))` reaction? A. `(CH_(3))_(3)C-Br+OH^(-) ... )CH_(2)OHunderset((-H_(2)O))rarrH_(2)C=CH_(2)`
Description : Which one of the following statements wrong about `S_(N^(2))` reaction?
Last Answer : Which one of the following statements wrong about `S_(N^(2))` reaction? A. The rate of ... The rate of reaction `prop` [substrate] [nucleophile]
Description : Which of the following is the correct order of decreasing `S_(N^(2))` reactivity ?
Last Answer : Which of the following is the correct order of decreasing `S_(N^(2))` reactivity ? A. `R_(2)CHXgtR_(3) ... 3)CXgtR_(2)CHXgtRCH_(2)X("X is a halogen")`
Description : Consider the following bromides: The correct order of `S_(N^(1))` reactivity is :
Last Answer : Consider the following bromides: The correct order of `S_(N^(1))` reactivity is : A. `IgtIIgtIII` B. `IIgtIIIgtI` C. `IIgtIgtIII` D. `IIIgtIIgtI`
Description : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC
Last Answer : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii ... (vi) `PCl_(3)` (vii) `AsCl_(3)`
Description : Which of the following halides is least reactive in an E2 reaction with sodium methoxide? (a) (CH3)3CCH2I (b) (CH3)2CHCHICH3 (c) (CH3)2CHCH2Br (d) (CH3)2CHCH2Cl
Last Answer : (CH3)3CCH2I
Description : Which of the following halides is most reactive in an E2 reaction with sodium methoxide? (a) (CH3)3CCH2I (b) (CH3)2CHCHICH3 (c) (CH3)2CHCH2Br (d) (CH3)2CHCH2C
Last Answer : (CH3)2CHCHICH3
Description : The order of stability of halides of sulphur with different halogens is
Last Answer : The order of stability of halides of sulphur with different halogens is A. `I^(-) gt Br^(-) gt Cl^(-) gt F^(-)` ... `F^(-) gt Cl^(-) gt I^(-) Br^(-)`
Description : The correct order of the thermal stability of hydrogen halides `(H-X)` is
Last Answer : The correct order of the thermal stability of hydrogen halides `(H-X)` is A. (1) HI gt HBrgt HCI gt HF B. ... HBr lt HI D. (4)Hl gt HCI lt HF lt HBr
Description : The stability of the halides of group 16 elements decreases in the order
Last Answer : The stability of the halides of group 16 elements decreases in the order A. `F gt Cl gt Br gt I` B. `Cl gt Br ... gt Cl gt F` D. `Br gt Cl gt F gt I`
Description : Assertion: Phosphorus tribromide is ofter preferred as a reagent for the transformation of an alcohol to the corresponding alkyl bromide Reason: The n
Last Answer : Assertion: Phosphorus tribromide is ofter preferred as a reagent for the transformation of an alcohol to ... D. Assertion is false, Reason is true
Description : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:-
Last Answer : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:- A. B. C. D.
Description : Compound P on treatement with `CH_(2)N_(2)` (diazomethane) produces compound Q. compound Q on reaction with Hl produces two alkyl iodides R and S . Al
Last Answer : Compound P on treatement with `CH_(2)N_(2)` (diazomethane) produces compound Q. compound Q on reaction ... 2-methyl-2-propanol D. 2-methyl-1-propanol
Description : Assertion (A): Alkyl aryl ethers on reaction with HI give alkyl iodide phenols Reason (R): Aryl - oxygen bond is weaker than alkyl oxygen bond
Last Answer : Assertion (A): Alkyl aryl ethers on reaction with HI give alkyl iodide phenols Reason (R): Aryl - oxygen ... is false D. A is false but R is true
Description : . Hunsdiecker reaction is used for the preparation of (a) Alkyl chlorides and bromides (b) Alkyl nitrates and nitrites (c) Ketenes (d) Alcohols
Last Answer : Alkyl chlorides and bromides
Description : Which reaction does not yield an ester as one of the products? (a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid
Last Answer : A Grignard reagent is added to a carboxylic acid
Description : The reaction of a sodium alkoxide with an alkyl halide is called (a) Wurtz-Fittig reaction (b) Perkin reaction (c) Williamson's synthesis (d) Aldol condensation
Last Answer : Williamson's synthesis
Description : Which is the most reactive alkyl halide in a SN1 reaction? (a) CH3F (b) CH3Br (c) CH3I (d) CH3Cl
Last Answer : CH3I
Description : Which of the following factors influence whether a reaction will proceed by an SN1, SN2, E1, or E2 mechanism? (a) Structure of the alkyl halide (b) Solvent (c) Concentration of reagents (d) Nature of the nucleophile (e) All of these
Last Answer : All of these
Description : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the carbon chain, the reagent used as sou
Last Answer : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the ... C_(6)H_(4)(CO)_(2)N^(-)K^(+)`
Description : If `alpha, beta` are roots of equation `x^(2)-4x-3=0` and `s_(n)=alpha^(n)+beta^(n), n in N` then the value of `(s_(7)-4s_(6))/s_(5)` is
Last Answer : If `alpha, beta` are roots of equation `x^(2)-4x-3=0` and `s_(n)=alpha^(n)+beta^(n), n in N` then the value ... 4s_(6))/s_(5)` is A. 4 B. 3 C. 5 D. 7
Description : Some amount of "20V" `H_(2)O_(2)` is mixed with excess of acidified solution of Kl. The iodine so liberated required 200 mL of 0.1 N `Na_(2)S_(2)O_(3)
Last Answer : Some amount of "20V" `H_(2)O_(2)` is mixed with excess of acidified solution of Kl. The iodine so liberated ... 56 mL B. 112 mL C. 168 mL D. 224 mL
Last Answer : Some amount of "20V" `H_(2)O_(2)` is mixed with excess of acidified solution of Kl. The iodine so liberated required ... . 0.8 g C. 4.2 g D. 0.98 g
Last Answer : Some amount of "20V" `H_(2)O_(2)` is mixed with excess of acidified solution of Kl. The iodine so liberated required ... 37.2 mL C. 5.6 mL D. 22.4 mL
Description : `underset("Brown")([(NH_(3))_(5)Co-O-O-Co(NH_(3))_(5)]^(4+)) underset("oxidise")overset([S_(2)O_(8)]^(2-))tounderset("Green")([(NH_(3))_(5)Co-O-O-Co(N
Last Answer : `underset("Brown")([(NH_(3))_(5)Co-O-O-Co(NH_(3))_(5)]^(4+)) underset("oxidise")overset([S_(2)O_(8) ... III " "IV" & "III" "III),("brown "" green"):}`