How do scientist make the determination that the sun's rays contain Vitamin C and E?

How do scientist make the determination that the sun's rays contain Vitamin C and E?
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Does the sun contain C and E? All I know about is D. I think it is like a precursor to D, and our bodies produce the D with the sun’s rays. Not sure how they measure. Interesting question. I do know that one cannot OD from D by being in the sun, but we can by taking vitamin D pills.
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