An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

An organic compound (A) has a molecular weight 78 and an empirical
formula CH. (A) is resistant to attack by oxidizing agents but undergoes
substitution and addition reactions. X-ray analysis shows that the distance
between adjacent carbon atoms is 1.39Å (intermediate between single and double
bond lengths). The evidence suggests that compound (A) is
(a) Benzene
(b) Cyclohexane
(c) Toluene
(d) n-Hexane
by

1 Answer

Answer :

Benzene
by

Related questions

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Description : Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Last Answer : there is delocalization of electrons

Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Description : Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Last Answer : there is delocalization of electrons

Which statement about the structure of benzene is not true? (a) The two Kekule structures of benzene are in equilibrium. (b) The carbon-carbon bond lengths in benzene are greater than the carbon-carbon double bonds in aliphatic compounds. (c) The molecular geometry of benzene is best described as planar. (d) The stability of benzene ring is much greater than the stability of 1,3,5- cycloheptatriene

Description : Which statement about the structure of benzene is not true? (a) The two Kekule structures of benzene are in equilibrium. (b) The carbon-carbon bond lengths in benzene are greater than the carbon- ... (d) The stability of benzene ring is much greater than the stability of 1,3,5- cycloheptatriene

Last Answer : The two Kekule structures of benzene are in equilibrium

Benzene reacts with H2 at 150°C at 30 atm in the presence of Ni catalyst to give (a) Cyclohexane (b) Cyclohexene (c) n-Hexane (d) No reaction occurs

Description : Benzene reacts with H2 at 150°C at 30 atm in the presence of Ni catalyst to give (a) Cyclohexane (b) Cyclohexene (c) n-Hexane (d) No reaction occurs

Last Answer : Cyclohexane

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Resorcinol on distillation with zinc dust gives (a) Benzene (b) Cyclohexane (c) Toluene (d) m-Xylene

Description : Resorcinol on distillation with zinc dust gives (a) Benzene (b) Cyclohexane (c) Toluene (d) m-Xylene

Last Answer : Benzene

What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Assertion: The O - O bond lengths in ozone molecule are intermediate between single and double bonds. Reason: `O_(3)` molecule is a resonance hybrid.

Description : Assertion: The O - O bond lengths in ozone molecule are intermediate between single and double bonds. Reason: `O_(3)` molecule is a resonance hybrid.

Last Answer : Assertion: The O - O bond lengths in ozone molecule are intermediate between single and double bonds. ... I is not correct and Statement-II is correct

Which of the following compounds undergoes nitration most readily? (a) Benzene (b) Toluene (c) Nitrobenzene (d) Benzoic acid

Description : Which of the following compounds undergoes nitration most readily? (a) Benzene (b) Toluene (c) Nitrobenzene (d) Benzoic acid

Last Answer : Toluene

The bond angle between carbon atoms in cyclohexane is (a) 60° (b) 90° (c) 109.5° (d) 120°

Description : The bond angle between carbon atoms in cyclohexane is (a) 60° (b) 90° (c) 109.5° (d) 120°

Last Answer : 109.5°

The bond angle between carbon atoms in cyclohexane is (a) 109°28' (b) 60° (c) 90° (d) 120°

Description : The bond angle between carbon atoms in cyclohexane is (a) 109°28' (b) 60° (c) 90° (d) 120°

Last Answer : 109°28'

The carbon-carbon bond lengths in rank of increasing bond length is (a) triple, double, single(b) single, double, triple(c) single, triple, double(d) triple, single, double:

Description : The carbon-carbon bond lengths in rank of increasing bond length is : (a) triple, double, single (b) single, double, triple (c) single, triple, double (d) triple, single, double

Last Answer : triple, double, single

Which of the following statements are false about benzene? (a) It is a planar molecule with bond angles 120°(b) It is immiscible with water forming the lower layer. (c) It can be converted into cyclohexane by hydrogenation at 200°C in the presence of Ni catalyst. (d) It reacts with ethyl chloride in the presence of aluminium chloride to form ethylbenzene..

Description : Which of the following statements are false about benzene? (a) It is a planar molecule with bond angles 120°. (b) It is immiscible with water forming the lower layer. (c) It can be ... Ni catalyst. (d) It reacts with ethyl chloride in the presence of aluminium chloride to form ethylbenzene.

Last Answer : It is immiscible with water forming the lower layer

Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Description : Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Last Answer : Nitrobenzene

Give the EMPIRICAL formula for the organic compound cyclopentene.

Description : Give the EMPIRICAL formula for the organic compound cyclopentene.

Last Answer : ANSWER: C5H8 

Give the empirical formula for the organic compound naphthalene?

Description : Give the empirical formula for the organic compound naphthalene?

Last Answer : ANSWER: C10H8

What is the molecular formula of a compound with an empirical formula of C2OH4 and a molar mass of 88 grams per mole?

Description : What is the molecular formula of a compound with an empirical formula of C2OH4 and a molar mass of 88 grams per mole?

Last Answer : This compound may be dioxane - C4H8O2.

Anthracene undergoes electrophilic substitution reactions mainly at (a) C-1 (b) C-2 (c) C-9 (d) C-1 and C-2

Description : Anthracene undergoes electrophilic substitution reactions mainly at (a) C-1 (b) C-2 (c) C-9 (d) C-1 and C-2

Last Answer : C-9

Compounds P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Q and S is `C_(8)H_(8)O`. Q undergoes cannizzaro reactions b

Description : Compounds P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Q and S is `C_(8)H_(8)O`. Q undergoes cannizzaro reactions b

Last Answer : Compounds P and R upon ozonolysis produce Q and S, respectively. The molecular formula of Q and S is `C_(8) ... R , respectively is (are) A. B. C. D.

What is the EMPIRICAL FORMULA for Benzene?

Description : What is the EMPIRICAL FORMULA for Benzene? 

Last Answer : ANSWER: CH

Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : (3) Elimination Explanation: Benzene can not undergo Elimination reaction.

Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Description : Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Last Answer : (2) Substitution reaction Explanation: The reaction between benzene and chlorine in the presence of a catalyst such as aluminium chloride gives Chlorobenzene. This reaction is an example of electrophilic substitution ... since one of the hydrogen atoms on the ring is replaced by a chlorine atom.

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Description : Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Last Answer : Substitution reaction

Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : Elimination

In an organic compound of molar mass `108 gm mol^-1 C, H and N` atoms are presents in `9 : 1 : 3.5` by mass. Molecular can be

Description : In an organic compound of molar mass `108 gm mol^-1 C, H and N` atoms are presents in `9 : 1 : 3.5` by mass. Molecular can be

Last Answer : In an organic compound of molar mass `108 gm mol^-1 C, H and N` atoms are presents in `9 : 1 : 3.5` by mass. ... (5)H_(6)N_(3)` D. `C_(4)H_(18)N_(3)`

Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Description : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Last Answer : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the ... D. A is incorrect but R is correct

Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.

Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Description : Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Last Answer : Benzene + Br2/FeBr3

Which of the following statements about benzene is correct? (a) All of the carbon atoms are sp3 hybridized. (b) It has no delocalized electrons. (c) The carbon-carbon bond length is longer than that of ethane. (d) It is a planar molecule.

Description : Which of the following statements about benzene is correct? (a) All of the carbon atoms are sp3 hybridized. (b) It has no delocalized electrons. (c) The carbon-carbon bond length is longer than that of ethane. (d) It is a planar molecule.

Last Answer : It is a planar molecule.

If two compounds have the same empirical formula but different molecular formula, they must have [MP PMT 1986] (A) Different percentage composition (B) Different molecular weights (C) Same viscosity (D) Same vapour density

Description : If two compounds have the same empirical formula but different molecular formula, they must have [MP PMT 1986] (A) Different percentage composition (B) Different molecular weights (C) Same viscosity (D) Same vapour density

Last Answer : (B) Different molecular weights

Which of the following solutions will follow Raoult's law most closely? (A) A solution of benzene, toluene and o-xylene (B) 35% solution of camphor in water (C) 35% solution of NH3 in water (D) A solution of polar organic compounds (not of homologue of a series)

Description : Which of the following solutions will follow Raoult's law most closely? (A) A solution of benzene, toluene and o-xylene (B) 35% solution of camphor in water (C) 35% solution of NH3 in water (D) A solution of polar organic compounds (not of homologue of a series)

Last Answer : (A) A solution of benzene, toluene and o-xylene

Which of the following statements is false about cyclohexane? (a) It is a saturated cyclic hydrocarbon (b) All C–C–C bond angles are 109°28' (c) It is very unstable, strained compound. (d) It can exist in two conformations which are designated as the boat-form and the chair-form

Description : Which of the following statements is false about cyclohexane? (a) It is a saturated cyclic hydrocarbon (b) All C–C–C bond angles are 109°28' (c) It is very unstable, strained compound. (d) It can exist in two conformations which are designated as the boat-form and the chair-form

Last Answer : It is very unstable, strained compound

Catalyst used in conversion of n-hexane into benzene in:

Description : Catalyst used in conversion of n-hexane into benzene in:

Last Answer : Catalyst used in conversion of n-hexane into benzene in: A. `AlCl_(3)` B. `SiO_(2)-Al_(2)O_(3)` C. `Cr_(r)O_(3)-Al_(2)O_(3)` D. `MnO_(2)`

Which of following statements is false about propane? (a) all bond angles are 109.5° (b) each carbon is sp3 hybridized (c) the compound is combustible (d) the compound undergoes polymerization to give polypropylene.

Description : Which of following statements is false about propane? (a) all bond angles are 109.5° (b) each carbon is sp3 hybridized (c) the compound is combustible (d) the compound undergoes polymerization to give polypropylene.

Last Answer : the compound undergoes polymerization to give polypropylene.

BHC (Benzene hexachloride) is made by the chlorination of benzene (A) Which is an addition reaction (B) Which is a substitution reaction (C) In absolute dark (D) In presence of sunlight

Description : BHC (Benzene hexachloride) is made by the chlorination of benzene (A) Which is an addition reaction (B) Which is a substitution reaction (C) In absolute dark (D) In presence of sunlight

Last Answer : (A) Which is an addition reaction

Which of the following solvents is used for the extraction of H3PO4 from CaCl2 solution during manufacture of ortho-phosphoric acid by wet process employing hydrochloric acid leaching? (A) Isopropyl alcohol (B) Butyl alcohol (C) Toluene (D) Hexane

Description : Which of the following solvents is used for the extraction of H3PO4 from CaCl2 solution during manufacture of ortho-phosphoric acid by wet process employing hydrochloric acid leaching? (A) Isopropyl alcohol (B) Butyl alcohol (C) Toluene (D) Hexane

Last Answer : (B) Butyl alcohol

Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Last Answer : nucleophilic addition; free radical addition

Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV

Description : Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV

Last Answer : I, II, and III

Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Last Answer : Nucleophilic substitution reactions

An organic compound ("X") is a disubstituted benzene containing 77.8% carbon and 7.4 % hydrogen. Heating an alkaline solution of "X" with chloroform g

Description : An organic compound ("X") is a disubstituted benzene containing 77.8% carbon and 7.4 % hydrogen. Heating an alkaline solution of "X" with chloroform g

Last Answer : An organic compound ("X") is a disubstituted benzene containing 77.8% carbon and 7.4 % hydrogen. Heating an alkaline ... "Z". "Z" is A. B. C. D.

Which of the following reactions of benzene proves the presence of three carbon-carbon double bonds in it :

Description : Which of the following reactions of benzene proves the presence of three carbon-carbon double bonds in it :

Last Answer : Which of the following reactions of benzene proves the presence of three carbon-carbon double ... of concentrated nitric acid and sulphuric acid

How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

A minimum boiling azeotrope is exemplified by (A) Toluene-benzene (B) Acetone-carbon disulphide (C) Water-isobutyl alcohol (D) None of these

Description : A minimum boiling azeotrope is exemplified by (A) Toluene-benzene (B) Acetone-carbon disulphide (C) Water-isobutyl alcohol (D) None of these

Last Answer : (B) Acetone-carbon disulphide

In the addition of HX to a double bond, the hydrogen goes to the carbon that already has more hydrogens is a statement of (a) Hund's rule (b) Markovnikov's rule (c) Huckel rule (d) Saytzeff rule

Description : In the addition of HX to a double bond, the hydrogen goes to the carbon that already has more hydrogens is a statement of (a) Hund's rule (b) Markovnikov's rule (c) Huckel rule (d) Saytzeff rule

Last Answer : Markovnikov's rule

The compound that has the least value for octane number is – (1) 2-methyl heptane (2) Iso-octane (3) 2,2-dimethyl hexane (4) n-heptane

Description : The compound that has the least value for octane number is – (1) 2-methyl heptane (2) Iso-octane (3) 2,2-dimethyl hexane (4) n-heptane

Last Answer : (4) n-heptane Explanation: Octane rating or octane number is a standard measure of the performance of a motor or aviation fuel. The higher the octane number, the more compression the fuel can withstand. Isooctane (upper) has an octane rating of 100 whereas n-heptane has an octane rating of O.

The compound that has the least value for octane number is : (1) 2-methyl heptane (2) Iso-octane (3) 2,2-dimethyl hexane (4) n-heptane

Description : The compound that has the least value for octane number is : (1) 2-methyl heptane (2) Iso-octane (3) 2,2-dimethyl hexane (4) n-heptane

Last Answer : n-heptane