A liquid decomposes by irreversible first order kinetics and the half life period of this reaction is 8 minutes. The time required for 75% conversion of the liquid will be __________ minutes. (A) 4 (B) 8 (C) 12 (D) 16

A liquid decomposes by irreversible first order kinetics and the half life
period of this reaction is 8 minutes. The time required for 75% conversion
of the liquid will be __________ minutes.
(A) 4
(B) 8
(C) 12
(D) 16
by

1 Answer

Answer :

(D) 16
by

Related questions

Half life period of decomposition of a liquid 'A' by irreversible first order reaction is 12 minutes. The time required for 75% conversion of 'A' is __________ minutes. (A) 18 (B) 24 (C) 6 (D) 12

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Last Answer : (B) 24

Time required for 50% decomposition of a liquid in an isothermal batch reactor following first order kinetics is 2 minutes. The time required for 75% decomposition will be about __________ minutes. (A) 3 (B) 4 (C) 6 (D) 10

Description : Time required for 50% decomposition of a liquid in an isothermal batch reactor following first order kinetics is 2 minutes. The time required for 75% decomposition will be about __________ minutes. (A) 3 (B) 4 (C) 6 (D) 10

Last Answer : (B) 4

. A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two reactors. (A) Both conversion as well as concentration are same (B) Conversion in both will be the same but concentrations will be different (C) Both the conversion as well as concentrations will be different (D) None of these

Description : . A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two ... be different (C) Both the conversion as well as concentrations will be different (D) None of these

Last Answer : (B) Conversion in both will be the same but concentrations will be different

An irreversible first order reaction is being carried out in a CSTR and PFR of same volume. The liquid flow rates are same. The relative conversion will (A) Be more in CSTR than in PFR (B) Be more in PFR than in CSTR (C) Be same in both cases (D) Depend on the temperature

Description : An irreversible first order reaction is being carried out in a CSTR and PFR of same volume. The liquid flow rates are same. The relative conversion will (A) Be more in CSTR than in PFR (B) Be more in PFR than in CSTR (C) Be same in both cases (D) Depend on the temperature

Last Answer : (B) Be more in PFR than in CSTR

For the liquid phase zero order irreversible reaction A → B, the conversion of A in a CSTR is found to be 0.3 at a space velocity of 0.1min -1 . What will be the conversion for a PFR with a space velocity of 0.2 min -1? Assume that all the other operating conditions are the same for CSTR and PFR. (A) 0.15(B) 0.30 (C) 0.60 (D) 0.90

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Last Answer : (C) 0.60

Half life period of a first order irreversible reaction A → B is (A) k/2 (B) ln k/2 (C) ln 2/k (D) ln 0.5/k

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Last Answer : (C) ln 2/k

Though kinetics of ammonia synthesis dictates the use of low temperature for high equilibrium conversion, yet it is kept moderately high (550°C), because at low temperature (A) Rate of reaction is very low (B) Very high pressure is required resulting in costly pressure vessel (C) Space velocity of gas is very low resulting in decreased conversion (D) None of these

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Last Answer : (A) Rate of reaction is very low

. Study of chemical kinetics is the easiest in the case of __________ reactions. (A) Irreversible (B) Reversible (C) Surface (D) Side

Description : . Study of chemical kinetics is the easiest in the case of __________ reactions. (A) Irreversible (B) Reversible (C) Surface (D) Side

Last Answer : (A) Irreversible

If a drug is eliminated by first order kinetics: A. A constant amount of the drug will be eliminated per unit time B. Its clearance value will remain constant C. Its elimination half life will increase with dose D. It will be completely eliminated from the body in 2 × half life period

Description : If a drug is eliminated by first order kinetics: A. A constant amount of the drug will be eliminated per unit time B. Its clearance value will remain constant C. Its elimination half life will increase with dose D. It will be completely eliminated from the body in 2 × half life period

Last Answer : B. Its clearance value will remain constant

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Last Answer : B. Its clearance value will remain constant

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In case of the irreversible unimolecular type, first order reaction, the fractional conversion at any time for constant volume system as compared to variable volume system is (A) More (B) Less (C) Same (D) Either (A) or (B), depends on other factors

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An isothermal irreversible reaction is being carried out in an ideal tubular flow reactor. The conversion in this case will __________ with decrease in space time. (A) Increase (B) Increase exponentially (C) Decrease (D) Remain unchanged

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Last Answer : (C) Decrease

6 gm of carbon is burnt with an amount of air containing 18 gm oxygen. The product contains 16.5 gms CO2 and 2.8 gms CO besides other constituents. What is the degree of conversion on the basis of disappearance of limiting reactant? (A) 100% (B) 95% (C) 75% (D) 20%

Description : 6 gm of carbon is burnt with an amount of air containing 18 gm oxygen. The product contains 16.5 gms CO2 and 2.8 gms CO besides other constituents. What is the degree of conversion on the basis of disappearance of limiting reactant? (A) 100% (B) 95% (C) 75% (D) 20%

Last Answer : (B) 95%

In case of a/an __________ chemical reaction, conversion increases with the rise in temperature. (A) Reversible exothermic (B) Irreversible exothermic (C) Irreversible endothermic (D) Reversible endothermic

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75% of a radioactive element decays in 6 hours. Its half life period is __________ hours. (A) 3/4 (B) 1/6 (C) 3 (D) 4

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Last Answer : (C) 3

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Last Answer : (C) No change

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Last Answer : (D) All (A), (B) and (C)

The half life period of a radioactive element is 100 days. After 400 days, one gm of the element will be reduced to __________ gm. (A) 1/4 (B) 1/8 (C) 1/2 (D) 1/16

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Last Answer : (D) 1/16

Half-life period for a first order reaction is __________ the initial concentration of the reactant. (A) Directly proportional to (B) Inversely proportional to (C) Independent of(D) None of these

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For a __________ order chemical reaction as shown in the bellow figure, the half life period is independent of the initial concentration of the reactant A(A) Zero(B) First(C) Second(D) Third.

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Half life period of a chemical reaction is proportional to CA0 -1 , if the reaction is of __________ order. (A) First(B) Zero(C) Second(D) Third

Description : Half life period of a chemical reaction is proportional to CA0 -1 , if the reaction is of __________ order. (A) First (B) Zero (C) Second (D) Third

Last Answer : (C) Second

The conversion of a reactant, undergoing a first order reaction, at a time equal to three times the half life of the reaction is: (A) 0.875 (B) 0.5 (C) 0.425 (D) Data insufficient to calculate

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Last Answer : (A) 0.875

Conversion of glucose to glucose-6-phosphate, the first irreversible reaction of glycolysis, is catalysed by (a) phosphofructokinase (b) aldolase (c) hexokinase (d) enolase.

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Last Answer : (c) hexokinase

In enzyme kinetics Km implies (A) The substrate concentration that gives one half Vmax (B) The dissocation constant for the enzyme substrate comples (C) Concentration of enzyme (D) Half of the substrate concentration required to achieve Vmax

Description : In enzyme kinetics Km implies (A) The substrate concentration that gives one half Vmax (B) The dissocation constant for the enzyme substrate comples (C) Concentration of enzyme (D) Half of the substrate concentration required to achieve Vmax

Last Answer : Answer : A

Which one of the following statements concerning glucose metabolism is correct? (A) The conversion of Glucose to lactate occurs only in the R.B.C (B) Glucose enters most cells by a mechanism in which Na+ and glucose are co-transported (C) Pyruvate kinase catalyses an irreversible reaction (D) An elevated level of insulin leads to a decreased level of fructose 2, 6-bisphosphate in hepatocyte

Description : Which one of the following statements concerning glucose metabolism is correct? (A) The conversion of Glucose to lactate occurs only in the R.B.C (B) Glucose enters most cells by a mechanism in ... ) An elevated level of insulin leads to a decreased level of fructose 2, 6-bisphosphate in hepatocyte

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. Radioactive decay follows __________ order kinetics. (A) First (B) Second (C) Third (D) Zero

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Kinetics of a catalytic reaction can be best studied on a/an __________ reactor. (A) Mixed (B) Integral (plug flow) (C) Differential (flow) (D) Either (A), (B) and (C)

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Last Answer : (D) Either (A), (B) and (C)

Equilibrium of a chemical reaction as viewed by kinetics is a __________ state. (A) Dynamic steady (B) Static steady (C) Dynamic unsteady (D) None of these

Description : Equilibrium of a chemical reaction as viewed by kinetics is a __________ state. (A) Dynamic steady (B) Static steady (C) Dynamic unsteady (D) None of these

Last Answer : (A) Dynamic steady

Chemical kinetics can predict the __________ of a chemical reaction. (A) Rate (B) Feasibility (C) Both (A) & (B) (D) Neither (A) nor (B)

Description : Chemical kinetics can predict the __________ of a chemical reaction. (A) Rate (B) Feasibility (C) Both (A) & (B) (D) Neither (A) nor (B)

Last Answer : (A) Rate

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Description : Kinetics of a solid catalysed reaction can best be studied in a __________ reactor. (A) Batch (B) Plug-flow (C) Mixed (D) None of these

Last Answer : (C) Mixed

What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second

Description : What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second

Last Answer : (A) Litre/mole.second

Pick out the correct statement. (A) If an insoluble gas is passed through a volatile liquid placed in a perfectly insulated container, the temperature of the liquid will increase (B) A process is irreversible as long as Δ S for the system is greater than zero (C) The mechanical work done by a system is always equal to∫P.dV (D) The heat of formation of a compound is defined as the heat of reaction leading to the formation of the compound from its reactants

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Last Answer : (D) The heat of formation of a compound is defined as the heat of reaction leading to the formation of the compound from its reactants

A liquid with high boiling point decomposes on simple distillation but it can be steam distilled for its purification .Explain how is it possible?

Description : A liquid with high boiling point decomposes on simple distillation but it can be steam distilled for its purification .Explain how is it possible?

Last Answer : In steam distillation boiling occurs when vapour pressure of organic compound & steam becomes equal to atmospheric pressure. As vapour pressure of water is higher than the organic liquid. ... organic liquid vaporizes at a temperature below its boiling point in steam distillation without decomposing.

Suggest a method to purify a liquid which decomposes at its boiling point.

Description : Suggest a method to purify a liquid which decomposes at its boiling point.

Last Answer : The process Distillation under reduced pressure is used to purify a liquid which decomposes at its boiling point.

Vasopressin and oxytocin circulate unbound to proteins and have very short plasma half lives, on the order of (A) 1–2 minutes (B) 2–4 minutes (C) 5–8 minutes (D) 10–12 minutes

Description : Vasopressin and oxytocin circulate unbound to proteins and have very short plasma half lives, on the order of (A) 1–2 minutes (B) 2–4 minutes (C) 5–8 minutes (D) 10–12 minutes

Last Answer : Answer : B

The Shopkeeper increased the price of a product by 75% so that customer finds it difficult to purchase the required amount. But somehow the customer managed to purchase only 140% of the required amount. What is the net difference in the expenditure on that product? a) 12.5 b) 26.0 c) 13.5 d) 17.5 e) 19.8

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Last Answer : Answer: D  Quantity×Rate=Price  1x1=1  1.4x1.75=2.45  Decrease in price = (0.175/1) × 100  = 17.5%

The conversion XA and residence time data are collected for zero order liquid phase reaction in a stirred tank reactor. Which of the following will be a straight line? (A) XA Vs . τ (B) XA Vs ln τ (C) XA /(1 - XA )Vs τ (D) XA (1 - XA )Vs τ

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Last Answer : (A) XA Vs . τ

The conversion for a first order liquid phase reaction. A → B in a CSTRis 50%. If another CSTR of the same volume is connected in series, then the % conversion at the exit of the second reactor will be (A) 60 (B) 75 (C) 90 (D) 100

Description : The conversion for a first order liquid phase reaction. A → B in a CSTRis 50%. If another CSTR of the same volume is connected in series, then the % conversion at the exit of the second reactor will be (A) 60 (B) 75 (C) 90 (D) 100

Last Answer : (B) 75

Half life period of a chemical reaction is (A) The time required to reduce the concentration of the reacting substance to half its initial value (B) Half of the space time of a reaction (C) Half of the residence time of a reaction (D) None of these

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Last Answer : (A) The time required to reduce the concentration of the reacting substance to half its initial value

The minimum energy required to allow a chemical reaction to proceed is termed as the 'threshold energy '. Chemical reactions with low activation energy are: (A) Always irreversible (B) Insensitive to temperature changes (C) Mostly irreversible (D) Highly temperature sensitive

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Pick out the wrong statement. (A) In a first order reaction, A → products; the reaction becomes slower as it proceeds, because the concentration of A decreases and the rate is proportional to the concentration of A (B) Transition state theory approaches the problem of calculating reaction rates by concentrating on the idea of activated complexes (C) According to the penetration theory, the mass transfer co-efficient decreases, if the exposure time of an eddy to the solute decreases (D) If the rate of an irreversible reaction, A + B → 2C is k.CA .CB , then the reaction is always elementary

Description : Pick out the wrong statement. (A) In a first order reaction, A → products; the reaction becomes slower as it proceeds, because the concentration of A decreases and the rate is proportional to the concentration ... irreversible reaction, A + B → 2C is k.CA .CB , then the reaction is always elementary

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Description : Compared to pork/beef insulins, the human insulins: A. Are more potent B. Have a faster kinetics of absorption and elimination C. Have longer biological action half life D. Penetrate blood-brain barrier more efficiently

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. For an isothermal second order aqueous phase reaction, A → B, the ratio of the time required for 90% conversion to the time required for 45% conversion is: (A) 2 (B) 4 (C) 11 (D) 22

Description : . For an isothermal second order aqueous phase reaction, A → B, the ratio of the time required for 90% conversion to the time required for 45% conversion is: (A) 2 (B) 4 (C) 11 (D) 22

Last Answer : (C) 11