Pick out the wrong statement. (A) In a first order reaction, A → products; the reaction becomes slower as it proceeds, because the concentration of A decreases and the rate is proportional to the concentration of A (B) Transition state theory approaches the problem of calculating reaction rates by concentrating on the idea of activated complexes (C) According to the penetration theory, the mass transfer co-efficient decreases, if the exposure time of an eddy to the solute decreases (D) If the rate of an irreversible reaction, A + B → 2C is k.CA .CB , then the reaction is always elementary

Pick out the wrong statement.
(A) In a first order reaction, A → products; the reaction becomes slower as it
proceeds, because the concentration of A decreases and the rate is proportional
to the concentration of A
(B) Transition state theory approaches the problem of calculating reaction
rates by concentrating on the idea of activated complexes
(C) According to the penetration theory, the mass transfer co-efficient
decreases, if the exposure time of an eddy to the solute decreases
(D) If the rate of an irreversible reaction, A + B → 2C is k.CA
.CB
, then the
reaction is always elementary
by

1 Answer

Answer :

(C) According to the penetration theory, the mass transfer co-efficient
decreases, if the exposure time of an eddy to the solute decreases
by

Related questions

Mass transfer co-efficient is directly proportional to DAB 0.5 , according to __________ theory. (A) Penetration (B) Surface renewal (C) Film (D) None of these

Description : Mass transfer co-efficient is directly proportional to DAB 0.5 , according to __________ theory. (A) Penetration (B) Surface renewal (C) Film (D) None of these

Last Answer : (A) Penetration

Mass transfer co-efficient is directly proportional to DAB according to the __________ theory. (A) Film (B) Penetration (C) Surface-renewal (D) None of these

Description : Mass transfer co-efficient is directly proportional to DAB according to the __________ theory. (A) Film (B) Penetration (C) Surface-renewal (D) None of these

Last Answer : (A) Film

Mass transfer co-efficient 'K' according to penetration theory varies with mass diffusivity as (A) D0.5 (B) D (C) 1/D (D) D1.5

Description : Mass transfer co-efficient 'K' according to penetration theory varies with mass diffusivity as (A) D0.5 (B) D (C) 1/D (D) D1.5

Last Answer : (A) D0.5

Pick out the wrong statement. (A) The shear stress at the pipe (dia = D, length = L) wall in case of laminar flow of Newtonian fluids is (D/4L). ∆p (B) In the equation, T. gc = k. (du/dy) n the value of 'n' for pseudoplastic and Dilatant fluid are < 1 and >1 respectively (C) Shear stress for Newtonian fluid is proportional to the rate of shear in the direction perpendicular to motion (D) With increase in the Mach number >0.6, the drag co-efficient decreases in case of compressible fluids

Description : Pick out the wrong statement. (A) The shear stress at the pipe (dia = D, length = L) wall in case of laminar flow of Newtonian fluids is (D/4L). ∆p (B) In the equation, T. gc = k. ... to motion (D) With increase in the Mach number >0.6, the drag co-efficient decreases in case of compressible fluids

Last Answer : (D) With increase in the Mach number >0.6, the drag co-efficient decreases in case of compressible fluids

Penetration theory relates the average mass transfer co-efficient (K) with diffusivity (D) as (A) K ∝D (B) K ∝√D (C) K ∝D1.5 (D) K ∝D

Description : Penetration theory relates the average mass transfer co-efficient (K) with diffusivity (D) as (A) K ∝D (B) K ∝√D (C) K ∝D1.5 (D) K ∝D

Last Answer : (B) K ∝√D

Pick out the wrong statement. (A) 'Solvates' are chemical compounds formed by solute with their solvents. When water is the solvent, then it is called a 'hydrate' (B) In heat exchanger calculations (Δt) weighted is used in place of Δt, when it involves more than one sequence of heating or cooling i.e., desuperheating & condensation or condensation & sub-cooling (C) Heat transfer co-efficient during nucleate boiling is not influenced by the agitation imparted (D) In case of short tube vertical evaporators, area of central downtake is about 50 to 100% of the total tube cross-sectional area

Description : Pick out the wrong statement. (A) 'Solvates' are chemical compounds formed by solute with their solvents. When water is the solvent, then it is called a 'hydrate' (B) In heat exchanger ... vertical evaporators, area of central downtake is about 50 to 100% of the total tube cross-sectional area

Last Answer : (C) Heat transfer co-efficient during nucleate boiling is not influenced by the agitation imparted

The rate of the chemical reaction A → B doubles as the concentration of A i.e.., CA is doubled. If rate of reaction is proportional to CA n , then what is the value of n for this reaction? (A) 0 (B) 0.5 (C) 1 (D) 2

Description : The rate of the chemical reaction A → B doubles as the concentration of A i.e.., CA is doubled. If rate of reaction is proportional to CA n , then what is the value of n for this reaction? (A) 0 (B) 0.5 (C) 1 (D) 2

Last Answer : (C) 1

Pick out the wrong statement. (A) In the McCabe-Thiele diagram for binary distillation, vertical feed line represents saturated liquid feed and horizontal feed line represents saturated vapour feed (B) In small columns, local efficiency is larger than Murphree efficiency; in large columns local efficiency is smaller than Murphree efficiency (C) For Laminar flow over a plate of length L, the local mass transfer co￾efficient at a distance L from the leading edge is 1.5 × 10 -2m/s. Then the average mass transfer co-efficient for the plate is 2 × 10 -2m/s (D) The concentration and hydrodynamic boundary layers over a flat plate are of equal thickness, if Schmidt number is equal to unity

Description : Pick out the wrong statement. (A) In the McCabe-Thiele diagram for binary distillation, vertical feed line represents saturated liquid feed and horizontal feed line represents saturated vapour feed (B) In ... layers over a flat plate are of equal thickness, if Schmidt number is equal to unity

Last Answer : (C) For Laminar flow over a plate of length L, the local mass transfer co￾efficient at a distance L from the leading edge is 1.5 × 10 -2m/s. Then the average mass transfer co-efficient for the plate is 2 × 10 -2m/s

For the irreversible reaction, Ca+ 2C = Ca C2, Δ H°298 = - 60000 J . mole-1. If a system initially containing 2 moles of calcium, 3 moles of carbon and 1 mole of calcium carbide is allowed to react to completion, the heat evolved at 298 K will be (A) 30,000 J (B) 60,000 J (C) 90,000 J (D) 2,40,000 J

Description : For the irreversible reaction, Ca+ 2C = Ca C2, Δ H°298 = - 60000 J . mole-1. If a system initially containing 2 moles of calcium, 3 moles of carbon and 1 mole of calcium carbide is allowed to react to completion, the heat evolved ... will be (A) 30,000 J (B) 60,000 J (C) 90,000 J (D) 2,40,000 J

Last Answer : (C) 90,000 J

Pick out the wrong statement. (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity(B) For an ideal mixed reactor at steady state, the exit stream has the samecomposition as fluid within the reactor and the space time is equivalent toholding time for constant density system(C) Plug flow reactor (PFR) is always smaller than mixed reactor for allpositive reaction orders for a particular duty(D) Reaction rate does not decrease appreciably as the reaction proceeds incase of an autocatalytic reaction

Description : Pick out the wrong statement. (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity(B) For an ideal ... D) Reaction rate does not decrease appreciably as the reaction proceeds in case of an autocatalytic reaction

Last Answer : (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity

The mass transfer co-efficient for a solid sphere of radius 'a' dissolving in a large volume of quiescent liquid, in which ‘D’ is the diffusivity of solute, is (A) D/a (B) D/2a (C) Proportional to √D (D) Dependent on the Reynolds number

Description : The mass transfer co-efficient for a solid sphere of radius 'a' dissolving in a large volume of quiescent liquid, in which ‘D’ is the diffusivity of solute, is (A) D/a (B) D/2a (C) Proportional to √D (D) Dependent on the Reynolds number

Last Answer : (D) Dependent on the Reynolds number

What is the value of 'n' if the reaction rate of the chemical reaction A → B, is proportional to CA n and it is found that the reaction rate triples, when the concentration of 'A' is increased 9 times? (A) 1/2 (B) 1/3 (C) 1/9 (D) 3

Description : What is the value of 'n' if the reaction rate of the chemical reaction A → B, is proportional to CA n and it is found that the reaction rate triples, when the concentration of 'A' is increased 9 times? (A) 1/2 (B) 1/3 (C) 1/9 (D) 3

Last Answer : (A) 1/2

A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume of the reacting mixture is V and the density of the liquid mixture is constant. The mass balance for A is (A) d(VCA )/dt = -F (CAF - CA ) - kCA 2V (B) d(VCA )/dt = F (CAF - CA ) - kCA 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V

Description : A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume ... 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V

Last Answer : (D) d(VCA )/dt = FCAF - kCA 2V

Calculation of mass transfer co-efficient is mostly/normally done using __________ theory. (A) Surface renewal (B) Film (C) Penetration (D) None of these

Description : Calculation of mass transfer co-efficient is mostly/normally done using __________ theory. (A) Surface renewal (B) Film (C) Penetration (D) None of these

Last Answer : (B) Film

Pick out the wrong statement. (A) The Reynolds analogy for mass transfer is given by Lewis relation and is applicable, when Schmidt number is one (B) Sherwood number for flow in pipes can be expressed as the ratio of the concentration gradient at wall to the overall concentration difference (C) According to film theory for equimolar counter diffusion, the mass transfer coefficient is given by DAB(B)P - 3, Q - 2 (D) The z-component of the total mass flux of a component A in binary mixture of A and B is given by - Dab'.dCA/dz

Description : Pick out the wrong statement. (A) The Reynolds analogy for mass transfer is given by Lewis relation and is applicable, when Schmidt number is one (B) Sherwood number for flow in pipes can be expressed ... flux of a component A in binary mixture of A and B is given by - Dab'.dCA/dz

Last Answer : (C) According to film theory for equimolar counter diffusion, the mass transfer coefficient is given by DAB(B)P - 3, Q - 2

Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For a second order reaction, the slope of the graph/plot between rate and (concentration) is equal to the rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero

Description : Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For ... rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero

Last Answer : (B) The order and molecularity of a complex reaction may not be the same

Mass transfer co-efficient (K) and diffusivity (D) are related according to film theory as (A) K ∝ D (B) K ∝√D (C) K ∝ D1.5 (D) K ∝ D

Description : Mass transfer co-efficient (K) and diffusivity (D) are related according to film theory as (A) K ∝ D (B) K ∝√D (C) K ∝ D1.5 (D) K ∝ D

Last Answer : (A) K ∝ D

To maximise the formation of R in the simultaneous reaction A + B → R, rR = 2CA 0.5 .CB 2 A + B→ S, rS = 1.5 CA. CB We should have (A) Low CA , low CB (B) Low CA , high CB (C) High CA , low CB (D) High CA , high CB

Description : To maximise the formation of R in the simultaneous reaction A + B → R, rR = 2CA 0.5 .CB 2 A + B→ S, rS = 1.5 CA. CB We should have (A) Low CA , low CB (B) Low CA , high CB (C) High CA , low CB (D) High CA , high CB

Last Answer : (B) Low CA , high CB

. A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two reactors. (A) Both conversion as well as concentration are same (B) Conversion in both will be the same but concentrations will be different (C) Both the conversion as well as concentrations will be different (D) None of these

Description : . A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two ... be different (C) Both the conversion as well as concentrations will be different (D) None of these

Last Answer : (B) Conversion in both will be the same but concentrations will be different

For a gaseous phase reaction, rate of reaction is equal to K. CA . CB. If the volume of the reactor is suddenly reduced to 1/4th of its initial volume, then the rate of reaction compared to the original rate will be __________ times. (A) 8 (B) 16 (C) 1/8 (D) 1/16

Description : For a gaseous phase reaction, rate of reaction is equal to K. CA . CB. If the volume of the reactor is suddenly reduced to 1/4th of its initial volume, then the rate of reaction compared to the original rate will be __________ times. (A) 8 (B) 16 (C) 1/8 (D) 1/16

Last Answer : (B) 16

The rate of a gas phase reaction is given by K . CA . CB. If the volume of the reaction vessel is reduced to l/4th of its initial volume, then the reaction rate compared to the original rate will be __________ times. (A) 4 (B) 16 (C) 8 (D) 2

Description : The rate of a gas phase reaction is given by K . CA . CB. If the volume of the reaction vessel is reduced to l/4th of its initial volume, then the reaction rate compared to the original rate will be __________ times. (A) 4 (B) 16 (C) 8 (D) 2

Last Answer : (B) 16

Pick out the wrong statement. (A) The condensing film co-efficient is about 3 times lower for vertical condenser as compared to the equivalent horizontal condenser for identical situation (B) Film co-efficient for vaporisation decreases as a result of vapor binding (C) In industrial practice, sub-cooling of condensate is required, when thecondensate is a volatile liquid and is to be transferred for storage(D) Overall heat transfer co-efficient in a heat exchanger is controlled by thevalue of the film co-efficient, which is higher

Description : Pick out the wrong statement. (A) The condensing film co-efficient is about 3 times lower for vertical condenser as compared to the equivalent horizontal condenser for identical situation ( ... in a heat exchanger is controlled by the value of the film co-efficient, which is higher

Last Answer : (D) Overall heat transfer co-efficient in a heat exchanger is controlled by the value of the film co-efficient, which is higher

The activity co-efficient of the solute in a dilute solution (A) Decreases with the increase of concentration of the solute (B) Increases with the increase of concentration of the solute (C) Remains constant (D) Is unity at infinite dilution

Description : The activity co-efficient of the solute in a dilute solution (A) Decreases with the increase of concentration of the solute (B) Increases with the increase of concentration of the solute (C) Remains constant (D) Is unity at infinite dilution

Last Answer : (C) Remains constant

Half life period of a first order irreversible reaction A → B is (A) k/2 (B) ln k/2 (C) ln 2/k (D) ln 0.5/k

Description : Half life period of a first order irreversible reaction A → B is (A) k/2 (B) ln k/2 (C) ln 2/k (D) ln 0.5/k

Last Answer : (C) ln 2/k

Chlorination of an alkane as compared to bromination proceeds (a) at a slower rate (b) at a faster rate (c) with equal rates (d) with equal or different rate depending upon the source of alkane

Description : Chlorination of an alkane as compared to bromination proceeds (a) at a slower rate (b) at a faster rate (c) with equal rates (d) with equal or different rate depending upon the source of alkane

Last Answer : at a faster rate

For the chemical reaction X → Y, it is observed that, on doubling the concentration of 'X', the reaction rate quadruples. If the reaction rate is proportional to Cx n , then what is the value of ‘n’? (A) 1/4 (B) 2 (C) 4 (D) 16

Description : For the chemical reaction X → Y, it is observed that, on doubling the concentration of 'X', the reaction rate quadruples. If the reaction rate is proportional to Cx n , then what is the value of ‘n’? (A) 1/4 (B) 2 (C) 4 (D) 16

Last Answer : (C) 4

For the chemical reaction P → Q, it is found that the rate of reaction doubles as the concentration of 'P' is doubled. If the reaction rate is proportional to Cp n , then what is the value of 'n' for this chemical reaction? (A) 0 (B) 1 (C) 2 (D) 3

Description : For the chemical reaction P → Q, it is found that the rate of reaction doubles as the concentration of 'P' is doubled. If the reaction rate is proportional to Cp n , then what is the value of 'n' for this chemical reaction? (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (B) 1

A first order reaction A → B occurs in an isothermal porous catalyst pellet of spherical shape. If the concentration of A at the centre of the pellet is much less than at the external surface, the process is limited by (A) Diffusion within the pellet (B) Reaction (C) External mass transfer (D) None of the above

Description : A first order reaction A → B occurs in an isothermal porous catalyst pellet of spherical shape. If the concentration of A at the centre of the pellet is much less than at the external surface, the ... A) Diffusion within the pellet (B) Reaction (C) External mass transfer (D) None of the above

Last Answer : (A) Diffusion within the pellet

Pick out the wrong statement. (A) Mass transfer co-efficient does not account for gas-liquid diffusion (B) Diffusion co-efficient and mass transfer co-efficient are not same in any mass transfer operation

Description : Pick out the wrong statement. (A) Mass transfer co-efficient does not account for gas-liquid diffusion (B) Diffusion co-efficient and mass transfer co-efficient are not same in any mass transfer operation

Last Answer : (A) Mass transfer co-efficient does not account for gas-liquid diffusion

If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower(C) Entropy changes(D) Free energy of activation is higher

Description : If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower (C) Entropy changes (D) Free energy of activation is higher

Last Answer : (D) Free energy of activation is higher

Pick out the wrong statement. (A) The binary diffusivity in liquids is of the order of 10 -5 cm2 /sec (B) Molecular diffusion in solid is much faster than that in liquids (C) Particles movement from higher concentration to lower concentration takes place in diffusion process (D) According to Poiseuille's law, the permeability decreases with increase in temperature for flow of a gas through a given capillary

Description : Pick out the wrong statement. (A) The binary diffusivity in liquids is of the order of 10 -5 cm2 /sec (B) Molecular diffusion in solid is much faster than that in liquids ( ... Poiseuille's law, the permeability decreases with increase in temperature for flow of a gas through a given capillary

Last Answer : (B) Molecular diffusion in solid is much faster than that in liquids

Pick out the wrong statement. (A) Superheated steam is preferably not used for process heating because of its low heat transfer film co-efficient (B) In a shell and tube heat exchanger, the shell pressure drop is maximum for orifice baffles (C) S.I. unit of fouling factor is Watt/m2 .°K (D) Longitudinal fins are used in extended surface heat exchangers, when the direction of fluid flow is parallel to the axis of the tube

Description : Pick out the wrong statement. (A) Superheated steam is preferably not used for process heating because of its low heat transfer film co-efficient (B) In a shell and tube heat exchanger ... surface heat exchangers, when the direction of fluid flow is parallel to the axis of the tube

Last Answer : (C) S.I. unit of fouling factor is Watt/m2 .°K

Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the reaction is practically irreversible in nature (C) The intercept of the Arrhenius plot is called the 'activation energy' (D) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy

Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is nonlinear in the case of steady state unimolal unidirectional diffusion (C) Azeotropes obey Raoult's law at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Description : Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial ... at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Last Answer : (C) Azeotropes obey Raoult's law at all temperature

The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Description : The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

The value of 'n' for a chemical reaction A → B, whose reaction rate is → CA n , will be __________ if the rate of the reaction increases by a factor of 8, when the concentration of is doubled. (A) 0 (B) 1 (C) 2 (D) 3

Description : The value of 'n' for a chemical reaction A → B, whose reaction rate is → CA n , will be __________ if the rate of the reaction increases by a factor of 8, when the concentration of is doubled. (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (D) 3

The experimentally determined overall order of the reaction, A + B → C + D, is two. Then the (A) Reaction is elementary with a molecularity of 2 (B) Molecularity of the reaction is 2, but the reaction may not be elementary (C) Reaction may be elementary with molecularity of 2 (D) Reaction is elementary but the molecularity may not be 2

Description : The experimentally determined overall order of the reaction, A + B → C + D, is two. Then the (A) Reaction is elementary with a molecularity of 2 (B) Molecularity of the reaction is 2, ... Reaction may be elementary with molecularity of 2 (D) Reaction is elementary but the molecularity may not be 2

Last Answer : (A) Reaction is elementary with a molecularity of 2

The reaction A → B is conducted in an adiabatic plug flow reactor (PFR). Pure A at a concentration of 2 kmol/m3 is fed to the reactor at the rate of 0.01 m3 /s and at a temperature of 500 K. If the exit conversion is 20%, then the exit temperature (in k) is (Data: Heat of reaction at 298 K = - 50000 kJ/ kmole of A reacted Heat capacities CPA = CPB = 100kJ/kmole. K (may be assumed to be independent of temperature)) (A) 400 (B) 500 (C) 600 (D) 1000

Description : The reaction A → B is conducted in an adiabatic plug flow reactor (PFR). Pure A at a concentration of 2 kmol/m3 is fed to the reactor at the rate of 0.01 m3 /s and at a temperature of 500 K. If the exit ... /kmole. K (may be assumed to be independent of temperature)) (A) 400 (B) 500 (C) 600 (D) 1000

Last Answer : (C) 600

Pick out the wrong statemen(A) Autocatalytic reactions are exemplified by microbial fermentation reactions (B) The slowest step has the greatest influence on the overall reaction rate in case of an irreversible series reaction (C) The fractional conversion at any time is same for both the constant as well as the variable volume system in case of an irreversible unimolecular type first order reaction (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction

Description : Pick out the wrong statemen (A) Autocatalytic reactions are exemplified by microbial fermentation reactions (B) The slowest step has the greatest influence on the overall reaction rate in case of an ... reaction (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction

Last Answer : (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction

Pick out the wrong statement. (A) The vessel dispersion number (D/UL) for plug flow and mixed flow approaches zero and infinity respectively (B) Space time in a flow reactor is a measure of its capacity and is equal to the residence time when the density of reaction mixture is constant (C) Mixed reactor is always smaller than the plug flow reactor for all positive reaction orders for a particular duty (D) In an ideal tubular flow reactor, mixing takes place in radial direction and there is no mixing in longitudinal direction

Description : Pick out the wrong statement. (A) The vessel dispersion number (D/UL) for plug flow and mixed flow approaches zero and infinity respectively (B) Space time in a flow reactor is a ... ideal tubular flow reactor, mixing takes place in radial direction and there is no mixing in longitudinal direction

Last Answer : (C) Mixed reactor is always smaller than the plug flow reactor for all positive reaction orders for a particular duty

The concentration of A in a first order reaction, A → B, decreases (A) Linearly with time (B) Exponentially with time (C) Very abruptly towards the end of the reaction (D) Logarithmically with time

Description : The concentration of A in a first order reaction, A → B, decreases (A) Linearly with time (B) Exponentially with time (C) Very abruptly towards the end of the reaction (D) Logarithmically with time

Last Answer : (B) Exponentially with time

In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases by a factor of 9 on trebling the concentration of the reactant. Then the rate of the reaction is proportional to(where, CA = concentration of the reactant) (A) CA (B) CA 2 (C) CA 3 (D) CA

Description : In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases ... where, CA = concentration of the reactant) (A) CA (B) CA 2 (C) CA 3 (D) CA

Last Answer : (B) CA 2

A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and kg respectively. The effective rate constant (ke ff) is given by (A) ke ff = k + kg (B) ke ff = (k+ kg )/2 (C) ke ff = (kkg ) 1/2 (D) 1/ke ff = 1/k + 1/kg

Description : A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and kg respectively. The effective rate constant (ke ff) is given by (A) ke ff = k + kg ( ... + kg )/2 (C) ke ff = (kkg ) 1/2 (D) 1/ke ff = 1/k + 1/kg

Last Answer : (D) 1/ke ff = 1/k + 1/kg

Overall rate of reaction in a heterogeneous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of catalyst, if it doesnot entail a chain mechanism.(A) Proportional to(B) Independent of(C) Inversely proportional to(D) Proportional to the square o

Description : Overall rate of reaction in a heterogeneous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of ... to (B) Independent of (C) Inversely proportional to (D) Proportional to the square o

Last Answer : (A) Proportional to