Mention the Points of Similarities between ‘Lithium and Magnesium’  

1 Answer

Answer :

 The similarity between lithium and magnesium is particularly striking and arises because of their similar sizes : (atomic radii, Li = 152 pm, Mg = 160 pm; ionic radii : Li+ = 76 pm, Mg2+= 72 pm. ) The main points of similarity are: (i) Both lithium and magnesium are harder and lighter than other elements in the respective groups. (ii) Lithium and magnesium react slowly with water. Their oxides and hydroxides are much less soluble and their hydroxides decompose on heating. Both form a nitride, Li3N and Mg3N2, by direct combination with nitrogen. (iii) The oxides, Li2O and MgO do not combine with excess oxygen to give any superoxide. (iv) The carbonates of lithium and magnesium decompose easily on heating to form the oxides and CO2. Solid hydrogencarbonates are not formed by lithium and magnesium. (v) Both LiCl and MgCl2 are soluble in ethanol. (vi) Both LiCl and MgCl2 are deliquescent and crystallise from aqueous solution as hydrates, LiCl·2H2O and MgCl2·8H2O.  

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