When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one nitrogen atom of semicarbazide acts as a nucleophile and attack

When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one nitrogen atom of semicarbazide acts as a nucleophile and attack
by

1 Answer

Answer :

When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one ... atoms of semicarbazide are relatively non nucleophilic ?
by

Related questions

Which of the following is correct? (a) When a Grignard reagent reacts with a ketone, the addition product is a primary alcohol. (b) When a Grignard reagent reacts with a ketone, the addition product is a secondaryalcoho(c) When a Grignard reagent reacts with a aldehyde, the addition product is a tertiary alcohol. (d) None of the above are correct.l

Description : Which of the following is correct? (a) When a Grignard reagent reacts with a ketone, the addition product is a primary alcohol. (b) When a Grignard reagent reacts with a ketone, the addition product ... with a aldehyde, the addition product is a tertiary alcohol. (d) None of the above are correct.

Last Answer : None of the above are correct.

Ethylmagnesium iodide reacts with formaldehyde to give a product which on acid-hydrolysis forms : (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol

Description : Ethylmagnesium iodide reacts with formaldehyde to give a product which on acid-hydrolysis forms : (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol

Last Answer : a primary alcohol

A nucleophile acts as a __________ when it reacts with an electrophile. (a) Bronsted-Lowry acid (b) Arrhenius base (c) Lewis acid (d) Lewis base

Description : A nucleophile acts as a __________ when it reacts with an electrophile. (a) Bronsted-Lowry acid (b) Arrhenius base (c) Lewis acid (d) Lewis base

Last Answer : Lewis base

An electrophile acts as a __________ when it reacts with a nucleophile. (a) Bronsted-Lowry base (b) Arrhenius base (c) Lewis acid(d) Lewis base

Description : An electrophile acts as a __________ when it reacts with a nucleophile. (a) Bronsted-Lowry base (b) Arrhenius base (c) Lewis acid (d) Lewis base

Last Answer : Lewis acid

Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Acid and alcohol react to form (a) Aldehyde and water (b) Ketone and water (c) Acid anhydride and water (d) Ester and water

Description : Acid and alcohol react to form (a) Aldehyde and water (b) Ketone and water (c) Acid anhydride and water (d) Ester and water

Last Answer : Ans:(d)

The mutarotation of glucose is characterized by : (a) a change from an aldehyde to ketone structure. (b) a change of specific rotation from a (+) to a (–) value. (c) the presence of an intramolecular bridge structure. (d) the irreversible change from α-D to the β-D form.

Description : The mutarotation of glucose is characterized by : (a) a change from an aldehyde to ketone structure. (b) a change of specific rotation from a (+) to a (–) value. (c) the presence of an intramolecular bridge structure. (d) the irreversible change from α-D to the β-D form.

Last Answer : the presence of an intramolecular bridge structure.

An aqueous solution of glucose behaves as an aldehyde because __________. (a) it is hydrolyzed by water to the free aldehyde (b) it is a ketone, but is in equilibrium with the aldehyde form (c) glucose is actually a cyclic aldehyde (d) its cyclic hemiacetal, the predominant form, is in equilibrium with the free aldehyde form

Description : An aqueous solution of glucose behaves as an aldehyde because __________. (a) it is hydrolyzed by water to the free aldehyde (b) it is a ketone, but is in equilibrium with the aldehyde form ... aldehyde (d) its cyclic hemiacetal, the predominant form, is in equilibrium with the free aldehyde form

Last Answer : its cyclic hemiacetal, the predominant form, is in equilibrium with the free aldehyde form

An aldehyde can be oxidized to form: w) a ketone x) an acid y) an alcohol z) an ester

Description : An aldehyde can be oxidized to form: w) a ketone x) an acid y) an alcohol z) an ester 

Last Answer : ANSWER: X -- AN ACID

Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an aldol condensation reaction. (a)2-Ethyl-3-hydroxy

Description : Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an aldol condensation reaction. (a)2-Ethyl-3-hydroxy

Last Answer : Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an ... hexanal (b) 4-Hydroxy-4-methyl-2-pentanone

Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an aldol condensation reaction. (a)2-Ethyl-3-hydroxy

Description : Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an aldol condensation reaction. (a)2-Ethyl-3-hydroxy

Last Answer : Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an ... hexanal (b) 4-Hydroxy-4-methyl-2-pentanone

Which disaccharide has no free aldehyde or ketone group?

Description : Which disaccharide has no free aldehyde or ketone group?

Last Answer : Sucrose.

. Monosaccharides are classified according to : (a) the number of carbon atoms in the molecule. (b) whether they contain an aldehyde or a ketone group(c) their configurational relationship to glyceraldehyde.(d) all of the above

Description : . Monosaccharides are classified according to : (a) the number of carbon atoms in the molecule. (b) whether they contain an aldehyde or a ketone group (c) their configurational relationship to glyceraldehyde. (d) all of the above

Last Answer : all of the above

Which of the following is the correct ranking in decreasing order of relative Boiling Point of carbonyl containing compounds? (a) primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone (b) ester > carboxylic acid >> amide ~ acyl chloride ~ aldehyde ~ ketone (c) aldehyde ~ ketone > carboxylic acid >> ester ~ acyl chloride ~ amide(d) carboxylic acid > amide >> ester ~ acyl chloride ~ aldehyde ~ ketone

Description : Which of the following is the correct ranking in decreasing order of relative Boiling Point of carbonyl containing compounds? (a) primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone ... chloride ~ amide (d) carboxylic acid > amide >> ester ~ acyl chloride ~ aldehyde ~ ketone

Last Answer : primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone

Organic compound (A), C4H8O, does not react with sodium or PCl5. However, it reduces an alkaline solution of a copper (II) salt on heating. Compound (A) could be (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol

Description : Organic compound (A), C4H8O, does not react with sodium or PCl5. However, it reduces an alkaline solution of a copper (II) salt on heating. Compound (A) could be (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol

Last Answer : an aldehyde

An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (A) could be (a) an aldehyde (b) a ketone (c) an alcohol (d) an ester

Description : An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (A) could be (a) an aldehyde (b) a ketone (c) an alcohol (d) an ester

Last Answer : an alcohol

The appearance of a silver mirror in Tollens' test indicates the presence of : (a) an aldehyde (b) a ketone (c) an alcohol (d) an alkene

Description : The appearance of a silver mirror in Tollens' test indicates the presence of : (a) an aldehyde (b) a ketone (c) an alcohol (d) an alkene

Last Answer : an aldehyde

Oxidation of a secondary alcohol with K2Cr2O7/H+ produces (a) a carboxylic acid (b) a ketone (c) an aldehyde (d) an ester

Description : Oxidation of a secondary alcohol with K2Cr2O7/H+ produces (a) a carboxylic acid (b) a ketone (c) an aldehyde (d) an ester

Last Answer : a ketone

Dry ice on reaction with GR gives_______ a) Ester b) Carboxylic acid c) Aldehyde d) Ketone

Description : Dry ice on reaction with GR gives_______ a) Ester b) Carboxylic acid c) Aldehyde d) Ketone

Last Answer : b) Carboxylic acid

Cyclohexanone is an example of: w) an aldehyde x) a carboxylic acid y) an alkyne z) a ketone

Description : Cyclohexanone is an example of: w) an aldehyde x) a carboxylic acid y) an alkyne z) a ketone

Last Answer : ANSWER: Z -- A KETONE 

What happens when urea is treated with hydrazine? (a) Biuret is formed (b) Semicarbazide is formed(c) Carbon dioxide and nitrogen is formed(d) Acetamide is formed

Description : What happens when urea is treated with hydrazine? (a) Biuret is formed (b) Semicarbazide is formed (c) Carbon dioxide and nitrogen is formed (d) Acetamide is formed

Last Answer : Semicarbazide is formed

Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds of alkynes are higher in energy than the bonds and are thus more reactive. (c) Unlike alkenes, alkynes fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.

Description : Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds ... fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.

Last Answer : Alkynes are generally more reactive than alkenes.

Group that reacts in the Biuret test: (A) Peptide (B) Amino group (C) Carboxylic group (D) Aldehyde group

Description : Group that reacts in the Biuret test: (A) Peptide (B) Amino group (C) Carboxylic group (D) Aldehyde group

Last Answer : Answer : A

Why does a H+ ion attacking a carbon-carbon double bond add to the carbon with the least number of substituents? (a) the reaction is resonance stabilized. (b) the hybrid geometry favors this process. (c) nucleophile tends to attack stable centers of negative charge. (d) a more stable carbonium ion is generated.

Description : Why does a H+ ion attacking a carbon-carbon double bond add to the carbon with the least number of substituents? (a) the reaction is resonance stabilized. (b) the hybrid geometry favors this ... tends to attack stable centers of negative charge. (d) a more stable carbonium ion is generated.

Last Answer : a more stable carbonium ion is generated.

In the reaction of propene with HCl, H+ ion acts as the : (a) electrophile (b) carbonium ion (c) nucleophile (d) carbanion

Description : In the reaction of propene with HCl, H+ ion acts as the : (a) electrophile (b) carbonium ion (c) nucleophile (d) carbanion

Last Answer : electrophile

Which of the following statements is incorrect? (a) Electrons move toward positively charged locations. (b) An electron-rich atom is called an electrophile. (c) An electrophile is electron loving. (d) A nucleophile has a a pair of electrons it can share

Description : Which of the following statements is incorrect? (a) Electrons move toward positively charged locations. (b) An electron-rich atom is called an electrophile. (c) An electrophile is electron loving. (d) A nucleophile has a a pair of electrons it can share

Last Answer : An electron-rich atom is called an electrophile.

A compound reacts with sodium and liberates hydrogen and on oxidation gives ketone. The formula of the compound could be

Description : A compound reacts with sodium and liberates hydrogen and on oxidation gives ketone. The formula of the compound could be

Last Answer : A compound reacts with sodium and liberates hydrogen and on oxidation gives ketone. The formula of the compound could ... `CH_(3)CH_(2)CH_(2)CH_(2)OH`

Chlorophyll a molecule at its carbon atom 3 of the pyrrole ring II has one of the following (a) carboxylic group (b) magnesium (c) aldehyde group (d) methyl group

Description : Chlorophyll a molecule at its carbon atom 3 of the pyrrole ring II has one of the following (a) carboxylic group (b) magnesium (c) aldehyde group (d) methyl group

Last Answer : d) methyl group.

Arrange the following compounds in decreasing order of nucleophilic addition with semicarbazide `NH_(2)NHCONH_(2)` i.e., `ddot(N)H_(2)-ddot(Z)`

Description : Arrange the following compounds in decreasing order of nucleophilic addition with semicarbazide `NH_(2)NHCONH_(2)` i.e., `ddot(N)H_(2)-ddot(Z)`

Last Answer : Arrange the following compounds in decreasing order of nucleophilic addition with semicarbazide `NH_(2)NHCONH_(2)` i.e., `ddot(N)H_(2)-ddot(Z)`

Arrange the following compounds in decreasing order of nucleophilic addition with semicarbazide `NH_(2)NHCONH_(2)` i.e., `ddot(N)H_(2)-ddot(Z)`

Description : Arrange the following compounds in decreasing order of nucleophilic addition with semicarbazide `NH_(2)NHCONH_(2)` i.e., `ddot(N)H_(2)-ddot(Z)`

Last Answer : Arrange the following compounds in decreasing order of nucleophilic addition with semicarbazide `NH_(2)NHCONH_(2)` i.e., `ddot(N)H_(2)-ddot(Z)`

In human and other ureotelic organisms, the end product of amino acid nitrogen metabolism: (A) Bile acids (B) Ketone bodies (C) Urea (D) Barium sulphate

Description : In human and other ureotelic organisms, the end product of amino acid nitrogen metabolism: (A) Bile acids (B) Ketone bodies (C) Urea (D) Barium sulphate

Last Answer : Answer : C

A chlorine atom reacts with a sodium atom to form sodium chloride, NaCl. A chlorine atom can also react with another chlorine atom to form a chlorine molecule, Cl2. Which statement BEST explains the behavior of chlorine in these two reactions?

Description : A chlorine atom reacts with a sodium atom to form sodium chloride, NaCl. A chlorine atom can also react with another chlorine atom to form a chlorine molecule, Cl2. Which statement BEST explains the behavior of chlorine in these two reactions?

Last Answer : A chlorine atom can form ionic bonds by accepting an electron and covalent bonds by sharing electrons.

When `H_(2)` reacts with Na, it acts as

Description : When `H_(2)` reacts with Na, it acts as

Last Answer : When `H_(2)` reacts with Na, it acts as A. Oxidising agent B. Peducing agent C. Both D. None

When a compound X reacts with ozone in aq medium, a compound Y is produced. Ozone also reacts with moist Y and produces compound Z. Z acts as an oxidi

Description : When a compound X reacts with ozone in aq medium, a compound Y is produced. Ozone also reacts with moist Y and produces compound Z. Z acts as an oxidi

Last Answer : When a compound X reacts with ozone in aq medium, a compound Y is produced. Ozone also reacts with moist Y and ... `X=HI, Y=I_(2) and Z=HIO_(4)`

A solution of sulphur dioxide in water reacts with `H_(2)S` precipitating sulphur. Here sulphur dioxide acts as

Description : A solution of sulphur dioxide in water reacts with `H_(2)S` precipitating sulphur. Here sulphur dioxide acts as

Last Answer : A solution of sulphur dioxide in water reacts with `H_(2)S` precipitating sulphur. Here sulphur dioxide ... a reducing agent C. an acid D. a catalyst

Which of the following is not a possible reaction of a carbocation? (a) addition of a nucleophile (b) rearrangement to a more stable carbocation (c) addition of a proton to form an alkane (d) loss of a β-hydrogen to form an alkene

Description : Which of the following is not a possible reaction of a carbocation? (a) addition of a nucleophile (b) rearrangement to a more stable carbocation (c) addition of a proton to form an alkane (d) loss of a β-hydrogen to form an alkene

Last Answer : addition of a proton to form an alkane

Chlorine atom and chloride ions - (1) Have an equal number of protons (2) Have an equal number of electrons (3) Unequal number neutrons (4) reacts spontaneously with water

Description : Chlorine atom and chloride ions - (1) Have an equal number of protons (2) Have an equal number of electrons (3) Unequal number neutrons (4) reacts spontaneously with water

Last Answer : (1) Have an equal number of protons

Which of the following is not a nucleophile ?

Description : Which of the following is not a nucleophile ?

Last Answer : Which of the following is not a nucleophile ? A. `H_(2)` B. `CH_(3)OH` C. `H_(2)O` D. `NH_(3)`

Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)=CH_(2))" "underset("(2)")(CH_(2)=

Description : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)=CH_(2))" "underset("(2)")(CH_(2)=

Last Answer : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)= ... and (4) D. (2), (3) and (4)

`NH_(3) + NaOCl overset("golatin or " EDTA^(+))rarr` products The number of moles of `N - H` bonds present in one mole of the strongest nucleophile pr

Description : `NH_(3) + NaOCl overset("golatin or " EDTA^(+))rarr` products The number of moles of `N - H` bonds present in one mole of the strongest nucleophile pr

Last Answer : `NH_(3) + NaOCl overset("golatin or " EDTA^(+))rarr` products The number of moles of ... mole of the strongest nucleophile present in the product is:

Which of the following is not a nucleophile ?

Description : Which of the following is not a nucleophile ?

Last Answer : Which of the following is not a nucleophile ? A. `H_(2)` B. `CH_(3)OH` C. `H_(2)O` D. `NH_(3)`

Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)=CH_(2))" "underset("(2)")(CH_(2)=

Description : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)=CH_(2))" "underset("(2)")(CH_(2)=

Last Answer : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)= ... and (4) D. (2), (3) and (4)

`NH_(3) + NaOCl overset("golatin or " EDTA^(+))rarr` products The number of moles of `N - H` bonds present in one mole of the strongest nucleophile pr

Description : `NH_(3) + NaOCl overset("golatin or " EDTA^(+))rarr` products The number of moles of `N - H` bonds present in one mole of the strongest nucleophile pr

Last Answer : `NH_(3) + NaOCl overset("golatin or " EDTA^(+))rarr` products The number of moles of ... mole of the strongest nucleophile present in the product is:

Which of the following are nucleophile?

Description : Which of the following are nucleophile?

Last Answer : Which of the following are nucleophile? A. `NH_(3)` B. `OH^(-)` C. `R-O-R` D. `AlCl_(3)`

A nucleophile must have :

Description : A nucleophile must have :

Last Answer : A nucleophile must have : A. a negative charge B. a positive charge C. a lone pair of electron D. an electron deficient centre

Which one of the following behaves both as a nucleophile and an electrophile ?

Description : Which one of the following behaves both as a nucleophile and an electrophile ?

Last Answer : Which one of the following behaves both as a nucleophile and an electrophile ? A. `CH_(3)NH_(2)` B. `CH_(3)OH` C. `CH_(3)CN` D. `CH_(3)Cl`

A nucleophile is:

Description : A nucleophile is:

Last Answer : A nucleophile is: A. electron-rich species B. electron-deficient species C. a Lewis base D. positively charged species

Why cyanide ion act as ambident nucleophile ?

Description : Why cyanide ion act as ambident nucleophile ?

Last Answer : Ans.---- Cyanide ion can link through either carbon or nitrogen, therefore it is an ambident nuclophile.

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Which of the following factors has no effect on the rate of SN1 reactions? (a) the nature of the alkyl halide (b) the nature of the leaving group (c) the concentration of the alkyl halide (d) the concentration of the nucleophile

Description : Which of the following factors has no effect on the rate of SN1 reactions? (a) the nature of the alkyl halide (b) the nature of the leaving group (c) the concentration of the alkyl halide (d) the concentration of the nucleophile

Last Answer : the concentration of the nucleophile