Description : Oxidation of a secondary alcohol with K2Cr2O7/H+ produces (a) a carboxylic acid (b) a ketone (c) an aldehyde (d) an ester
Last Answer : a ketone
Description : An alcohol is related to an ester as a hydroxide compound is related to: w) an acid x) a ketone y) an ether z) a salt
Last Answer : ANSWER: Z -- A SALT
Description : Acid and alcohol react to form (a) Aldehyde and water (b) Ketone and water (c) Acid anhydride and water (d) Ester and water
Last Answer : Ans:(d)
Description : An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (A) could be (a) an aldehyde (b) a ketone (c) an alcohol (d) an ester
Last Answer : an alcohol
Description : Cyclohexanone is an example of: w) an aldehyde x) a carboxylic acid y) an alkyne z) a ketone
Last Answer : ANSWER: Z -- A KETONE
Description : Which of the following is the correct ranking in decreasing order of relative Boiling Point of carbonyl containing compounds? (a) primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone ... chloride ~ amide (d) carboxylic acid > amide >> ester ~ acyl chloride ~ aldehyde ~ ketone
Last Answer : primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone
Description : Dry ice on reaction with GR gives_______ a) Ester b) Carboxylic acid c) Aldehyde d) Ketone
Last Answer : b) Carboxylic acid
Description : Ethylmagnesium iodide reacts with formaldehyde to give a product which on acid-hydrolysis forms : (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol
Last Answer : a primary alcohol
Description : Which of the following compounds will not be easily oxidized? (a) Primary alcohol (b) Secondary alcohol (c) Tertiary alcohol (d) Aldehyde
Last Answer : Tertiary alcohol
Description : Which one of the following organic compounds has fruity smell? (1) Alcohol (2) Aldehyde (3) Ester (4) Ether
Last Answer : (3) Ester Explanation: Esters are common in organic chemistry and biological materials, and often have a characteristic pleasant, fruity odour. This leads to their extensive use in the fragrance and ... ester as the reaction product. Esters are widespread in nature and are widely used in industry.
Last Answer : Ester
Description : Organic compound (A), C4H8O, does not react with sodium or PCl5. However, it reduces an alkaline solution of a copper (II) salt on heating. Compound (A) could be (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol
Last Answer : an aldehyde
Description : The appearance of a silver mirror in Tollens' test indicates the presence of : (a) an aldehyde (b) a ketone (c) an alcohol (d) an alkene
Description : Which of the following is correct? (a) When a Grignard reagent reacts with a ketone, the addition product is a primary alcohol. (b) When a Grignard reagent reacts with a ketone, the addition product ... with a aldehyde, the addition product is a tertiary alcohol. (d) None of the above are correct.
Last Answer : None of the above are correct.
Description : The mutarotation of glucose is characterized by : (a) a change from an aldehyde to ketone structure. (b) a change of specific rotation from a (+) to a (–) value. (c) the presence of an intramolecular bridge structure. (d) the irreversible change from α-D to the β-D form.
Last Answer : the presence of an intramolecular bridge structure.
Description : An aqueous solution of glucose behaves as an aldehyde because __________. (a) it is hydrolyzed by water to the free aldehyde (b) it is a ketone, but is in equilibrium with the aldehyde form ... aldehyde (d) its cyclic hemiacetal, the predominant form, is in equilibrium with the free aldehyde form
Last Answer : its cyclic hemiacetal, the predominant form, is in equilibrium with the free aldehyde form
Description : When an aldehyde is heated with Fehling's solution, the aldehyde undergoes one of the following processes. Does it undergo: w) neutralization x) oxidation y) reduction z) esterification
Last Answer : ANSWER: X -- OXIDATION
Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Description : . Monosaccharides are classified according to : (a) the number of carbon atoms in the molecule. (b) whether they contain an aldehyde or a ketone group (c) their configurational relationship to glyceraldehyde. (d) all of the above
Last Answer : all of the above
Description : Which of the following is NOT oxidized by chlorine? w) F- (read: F minus) x) Br- (read: B - R minus) y) F2 (read: F - 2) z) I- (read: I minus)
Last Answer : ANSWER: A -- F
Description : In the common dry cell, the zinc atoms are: w) reduced at the cathode x) oxidized at the cathode y) oxidized at the anode z) reduced at the anode
Last Answer : ANSWER: Y -- OXIDIZED AT THE ANODE
Description : Which of the following odors does the ester isoamyl isovalerate produce? Is it an odor of: w) bananas x) apples y) cherries z) strawberries
Last Answer : ANSWER: B -- APPLES
Description : Which of the following odors does the ester, methyl salicylate, produce? Is the odor that of: w) cinnamon x) avocado y) orange z) oil of wintergreen
Last Answer : ANSWER: D -- OIL OF WINTERGREEN
Description : When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one nitrogen atom of semicarbazide acts as a nucleophile and attack
Last Answer : When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one ... atoms of semicarbazide are relatively non nucleophilic ?
Description : Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an aldol condensation reaction. (a)2-Ethyl-3-hydroxy
Last Answer : Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an ... hexanal (b) 4-Hydroxy-4-methyl-2-pentanone
Description : Which disaccharide has no free aldehyde or ketone group?
Last Answer : Sucrose.
Description : The Statue of Liberty is green because of: w) green stone x) oxidized brass y) steel painted green z) oxidized copper
Last Answer : ANSWER: Z -- OXIDIZED COPPER
Description : All the following statements about ketone bodies are true except (A) Their synthesis increases in diabetes mellitus (B) They are synthesized in mitchondria (C) They can deplete the alkali reserve (D) They can be oxidized in the liver
Last Answer : Answer : D
Description : A hydrazone will result from the reaction of hydrazine with (a) a phenol (b) an aldehyde (c) an alcohol (d) an acid
Description : . The reduction of cyclohexanone with LiAlH4 (or NaBH4) will give (a) an alcohol (b) an organic acid (c) an aldehyde (d) a hemiketal
Description : In the United States, Grain alcohol is made: w) from coal x) by fermenting starches y) from methanol z) from vinegar e) by fermenting acetic acid
Last Answer : ANSWER: X -- BY FERMENTING STARCHES
Description : During preparation of esters from a carboxylic acid and an alcohol in the presence of an acid catalyst, water or the ester formed should be removed as soon as it is formed.
Last Answer : Ans. The formation of esters from a carboxylic acid and an alcohol in the presence of acid catalyst in a reversible reaction. To shift the equilibrium in the forward direction, the water or ester formed should be removed as fast as it is formed.
Description : Consider a small aliphatic 1° amine, 1° alcohol, ester, carboxylic acid, and amide, all of similar molecular weight. Which one is most likely to have the highest boiling point? (a) The amide (b) The alcohol (c) The ester (d) The carboxylic acid
Last Answer : The amide
Description : A compound undergoes reduction with LiAlH4. It also dissolves in aqueous NaOH from which it can be recovered by addition of HCl. The compound is (a) a carboxylic acid (b) an ester (c) an acid anhydride (d) an alcohol
Last Answer : a carboxylic acid
Description : Which reaction does not yield an ester as one of the products? (a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid
Last Answer : A Grignard reagent is added to a carboxylic acid
Description : The reduction of a ketone (a) always gives a primary alcohol (b) always gives a secondary alcohol (c) always gives a carboxylic acid (d) always gives a ketal
Last Answer : always gives a secondary alcoho
Description : Oxidation of a primary alcohol with produces (a) a carboxylic acid (b) an ether (c) a ketone (d) an ester
Description : The conversion of aldehyde having no alpha hydrogen to a mixture to a mixture of carboxylic acid and primary alcohol is known as cannizzaro reaction.
Last Answer : The conversion of aldehyde having no alpha hydrogen to a mixture to a mixture of carboxylic acid and primary ... final product is A. B. C. D.
Last Answer : The conversion of aldehyde having no alpha hydrogen to a mixture to a mixture of carboxylic acid and primary ... C. step III D. step I and II both
Description : Base-catalyzed condensation of two ester molecules to form an alcohol and β-keto ester is called (a) Claisen condensation (b) Corey-House reaction (c) Aldol condensation (d) Transesterification
Last Answer : Claisen condensation
Description : Based on the intermolecular forces involved, which of the following molecules will have the lowest boiling point? w) ethane x) methyl alcohol y) methyl amine z) methyl fluoride
Last Answer : ANSWER: W -- ethane
Description : The alcohol with lowest molecular weight is: w) isopropanol x) propanol y) ethanol z) methanol
Last Answer : ANSWER: Z -- METHANOL
Description : The substance whose chemical formula is CH3OH is known as w) carbonated water x) grain alcohol y) potable alcohol z) methanol
Description : What are soaps? (1) Salts of silicates (2) Ester of heavy fatty acids (3) Sodium or potassium salts of heavier fatty acids (4) Mixture of glycerol and alcohol
Last Answer : (3) Sodium or potassium salts of heavier fatty acids
Description : Which of the following conditions will drive the equilibrium of the Fischer esterification towards ester formation? (a) addition of water (b) removal of water as it is formed (c) addition of alcohol (d) both (b) and (c)
Last Answer : both (b) and (c)
Description : Alcohol is produced by the (A) Oxidation of an aldehyde (B) Hydrolysis of an ether (C) Esterification of a fat (D) None of these
Last Answer : (B) Hydrolysis of an ether
Description : Safety aside, for which of the following reasons is alcohol used in preference to mercury in a minimum thermometer? w) Alcohol has a higher boiling point x) Alcohol has a lower freezing point y) Alcohol contracts more uniformly z) Alcohol can be dyed for visibility
Last Answer : ANSWER: X -- ALCOHOL HAS A LOWER FREEZING POINT