Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an aldol condensation reaction. (a)2-Ethyl-3-hydroxy

Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an aldol condensation reaction. (a)2-Ethyl-3-hydroxy
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Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an ... hexanal (b) 4-Hydroxy-4-methyl-2-pentanone
by

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Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an aldol condensation reaction. (a)2-Ethyl-3-hydroxy

Description : Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an aldol condensation reaction. (a)2-Ethyl-3-hydroxy

Last Answer : Indicate the starting aldehyde or ketone from which each of the following compounds are formed by an ... hexanal (b) 4-Hydroxy-4-methyl-2-pentanone

Total aldol condensation products (including stereosimers) formed by the reaction between acetaldehyde and acetophenone is :

Description : Total aldol condensation products (including stereosimers) formed by the reaction between acetaldehyde and acetophenone is :

Last Answer : Total aldol condensation products (including stereosimers) formed by the reaction between acetaldehyde and acetophenone is :

Total aldol condensation products (including stereosimers) formed by the reaction between acetaldehyde and acetophenone is :

Description : Total aldol condensation products (including stereosimers) formed by the reaction between acetaldehyde and acetophenone is :

Last Answer : Total aldol condensation products (including stereosimers) formed by the reaction between acetaldehyde and acetophenone is :

Which of the following is the correct ranking in decreasing order of relative Boiling Point of carbonyl containing compounds? (a) primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone (b) ester > carboxylic acid >> amide ~ acyl chloride ~ aldehyde ~ ketone (c) aldehyde ~ ketone > carboxylic acid >> ester ~ acyl chloride ~ amide(d) carboxylic acid > amide >> ester ~ acyl chloride ~ aldehyde ~ ketone

Description : Which of the following is the correct ranking in decreasing order of relative Boiling Point of carbonyl containing compounds? (a) primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone ... chloride ~ amide (d) carboxylic acid > amide >> ester ~ acyl chloride ~ aldehyde ~ ketone

Last Answer : primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone

In the scheme given below, the total number of intramolecular aldol condensation products formed from (Y) is

Description : In the scheme given below, the total number of intramolecular aldol condensation products formed from (Y) is

Last Answer : In the scheme given below, the total number of intramolecular aldol condensation products formed from (Y) is

Dry ice on reaction with GR gives_______ a) Ester b) Carboxylic acid c) Aldehyde d) Ketone

Description : Dry ice on reaction with GR gives_______ a) Ester b) Carboxylic acid c) Aldehyde d) Ketone

Last Answer : b) Carboxylic acid

Base-catalyzed condensation of two ester molecules to form an alcohol and β-keto ester is called (a) Claisen condensation (b) Corey-House reaction (c) Aldol condensation (d) Transesterification

Description : Base-catalyzed condensation of two ester molecules to form an alcohol and β-keto ester is called (a) Claisen condensation (b) Corey-House reaction (c) Aldol condensation (d) Transesterification

Last Answer : Claisen condensation

When formaldehyde is treated with 50% NaOH solution, it undergoes (a) Cannizzaro reaction (b) Wurtz reaction (c) Aldol condensation (d) Hydrolysis

Description : When formaldehyde is treated with 50% NaOH solution, it undergoes (a) Cannizzaro reaction (b) Wurtz reaction (c) Aldol condensation (d) Hydrolysis

Last Answer : Cannizzaro reaction

Acetone undergoes reduction with zinc amalgam in HCl to form propane. This reaction is known as (a) Clemmensen reduction (b) Wolf-Kishner reduction (c) Rosenmund reduction(d) Aldol condensation

Description : Acetone undergoes reduction with zinc amalgam in HCl to form propane. This reaction is known as (a) Clemmensen reduction (b) Wolf-Kishner reduction (c) Rosenmund reduction (d) Aldol condensation

Last Answer : Clemmensen reduction

The reaction of a sodium alkoxide with an alkyl halide is called (a) Wurtz-Fittig reaction (b) Perkin reaction (c) Williamson's synthesis (d) Aldol condensation

Description : The reaction of a sodium alkoxide with an alkyl halide is called (a) Wurtz-Fittig reaction (b) Perkin reaction (c) Williamson's synthesis (d) Aldol condensation

Last Answer : Williamson's synthesis

The conversion of secondary alcohol to ketones in presence of aluminium isopropoxide and acetone as solvent is? a. Canizarro reaction b. Oppenauer oxidation c. Suzuki reaction d. Aldol Condensation

Description : The conversion of secondary alcohol to ketones in presence of aluminium isopropoxide and acetone as solvent is? a. Canizarro reaction b. Oppenauer oxidation c. Suzuki reaction d. Aldol Condensation

Last Answer : b. Oppenauer oxidation

When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one nitrogen atom of semicarbazide acts as a nucleophile and attack

Description : When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one nitrogen atom of semicarbazide acts as a nucleophile and attack

Last Answer : When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one ... atoms of semicarbazide are relatively non nucleophilic ?

Acid and alcohol react to form (a) Aldehyde and water (b) Ketone and water (c) Acid anhydride and water (d) Ester and water

Description : Acid and alcohol react to form (a) Aldehyde and water (b) Ketone and water (c) Acid anhydride and water (d) Ester and water

Last Answer : Ans:(d)

Which disaccharide has no free aldehyde or ketone group?

Description : Which disaccharide has no free aldehyde or ketone group?

Last Answer : Sucrose.

The mutarotation of glucose is characterized by : (a) a change from an aldehyde to ketone structure. (b) a change of specific rotation from a (+) to a (–) value. (c) the presence of an intramolecular bridge structure. (d) the irreversible change from α-D to the β-D form.

Description : The mutarotation of glucose is characterized by : (a) a change from an aldehyde to ketone structure. (b) a change of specific rotation from a (+) to a (–) value. (c) the presence of an intramolecular bridge structure. (d) the irreversible change from α-D to the β-D form.

Last Answer : the presence of an intramolecular bridge structure.

. Monosaccharides are classified according to : (a) the number of carbon atoms in the molecule. (b) whether they contain an aldehyde or a ketone group(c) their configurational relationship to glyceraldehyde.(d) all of the above

Description : . Monosaccharides are classified according to : (a) the number of carbon atoms in the molecule. (b) whether they contain an aldehyde or a ketone group (c) their configurational relationship to glyceraldehyde. (d) all of the above

Last Answer : all of the above

An aqueous solution of glucose behaves as an aldehyde because __________. (a) it is hydrolyzed by water to the free aldehyde (b) it is a ketone, but is in equilibrium with the aldehyde form (c) glucose is actually a cyclic aldehyde (d) its cyclic hemiacetal, the predominant form, is in equilibrium with the free aldehyde form

Description : An aqueous solution of glucose behaves as an aldehyde because __________. (a) it is hydrolyzed by water to the free aldehyde (b) it is a ketone, but is in equilibrium with the aldehyde form ... aldehyde (d) its cyclic hemiacetal, the predominant form, is in equilibrium with the free aldehyde form

Last Answer : its cyclic hemiacetal, the predominant form, is in equilibrium with the free aldehyde form

Organic compound (A), C4H8O, does not react with sodium or PCl5. However, it reduces an alkaline solution of a copper (II) salt on heating. Compound (A) could be (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol

Description : Organic compound (A), C4H8O, does not react with sodium or PCl5. However, it reduces an alkaline solution of a copper (II) salt on heating. Compound (A) could be (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol

Last Answer : an aldehyde

An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (A) could be (a) an aldehyde (b) a ketone (c) an alcohol (d) an ester

Description : An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (A) could be (a) an aldehyde (b) a ketone (c) an alcohol (d) an ester

Last Answer : an alcohol

The appearance of a silver mirror in Tollens' test indicates the presence of : (a) an aldehyde (b) a ketone (c) an alcohol (d) an alkene

Description : The appearance of a silver mirror in Tollens' test indicates the presence of : (a) an aldehyde (b) a ketone (c) an alcohol (d) an alkene

Last Answer : an aldehyde

Oxidation of a secondary alcohol with K2Cr2O7/H+ produces (a) a carboxylic acid (b) a ketone (c) an aldehyde (d) an ester

Description : Oxidation of a secondary alcohol with K2Cr2O7/H+ produces (a) a carboxylic acid (b) a ketone (c) an aldehyde (d) an ester

Last Answer : a ketone

Which of the following is correct? (a) When a Grignard reagent reacts with a ketone, the addition product is a primary alcohol. (b) When a Grignard reagent reacts with a ketone, the addition product is a secondaryalcoho(c) When a Grignard reagent reacts with a aldehyde, the addition product is a tertiary alcohol. (d) None of the above are correct.l

Description : Which of the following is correct? (a) When a Grignard reagent reacts with a ketone, the addition product is a primary alcohol. (b) When a Grignard reagent reacts with a ketone, the addition product ... with a aldehyde, the addition product is a tertiary alcohol. (d) None of the above are correct.

Last Answer : None of the above are correct.

Ethylmagnesium iodide reacts with formaldehyde to give a product which on acid-hydrolysis forms : (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol

Description : Ethylmagnesium iodide reacts with formaldehyde to give a product which on acid-hydrolysis forms : (a) an aldehyde (b) a primary alcohol (c) a ketone (d) a secondary alcohol

Last Answer : a primary alcohol

An aldehyde can be oxidized to form: w) a ketone x) an acid y) an alcohol z) an ester

Description : An aldehyde can be oxidized to form: w) a ketone x) an acid y) an alcohol z) an ester 

Last Answer : ANSWER: X -- AN ACID

Cyclohexanone is an example of: w) an aldehyde x) a carboxylic acid y) an alkyne z) a ketone

Description : Cyclohexanone is an example of: w) an aldehyde x) a carboxylic acid y) an alkyne z) a ketone

Last Answer : ANSWER: Z -- A KETONE 

Number of possible intra molecular aldol condensation product on heating with NaOH `H_(3)C-overset(O)overset(||)(C)-CH_(2)-CH_(2)-CH_(2)-overset(O)ove

Description : Number of possible intra molecular aldol condensation product on heating with NaOH `H_(3)C-overset(O)overset(||)(C)-CH_(2)-CH_(2)-CH_(2)-overset(O)ove

Last Answer : Number of possible intra molecular aldol condensation product on heating with NaOH `H_(3)C-overset(O)overset(|| ... CH_(2)-overset(O)overset(||)(C)-H`

(X) is the product of cross aldol condensation between benzaldehyde `(C_(6)H_(5)CHO)` and acetone. What is its structure ?

Description : (X) is the product of cross aldol condensation between benzaldehyde `(C_(6)H_(5)CHO)` and acetone. What is its structure ?

Last Answer : (X) is the product of cross aldol condensation between benzaldehyde `(C_(6)H_(5)CHO)` and acetone. What is its ... )-C=(CH_(3))_(2)` D. None of these

Number of possible intra molecular aldol condensation product on heating with NaOH `H_(3)C-overset(O)overset(||)(C)-CH_(2)-CH_(2)-CH_(2)-overset(O)ove

Description : Number of possible intra molecular aldol condensation product on heating with NaOH `H_(3)C-overset(O)overset(||)(C)-CH_(2)-CH_(2)-CH_(2)-overset(O)ove

Last Answer : Number of possible intra molecular aldol condensation product on heating with NaOH `H_(3)C-overset(O)overset(|| ... CH_(2)-overset(O)overset(||)(C)-H`

(X) is the product of cross aldol condensation between benzaldehyde `(C_(6)H_(5)CHO)` and acetone. What is its structure ?

Description : (X) is the product of cross aldol condensation between benzaldehyde `(C_(6)H_(5)CHO)` and acetone. What is its structure ?

Last Answer : (X) is the product of cross aldol condensation between benzaldehyde `(C_(6)H_(5)CHO)` and acetone. What is its ... )-C=(CH_(3))_(2)` D. None of these

Why does methanal not give aldol condensation while ethanol gives ?

Description : Why does methanal not give aldol condensation while ethanol gives ? 

Last Answer : Ans. This is because only those compounds which have hydrogen atoms can undergo  aldol reaction. Ethanol possesses -hydrogen and undergoes aldol condensation.   Methanal has no hydrogen atoms, hence does not undergo aldol condensation. 

Which of the following will undergo Aldol condensation? (a) Acetone (b) Benzaldehyde (c) Benzoic acid (c) Benzophenone

Description : Which of the following will undergo Aldol condensation? (a) Acetone (b) Benzaldehyde (c) Benzoic acid (c) Benzophenone

Last Answer : Acetone

Which of the following statements describes the first step in the mechanism of the aldol condensation? (a) An alpha hydrogen is abstracted by the base to form an enolate anion. (b) A nucleophilic base attacks the carbonyl carbon atom. (c) The carbonyl oxygen is protonated by the base ion. (d) The alpha hydrogen is abstracted by an acid to the enolate anion.

Description : Which of the following statements describes the first step in the mechanism of the aldol condensation? (a) An alpha hydrogen is abstracted by the base to form an enolate anion. (b) A nucleophilic base attacks ... by the base ion. (d) The alpha hydrogen is abstracted by an acid to the enolate anion.

Last Answer : An alpha hydrogen is abstracted by the base to form an enolate anion

Pick out the wrong statement. (A) DDT is manufactured by the condensation of chlorobenzene with chloral at 30°C in presence of oleum, which is a highly exothermic reaction (B) Chloral is obtained by the chlorination of ethyl alcohol (C) Insecticides acting on the insects through the respiratory system are called fumigants (D) Benzene hexachloride is not a contact insecticide

Description : Pick out the wrong statement. (A) DDT is manufactured by the condensation of chlorobenzene with chloral at 30°C in presence of oleum, which is a highly exothermic reaction (B) Chloral ... through the respiratory system are called fumigants (D) Benzene hexachloride is not a contact insecticide

Last Answer : (D) Benzene hexachloride is not a contact insecticide

What is different between methyl ethyl ketone and paint thinner?

Description : What is different between methyl ethyl ketone and paint thinner?

Last Answer : paint thinner is any solvent used either to thin paint or cleanup after finishing painting, typically a mixture of organic solvents with mineral spirits being a major componentmethyl ethyl ketone is an ... be a component in a given brand of paint thinner, also available as a separate product

Which of the following is used as a solvent in deasphalting of petroleum products? (A) Furfural (B) Propane (C) Methyl ethyl ketone (D) Liquid sulphur dioxide

Description : Which of the following is used as a solvent in deasphalting of petroleum products? (A) Furfural (B) Propane (C) Methyl ethyl ketone (D) Liquid sulphur dioxide

Last Answer : (B) Propane

Solvent used in the Udex (glycol) extraction process for removal of light aromatics from cracked naphtha is (A) Propane (B) Diethylene glycol (C) Aqueous solution (10% water) of diethylene glycol (D) Methyl ethyl ketone (MEK)

Description : Solvent used in the Udex (glycol) extraction process for removal of light aromatics from cracked naphtha is (A) Propane (B) Diethylene glycol (C) Aqueous solution (10% water) of diethylene glycol (D) Methyl ethyl ketone (MEK)

Last Answer : (C) Aqueous solution (10% water) of diethylene glycol

Solvent used in duo-sol extraction for lube oil upgradation is a mixture of (A) Propane & phenol-cresol mixture(B) Methyl ethyl ketone & glycol(C) Phenol & furfural(D) Propane & liquid sulphur dioxide

Description : Solvent used in duo-sol extraction for lube oil upgradation is a mixture of (A) Propane & phenol-cresol mixture (B) Methyl ethyl ketone & glycol (C) Phenol & furfural (D) Propane & liquid sulphur dioxide

Last Answer : (A) Propane & phenol-cresol mixture

Solvent deoiling process is used for separating oil and soft wax from hard wax. Methyl iso-butyl ketone and methyl ethyl ketone (MEK) are two commonly used deoiling solvents. Use of former as the deoiling solvent has the advantages of the (A) Elimination of solvent drying facility (B) Higher nitration temperature (C) Lower solvent dilution ratio (D) All (A), (B) & (C)

Description : Solvent deoiling process is used for separating oil and soft wax from hard wax. Methyl iso-butyl ketone and methyl ethyl ketone (MEK) are two commonly used deoiling solvents. Use of former as the deoiling solvent ... nitration temperature (C) Lower solvent dilution ratio (D) All (A), (B) & (C)

Last Answer : (D) All (A), (B) & (C)

Most widely used solvent for dewaxing is (A) Methyl-ethyl-ketone (MEK) (B) Naphtha (C) Petroleum ether (D) Sodium plumbite

Description : Most widely used solvent for dewaxing is (A) Methyl-ethyl-ketone (MEK) (B) Naphtha (C) Petroleum ether (D) Sodium plumbite

Last Answer : (A) Methyl-ethyl-ketone (MEK)

The most suitable solvent for deasphalting vacuum residue is (A) Propane (B) Methyl ethyl ketone (C) Doctor's solution (D) Methanol amine

Description : The most suitable solvent for deasphalting vacuum residue is (A) Propane (B) Methyl ethyl ketone (C) Doctor's solution (D) Methanol amine

Last Answer : (B) Methyl ethyl ketone

The solvent used in Barisol dewaxing process is (A) Hexane (B) Furfural (C) Benzol and ethylene dichloride (D) Methyl ethyl ketone (MEK

Description : The solvent used in Barisol dewaxing process is (A) Hexane (B) Furfural (C) Benzol and ethylene dichloride (D) Methyl ethyl ketone (MEK

Last Answer : (C) Benzol and ethylene dichloride

Solvent used for dewaxing of petroleum products are (A) Furfural (B) Methyl ethyl ketone (MEK) (C) Propane (D) Both (B) & (C

Description : Solvent used for dewaxing of petroleum products are (A) Furfural (B) Methyl ethyl ketone (MEK) (C) Propane (D) Both (B) & (C

Last Answer : (C) Propane

The commonly used solvent in supercritical extraction is (A) Methyl ethyl ketone (B) Water (C) Carbon tetrachloride (D) Carbon dioxide

Description : The commonly used solvent in supercritical extraction is (A) Methyl ethyl ketone (B) Water (C) Carbon tetrachloride (D) Carbon dioxide

Last Answer : (D) Carbon dioxide

When ethyl acetoacetate is subjected to ketonic hydrolysis, the ketoneobtained is(a) Dimethyl ketone(b) Methyl ethyl ketone(c) Diethyl ketone(d) Methyl n-propyl ketone

Description : When ethyl acetoacetate is subjected to ketonic hydrolysis, the ketone obtained is (a) Dimethyl ketone (b) Methyl ethyl ketone (c) Diethyl ketone (d) Methyl n-propyl ketone

Last Answer : Diethyl ketone

Solvent used for extraction of oil is (A) Hexane (B) Methyl ethyl ketone (C) Furfural (D) None of these

Description : Solvent used for extraction of oil is (A) Hexane (B) Methyl ethyl ketone (C) Furfural (D) None of these

Last Answer : (A) Hexane

Pick out the wrong statement. (A) 'Solvates' are chemical compounds formed by solute with their solvents. When water is the solvent, then it is called a 'hydrate' (B) In heat exchanger calculations (Δt) weighted is used in place of Δt, when it involves more than one sequence of heating or cooling i.e., desuperheating & condensation or condensation & sub-cooling (C) Heat transfer co-efficient during nucleate boiling is not influenced by the agitation imparted (D) In case of short tube vertical evaporators, area of central downtake is about 50 to 100% of the total tube cross-sectional area

Description : Pick out the wrong statement. (A) 'Solvates' are chemical compounds formed by solute with their solvents. When water is the solvent, then it is called a 'hydrate' (B) In heat exchanger ... vertical evaporators, area of central downtake is about 50 to 100% of the total tube cross-sectional area

Last Answer : (C) Heat transfer co-efficient during nucleate boiling is not influenced by the agitation imparted

Which one of the following organic compounds has fruity smell? (1) Alcohol (2) Aldehyde (3) Ester (4) Ether

Description : Which one of the following organic compounds has fruity smell? (1) Alcohol (2) Aldehyde (3) Ester (4) Ether

Last Answer : (3) Ester Explanation: Esters are common in organic chemistry and biological materials, and often have a characteristic pleasant, fruity odour. This leads to their extensive use in the fragrance and ... ester as the reaction product. Esters are widespread in nature and are widely used in industry.

Which of the following compounds will not be easily oxidized? (a) Primary alcohol (b) Secondary alcohol (c) Tertiary alcohol (d) Aldehyde

Description : Which of the following compounds will not be easily oxidized? (a) Primary alcohol (b) Secondary alcohol (c) Tertiary alcohol (d) Aldehyde

Last Answer : Tertiary alcohol

Which one of the following organic compounds has fruity smell? (1) Alcohol (2) Aldehyde (3) Ester (4) Ether

Description : Which one of the following organic compounds has fruity smell? (1) Alcohol (2) Aldehyde (3) Ester (4) Ether

Last Answer : Ester

Bisphenol A is produced by the condensation of acetone with (A) Formaldehyde (B) Ethyl alcohol (C) Diethyl ether (D) Phenol

Description : Bisphenol A is produced by the condensation of acetone with (A) Formaldehyde (B) Ethyl alcohol (C) Diethyl ether (D) Phenol

Last Answer : (D) Phenol