Description : The hydroboration-oxidation reaction can be characterized as the _________ to an alkene. (a) anti-Markovnikov syn addition of water (b) anti-Markovnikov anti addition of water (c) Markovnikov syn addition of water (d) Markovnikov anti addition of water
Last Answer : anti-Markovnikov syn addition of water
Description : Disappearance of pink colour of water of a well due of KMnO4 indicates that water contains (A) Acidity (B) Alkalinity (C) Turbidity (D) Organic matter
Last Answer : (D) Organic matter
Description : Sodium phenoxide reacts with CO2 at 125°C under 5 atm pressure to give salicylic acid. This reaction is called (a) Kolbe's reaction (b) Perkin reaction (c) Wurtz reaction (d) HVZ reaction
Last Answer : Kolbe's reaction
Description : Silver acetate reacts with Br2 to form methyl bromide, carbon dioxide, and AgBr. This is an example of (a) Wurtz reaction (b) Etard's reaction (c) Hunsdiecker reaction (d) Perkin reaction
Last Answer : Hunsdiecker reaction
Description : When formaldehyde is treated with 50% NaOH solution, it undergoes (a) Cannizzaro reaction (b) Wurtz reaction (c) Aldol condensation (d) Hydrolysis
Last Answer : Cannizzaro reaction
Description : The reaction of a sodium alkoxide with an alkyl halide is called (a) Wurtz-Fittig reaction (b) Perkin reaction (c) Williamson's synthesis (d) Aldol condensation
Last Answer : Williamson's synthesis
Description : Which of the following reactions can be used to prepare alkanes? (a) Wurtz reaction (b) Wolf-kishner reduction (c) Kolbe's electrolysis (d) All of these
Last Answer : All of these
Description : Which reaction does not yield an ester as one of the products? (a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid
Last Answer : A Grignard reagent is added to a carboxylic acid
Description : Which of the following alcohols can be prepared by the reaction of methyl formate with excess Grignard reagent? (a) 1-pentanol (b) 2-pentanol (c) 3-pentanol (d) 2-methyl-2-pentanol
Last Answer : 3-pentanol
Description : Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides
Last Answer : Alkoxyalkanes
Description : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:-
Last Answer : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:- A. B. C. D.
Description : What happens when a drop of glycerol is added to crushed KMnO4 spread on a paper? (1) There is a crackling sound (2) There is a violent explosion (3) There is no reaction (4) The paper ignites
Last Answer : (2) There is a violent explosion Explanation: When solid Potassium Permanganate (KMnO4) is mixed with pure glycerol or other simple alcohols, it will result in a violent combustion ... Permanganate is an extremely powerful oxidizer which spontaneously ignites after coming in contact with glycerol.
Description : What happens when a drop of glycerol is added to crushed KMnO4 spread on a paper ? (1) There is a crackling sound. (2) There is a violent explosion. (3) There is no reaction. (4) The paper ignites.
Last Answer : There is a violent explosion.
Description : The appearance of a silver mirror in Tollens' test indicates the presence of : (a) an aldehyde (b) a ketone (c) an alcohol (d) an alkene
Last Answer : an aldehyde
Description : Which of the following is not a possible reaction of a carbocation? (a) addition of a nucleophile (b) rearrangement to a more stable carbocation (c) addition of a proton to form an alkane (d) loss of a β-hydrogen to form an alkene
Last Answer : addition of a proton to form an alkane
Description : What is Grignard reagent?
Last Answer : Ans. Alkyl magnesium halides
Description : Explain why Grignard reagents do not reacts with alkanes.
Last Answer : Ans. In alkanes , the C – H bond has very little polarity . The hydrogen cannot be abstracted by the Grignard reagent.
Description : Why are Grignard reagents soluble in ether but not in benzene ?
Last Answer : Ans. Grignard reagents from co-ordination complexes with ether but not benzene since the former has lone pair of electrons but the later does not.
Description : Which of the following reagents will react readily with both aldehydes and ketones? (a) Grignard reagent (b) Fehling's reagent (c) Tollens' reagent (d) Schiff's reagen
Last Answer : Grignard reagent
Description : Which of the following is correct? (a) When a Grignard reagent reacts with a ketone, the addition product is a primary alcohol. (b) When a Grignard reagent reacts with a ketone, the addition product ... with a aldehyde, the addition product is a tertiary alcohol. (d) None of the above are correct.
Last Answer : None of the above are correct.
Description : Ketones react with Grignard reagents to form an addition product which on hydrolysis gives a (a) Primary alcohol (b) Tertiary alcohol (c) Secondary alcohol (d) Ketal
Last Answer : Tertiary alcohol
Description : The Grignard reagent, CH3CH2MgBr, can be used to prepare (a) Ethane (b) 3-Ethyl-3-pentanol (c) Propanoic acid (d) All of these
Description : Whose name is given to alkylmagnesium halides: w) Victor Grignard x) Daniel Rutherford y) Dmitri Mendeleev
Last Answer : ANSWER: W -- VICTOR GRIGNARD
Description : The modern atomic theory was conceived by : w) Victor Grignard x) Daniel Rutherford y) Svante Arrhenius z) John Dalton
Last Answer : ANSWER: Z -- JOHN DALTON
Description : Which of the following organic compounds is known as a saturated chain hydrocarbon ? w) an aromatic compound x) an alkene y) an alkyne z) an alkane
Last Answer : ANSWER: Z -- AN ALKANE
Description : Grignard reagent is chemically known as (A) Ethyl magnesium chloride (B) Methyl magnesium chloride (C) Dichlorophenol (D) Monochloroacetic acid
Last Answer : (A) Ethyl magnesium chloride
Description : Which of the following holds good for an elementary reaction as shown in the bellow figure? (A) The rate of disappearance of 'Y' is equal to the rate of appearance of 'Z' (B) The rate of disappearance of 'Y ... of 'Z' (D) The rate of disappearance of 'X' is equal to the rate of appearance of 'Z
Last Answer : (C) Three times the rate of disappearance of 'X' is equal to the rate of appearance of 'Z
Description : For the reaction as shown in the bellow figure, the rate of formation of Z is 0.2 gm mole/litre.hr. What is the rate of disappearance of X in gm mole/litre.hr? (A) 0.4 (B) 0.1 (C) 0.2 (D) None of these
Last Answer : (A) 0.4
Description : What is the product of a reaction between Cu3PO4 and KMnO4?
Last Answer : The chemical reaction is:Cu3PO4 + 3 KMnO4 = 3 CuMnO4 + K3PO4
Description : An alkene (A) `C_(16)H_(16)` on ozonolysis gives only one product (B) `C_8H_8O`. Compound (B) on reaction with NaOH/`I_(2)` yeilds sodium benzoate. Co
Last Answer : An alkene (A) `C_(16)H_(16)` on ozonolysis gives only one product (B) `C_8H_8O`. Compound (B) ... `(H_(2)//Pd-C)` gives a racemic mixture
Description : KMnO4 can be used as a/an - (1) insecticide (2) fertiliser (3) pesticide (4) disinfectant
Last Answer : (4) disinfectant Explanation: Potassium permanganate is an inorganic chemical compound with the formula KMnO4. As an oxidant, potassium permanganate can act as an antiseptic. For example, dilute solutions ... infections of the hands or feet. It is used extensively in the water treatment industry.
Description : KMnO4 can be used as – (1) Insecticide (2) Fertilizer (3) Pesticide (4) Disinfectant
Last Answer : (4) Disinfectant Explanation: Potassium permanganate is an inorganic chemical compound with the formula KMnO4. As an oxidant, potassium permanganate can act as an antiseptic. For example, dilute ... of the hands or feet. Potassium permanganate is used extensively in the water treatment industry.
Description : Why pcc cannot oxidise methanol to methane and while KMnO4 can ?
Last Answer : Ans. This is because pcc is a mild oxidising agent and can oxide methanol to methanal only. While KMnO4 being strong oxidising agent oxidises it to methanoic acid.
Last Answer : This is because pcc is a mild oxidising agent and can oxide methanol to methanal only. While KMnO4 being strong oxidising agent oxidises it to methanoic acid.
Description : Which of the following statements is false about benzylamine? (a) can be prepared by reduction of benzonitrile with LiAlH4. (b) cannot be prepared by reduction of benzamide with LiAlH4. (c) reacts with nitrous acid to give benzyl alcohol. (d) reacts with KMnO4 to give benzoic acid.
Last Answer : cannot be prepared by reduction of benzamide with LiAlH
Description : Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.
Last Answer : can be oxidized with KMnO4 to give benzoic acid
Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.
Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene
Description : Uric acid on oxidation with alkaline KMnO4 forms : (a) Urea (b) Barbituric acid (c) Allantoin (d) Caffeine
Last Answer : Allantoin
Description : Aldehydes undergo oxidation with KMnO4/H+ to give (a) Alcohols (b) Acetals (c) Ketones (d) Acids
Last Answer : Acids
Description : Which of the following reagents readily react with ethyl methyl ether? (a) NaOH (b) Conc HI (c) KMnO4 (d) H2O
Last Answer : Conc HI
Description : Ethylene glycol undergoes oxidation with hot acidic KMnO4 to form : (a) Formic acid (b) Formaldehyde (c) Acetic acid (d) Acetaldehyde
Last Answer : Formic acid
Description : Which of the following reagents can be used to oxidize 1° alcohols to aldehydes? (a) KMnO4 (b) MnO2 (c) K2Cr2O7 (d) PCC
Last Answer : PCC
Description : Which one of the following compounds will (a) decolorizes dilute cold KMnO4 ; (b) decolorizes bromine water ; and (c) gives a white precipitate with ammoniacal AgNO3 solution. (a) 1-Hexene (b) 1-Hexyne (c) 2-Hexene (d) 2-Hexyne
Last Answer : 1-Hexyne
Description : Which of the following alkenes gives only acetic acid on oxidation with hot concentrated KMnO4. (a) Ethylene (b) 1-Butene (c) Propene (d) 2-Butene
Last Answer : 2-Butene
Description : Which of the following reagents will react with propene? (a) Hot alkaline KMnO4 (b) Sodium metal (c) Cold dilute HNO3 (d) LiAlH4
Last Answer : Hot alkaline KMnO4
Description : Baeyer's reagent is (a) dilute KMnO4 (b) HCl + ZnCl2 (c) Br2 in CCl4 (d) NH2NH2
Last Answer : dilute KMnO4
Description : Which reagent is used for conversion of benzaldehyde into toluene? a. KMnO4/NaOH b. NH2NH2/KOH c. HIO4 d. V2O5
Last Answer : b. NH2NH2/KOH
Description : KMnO4 can be used as a/an (1) insecticide(2) fertiliser (3) pesticide (4) disinfectant
Last Answer : disinfectant
Description : A compound of formula C6H12 does not react with concentrated sulfuric acid. The compound could be (a) Alkane (b) Cycloalkane (c) Alkene (d) Cycloalkene
Last Answer : Cycloalkane