Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides

Grignard reagents do not show any reaction with
(a) Alkoxyalkanes
(b) Alkanones
(c) Alkyl alkanoates
(d) Acyl halides
by

1 Answer

Answer :

Alkoxyalkanes
by

Related questions

Which reaction does not yield an ester as one of the products?(a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid

Description : Which reaction does not yield an ester as one of the products? (a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid

Last Answer : A Grignard reagent is added to a carboxylic acid

Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the concentration of the alkyl halide. (c) The rate of reaction of a particular alkyl bromide depends on the steric accessibility of the carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides

Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides

Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides

Whose name is given to alkylmagnesium halides: w) Victor Grignard x) Daniel Rutherford y) Dmitri Mendeleev

Description : Whose name is given to alkylmagnesium halides: w) Victor Grignard x) Daniel Rutherford y) Dmitri Mendeleev

Last Answer : ANSWER: W -- VICTOR GRIGNARD

Which of the following factors influence whether a reaction will proceed by an SN1, SN2, E1, or E2 mechanism? (a) Structure of the alkyl halide (b) Solvent (c) Concentration of reagents (d) Nature of the nucleophile (e) All of these

Description : Which of the following factors influence whether a reaction will proceed by an SN1, SN2, E1, or E2 mechanism? (a) Structure of the alkyl halide (b) Solvent (c) Concentration of reagents (d) Nature of the nucleophile (e) All of these

Last Answer : All of these

Explain why Grignard reagents do not reacts with alkanes.

Description : Explain why Grignard reagents do not reacts with alkanes.

Last Answer : Ans. In alkanes , the C – H bond has very little polarity . The hydrogen cannot be abstracted by the Grignard reagent.

Why are Grignard reagents soluble in ether but not in benzene ?

Description : Why are Grignard reagents soluble in ether but not in benzene ? 

Last Answer : Ans. Grignard reagents from co-ordination complexes with ether but not benzene since the former has lone pair of electrons but the later does not.

Which of the following reagents will react readily with both aldehydes and ketones? (a) Grignard reagent (b) Fehling's reagent (c) Tollens' reagent (d) Schiff's reagen

Description : Which of the following reagents will react readily with both aldehydes and ketones? (a) Grignard reagent (b) Fehling's reagent (c) Tollens' reagent (d) Schiff's reagen

Last Answer : Grignard reagent

Ketones react with Grignard reagents to form an addition product which on hydrolysis gives a (a) Primary alcohol (b) Tertiary alcohol (c) Secondary alcohol (d) Ketal

Description : Ketones react with Grignard reagents to form an addition product which on hydrolysis gives a (a) Primary alcohol (b) Tertiary alcohol (c) Secondary alcohol (d) Ketal

Last Answer : Tertiary alcohol

The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is :

Description : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is :

Last Answer : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is : A. RF > RCl > RBr > ... RBr > RF > RI D. RI > RBr > RCl > RF

Why the presence of a base is essential in the ammonolysis of alkyl halides ?

Description : Why the presence of a base is essential in the ammonolysis of alkyl halides ?

Last Answer : During ammonolysis of alkyl halides, the acid liberated during the reaction combines with the amine formed to form amine salt. To liberate free amine from the amine salt, a base is needed.

When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form

Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form

Last Answer : primary amines form

Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism

Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism

Last Answer : Resonance stabilization

Alkyl halides react with ammonia in the presence of base to form : (a) primary amines(b) nitrated alkyl halides(c) amides(d) quaternary ammonium salts

Description : Alkyl halides react with ammonia in the presence of base to form : (a) primary amines (b) nitrated alkyl halides (c) amides (d) quaternary ammonium salts

Last Answer : primary amines

Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an sp3 hybridized carbon undergo substitution and elimination reactions. (c) The electronegative atom is replaced by another atom or group in substitution reactions. (d) (a) and (b)

Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)

Last Answer : (a) and (b)

Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F

Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F

Last Answer : CH3CH2I

Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Last Answer : Nucleophilic substitution reactions

Which of the following reagents cannot be used to prepare an alkyl chloride from an alcohol? (a) HCl + ZnCl2 (b) SOCl2 (c) NaCl (d) PCl5

Description : Which of the following reagents cannot be used to prepare an alkyl chloride from an alcohol? (a) HCl + ZnCl2 (b) SOCl2 (c) NaCl (d) PCl5

Last Answer : NaCl

Which of the following is not a correct statement concerning the FriedelCrafts acylation of benzene? (a) An alkyl group substitutes for a hydrogen. (b) The benzene ring attacks an acylium ion. (c) The acylium ion is resonance stabilized. (d) The acylium ion is often produced from an acyl chloride.

Description : Which of the following is not a correct statement concerning the FriedelCrafts acylation of benzene? (a) An alkyl group substitutes for a hydrogen. (b) The benzene ring attacks an acylium ion. (c) The acylium ion is resonance stabilized. (d) The acylium ion is often produced from an acyl chloride.

Last Answer : An alkyl group substitutes for a hydrogen

Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is

Description : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is

Last Answer : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in ... reaction D. Reaction with `NH_(3)`

Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism?

Description : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism?

Last Answer : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism? A. `CH_(3)Cl` B. `CH_(3)CH_(2)Cl` ... (2)CH_(2)Cl` D. `(CH_(3))_(3)"CCl"`

Which of the following alcohols can be prepared by the reaction of methyl formate with excess Grignard reagent? (a) 1-pentanol (b) 2-pentanol (c) 3-pentanol (d) 2-methyl-2-pentanol

Description : Which of the following alcohols can be prepared by the reaction of methyl formate with excess Grignard reagent? (a) 1-pentanol (b) 2-pentanol (c) 3-pentanol (d) 2-methyl-2-pentanol

Last Answer : 3-pentanol

The disappearance of the purple color of KMnO4 in its reaction with alkene is known as (a) Markovnikov test (b) Grignard test (c) Baeyer test (d) Wurtz test

Description : The disappearance of the purple color of KMnO4 in its reaction with alkene is known as (a) Markovnikov test (b) Grignard test (c) Baeyer test (d) Wurtz test

Last Answer : Baeyer test

Which of the following halides is least reactive in an E2 reaction with sodium methoxide? (a) (CH3)3CCH2I (b) (CH3)2CHCHICH3 (c) (CH3)2CHCH2Br (d) (CH3)2CHCH2Cl

Description : Which of the following halides is least reactive in an E2 reaction with sodium methoxide? (a) (CH3)3CCH2I (b) (CH3)2CHCHICH3 (c) (CH3)2CHCH2Br (d) (CH3)2CHCH2Cl

Last Answer : (CH3)3CCH2I

Which of the following halides is most reactive in an E2 reaction with sodium methoxide? (a) (CH3)3CCH2I (b) (CH3)2CHCHICH3 (c) (CH3)2CHCH2Br (d) (CH3)2CHCH2C

Description : Which of the following halides is most reactive in an E2 reaction with sodium methoxide? (a) (CH3)3CCH2I (b) (CH3)2CHCHICH3 (c) (CH3)2CHCH2Br (d) (CH3)2CHCH2C

Last Answer : (CH3)2CHCHICH3

(4) None of these Explanation: Catalysis is the change in rate of a chemical reaction due to the participation of a substance called a catalyst. Unlike other reagents that participate in the chemical reaction, a catalyst is not consumed by the reaction itself. A catalyst may participate in multiple chemical transformations. Catalysts that speed the reaction are called positive catalysts.

Description : (4) None of these Explanation: Catalysis is the change in rate of a chemical reaction due to the participation of a substance called a catalyst. Unlike other reagents that ... may participate in multiple chemical transformations. Catalysts that speed the reaction are called positive catalysts.

Last Answer : Table salt gets moist during rainy season because – (1) sodium chloride is hygroscopic (2) sodium chloride is deliquescent (3) sodium chloride contains some quantity of sodium iodide (4) sodium chloride contains hygroscopic impurities like magnesium chloride

. Hunsdiecker reaction is used for the preparation of (a) Alkyl chlorides and bromides (b) Alkyl nitrates and nitrites (c) Ketenes (d) Alcohols

Description : . Hunsdiecker reaction is used for the preparation of (a) Alkyl chlorides and bromides (b) Alkyl nitrates and nitrites (c) Ketenes (d) Alcohols

Last Answer : Alkyl chlorides and bromides

The reaction of a sodium alkoxide with an alkyl halide is called (a) Wurtz-Fittig reaction (b) Perkin reaction (c) Williamson's synthesis (d) Aldol condensation

Description : The reaction of a sodium alkoxide with an alkyl halide is called (a) Wurtz-Fittig reaction (b) Perkin reaction (c) Williamson's synthesis (d) Aldol condensation

Last Answer : Williamson's synthesis

Which is the most reactive alkyl halide in a SN1 reaction? (a) CH3F (b) CH3Br (c) CH3I (d) CH3Cl

Description : Which is the most reactive alkyl halide in a SN1 reaction? (a) CH3F (b) CH3Br (c) CH3I (d) CH3Cl

Last Answer : CH3I

What is Grignard reagent?

Description : What is Grignard reagent?

Last Answer : Ans. Alkyl magnesium halides

Which of the following is correct? (a) When a Grignard reagent reacts with a ketone, the addition product is a primary alcohol. (b) When a Grignard reagent reacts with a ketone, the addition product is a secondaryalcoho(c) When a Grignard reagent reacts with a aldehyde, the addition product is a tertiary alcohol. (d) None of the above are correct.l

Description : Which of the following is correct? (a) When a Grignard reagent reacts with a ketone, the addition product is a primary alcohol. (b) When a Grignard reagent reacts with a ketone, the addition product ... with a aldehyde, the addition product is a tertiary alcohol. (d) None of the above are correct.

Last Answer : None of the above are correct.

The modern atomic theory was conceived by : w) Victor Grignard x) Daniel Rutherford y) Svante Arrhenius z) John Dalton

Description : The modern atomic theory was conceived by : w) Victor Grignard x) Daniel Rutherford y) Svante Arrhenius z) John Dalton

Last Answer : ANSWER: Z -- JOHN DALTON

Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Description : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Last Answer : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii ... (vi) `PCl_(3)` (vii) `AsCl_(3)`

Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Description : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Last Answer : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii ... (vi) `PCl_(3)` (vii) `AsCl_(3)`

Which of the following halides will be most reactive towards `S_(N^(2))` reaction?

Description : Which of the following halides will be most reactive towards `S_(N^(2))` reaction?

Last Answer : Which of the following halides will be most reactive towards `S_(N^(2))` reaction? A. `C_(6)H_(5)CH_(2 ... (2)-underset(Br)underset("| ")"CH"-CH_(3)`

The correct increasing order of the reactivity of halides for `S_(N^(1))` reaction is:

Description : The correct increasing order of the reactivity of halides for `S_(N^(1))` reaction is:

Last Answer : The correct increasing order of the reactivity of halides for `S_(N^(1))` reaction is: A. `CH_(3)CH_(2)-Xlt( ... -Xlt(CH_(3))_(2)CH-XltCH_(3)CH_(2)-X`

How would you synthesise 4-methoxyphenol from bromobenzene in not more than five steps? State clearly the reagents used in each step and show the stru

Description : How would you synthesise 4-methoxyphenol from bromobenzene in not more than five steps? State clearly the reagents used in each step and show the stru

Last Answer : How would you synthesise 4-methoxyphenol from bromobenzene in not more than five steps? ... the intermediate compounds in your synthetic scheme.

Ozone on reaction with one of the following reagents uses all its 3 oxygen atoms for oxidation

Description : Ozone on reaction with one of the following reagents uses all its 3 oxygen atoms for oxidation

Last Answer : Ozone on reaction with one of the following reagents uses all its 3 oxygen atoms for oxidation A. `SO_(2)` B. ` ... of HCl C. `CH_(2)=CH_(2)` D. All

Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:-

Description : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:-

Last Answer : Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:- A. B. C. D.

Compound P on treatement with `CH_(2)N_(2)` (diazomethane) produces compound Q. compound Q on reaction with Hl produces two alkyl iodides R and S . Al

Description : Compound P on treatement with `CH_(2)N_(2)` (diazomethane) produces compound Q. compound Q on reaction with Hl produces two alkyl iodides R and S . Al

Last Answer : Compound P on treatement with `CH_(2)N_(2)` (diazomethane) produces compound Q. compound Q on reaction ... 2-methyl-2-propanol D. 2-methyl-1-propanol

Assertion (A): Alkyl aryl ethers on reaction with HI give alkyl iodide phenols Reason (R): Aryl - oxygen bond is weaker than alkyl oxygen bond

Description : Assertion (A): Alkyl aryl ethers on reaction with HI give alkyl iodide phenols Reason (R): Aryl - oxygen bond is weaker than alkyl oxygen bond

Last Answer : Assertion (A): Alkyl aryl ethers on reaction with HI give alkyl iodide phenols Reason (R): Aryl - oxygen ... is false D. A is false but R is true

Grignard reagent is chemically known as (A) Ethyl magnesium chloride (B) Methyl magnesium chloride (C) Dichlorophenol (D) Monochloroacetic acid

Description : Grignard reagent is chemically known as (A) Ethyl magnesium chloride (B) Methyl magnesium chloride (C) Dichlorophenol (D) Monochloroacetic acid

Last Answer : (A) Ethyl magnesium chloride

Chemical name of Grignard reagent is (A) Sodium thiosulphate (B) Ethyl magnesium chloride (C) Sodium sulphite (D) Sodium bicarbonate

Description : Chemical name of Grignard reagent is (A) Sodium thiosulphate (B) Ethyl magnesium chloride (C) Sodium sulphite (D) Sodium bicarbonate

Last Answer : (B) Ethyl magnesium chloride

Silver halides are used in photographic plates because they are - (1) oxidised in air (2) soluble in hyposolution (3) reduced by light (4) totally colourless

Description : Silver halides are used in photographic plates because they are - (1) oxidised in air (2) soluble in hyposolution (3) reduced by light (4) totally colourless

Last Answer : (3) reduced by light Explanation: The light-sensitive chemicals used in photographic film and paper are silver halides. Silver halides are used in photographic film and photographic paper, including ... - meaning that it can undergo development which turns the entire crystal into metallic silver.

Metal sulphides occur mainly in rocks and metal halides in lakes and seas. Explain.

Description : Metal sulphides occur mainly in rocks and metal halides in lakes and seas. Explain.

Last Answer : Ans.: Metal halides being soluble in water, get dissolved in rain water and are carried to lakes and seas during weathering of rocks. On the otherhand, metal sulphides being insoluble are left behind in the rocks as residue.

Give reason for the appearance of colour in alkali metal halides.

Description : Give reason for the appearance of colour in alkali metal halides. 

Last Answer : Due to F-centres.

Silver halides are used in photographic plates because they are (1) oxidised in air (2) soluble in hyposolution (3) reduced by light (4) totally colourless

Description : Silver halides are used in photographic plates because they are (1) oxidised in air (2) soluble in hyposolution (3) reduced by light (4) totally colourless

Last Answer :  reduced by light

All the following statements about charging of tRNA are correct except (A) It is catalysed by amino acyl tRNA synthetase (B) ATP is converted into ADP and Pi in this reaction (C) The enzyme recognizes the tRNA and the amino acid (D) There is a separate enzyme for each tRNA

Description : All the following statements about charging of tRNA are correct except (A) It is catalysed by amino acyl tRNA synthetase (B) ATP is converted into ADP and Pi in this reaction (C) The enzyme recognizes the tRNA and the amino acid (D) There is a separate enzyme for each tRNA

Last Answer : Answer : B

The α-amino group of the new amino acyl tRNA in the A site carries out a nucleophilic attack on the esterified carboxyl group of the peptidyl tRNA occupying the P site. This reaction is catalysed by (A) DNA polymerase (B) RNA polymerase (C) Peptidyl transferase (D) DNA ligase

Description : The α-amino group of the new amino acyl tRNA in the A site carries out a nucleophilic attack on the esterified carboxyl group of the peptidyl tRNA occupying the P site. This reaction is catalysed by (A) DNA polymerase (B) RNA polymerase (C) Peptidyl transferase (D) DNA ligase

Last Answer : Answer : C

Riboflavin is a coenzyme in the reaction catalysed by the enzyme (A) Acyl CoA synthetase (B) Acyl CoA dehydrogenase (C) β-Hydroxy acyl CoA (D) Enoyl CoA dehydrogenase

Description : Riboflavin is a coenzyme in the reaction catalysed by the enzyme (A) Acyl CoA synthetase (B) Acyl CoA dehydrogenase (C) β-Hydroxy acyl CoA (D) Enoyl CoA dehydrogenase

Last Answer : Answer : B