How is aniline distinguished from N-methyl aniline ?

How is aniline distinguished from N-methyl aniline ?
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1 Answer

Answer :

Ans.—On adding CHCl3 & KOH , aniline gives offensive smell forming isocyanide compound whereas N-methyle aniline not.
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Reference fuels for knock rating of SI engine fuels would include (a) Iso octane alpha methyl naphthalene (b) Normal octance and aniline (c) Isooctance and n octane (d) N heptane and iso octane

Description : Reference fuels for knock rating of SI engine fuels would include (a) Iso octane alpha methyl naphthalene (b) Normal octance and aniline (c) Isooctance and n octane (d) N heptane and iso octane

Last Answer : Ans : d

Pkb of aniline is more than that of methyl amine.

Description : Pkb of aniline is more than that of methyl amine.

Last Answer : In aniline, the lone pair of electrons on the N-atom are delocalized over the benzene ring. As a result electron density on the nitrogen decreases. In contrast in CH2NH2 , + I effect of CH3 ... , aniline is a weaker base than methylamine and hence its Pkb value is higher than that of methylamine.

Aniline reacts with acetic anhydride to give : (a) N-Methylaniline (b) p-Aminoacetophenone (c) Acetanilide (d) m-Aminoacetophenone

Description : Aniline reacts with acetic anhydride to give : (a) N-Methylaniline (b) p-Aminoacetophenone (c) Acetanilide (d) m-Aminoacetophenone

Last Answer : Acetanilide

Aniline reacts with nitrous acid at low temperatures to give (a) a N-nitrosoamine (b) a nitrile (c) a diazonium salt (d) a nitrite salt

Description : Aniline reacts with nitrous acid at low temperatures to give (a) a N-nitrosoamine (b) a nitrile (c) a diazonium salt (d) a nitrite salt

Last Answer : a diazonium salt

Which of the following compounds does not dissolve in concentrated H2SO4 on warming? (a) n-Hexane (b) Diethyl ether (c) 1-Butene (d) Aniline

Description : Which of the following compounds does not dissolve in concentrated H2SO4 on warming? (a) n-Hexane (b) Diethyl ether (c) 1-Butene (d) Aniline

Last Answer : n-Hexane

The compound that has the least value for octane number is – (1) 2-methyl heptane (2) Iso-octane (3) 2,2-dimethyl hexane (4) n-heptane

Description : The compound that has the least value for octane number is – (1) 2-methyl heptane (2) Iso-octane (3) 2,2-dimethyl hexane (4) n-heptane

Last Answer : (4) n-heptane Explanation: Octane rating or octane number is a standard measure of the performance of a motor or aviation fuel. The higher the octane number, the more compression the fuel can withstand. Isooctane (upper) has an octane rating of 100 whereas n-heptane has an octane rating of O.

When ethyl acetoacetate is subjected to ketonic hydrolysis, the ketoneobtained is(a) Dimethyl ketone(b) Methyl ethyl ketone(c) Diethyl ketone(d) Methyl n-propyl ketone

Description : When ethyl acetoacetate is subjected to ketonic hydrolysis, the ketone obtained is (a) Dimethyl ketone (b) Methyl ethyl ketone (c) Diethyl ketone (d) Methyl n-propyl ketone

Last Answer : Diethyl ketone

Diethyl ether on heating with excess concentrated HI gives (a) Methyl iodide (b) Isopropyl iodide (c) Ethyl iodide (d) n-Propyl iodide

Description : Diethyl ether on heating with excess concentrated HI gives (a) Methyl iodide (b) Isopropyl iodide (c) Ethyl iodide (d) n-Propyl iodide

Last Answer : Ethyl iodide

Ethyl bromide reacts with sodium methoxide to form (a) Diethyl ether (b) Ethyl methyl ether (c) Dimethyl ether (d) n-Propyl alcohol

Description : Ethyl bromide reacts with sodium methoxide to form (a) Diethyl ether (b) Ethyl methyl ether (c) Dimethyl ether (d) n-Propyl alcohol

Last Answer : Ethyl methyl ether

Grain alcohol is another name for (a) Methyl alcohol (b) Isopropyl alcohol (c) Ethyl alcohol (d) n-Propyl alcoho

Description : Grain alcohol is another name for (a) Methyl alcohol (b) Isopropyl alcohol (c) Ethyl alcohol (d) n-Propyl alcoho

Last Answer : Ethyl alcohol

Which hydrocarbon molecule with eight carbons would produce the lowest octane number (i.e., the most knocking) when used as a fuel in automobile? (a) 2-Methyl-3,3-dimethylpentane (b) n-Octane (c) 2-Isopropylpentane (d) 2-Methylheptane

Description : Which hydrocarbon molecule with eight carbons would produce the lowest octane number (i.e., the most knocking) when used as a fuel in automobile? (a) 2-Methyl-3,3-dimethylpentane (b) n-Octane (c) 2-Isopropylpentane (d) 2-Methylheptane

Last Answer : n-Octane

The compound that has the least value for octane number is : (1) 2-methyl heptane (2) Iso-octane (3) 2,2-dimethyl hexane (4) n-heptane

Description : The compound that has the least value for octane number is : (1) 2-methyl heptane (2) Iso-octane (3) 2,2-dimethyl hexane (4) n-heptane

Last Answer : n-heptane

Chemical name of Gammaxane is - (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Description : Chemical name of Gammaxane is - (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Last Answer : (4) Benzene hexachloride Explanation: Gammexane is an insecticide that is the gamma isomer of benzene hexachloride. It is also known as lindane. Benzene hexachloride is any of several stereoisomers of 1,2,3,4,5,6- hexachlorocyclohexane formed by the lightinduced addition of chlorine to benzene.

Polythene is polymer of – (1) Ethylene (2) Propylene (3) Acetylene (4) Aniline

Description : Polythene is polymer of – (1) Ethylene (2) Propylene (3) Acetylene (4) Aniline

Last Answer : (1) Ethylene Explanation: The ingredient or monomer is ethylene (IUPAC name ethene). It has the formula C2H4, consisting of a pair of CH2 groups connected by a double bond. Because the catalysts are highly reactive, the ethylene must be of high purity. Typical specifications are H2SO4

'Red Ink' is prepared from - (1) Phenol (2) Aniline (3) Congo redd (4) Eosin

Description : 'Red Ink' is prepared from - (1) Phenol (2) Aniline (3) Congo redd (4) Eosin

Last Answer : (4) Eosin Explanation: Eosin is a dye used to prepare red ink. Eosin Y is a xanthene dye and is used for the differential staining of connective tissue and cytoplasm.

Which of the following is a natural dye? (1) Crystal violet (2) Aniline blue (3) Alizarin (4) Phenolphthalein

Description : Which of the following is a natural dye? (1) Crystal violet (2) Aniline blue (3) Alizarin (4) Phenolphthalein

Last Answer : (3) Alizarin Explanation: Alizarin or 1,2- dihydroxyanthraquinone (also known as Mordant Red 11 and Turkey Red is an organic compound with formula C14H8O4 that has been used throughout history as a ... of the madder genus. In 1869, it became the first natural pigment to be duplicated synthetically.

By which method aniline can be purified?

Description : By which method aniline can be purified?

Last Answer : By steam distillation.

How can tri substitution of Bromine be prevented in aniline ? OR How can we prepare mono bromo aniline ?

Description : How can tri substitution of Bromine be prevented in aniline ? OR How can we prepare mono bromo aniline ?

Last Answer : Because of high reactivity of aromatic amines substitution tends to occur at o- and ppositions. Monosubstituted aniline can be prepared by protecting — NH2 group by acetylation with acetic anhydride, then carrying out substitution followed by hydrolysis of substituted amide.

Aniline gets coloured on standing in air for a long time. Why ?

Description : Aniline gets coloured on standing in air for a long time. Why ?

Last Answer : Due to strong electron-donating effect (+ R effect) of NH2 gp, the electron density on the benzene ring increases. As a result, aniline is easily oxidised on standing in air for a long time to form coloured products.

Although — NH2 gp is an ortho and para directing gp, nitration of aniline gives along with ortho and para, meta derivatives also.

Description : Although — NH2 gp is an ortho and para directing gp, nitration of aniline gives along with ortho and para, meta derivatives also.

Last Answer : Nitration is carried out with a mixture of Conc. NO3 + Conc. H2 SO4 (nitrating mix). In the presence of these acids, most of aniline gets protonated to form anilinium ion. Therefore, in the ... is m-directing and deactivating hence a mixture of all three-ortho, para and meta derivatives is formed.

When aniline is heated with glycerol in the presence of sulfuric acid and nitrobenzene, it gives quinoline. This reaction in called (a) Fischer synthesis (b) Skraup synthesis (c) Diazotization (d) Corey-House synthesis

Description : When aniline is heated with glycerol in the presence of sulfuric acid and nitrobenzene, it gives quinoline. This reaction in called (a) Fischer synthesis (b) Skraup synthesis (c) Diazotization (d) Corey-House synthesis

Last Answer : Skraup synthesis

Benzenediazonium chloride reacts with hypophosphorus acid to form : (a) Phenol (b) Benzaldehyde (c) Aniline (d) Benzene

Description : Benzenediazonium chloride reacts with hypophosphorus acid to form : (a) Phenol (b) Benzaldehyde (c) Aniline (d) Benzene

Last Answer : Benzene

Chlorobenzene can be prepared by treatment of aniline with (a) Cuprous chloride (b) Chlorine in the presence of UV light (c) Nitrous acid followed by treatment with CuCl (d) Chlorine in the presence of FeCl3

Description : Chlorobenzene can be prepared by treatment of aniline with (a) Cuprous chloride (b) Chlorine in the presence of UV light (c) Nitrous acid followed by treatment with CuCl (d) Chlorine in the presence of FeCl3

Last Answer : Nitrous acid followed by treatment with CuCl

Bromobenzene can be prepared by treating aniline with (a) Conc HBr (b) Br2/FeBr3 (b) CuBr (d) Nitrous acid then CuBr

Description : Bromobenzene can be prepared by treating aniline with (a) Conc HBr (b) Br2/FeBr3 (b) CuBr (d) Nitrous acid then CuBr

Last Answer : Nitrous acid then CuBr

Benzenediazonium chloride reacts with warm water to give (a) Aniline (b) Phenol (c) Benzene (d) Chlorobenzene

Description : Benzenediazonium chloride reacts with warm water to give (a) Aniline (b) Phenol (c) Benzene (d) Chlorobenzene

Last Answer : Phenol

Which of the following are optimum temperature conditions for making benzenediazonium chloride from aniline? (a) 0°C to 10°C (b) 20°C to 25°C (c) 30°C to 40°C (d) 45°C to 50°C

Description : Which of the following are optimum temperature conditions for making benzenediazonium chloride from aniline? (a) 0°C to 10°C (b) 20°C to 25°C (c) 30°C to 40°C (d) 45°C to 50°C

Last Answer : 0°C to 10°C

Which of the following reagents is used to prepare benzenediazoniumchloride from aniline?(a) NaNO2 + HCl(b) LiAlH4(c) NH2NH2 + KOH(d) NaOH

Description : Which of the following reagents is used to prepare benzenediazonium chloride from aniline? (a) NaNO2 + HCl (b) LiAlH4 (c) NH2NH2 + KOH (d) NaOH

Last Answer : NaNO2 + HCl

Which of the following compounds is most basic? (a) Aniline (b) Benzylamine (c) Acetanilide (d) p-nitroaniline

Description : Which of the following compounds is most basic? (a) Aniline (b) Benzylamine (c) Acetanilide (d) p-nitroaniline

Last Answer : Benzylamine

Which of the following reagents does not react with aniline? (a) Acetyl chloride (b) Acetic anhydride (c) Ammonia (d) Nitrous acid

Description : Which of the following reagents does not react with aniline? (a) Acetyl chloride (b) Acetic anhydride (c) Ammonia (d) Nitrous acid

Last Answer : Ammonia

Aniline undergoes oxidation with Na2Cr2O7/H2SO4 to give (a) Schiff's base (b) p-Benzoquinone (c) Phenol (d) Benzoic acid

Description : Aniline undergoes oxidation with Na2Cr2O7/H2SO4 to give (a) Schiff's base (b) p-Benzoquinone (c) Phenol (d) Benzoic acid

Last Answer : p-Benzoquinone

When aniline is heated with chloroform and alcoholic KOH, the product is (a) Benzonitrile (b) p-Chloroaniline (c) Phenylisocyanide (d) m-Chloroaniline

Description : When aniline is heated with chloroform and alcoholic KOH, the product is (a) Benzonitrile (b) p-Chloroaniline (c) Phenylisocyanide (d) m-Chloroaniline

Last Answer : Phenylisocyanide

Which of the following will give a precipitate with excess bromine water? (a) Bromobenzene (b) Aniline (c) Nitrobenzene (d) Toluene

Description : Which of the following will give a precipitate with excess bromine water? (a) Bromobenzene (b) Aniline (c) Nitrobenzene (d) Toluene

Last Answer : Aniline

Aniline reacts with bromine water to form (a) Bromobenzene (b) m-Bromoaniline (c) 2,4,6-Tribromoaniline (d) o- plus p-Bromoaniline

Description : Aniline reacts with bromine water to form (a) Bromobenzene (b) m-Bromoaniline (c) 2,4,6-Tribromoaniline (d) o- plus p-Bromoaniline

Last Answer : 2,4,6-Tribromoaniline

Benzamide reacts with Br2 and KOH to give (a) Benzene (b) Benzylamine (c) Aniline (d) Benzonitrile

Description : Benzamide reacts with Br2 and KOH to give (a) Benzene (b) Benzylamine (c) Aniline (d) Benzonitrile

Last Answer : Benzylamine

Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Description : Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Last Answer : the reduction of nitrobenzene with Sn/HCl

Which of the following statements is correct about aniline? (a) is weak acid. (b) diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid. (c) can be nitrated with concentrated HNO3 to form p-nitroaniline. (d) gives an intense green color with a suspension of bleaching powder in water

Description : Which of the following statements is correct about aniline? (a) is weak acid. (b) diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid. (c) can be nitrated with ... p-nitroaniline. (d) gives an intense green color with a suspension of bleaching powder in water

Last Answer : diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid.

Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid

Nitrobenzene undergoes reduction with zinc and KOH to give (a) Aniline (b) Hydrazobenzene (c) Azobenzene (d) None of these

Description : Nitrobenzene undergoes reduction with zinc and KOH to give (a) Aniline (b) Hydrazobenzene (c) Azobenzene (d) None of these

Last Answer : Hydrazobenzene

Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Description : Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Last Answer : can be oxidized with KMnO4 to give benzoic acid

Which of the following compounds does not react with acetyl chloride? (a) Methylamine (b) Dimethylamine (c) Aniline (d) Trimethylamine

Description : Which of the following compounds does not react with acetyl chloride? (a) Methylamine (b) Dimethylamine (c) Aniline (d) Trimethylamine

Last Answer : Trimethylamine

Which of the following is least soluble in water? (a) Methylamine (b) Trimethylamine (c) Dimethylamine (d) Aniline

Description : Which of the following is least soluble in water? (a) Methylamine (b) Trimethylamine (c) Dimethylamine (d) Aniline

Last Answer : Methylamine

Chemical name of Gammaxane is (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Description : Chemical name of Gammaxane is (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Last Answer : Benzene hexachloride

Polythene is polymer of (1) Ethylene (2) Propylene (3) Acetylene (4) Aniline

Description : Polythene is polymer of (1) Ethylene (2) Propylene (3) Acetylene (4) Aniline

Last Answer : Ethylene

Which of the following is a natural dye ? (1) Crystal violet (2) Aniline blue (3) Alizarin (4) Phenolphthalein

Description : Which of the following is a natural dye ? (1) Crystal violet (2) Aniline blue (3) Alizarin (4) Phenolphthalein

Last Answer : Alizarin

Hard water and soft water can be distinguished by using – (1) dilute acid (2) ordinary soap (3) detergent (4) liquid soap

Description : Hard water and soft water can be distinguished by using – (1) dilute acid (2) ordinary soap (3) detergent (4) liquid soap

Last Answer : (3) detergent

How can a colloidal solution and true solution of the same colour be distinguished from each other?

Description : How can a colloidal solution and true solution of the same colour be distinguished from each other?

Last Answer : Ans.: By Tyndal effect( colloidal solution will scatter light and path becomes lighted where as no such phenomena is observed in true solution.)

Benzaldehyde can be distinguished from acetophenone by using : (a) Tollens' reagent (b) Lucas reagent (c) Fehling's reagent (d) All of these

Description : Benzaldehyde can be distinguished from acetophenone by using : (a) Tollens' reagent (b) Lucas reagent (c) Fehling's reagent (d) All of these

Last Answer : Tollens' reagent

Phenols can be easily distinguished from alcohols because (a) phenols are soluble in NaOH, but alcohols are not (b) alcohols are soluble in NaOH, but phenols are not (c) phenols are soluble in NaHCO3, but alcohols are not (d) alcohols are soluble in NaHCO3, but phenols are not

Description : Phenols can be easily distinguished from alcohols because (a) phenols are soluble in NaOH, but alcohols are not (b) alcohols are soluble in NaOH, but phenols are not (c) phenols are soluble in NaHCO3, but alcohols are not (d) alcohols are soluble in NaHCO3, but phenols are not

Last Answer : phenols are soluble in NaOH, but alcohols are not

Aldehydes can be distinguished from ketones by using (a) Ammoniacal AgNO3 solution (b) Phenylhydrazine (c) Saturated NaHSO3 solution (d) Thionyl chloride

Description : Aldehydes can be distinguished from ketones by using (a) Ammoniacal AgNO3 solution (b) Phenylhydrazine (c) Saturated NaHSO3 solution (d) Thionyl chloride

Last Answer : Ammoniacal AgNO3 solution

1-Butyne can be distinguished from 2-butyne by using (a) potassium permanganate (b) bromine in CCl4 (c) Tollens' reagent (d) chlorine in CCl4

Description : 1-Butyne can be distinguished from 2-butyne by using (a) potassium permanganate (b) bromine in CCl4 (c) Tollens' reagent (d) chlorine in CCl4

Last Answer : chlorine in CCl4