Pkb of aniline is more than that of methyl amine.

Pkb of aniline is more than that of methyl amine.
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1 Answer

Answer :

In aniline, the lone pair of electrons on the N-atom are delocalized over the benzene ring. As a result electron density on the nitrogen decreases. In contrast in CH2NH2 , + I effect of CH3 increase the electron density on the N-atom. Therefore, aniline is a weaker base than methylamine and hence its Pkb value is higher than that of methylamine.
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Related questions

Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid

How is aniline distinguished from N-methyl aniline ?

Description : How is aniline distinguished from N-methyl aniline ?

Last Answer : Ans.—On adding CHCl3 & KOH , aniline gives offensive smell forming isocyanide compound whereas N-methyle aniline not.

Carbylamine test involves heating a mixture of (a) alcoholic KOH, methyl iodide, and sodium metal (b) alcoholic KOH, methyl iodide, and primary amine (c) alcoholic KOH, chloroform, and primary amine (d) alcoholic KOH, methyl alcohol, and primary amine

Description : Carbylamine test involves heating a mixture of (a) alcoholic KOH, methyl iodide, and sodium metal (b) alcoholic KOH, methyl iodide, and primary amine (c) alcoholic KOH, chloroform, and primary amine (d) alcoholic KOH, methyl alcohol, and primary amine

Last Answer : alcoholic KOH, chloroform, and primary amine

Based on the intermolecular forces involved, which of the following molecules will have the lowest boiling point? w) ethane x) methyl alcohol y) methyl amine z) methyl fluoride

Description : Based on the intermolecular forces involved, which of the following molecules will have the lowest boiling point? w) ethane x) methyl alcohol y) methyl amine z) methyl fluoride

Last Answer : ANSWER: W -- ethane

Which of the following would be most acidic? w) phenol x) methanol y) acetic acid z) methyl amine

Description : Which of the following would be most acidic? w) phenol x) methanol y) acetic acid z) methyl amine

Last Answer : ANSWER: C -- ACETIC ACID

Reference fuels for knock rating of SI engine fuels would include (a) Iso octane alpha methyl naphthalene (b) Normal octance and aniline (c) Isooctance and n octane (d) N heptane and iso octane

Description : Reference fuels for knock rating of SI engine fuels would include (a) Iso octane alpha methyl naphthalene (b) Normal octance and aniline (c) Isooctance and n octane (d) N heptane and iso octane

Last Answer : Ans : d

Tetra hydroglolate can be freed from N5 methyl tetrahydrofolate only by (A) Nor epinephrine (B) Ethanol amine (C) Nicotinamide (D) Vitamin B12

Description : Tetra hydroglolate can be freed from N5 methyl tetrahydrofolate only by (A) Nor epinephrine (B) Ethanol amine (C) Nicotinamide (D) Vitamin B12

Last Answer : Answer : D

Nylon-66 is a polyamide of (A) Hexamethylene diamine and adipic acid (B) Adipic acid and methyl amine (C) Vinyl chloride and formaldehyde (D) None of these

Description : Nylon-66 is a polyamide of (A) Hexamethylene diamine and adipic acid (B) Adipic acid and methyl amine (C) Vinyl chloride and formaldehyde (D) None of these

Last Answer : (A) Hexamethylene diamine and adipic acid

The most suitable solvent for deasphalting vacuum residue is (A) Propane (B) Methyl ethyl ketone (C) Doctor's solution (D) Methanol amine

Description : The most suitable solvent for deasphalting vacuum residue is (A) Propane (B) Methyl ethyl ketone (C) Doctor's solution (D) Methanol amine

Last Answer : (B) Methyl ethyl ketone

Naphthols are derivates of (A) Methyl amine (B) Naphthalene (C) Phenol (D) Xylene

Description : Naphthols are derivates of (A) Methyl amine (B) Naphthalene (C) Phenol (D) Xylene

Last Answer : (B) Naphthalene

Why is amide more acidic than an amine ?

Description : Why is amide more acidic than an amine ?

Last Answer : Ans.—In amide there is C=O group attached NH2 , electron withdrawing & increases acidic nature of amide whereas in amines there is alkyl group which is electron releasing and makes it more basic & hence less acidic.

Chemical name of Gammaxane is - (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Description : Chemical name of Gammaxane is - (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Last Answer : (4) Benzene hexachloride Explanation: Gammexane is an insecticide that is the gamma isomer of benzene hexachloride. It is also known as lindane. Benzene hexachloride is any of several stereoisomers of 1,2,3,4,5,6- hexachlorocyclohexane formed by the lightinduced addition of chlorine to benzene.

Polythene is polymer of – (1) Ethylene (2) Propylene (3) Acetylene (4) Aniline

Description : Polythene is polymer of – (1) Ethylene (2) Propylene (3) Acetylene (4) Aniline

Last Answer : (1) Ethylene Explanation: The ingredient or monomer is ethylene (IUPAC name ethene). It has the formula C2H4, consisting of a pair of CH2 groups connected by a double bond. Because the catalysts are highly reactive, the ethylene must be of high purity. Typical specifications are H2SO4

'Red Ink' is prepared from - (1) Phenol (2) Aniline (3) Congo redd (4) Eosin

Description : 'Red Ink' is prepared from - (1) Phenol (2) Aniline (3) Congo redd (4) Eosin

Last Answer : (4) Eosin Explanation: Eosin is a dye used to prepare red ink. Eosin Y is a xanthene dye and is used for the differential staining of connective tissue and cytoplasm.

Which of the following is a natural dye? (1) Crystal violet (2) Aniline blue (3) Alizarin (4) Phenolphthalein

Description : Which of the following is a natural dye? (1) Crystal violet (2) Aniline blue (3) Alizarin (4) Phenolphthalein

Last Answer : (3) Alizarin Explanation: Alizarin or 1,2- dihydroxyanthraquinone (also known as Mordant Red 11 and Turkey Red is an organic compound with formula C14H8O4 that has been used throughout history as a ... of the madder genus. In 1869, it became the first natural pigment to be duplicated synthetically.

By which method aniline can be purified?

Description : By which method aniline can be purified?

Last Answer : By steam distillation.

How can tri substitution of Bromine be prevented in aniline ? OR How can we prepare mono bromo aniline ?

Description : How can tri substitution of Bromine be prevented in aniline ? OR How can we prepare mono bromo aniline ?

Last Answer : Because of high reactivity of aromatic amines substitution tends to occur at o- and ppositions. Monosubstituted aniline can be prepared by protecting — NH2 group by acetylation with acetic anhydride, then carrying out substitution followed by hydrolysis of substituted amide.

Aniline gets coloured on standing in air for a long time. Why ?

Description : Aniline gets coloured on standing in air for a long time. Why ?

Last Answer : Due to strong electron-donating effect (+ R effect) of NH2 gp, the electron density on the benzene ring increases. As a result, aniline is easily oxidised on standing in air for a long time to form coloured products.

Although — NH2 gp is an ortho and para directing gp, nitration of aniline gives along with ortho and para, meta derivatives also.

Description : Although — NH2 gp is an ortho and para directing gp, nitration of aniline gives along with ortho and para, meta derivatives also.

Last Answer : Nitration is carried out with a mixture of Conc. NO3 + Conc. H2 SO4 (nitrating mix). In the presence of these acids, most of aniline gets protonated to form anilinium ion. Therefore, in the ... is m-directing and deactivating hence a mixture of all three-ortho, para and meta derivatives is formed.

When aniline is heated with glycerol in the presence of sulfuric acid and nitrobenzene, it gives quinoline. This reaction in called (a) Fischer synthesis (b) Skraup synthesis (c) Diazotization (d) Corey-House synthesis

Description : When aniline is heated with glycerol in the presence of sulfuric acid and nitrobenzene, it gives quinoline. This reaction in called (a) Fischer synthesis (b) Skraup synthesis (c) Diazotization (d) Corey-House synthesis

Last Answer : Skraup synthesis

Benzenediazonium chloride reacts with hypophosphorus acid to form : (a) Phenol (b) Benzaldehyde (c) Aniline (d) Benzene

Description : Benzenediazonium chloride reacts with hypophosphorus acid to form : (a) Phenol (b) Benzaldehyde (c) Aniline (d) Benzene

Last Answer : Benzene

Chlorobenzene can be prepared by treatment of aniline with (a) Cuprous chloride (b) Chlorine in the presence of UV light (c) Nitrous acid followed by treatment with CuCl (d) Chlorine in the presence of FeCl3

Description : Chlorobenzene can be prepared by treatment of aniline with (a) Cuprous chloride (b) Chlorine in the presence of UV light (c) Nitrous acid followed by treatment with CuCl (d) Chlorine in the presence of FeCl3

Last Answer : Nitrous acid followed by treatment with CuCl

Bromobenzene can be prepared by treating aniline with (a) Conc HBr (b) Br2/FeBr3 (b) CuBr (d) Nitrous acid then CuBr

Description : Bromobenzene can be prepared by treating aniline with (a) Conc HBr (b) Br2/FeBr3 (b) CuBr (d) Nitrous acid then CuBr

Last Answer : Nitrous acid then CuBr

Benzenediazonium chloride reacts with warm water to give (a) Aniline (b) Phenol (c) Benzene (d) Chlorobenzene

Description : Benzenediazonium chloride reacts with warm water to give (a) Aniline (b) Phenol (c) Benzene (d) Chlorobenzene

Last Answer : Phenol

Which of the following are optimum temperature conditions for making benzenediazonium chloride from aniline? (a) 0°C to 10°C (b) 20°C to 25°C (c) 30°C to 40°C (d) 45°C to 50°C

Description : Which of the following are optimum temperature conditions for making benzenediazonium chloride from aniline? (a) 0°C to 10°C (b) 20°C to 25°C (c) 30°C to 40°C (d) 45°C to 50°C

Last Answer : 0°C to 10°C

Which of the following reagents is used to prepare benzenediazoniumchloride from aniline?(a) NaNO2 + HCl(b) LiAlH4(c) NH2NH2 + KOH(d) NaOH

Description : Which of the following reagents is used to prepare benzenediazonium chloride from aniline? (a) NaNO2 + HCl (b) LiAlH4 (c) NH2NH2 + KOH (d) NaOH

Last Answer : NaNO2 + HCl

Which of the following compounds is most basic? (a) Aniline (b) Benzylamine (c) Acetanilide (d) p-nitroaniline

Description : Which of the following compounds is most basic? (a) Aniline (b) Benzylamine (c) Acetanilide (d) p-nitroaniline

Last Answer : Benzylamine

Which of the following reagents does not react with aniline? (a) Acetyl chloride (b) Acetic anhydride (c) Ammonia (d) Nitrous acid

Description : Which of the following reagents does not react with aniline? (a) Acetyl chloride (b) Acetic anhydride (c) Ammonia (d) Nitrous acid

Last Answer : Ammonia

Aniline undergoes oxidation with Na2Cr2O7/H2SO4 to give (a) Schiff's base (b) p-Benzoquinone (c) Phenol (d) Benzoic acid

Description : Aniline undergoes oxidation with Na2Cr2O7/H2SO4 to give (a) Schiff's base (b) p-Benzoquinone (c) Phenol (d) Benzoic acid

Last Answer : p-Benzoquinone

Aniline reacts with acetic anhydride to give : (a) N-Methylaniline (b) p-Aminoacetophenone (c) Acetanilide (d) m-Aminoacetophenone

Description : Aniline reacts with acetic anhydride to give : (a) N-Methylaniline (b) p-Aminoacetophenone (c) Acetanilide (d) m-Aminoacetophenone

Last Answer : Acetanilide

When aniline is heated with chloroform and alcoholic KOH, the product is (a) Benzonitrile (b) p-Chloroaniline (c) Phenylisocyanide (d) m-Chloroaniline

Description : When aniline is heated with chloroform and alcoholic KOH, the product is (a) Benzonitrile (b) p-Chloroaniline (c) Phenylisocyanide (d) m-Chloroaniline

Last Answer : Phenylisocyanide

Aniline reacts with nitrous acid at low temperatures to give (a) a N-nitrosoamine (b) a nitrile (c) a diazonium salt (d) a nitrite salt

Description : Aniline reacts with nitrous acid at low temperatures to give (a) a N-nitrosoamine (b) a nitrile (c) a diazonium salt (d) a nitrite salt

Last Answer : a diazonium salt

Which of the following will give a precipitate with excess bromine water? (a) Bromobenzene (b) Aniline (c) Nitrobenzene (d) Toluene

Description : Which of the following will give a precipitate with excess bromine water? (a) Bromobenzene (b) Aniline (c) Nitrobenzene (d) Toluene

Last Answer : Aniline

Aniline reacts with bromine water to form (a) Bromobenzene (b) m-Bromoaniline (c) 2,4,6-Tribromoaniline (d) o- plus p-Bromoaniline

Description : Aniline reacts with bromine water to form (a) Bromobenzene (b) m-Bromoaniline (c) 2,4,6-Tribromoaniline (d) o- plus p-Bromoaniline

Last Answer : 2,4,6-Tribromoaniline

Benzamide reacts with Br2 and KOH to give (a) Benzene (b) Benzylamine (c) Aniline (d) Benzonitrile

Description : Benzamide reacts with Br2 and KOH to give (a) Benzene (b) Benzylamine (c) Aniline (d) Benzonitrile

Last Answer : Benzylamine

Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Description : Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Last Answer : the reduction of nitrobenzene with Sn/HCl

Which of the following statements is correct about aniline? (a) is weak acid. (b) diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid. (c) can be nitrated with concentrated HNO3 to form p-nitroaniline. (d) gives an intense green color with a suspension of bleaching powder in water

Description : Which of the following statements is correct about aniline? (a) is weak acid. (b) diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid. (c) can be nitrated with ... p-nitroaniline. (d) gives an intense green color with a suspension of bleaching powder in water

Last Answer : diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid.

Nitrobenzene undergoes reduction with zinc and KOH to give (a) Aniline (b) Hydrazobenzene (c) Azobenzene (d) None of these

Description : Nitrobenzene undergoes reduction with zinc and KOH to give (a) Aniline (b) Hydrazobenzene (c) Azobenzene (d) None of these

Last Answer : Hydrazobenzene

Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Description : Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Last Answer : can be oxidized with KMnO4 to give benzoic acid

Which of the following compounds does not react with acetyl chloride? (a) Methylamine (b) Dimethylamine (c) Aniline (d) Trimethylamine

Description : Which of the following compounds does not react with acetyl chloride? (a) Methylamine (b) Dimethylamine (c) Aniline (d) Trimethylamine

Last Answer : Trimethylamine

Which of the following is least soluble in water? (a) Methylamine (b) Trimethylamine (c) Dimethylamine (d) Aniline

Description : Which of the following is least soluble in water? (a) Methylamine (b) Trimethylamine (c) Dimethylamine (d) Aniline

Last Answer : Methylamine

Which of the following compounds does not dissolve in concentrated H2SO4 on warming? (a) n-Hexane (b) Diethyl ether (c) 1-Butene (d) Aniline

Description : Which of the following compounds does not dissolve in concentrated H2SO4 on warming? (a) n-Hexane (b) Diethyl ether (c) 1-Butene (d) Aniline

Last Answer : n-Hexane

Chemical name of Gammaxane is (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Description : Chemical name of Gammaxane is (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Last Answer : Benzene hexachloride

Polythene is polymer of (1) Ethylene (2) Propylene (3) Acetylene (4) Aniline

Description : Polythene is polymer of (1) Ethylene (2) Propylene (3) Acetylene (4) Aniline

Last Answer : Ethylene

Which of the following is a natural dye ? (1) Crystal violet (2) Aniline blue (3) Alizarin (4) Phenolphthalein

Description : Which of the following is a natural dye ? (1) Crystal violet (2) Aniline blue (3) Alizarin (4) Phenolphthalein

Last Answer : Alizarin

What is carbil amine reaction ?

Description : What is carbil amine reaction ?

Last Answer : The primary or 1 degree amine ( CH3-NH2 and aniline) reacts with chloroform and alcoholic caustic potash ( KOH) to produce methyl carbil amine ( CH3-NC) . This reaction is called carbil amine reaction.

Trimetyl amine is pyramidal while trisilyl amine is trigonal planer . explain ?

Description : Trimetyl amine is pyramidal while trisilyl amine is trigonal planer . explain ?

Last Answer : Ans. In tri silylamine N is sp2 hybridised and pπ-dπ bonding take place while In trimethyl amine N is SP3 hybridised and No pπ-dπ bonding .

How would you remove nonpolar impurities from an amine ?

Description : How would you remove nonpolar impurities from an amine ?

Last Answer : Ans.--- Adding HCl , amine will form salt whereas nonpolar impurities will not react . Amines can be regenerated by adding NaOH . 

Preparation of a diazonium salt from a primary aromatic amine is known as : (a) Coupling reaction (b) Sandmeyer reaction (c) Diazotization (d) Corey-House synthesis

Description : Preparation of a diazonium salt from a primary aromatic amine is known as : (a) Coupling reaction (b) Sandmeyer reaction (c) Diazotization (d) Corey-House synthesis

Last Answer : Diazotization

A primary amine can be identified by using (a) HCl (b) CHCl3 (c) NaOH (d) CHCl3 + KOH

Description : A primary amine can be identified by using (a) HCl (b) CHCl3 (c) NaOH (d) CHCl3 + KOH

Last Answer : CHCl3 + KOH