The hyperconjugative stabilities of tert-butyl cation and `2`-butene, respectively, are due to

1 Answer

Answer :

The hyperconjugative stabilities of tert-butyl cation and `2`-butene, respectively, are due to A ... and `sigma rarrpi^(**)` electron delocalizations

Related questions

Description : The major product obtained when tert- butyl bromide is heated with sodium ethoxide is

Last Answer : The major product obtained when tert- butyl bromide is heated with sodium ethoxide is A. 2- ... Ehene C. tert- Buty1methy1ether D. Diethyl ether

Description : Which of the following alkenes when passed through conc. `H_(2)SO_(4)` followed by hydrolysis with boiling water would give tert-butyl alcohol

Last Answer : Which of the following alkenes when passed through conc. `H_(2)SO_(4)` followed by hydrolysis with ... B. Isobutylene C. Propylene D. But-1-ene

Description : Di-tert butyl ether cannot be made by Williamson’s synthesis. Explain why ?

Last Answer : Ans. To prepare di tert-butyl ether by Williamson's synthesis, we need tert-butyl bromide and Sodium tertiary butoxide. Since tert-butyl bromide being 3°-alkyl halide prefers to ... rather than substitution, therefore the product obtained is isobutylene rather than ditertiary butyl ether.

Description : Hydroboration-oxidation of propene gives : (a) Isopropyl alcohol (b) n-Propyl alcohol (c) Isobutyl alcohol (d) tert-Butyl alcohol

Last Answer : n-Propyl alcohol

Description : Which of the following compounds will react with methylmagnesium bromide to give tert-butyl alcohol? (a) Acetyl chloride (b) Acetone (c) Isopropyl alcohol (d) Acetaldehyde

Last Answer : Acetone

Description : Which compound reacts most rapidly by an SN1 mechanism? (a) Methyl chloride (b) Isopropyl chloride (c) Ethyl chloride (d) tert-Butyl chloride

Last Answer : tert-Butyl chloride

Description : 2-Methylpropene reacts with HBr to give (a) tert-Butyl bromide (b) Isobutane (c) n-Butyl bromide (d) None of these

Last Answer : tert-Butyl bromide

Description : Optical isomerism is shown by (a) n-Butyl chloride (b) sec-Butyl chloride (c) tert-Butyl chloride (d) Isobutyl chloride

Last Answer : sec-Butyl chloride

Description : Relative stabilities of the following carbocations will be in the order:

Last Answer : Relative stabilities of the following carbocations will be in the order: A. I lt II lt III lt IV B. IV lt III ... lt III lt I D. II lt IV lt III lt I

Description : Which of the following correctly reflects relative stabilities of carbocations? (a) 3° allylic > 2° > 1° benzylic (b) methyl > 2° benzylic > 3° (c) 3° benzylic > vinyl > 1° (d) 2° allylic > 2° > vinyl

Last Answer : (d) 2° allylic > 2° > viny

Description : Why tert. Amines donot undergo acylation reaction ?

Last Answer : Ans.-- Tert. Amines donot undergo acylation reaction because they donot have Nattached to H- atom. 

Description : What is the major organic product of the reaction between benzene and isobutyl chloride in the presence of AlCl3? (a) tert-butylbenzene (b) isobutylbenzene (c) n-butylbenzene (d) chlorobenzene

Last Answer : tert-butylbenzene

Description : Due to its excellent permeability to air/gas and oxidation resistance, the tubes of automobile tyres is made of (A) Cold SBR (B) Butyl rubber (C) Bunai N (D) Buna S

Last Answer : (B) Butyl rubber

Description : Symptoms where shoots/leaves are bleached white are caused due to a). Atrazine b). Glufosinate c). Tembotrione d). Fluazifop-p-butyl

Last Answer : c). Tembotrione

Description : What is the composition of zircon , monazite , butyl etc. ?

Last Answer : Black gold is made up of zircon , monazite , butyl etc.

Description : Tertiary butyl amine is a-

Last Answer : Tertiary butyl amine is a- A. `1^(@)` Amine B. `2^(@)` Amine C. `3^(@)` Amine D. Quaternary salt

Description : (A) Tertiary butyl carbonion is more stable than methyl carbanion. (R) `+I` effect of the three methyl groups in tertiary butyl carbanion tends to mak

Last Answer : (A) Tertiary butyl carbonion is more stable than methyl carbanion. (R) `+I` effect of the three methyl ... IF (A) is incorrect but (R) is correct.

Description : Tertiary butyl chloride preferably undergo hydrolysis by:

Last Answer : Tertiary butyl chloride preferably undergo hydrolysis by: A. `S_(N^(1))` mechanism B. `S_(N^(2))` mechanism C. and of (a) and (b) D. none of these

Description : When tertiary butyl alcohol is passed over reduced copper, the reaction taking placed is

Last Answer : When tertiary butyl alcohol is passed over reduced copper, the reaction taking placed is A. oxidation B. reduction C. dehydration D. substitution

Description : When tertiary butyl alcohol is passed over reduced copper, the reaction taking placed is

Last Answer : When tertiary butyl alcohol is passed over reduced copper, the reaction taking placed is A. Ethylene B. Acetone C. Ether D. Acetaldehyde

Description : Wood spirit is – (1) Methyl alcohol (2) Ethyl alcohol (3) Butyl alcohol (4) Propyl alcohol

Last Answer : (1) Methyl alcohol Explanation: Methanol is also known as methyl alcohol, wood alcohol, wood naphtha or wood spirits. It acquired the name "wood alcohol" because it was once produced ... is produced in a catalytic industrial process directly from carbon monoxide, carbon dioxide, and hydrogen.

Description : lodex, a pain relief balm, has the smell of _______. (1) Methyl salicylate (2) Ethyl salicylate (3) Propyl salicylate (4) Butyl salicylate

Last Answer : (1) Methyl salicylate Explanation: Iodex has the characteristic odour of Methyl salicylate, an organic ester naturally produced by many species of plants, particularly wintergreens. It is used in high ... as a rubefacient and analgesic in deep heating liniments to treat joint and muscular pain.

Description : Which of the following rubbers has the widest service temperature range (-75 to 275°C)? (A) Butyl rubber (B) Silicon rubber (C) Nitrile rubber (D) Silicone rubber

Last Answer : (D) Silicone rubber

Description : __________ is produced by polymerisation of chloroprene. (A) Thiokol (a polysulphide rubber) (B) Butyl rubber (C) Neoprene (D) Polyurethane rubber

Last Answer : (C) Neoprene

Description : Buna-N is also called (A) Butyl rubber (B) Nitrile rubber (C) Neoprene (D) Thiokol

Last Answer : (B) Nitrile rubber

Description : Solvent deoiling process is used for separating oil and soft wax from hard wax. Methyl iso-butyl ketone and methyl ethyl ketone (MEK) are two commonly used deoiling solvents. Use of former as the deoiling solvent ... nitration temperature (C) Lower solvent dilution ratio (D) All (A), (B) & (C)

Last Answer : (D) All (A), (B) & (C)

Description : Methyl tertiary butyl ether (MTBE), a high octane (octane no. = 115) gasoline blending component is produced by the simple additive reaction of isobutylene with (A) Methyl alcohol (B) Ethyl alcohol (C) Methane (D) Ethane

Last Answer : (A) Methyl alcohol

Description : H2SO4 (< 50% concentration) is corrosive to (A) Aluminium, mild steel, stainless steel, concrete & tin (B) Copper, cast iron & high silicon iron (14% Si) (C) Rubber (butyl and hard), silicone rubber & Teflon (D) Glass, graphite, porcelain & stoneware

Last Answer : (A) Aluminium, mild steel, stainless steel, concrete & tin

Description : Which of the following mixtures does not form an azeotrope at atmospheric pressure? (A) Water-alcohol (B) Methyl alcohol-acetone (C) Butyl acetate-water (D) None of these

Last Answer : (D) None of these

Description : __________ is used as an 'entrainer' for the separation of acetic acid￾water mixture by distillation. (A) Furfural (B) Benzol (C) Butyl acetate (D) Hexane

Last Answer : (C) Butyl acetate

Description : What is the main product obtained when vapours of t-butyl alcohol are passed over copper at 300° ?

Last Answer : Ans. Isobutylene (2-Methyl propene) 

Description : From where is Butyl obtained; for the  treatment of AIDS?

Last Answer : Black mulberry

Description : Which of the following solvents is used for the extraction of H3PO4 from CaCl2 solution during manufacture of ortho-phosphoric acid by wet process employing hydrochloric acid leaching? (A) Isopropyl alcohol (B) Butyl alcohol (C) Toluene (D) Hexane

Last Answer : (B) Butyl alcohol

Description : Which of the following esters produces butyric acid and phenol on hydrolysis? (a) Phenyl butyrate (b) Butyl benzoate (c) Benzyl propionate (d) Phenyl propionate

Last Answer : Phenyl butyrate

Description : Which of the following describes the side chain of Leucine? (a) ethyl group (b) isopropyl group (c) sec-butyl group (d) isobutyl group

Last Answer : isobutyl group

Description : n-Butyl bromide reacts with NaSH to give (a) CH3CH2CH2SH (b) CH3SCH3 (c) CH3CH2CH2CH2SH (d) CH3CH2SCH2CH3

Last Answer : CH3CH2CH2CH2SH

Description : Which of the following is sec-butyl alcohol? (a) CH3CH2CH2CH2OH (b) CH3CH(OH)CH2CH3 (c) (CH3)2CHCH2OH (d) (CH3)2CHOH

Last Answer : CH3CH(OH)CH2CH3

Description : Which of the following has the highest boiling point? (a) diethyl ether (b) n-Butyraldehyde (c) n-propyl chloride (d) n-Butyl alcohol

Last Answer : n-Butyl alcohol

Description : . In industrial nomenclature, alcohol means (A) Butyl alcohol (B) Propyl alcoho (C) Ethanol (D) Methyl alcohol

Last Answer : (C) Ethanol

Description : H2S is scrubbed from refinery gases by absorption using (A) Dilute H2SO4 (B) Ethanol amine (C) Chilled water (D) Tri-butyl phosphate

Last Answer : (B) Ethanol amine

Description : Penicillin is separated from fermented broth by (A) Extraction with amyl or butyl acetate (B) Ternary Azeotropic distillation (C) Evaporator in calandria (D) Extractive distillation

Last Answer : (A) Extraction with amyl or butyl acetate

Description : The most suitable chemical which can be applied to the water surface for reducing evaporation is (A) Methyl alcohol (B) Ethyl alcohol (C) Cetyl alcohol (D) Butyl alcohol

Last Answer : Answer: Option C

Description : From site of uptake to site of action, fluazi fop-butyl move in a). water conducting stream b). sap conducting stream c). Both d). None

Last Answer : c). Both

Description : Which of the herbicide (ai) requiring higher amount for a unit area to be sprayed a). Bispyribac-sodium b). Butachlor c). Cyhalofop-butyl d). Pyrazosulfuron-ethyl

Last Answer : b). Butachlor

Description : Iodex, a pain relief balm, has the smell of __________ . (1) Methyl salicylate (2) Ethyl salicylate (3) Propyl salicylate (4) Butyl salicylate

Last Answer : Methyl salicylate

Description : Wood spirit is (1) Methyl alcohol (2) Ethyl alcohol (3) Butyl alcohol (4) Propyl alcohol

Last Answer : Methyl alcohol

Description : The effect that makes 2,3-dimethyl-2-butene more stable than 2-butene is :

Last Answer : The effect that makes 2,3-dimethyl-2-butene more stable than 2-butene is : A. hyperconjugation B. reseonce C. steric effect D. inductive effect

Description : Polymerisation (A) Produces i-octane from cracked gases containing i-butane and butene (B) Causes olefins to combine with each other (C) Causes aromatics to combine with each other (D) Is aimed at producing lubricating oil

Last Answer : (B) Causes olefins to combine with each other

Description : Which of the following is a Naphthene? (A) Butene (B) Butadiene (C) Cyclohexane (D) Acetylene

Last Answer : (C) Cyclohexan

Description : Classify the following into saturated and unsaturated hydrocarbons – Benzene, cyclopropane, alkene and alkane, methane, ethene, Propyne, butene

Last Answer : Saturated: Alkane, cyclopropane, methane Unsaturated: Benzene, alkene, ethene, Propyne, butene