Description : For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify (i) the oxidation number of iron, (ii) the hybrid orbitals and the shape of the complex, (iii) the magnetic behaviour of the complex, (iv) ... an optical isomer also, and (vi) name of the complex. (At. no. of Fe = 26) \ -Chemistry
Last Answer : i) [Fe(en)2Cl2] Cl or x + 0 + 2 (-1) + (-1) = 0 x + (- 3) = 0 or x = + 3 ∴ Oxidation number of iron, x = + 3 (ii) The complex has two bidentate ligands and two ... )2Cl2] Cl, only cis-isomer shows optical isomerism. (vi) Name of complex: Dichloridobis (ethane-1, 2- diamine) Iron (III) chloride
Description : Find the sum of number of geometrical isomers for following complexes. `(a) [CoCl_(2)Br_(2)]^(2-) " " (b) [Rh(en)_(3)]^(3+) " " ( c) [Cr(en)_(2)Br_(2)
Last Answer : Find the sum of number of geometrical isomers for following complexes. `(a) [CoCl_(2)Br_(2)]^(2-) " " (b) [Rh(en ... e) [Co(NH_(3))_(3)(NO_(2))_(3)]`
Description : How many isomers are possible for the complex `[Co(en)_(2)Cl_(2)]`(en=ethylene diamine )
Last Answer : How many isomers are possible for the complex `[Co(en)_(2)Cl_(2)]`(en=ethylene diamine ) A. 4 B. 2 C. 6 D. 3
Description : The bond energies of `F_(2),Cl_(2),Br_(2)` and `I_(2)` are 155.4, 243.6, 193.2 and `151.2 Kjmol^(-1)` respectively. The strongest bond is :
Last Answer : The bond energies of `F_(2),Cl_(2),Br_(2)` and `I_(2)` are 155.4, 243.6, 193.2 and `151.2 Kjmol^(-1)` ... . F -F B. Cl - Cl C. Br - Br D. I - I
Description : With respect to halogens, four statements are given below: (P) The bond dissociation energies for halogens are in the order: `I_(2) lt F_(2) lt Br_(2)
Last Answer : With respect to halogens, four statements are given below: (P) The bond dissociation energies for halogens are in ... ,III,IV C. II,III,IV D. I,III
Description : Which of the following statements is not true about the complex ion `[Pt(en)_2Cl_2]^(2+)`?
Last Answer : Which of the following statements is not true about the complex ion `[Pt(en)_2Cl_2]^(2+) ... Only the cis isomer has non-superimposable mirror image.
Description : Which of the following complexes can exists as enantiomers ? Draw their structures `(a) cis-[Co(NH_(3))_(4)Br_(2)]^(+) " " (b) cis-[Cr(H_(2)O)_(2)(en)
Last Answer : Which of the following complexes can exists as enantiomers ? Draw their structures `(a) cis-[Co(NH_(3))_(4)Br_(2)]^ ... [Co(NH_(3))_(2)(en)_(2)]^(2+)`
Description : Which of the following terms denotes the polar molecules or negative ions clustered about a central positive ion? w) ligands x) isomers y) complex ions z) dipoles
Last Answer : ANSWER: W -- LIGAND
Description : Consider the following reaction and statements: `[Co(NH_(3))_(4)Br_(2)]^(+)+Br^(-) to [Co(NH_(3))_(3)Br_(3)]+NH_(3)` Two isomers are produced if the r
Last Answer : Consider the following reaction and statements: `[Co(NH_(3))_(4)Br_(2)]^(+)+Br^(-) to [Co(NH_(3))_(3) ... II B. III and IV C. I and IV D. II and III
Description : `P` and `Q` are isomers of dicarboxylic acid `C_(4)H_(4)O_(4)`. Bothdecolorize `Br_(2)//H_(2)O`. On heating, `P` forms the cyclic anhydride. Upon trea
Last Answer : `P` and `Q` are isomers of dicarboxylic acid `C_(4)H_(4)O_(4)`. Bothdecolorize `Br_(2)// ... . Optically inactive pair (T, U) and optically inactive S
Description : How many geomatrical isomers are possible for each of the following complexes ? `(a) [Pt(NH_(3))_(2)(SCN)_(2)] " " (b) [CoCl_(2)Br_(2)]^(2-)("tetrahed
Last Answer : How many geomatrical isomers are possible for each of the following complexes ? `(a) [Pt(NH_(3))_(2)(SCN)_(2)] " " ... (+) " " (f) [Rh(en)_(3)]^(3+)`
Description : How many isomers are possible for a compound with formula, `[Rn(en)_(2)Cl(NO_(2))]` ?
Last Answer : How many isomers are possible for a compound with formula, `[Rn(en)_(2)Cl(NO_(2))]` ? A. 2 B. 4 C. 6 D. 8
Description : The number of geometrical isomers for octahedral `[CoCl_(4)(NH_(3))_(2)]^(-)`, square planar `[AuBr_(2)Cl_(2)]^(-)` and `[PtCl_(2)(en)]` are
Last Answer : The number of geometrical isomers for octahedral `[CoCl_(4)(NH_(3))_(2)]^(-)`, square planar `[AuBr_(2)Cl_(2)]^(-) ... are A. 4,2 B. 2,2 C. 3,2 D. 2,3
Description : What type of isomers are the following : `(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]` `(ii) [Co(en)_(3)[Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)]` `(iii)
Last Answer : What type of isomers are the following : `(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]` `(ii) [Co(en)_(3)[Cr( ... ]Cl and [Co(H_(2)O)Cl_(3)(py)_(2)]H_(2)O`
Description : A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. mxylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture? (A) The mixture exhibits ... : o-xylene 30, p-xylene 60 and m-xyoene 10 (D) The mixture contain optical isomers
Last Answer : (A) The mixture exhibits an azeotrope at 101.3 kPa
Description : An octahedral complex with molecular composition `M.5NH_(3).Cl.SO_(4)` has two isomers. A and B. The solution A gives a white precipitation with `AgNO
Last Answer : An octahedral complex with molecular composition `M.5NH_(3).Cl.SO_(4)` has two isomers ... isomerism C. coordination isomers D. Geometrical isomerism
Description : Statement-1: The geometrical isomers of the complex `[M(NH_(4))_(4)Cl_(2)]` are optically inactive, and Statement-2: Both geometrical isomers of the c
Last Answer : Statement-1: The geometrical isomers of the complex `[M(NH_(4))_(4)Cl_(2)]` are optically inactive, ... D. Statement-1 is false, statement-2 is true.
Description : The complex `[Cr(H_(2)O)_(4)Br_(2)]Cl` gives the test for :
Last Answer : The complex `[Cr(H_(2)O)_(4)Br_(2)]Cl` gives the test for : A. `Br^(-)` B. `Cl^(-)` C. `Cr^(3+)` D. `Br^(-) and Cl^(-)` both
Description : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion. -Chemistry
Last Answer : Tetra amminechloridonitro cobalt (III) ion.
Description : Which of the following complexes shows optical isomerism ? (en=ethylenediamine )
Last Answer : Which of the following complexes shows optical isomerism ? (en=ethylenediamine ) A. `cis[Co(en)_(2)Cl_(2)]Cl` B. ` ... Cl` D. `[Co(NH_(3))_(3)Cl_(3)]`
Description : Which one of the following has an optical isomer ? (en=ethylenediamine )
Last Answer : Which one of the following has an optical isomer ? (en=ethylenediamine ) A. `[Zn(en)(NH_(3))_(2)]^(2+)` B. `[Co( ... en)]^(3+)` D. `[Zn(en)_(2)]^(2+)`
Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry
Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+
Description : Write IUPAC name of the complex: [CoCl2(en)2]+ -Chemistry
Last Answer : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion.
Description : Which of the following is more stable complex and why? [Co(NH3)6]3+ and [Co(en)3]3+ -Chemistry
Last Answer : Co(en)3]3+ is more stable complex than [CO(NH3)6]3+ because of chelate effect.
Description : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2)]` is :
Last Answer : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2 ... (ethane-1,2-diammine) nitritioplatinum(IV) dicyanoargentate (I)
Description : The IUPAC name of complex `[Cu(en)_(2)(H_(2)O)_(2)]^(22+)`
Last Answer : The IUPAC name of complex `[Cu(en)_(2)(H_(2)O)_(2)]^(22+)` A. ethylene ... C. diaquobisdietyleamineCU(II)ion D. diaquobis(ethylenediamine)cuprate(II)
Description : Three arrangements are shown for the complex `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)` pick up the wrong statement.
Last Answer : Three arrangements are shown for the complex `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)` pick up ... are optical isomers D. II and III are geometrical isomers.
Description : How many isomeric forms are possible for the octahedral complex. `[Rh(en)_(2)(NO_(2))(SCN)]^(+)` ?
Last Answer : How many isomeric forms are possible for the octahedral complex. `[Rh(en)_(2)(NO_(2))(SCN)]^(+)` ?
Description : In the complex `[CoCl_(2)(en)_(2)]Br`, the co-ordination number and oxidation state of cobalt are :
Last Answer : In the complex `[CoCl_(2)(en)_(2)]Br`, the co-ordination number and oxidation state of cobalt are : A. 6 and +3 B. 3 and +3 C. 4 and +2 D. 6 and +1
Description : Two sugars which differ from one another only in configuration around a single carbon atom are termed (A) Epimers (B) Anomers (C) Optical isomers (D) Stereoisomers
Last Answer : A
Last Answer : (A) Epimers
Description : Optical isomers of all aminoacids exist except (A) Glycine (B) Arginine (C) Alanine (D) Hydroxy proline
Last Answer : Answer : A
Description : Optical isomers that are mirror images and non superimposable are called (A) Diastereomers (B) Euantiomers (C) dl isomers (D) Stereomers
Last Answer : Answer : B
Description : This amino acid cannot have optical isomers: (A) Alanine (B) Histidine (C) Threonine (D) Glycine
Last Answer : Answer : D
Description : Compounds having the same structural formula but differing in spatial configuration are known as (A) Stereoisomers (B) Anomers (C) Optical isomers (D) Epimers
Description : Isomers differing as a result of variations in configuration of the —OH and —H on carbon atoms 2, 3 and 4 of glucose are known as (A) Epimers (B) Anomers (C) Optical isomers (D) Steroisomers
Description : How many optical isomers are possible for lactic acid? (a) 2 (b) 4 (c) 6 (d) 8
Last Answer : 2
Description : What is the possible number of optical isomers for a compound containing 2 dissimilar asymmetric carbon atoms? (a) 2 (b) 4 (c) 6 (d) 8
Last Answer : 4
Description : What is the possible number of optical isomers for a compound containing n dissimilar asymmetric carbon atoms? (a) n2 (b) 2n (c) n + 1 (d) n + 2
Last Answer : 2n
Description : Optical isomers that are not mirror images are called (a) Diastereomers (b) Enantiomers (c) Metamers (d) Meso compounds
Last Answer : Diastereomers
Description : Optical isomers that are mirror images are called : (a) Tautomers (b) Diastereomers (c) Enantiomers (d) Metamers
Last Answer : Enantiomers
Description : It is possible to distinguish between optical isomers (a) by using chemical tests (b) by mass spectrometry (c) by IR spectroscopy (d) by polarimetry
Last Answer : (d) by polarimetry
Description : The compounds CH3CH2OCH2CH3 and CH3OCH2CH2CH3 are (a) Enantiomers (b) Conformational isomers (c) Metamers (d) Optical isomers
Last Answer : Metamers
Description : Optical isomers are ------. a. Identical structures b. Not mirror images of each other c. Non super-imposable mirror images of each other. d. Super-imposable mirror images of each other
Last Answer : c. Non super-imposable mirror images of each other.
Last Answer : (A) Stereoisomers
Description : A coordination complex of type `MX_(2)Y_(2)`[M=metal ion, X,Y=monodentata ligands ], can have either a tetrahedral of a square planar geometry. The ma
Last Answer : A coordination complex of type `MX_(2)Y_(2)`[M=metal ion, X,Y=monodentata ligands ], can have either a tetrahedral ... 2 and 1 C. 1 and 3 D. 3 and 2
Description : The octahedral complex of a metal ion `M^(3+)` with four monodentate ligands `L_(1),L_(2),L_(3) and L_(4)` absorb wavelength in the region of red, gre
Last Answer : The octahedral complex of a metal ion `M^(3+)` with four monodentate ligands `L_(1),L_(2),L_(3) and L_(4)` ... `L_(1) lt L_(2) lt L_(4) lt L_(3)`
Description : A cationic complex has two isomers A & B. Each has one Co3+, five NH3 , one Br and one SO4 2 . A gives a white precipitate with BaCl2 solution while B gives a yellow precipitate with AgNO3 ... are the possible structures of the complexes A and B ? (a) Will the two complexes have same colour ?
Last Answer : (a) [CO (NH3 ) 5 Br] SO4 and [CO (NH3 ) 5 SO4 ] Br (b) NO
Description : How many isomers are possible for complex `[Co(ox)_(2)Cl_(2)]^(+)` ?
Last Answer : How many isomers are possible for complex `[Co(ox)_(2)Cl_(2)]^(+)` ? A. 1 B. 3 C. 2 D. 4