Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry
Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+
Description : Name the following coordination compounds according to IUPAC system of nomenclature :(i) [Co(NH3)4 (H2O)Cl]Cl2 (ii) [CrCl2(en)2]Cl, (en = ethane – 1, 2 – diamine) -Chemistry
Last Answer : (i) [CO(NH3)4 (H2O)Cl]Cl2 Tetraammine aquachlorido cobalt (III) chloride (ii) [CrCl2(en)2]Cl Dichlorobis (ethane-1, 2-diamine) chromium (III) chloride
Description : Explain why [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex. (At. no. Co = 27, Ni = 28) -Chemistry
Last Answer : In [Co(NH3)6]3+, the d-electrons of Co3+ ([Ar]3d6 45°) get paired leaving behind two empty d-orbital and undergo d2sp3 hybridization and hence inner orbital complex, while in [Ni(NH3)6]2+ ... of Ni2+([Ar]3d8 45°) do not pair up and use outer 4d subshell hence outer orbital complex.
Description : Write the IUPAC name of the following complex : [CO(NH3)6]3+ -Chemistry
Last Answer : Hexaamminecobalt (III) ion.
Description : (i) Write down the IUPAC name of the following complex : [CO(NH3)5Cl]2+ (ii) Write the formula for the following complex : Potassium tetrachloridonickelate (II) -Chemistry
Last Answer : i) [CO(NH3)5Cl]2+ IUPAC name : Pentaammine chlorido cobalt (III) ion (ii) Formula of the complex potassium tetrachloridonickelate (II) K2[NiCl4]
Description : Indicate the types of isomerisms exhibited by the complex [Co(NH3)5 (NO2)] (NO3)2. (At. no. Co = 27) -Chemistry
Last Answer : It shows ionisation isomerism and linkage isomerism.
Description : What is the IUPAC name of the complex [Ni(NH3)6]Cl2? -Chemistry
Last Answer : [Ni(NH3)6]Cl2 IUPAC name : Hexaamminenickel (II) chloride.
Description : For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify (i) the oxidation number of iron, (ii) the hybrid orbitals and the shape of the complex, (iii) the magnetic behaviour of the complex, (iv) ... an optical isomer also, and (vi) name of the complex. (At. no. of Fe = 26) \ -Chemistry
Last Answer : i) [Fe(en)2Cl2] Cl or x + 0 + 2 (-1) + (-1) = 0 x + (- 3) = 0 or x = + 3 ∴ Oxidation number of iron, x = + 3 (ii) The complex has two bidentate ligands and two ... )2Cl2] Cl, only cis-isomer shows optical isomerism. (vi) Name of complex: Dichloridobis (ethane-1, 2- diamine) Iron (III) chloride
Description : Write IUPAC name of the complex: [CoCl2(en)2]+ -Chemistry
Last Answer : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion.
Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.
Description : Describe the shape and magnetic behaviour of following complexes : (i) [CO(NH3)6]3+ (ii) [Ni(CN)4]2- (At. No. Co = 27, Ni = 28) -Chemistry
Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-
Description : Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit? -Chemistry
Last Answer : IUPAC name : Tetraamine dichlorido chromium (III) ion. It exhibits geometrical isomerism.
Description : A complex compound in which the oxidation number of a metal is zero is - (1) K4 [Fe (CN)6] (2) K3 [Fe (CN)6] (3) [Ni (CO)4] (4) [Pl (NH3)4]Cl2
Last Answer : (3) [Ni (CO)4]
Description : How many isomers are possible for the complex `[Co(en)_(2)Cl_(2)]`(en=ethylene diamine )
Last Answer : How many isomers are possible for the complex `[Co(en)_(2)Cl_(2)]`(en=ethylene diamine ) A. 4 B. 2 C. 6 D. 3
Description : Three arrangements are shown for the complex `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)` pick up the wrong statement.
Last Answer : Three arrangements are shown for the complex `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)` pick up ... are optical isomers D. II and III are geometrical isomers.
Description : In the complex `[CoCl_(2)(en)_(2)]Br`, the co-ordination number and oxidation state of cobalt are :
Last Answer : In the complex `[CoCl_(2)(en)_(2)]Br`, the co-ordination number and oxidation state of cobalt are : A. 6 and +3 B. 3 and +3 C. 4 and +2 D. 6 and +1
Description : When a co-ordination compound CrCl3.6H2O is mixed with AgNO3, 2 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex. (ii) IUPAC name of the complex. -Chemistry
Last Answer : (i) The complex formed on mixing a coordination compound CrCl3.6H2O with AgNO3 is as follows CrCl3.6H2O + AgNO3 → [Cr(H2O5)Cl]Cl2. H2O (ii) Pentaaquachloridochromium (III) chloride monohydrate
Description : How is the stability of a co-ordination compound in solution decided ? How is the dissociation constant of a complex defined? -Chemistry
Last Answer : Stability of a complex in solution means the measure of resistance to the replacement of a ligand by some other ligand. This stablility can be expressed in terms of equilibrium constant. Let the ... is its tendency to donate electron pair and therefore, more is the stability of the complex.
Description : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion. -Chemistry
Last Answer : Tetra amminechloridonitro cobalt (III) ion.
Description : Give IUPAC name of the ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry
Last Answer : IUPAC name : Triammine chlorido nickel (II) nitrate [Ni(NH3)3NO3]Cl
Description : Give IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry
Last Answer : IUPAC name : Triammine nitrato nickel (III) chloride
Description : A cationic complex has two isomers A & B. Each has one Co3+, five NH3 , one Br and one SO4 2 . A gives a white precipitate with BaCl2 solution while B gives a yellow precipitate with AgNO3 ... are the possible structures of the complexes A and B ? (a) Will the two complexes have same colour ?
Last Answer : (a) [CO (NH3 ) 5 Br] SO4 and [CO (NH3 ) 5 SO4 ] Br (b) NO
Description : What type of isomers are the following : `(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]` `(ii) [Co(en)_(3)[Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)]` `(iii)
Last Answer : What type of isomers are the following : `(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]` `(ii) [Co(en)_(3)[Cr( ... ]Cl and [Co(H_(2)O)Cl_(3)(py)_(2)]H_(2)O`
Description : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2)]` is :
Last Answer : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2 ... (ethane-1,2-diammine) nitritioplatinum(IV) dicyanoargentate (I)
Description : The complex ion . `[M(en)Br_(2)I_(2)]^(-1)`, has two optical isomers. Their correct configurations are:
Last Answer : The complex ion . `[M(en)Br_(2)I_(2)]^(-1)`, has two optical isomers. Their correct configurations are: A. B. C. D.
Description : The IUPAC name of complex `[Cu(en)_(2)(H_(2)O)_(2)]^(22+)`
Last Answer : The IUPAC name of complex `[Cu(en)_(2)(H_(2)O)_(2)]^(22+)` A. ethylene ... C. diaquobisdietyleamineCU(II)ion D. diaquobis(ethylenediamine)cuprate(II)
Description : How many isomeric forms are possible for the octahedral complex. `[Rh(en)_(2)(NO_(2))(SCN)]^(+)` ?
Last Answer : How many isomeric forms are possible for the octahedral complex. `[Rh(en)_(2)(NO_(2))(SCN)]^(+)` ?
Description : Which of the following statements is not true about the complex ion `[Pt(en)_2Cl_2]^(2+)`?
Last Answer : Which of the following statements is not true about the complex ion `[Pt(en)_2Cl_2]^(2+) ... Only the cis isomer has non-superimposable mirror image.
Description : Write the IUPAC name of [CO (NH3 ) 4 B12] 2 [ZnCl4 ].
Last Answer : Ans. Tetraamminedibromocobalt (III) tetrachlorozincate (II)
Description : Out of CO and NH3 which is adsorbed on activated charcoal to a large extent and why ?
Last Answer : Ans. Ammonia; because more easily liquefiable gas undergoes adsorption to a greater extent.
Description : Which of the following complexes can exists as enantiomers ? Draw their structures `(a) cis-[Co(NH_(3))_(4)Br_(2)]^(+) " " (b) cis-[Cr(H_(2)O)_(2)(en)
Last Answer : Which of the following complexes can exists as enantiomers ? Draw their structures `(a) cis-[Co(NH_(3))_(4)Br_(2)]^ ... [Co(NH_(3))_(2)(en)_(2)]^(2+)`
Description : When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex (ii) IUPAC name of the complex -Chemistry
Last Answer : i) Complex so formed is: CoCl3.6NH3 + AgNO3 → [Co(NH3)6]Cl3 (ii) IUPAC name of complex is: Hexaamminecobalt (III) chloride
Description : Write IUPAC name of the complex: -Chemistry
Last Answer : Dichloridobis ethylenediamine cobalt (III) ion.
Description : Which complex ion is formed when undecomposed AgBr is washed with hypo solution in photography? (Comptt. All India 2013) -Chemistry
Last Answer : Sodium dithiosulphato argentate (I) complex is formed
Description : Acid rains are due to which of the following gases? (a) CO2 and CO (b) Ozone and CO2(c) NO2 and SO2 (d) NH3 and CO2
Last Answer : (c) NO2 and SO2
Description : Raw materials for urea production are (A) CO2 and N2 (B) CO2 , H2 and N2 (C) NH3 and CO (D) HNO3 and CaCO3
Last Answer : (B) CO2 , H2 and N2
Description : Urea is represented as (A) NH2 .CO.NH2 (B) NH3CO.CH3 (C) NH.CO2 .NH (D) NH3 .CO2 .NH3
Last Answer : (A) NH2 .CO.NH2
Description : . Chemical formula of biuret is (A) NH2 .CO.NH2 (B) NH3 .COO.NH3 (C) NH2CONHCONH2 (D) NH4COONH2
Last Answer : (C) NH2CONHCONH2
Description : Automobile exhaust is passed through two compartments catalytic converter employing platinum as catalyst for (A) Conversion of CO into CO2 in the second compartment (B) Conversion of NOx into N2 and NH3 in the first ... of unburnt hydrocarbon fuel in the second compartment (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : Which of the following pollutants is absent in the emissions from a fertiliser plant? (A) SO2 & SO3 (B) NO2 (C) NH3 (D) CO
Last Answer : (D) CO
Description : . Shift conversion reaction (A) Converts N2 and H2 into NH3 (B) Converts CO to CO2 with steam (C) Is non-catalytic (D) Is highly exothermic
Last Answer : (B) Converts CO to CO2 with steam
Description : The worst enemy of ozone is a) Liquid NH3 b) SO2 c) CH4 d) CO.
Last Answer : c) CH4
Description : Acid rain is caused by a) SO2 and NO2 b) SO2 and CO c) NH3 and CO d) SO2 and NH3.
Last Answer : a) SO2
Description : Compare the following complexes’ with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : (i) [Ni(CN)4]2- (ii) [NiCl4]2- (iii) [CoF6]3- [At. Nos. : Ni = 28; Co = 27] -Chemistry
Last Answer : (i) [Ni(CN)4]2- Shape : Octahedral outer orbital complex Hybridisation : sp3d2 Magnetic behaviour : Paramagnetic (4 unpaired electrons)
Description : Explain the following : (i) Low spin octahedral complexes of nickel are not known. (ii) The π-complexes are known for transition elements only. (iii) CO is a stronger ligand than NTL, for many metals. -Chemistry
Last Answer : (i) The electronic configuration of Ni is [Ar] 3d8 4s2 which shows that it can only form two types of complexes i.e. square planar (dsp2) in presence of strong ligand and tetrahedral (sp3) in ... more splitting of d-orbitals and moreover it is also able to form π bond due to back bonding.
Description : Compare the following complexes with respect to their shape, magnetic behaviour and the hybrid orbitals involved : (i) [CoF4]2- (ii) [Cr(H2O)2(C2O4)2]– (iii) [Ni(CO)4] (Atomic number : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [COF4]2_ : Tetrafluorido cobalt (III) ion Coordination number = 4 Shape = Tetrahedral Hybridisation = sp3 Important Questions for Class 12 Chemistry Chapter 9 Coordination Compounds Class 12 Important Questions 7
Description : The MOST stable area to evaluate the craniofacial growth is: A. Nasal floor B. Cranial vault C. Occlusal plane D. Naso maxillary complex E. Anterior cranial base
Last Answer : E. Anterior cranial base
Description : In coordination chemistry there are a veriety of methods applied to find out the structure of complexes. One method involves treating the complex with
Last Answer : In coordination chemistry there are a veriety of methods applied to find out the structure of complexes. One method involves ... A. 2 B. 3 C. 4 D. 1
Last Answer : In coordination chemistry there are a veriety of methods applied to find out the structure of complexes. One method involves ... 0` C. `0.0` D. `3.0`
Last Answer : In coordination chemistry there are a veriety of methods applied to find out the structure of complexes. One method ... BM C. 4.9 BM D. 5.9 BM