Giving a suitable example for each, explain the following : (i) Crystal field splitting (ii) Linkage isomerism (iii) Ambidentate ligand -Chemistry

Giving a suitable example for each, explain the following : (i) Crystal field splitting (ii) Linkage isomerism (iii) Ambidentate ligand -Chemistry
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i) Crystal field splitting: It is the splitting of the degenerate energy levels due to the presence of ligands. When ligand approaches a transition metal ion, the degenerate d-orbitals split into two sets, one with lower energy and the other with higher energy. This is known as crystal field splitting and the difference between the lower energy set and higher energy set is known as crystal field splitting energy (CFSE) Example : 3d5 of Mn2+ (ii) Linkage isomerism: When more than one atom in an ambidentate ligand is linked with central metal ion to form two types of complexes, then the formed isomers are called linkage isomers and the phenomenon is called linkage isomerism. [Cr(H2O)5(NCS)]2+ Pentaaquathiocyanate chromium (III) ion [Cr(H2O)5(NCS)]2+ Pentaaquaisothiocyanate chromium (III) ion (iii) Ambidentate ligand: The monodentate ligands with more than one coordinating atoms is known as ambidentate ligand. Monodentate ligands have only one atom capable of binding to a central metal atom or ion. For example, the nitrate ion NO2– can bind to the central metal atom/ion at either the nitrogen atom or one of the oxygen atoms. Example : — SCN thiocyanate, — NCS isothiocyanate
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Description : Identify the type of reaction(s) in the following equations. (i)CH4 + 2O2 CO2 + 2 H2O (ii) Pb(NO3)2 + 2KI ——–>Pbl2 + 2KNOs (iii) CaO + H2O ——–> Ca(OH)2 (iv) CuSO4 + Zn ——–> ZnSO4 + Cu -Chemistry

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Description : Using IUPAC norms write the formulae for the following: (a) Tris(ethane-1,2-diamine) chromium (III) chloride (b) Potassium tetrahydroxozincate(II) -Chemistry

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Description : What are metalloids? Explain by giving examples. -Chemistry-10

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Write the balanced equation for the following chemical reactions. (i) Hydrogen + Chlorine → Hydrogen chloride (ii) Barium chloride + Aluminium sulphate → Barium sulphate + Aluminium chloride (iii) Sodium + Water → Sodium hydroxide + Hydrogen -Chemistry-10

Description : Write the balanced equation for the following chemical reactions. (i) Hydrogen + Chlorine → Hydrogen chloride (ii) Barium chloride + Aluminium sulphate → Barium sulphate + Aluminium chloride (iii) Sodium + Water → Sodium hydroxide + Hydrogen -Chemistry-10

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Description : Nickel `(Z=28)` combines with a uninegative monodentate ligand `X^(-)` to form a paramagnetic complex `[NiX_4]^(2-)`. The number of unpaired electron(

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Description : The lone pair of electrons at one of the ring nitrogens in the given amino acid makes a potential ligand, which is important in binding the iron atoms in hemoglobin: (A) Tryptophan (B) Threonine (C) Histidine (D) Serine

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