Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit? -Chemistry

1 Answer

Answer :

IUPAC name : Tetraamine dichlorido chromium (III) ion. It exhibits geometrical isomerism.

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Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry

Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+

Description : (i) Write down the IUPAC name of the following complex : [CO(NH3)5Cl]2+ (ii) Write the formula for the following complex : Potassium tetrachloridonickelate (II) -Chemistry

Last Answer : i) [CO(NH3)5Cl]2+ IUPAC name : Pentaammine chlorido cobalt (III) ion (ii) Formula of the complex potassium tetrachloridonickelate (II) K2[NiCl4]

Description : Write the IUPAC name of the following complex : [CO(NH3)6]3+ -Chemistry

Last Answer : Hexaamminecobalt (III) ion.

Description : What is the IUPAC name of the complex [Ni(NH3)6]Cl2? -Chemistry

Last Answer : [Ni(NH3)6]Cl2 IUPAC name : Hexaamminenickel (II) chloride.

Description : For the complex `K_(2)[Cr(NO)(NH_(3))(CN)_(4)],mu=1.73 BM`. (i) Write IUPAC name. (ii) What will be structure ? (iii) How many unpaired electrons are

Last Answer : For the complex `K_(2)[Cr(NO)(NH_(3))(CN)_(4)],mu=1.73 BM`. (i) Write IUPAC name. ... the complex. (vi) What will be the hybridisation of the complex.

Description : Name the following coordination compounds according to IUPAC system of nomenclature :(i) [Co(NH3)4 (H2O)Cl]Cl2 (ii) [CrCl2(en)2]Cl, (en = ethane – 1, 2 – diamine) -Chemistry

Last Answer : (i) [CO(NH3)4 (H2O)Cl]Cl2 Tetraammine aquachlorido cobalt (III) chloride (ii) [CrCl2(en)2]Cl Dichlorobis (ethane-1, 2-diamine) chromium (III) chloride

Description : Give IUPAC name of the ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Last Answer : IUPAC name : Triammine chlorido nickel (II) nitrate [Ni(NH3)3NO3]Cl

Description : Give IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Last Answer : IUPAC name : Triammine nitrato nickel (III) chloride

Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry

Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.

Description : When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex (ii) IUPAC name of the complex -Chemistry

Last Answer : i) Complex so formed is: CoCl3.6NH3 + AgNO3 → [Co(NH3)6]Cl3 (ii) IUPAC name of complex is: Hexaamminecobalt (III) chloride

Description : When a co-ordination compound CrCl3.6H2O is mixed with AgNO3, 2 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex. (ii) IUPAC name of the complex. -Chemistry

Last Answer : (i) The complex formed on mixing a coordination compound CrCl3.6H2O with AgNO3 is as follows CrCl3.6H2O + AgNO3 → [Cr(H2O5)Cl]Cl2. H2O (ii) Pentaaquachloridochromium (III) chloride monohydrate

Description : Write IUPAC name of the complex: -Chemistry

Last Answer : Dichloridobis ethylenediamine cobalt (III) ion.

Description : Write IUPAC name of the complex: [CoCl2(en)2]+ -Chemistry

Last Answer : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion.

Description : Which of the following complex species is not expected to exhibit optical isomerism ?

Last Answer : Which of the following complex species is not expected to exhibit optical isomerism ? A. `[Co(en)_(3)]^(3+)` B. ` ... `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)`

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Last Answer : Ans. Tetraamminedibromocobalt (III) tetrachlorozincate (II) 

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Last Answer : In [Co(NH3)6]3+, the d-electrons of Co3+ ([Ar]3d6 45°) get paired leaving behind two empty d-orbital and undergo d2sp3 hybridization and hence inner orbital complex, while in [Ni(NH3)6]2+ ... of Ni2+([Ar]3d8 45°) do not pair up and use outer 4d subshell hence outer orbital complex.

Description : Which of the following is more stable complex and why? [Co(NH3)6]3+ and [Co(en)3]3+ -Chemistry

Last Answer : Co(en)3]3+ is more stable complex than [CO(NH3)6]3+ because of chelate effect.

Description : Indicate the types of isomerisms exhibited by the complex [Co(NH3)5 (NO2)] (NO3)2. (At. no. Co = 27) -Chemistry

Last Answer : It shows ionisation isomerism and linkage isomerism.

Description : Which of the following compounds exhibit geometrical isomerism? (a) 1-Pentene (b) 2-Methyl-2-pentene (c) 2-Pentene (d) 2-Methyl-2-butene

Last Answer : 2-Pentene

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Last Answer : (a) K3[Al(C2O4)3] (b) [Co(Cl)2(en)2]+

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Last Answer : a) [Cr(en)3] Cl3 (b) K2[Zn(OH)4]

Description : Using IUPAC norms write the formulae for the following: (i) Sodium dicyanidoaurate (I) (it) Tetraamminechloridonitrito-N-platinum (IV) sulphate -Chemistry

Last Answer : (i) Na[Au(CN)2] (ii) [Pt(NH3)4 Cl(NO2)] (SO4)

Description : Write the IUPAC name of the following coordination compound [NiCl4]2-. -Chemistry

Last Answer : Tetrachloridonickelate (II) ion.

Description : The type of isomerism that `Co(NH_(3))_(4)Br_(2)Cl_(2)` can exhibit is/are

Last Answer : The type of isomerism that `Co(NH_(3))_(4)Br_(2)Cl_(2)` can exhibit is/are A. ... C. Optical and ionisation D. Optical, ionisation and geometric

Description : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is :

Last Answer : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is : A. ... (II) tris(oxalato)chromium(III) D. Hexaamminecobalt(III)trioxalatechromium(III)

Description : The IUPAC name of `K_(2)[Cr(CN)_(2)O_(2)(O)_(2)(NH_(3))]` is :

Last Answer : The IUPAC name of `K_(2)[Cr(CN)_(2)O_(2)(O)_(2)( ... Potassium amminedicyanoperoxooxochromate(VI) D. Potassium amminecyanodiperoxodioxochromate(VI)

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Last Answer : Which isomerism is exhibited by `[Co(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(6) ... )]`? A. Ionization B. Linkage C. Coordination D. Polymerization.

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Last Answer : Butane, Pentane

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Description : Give an example of ionization isomerism. -Chemistry

Last Answer : Example : [Pt (NH3)5 (Br)3] SO4 and [Co (NH3)5 (SO4)] Br

Description : Give an example of coordination isomerism. -Chemistry

Last Answer : Example : [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [CO(CN)6]

Description : Give an example of linkage isomerism. -Chemistry

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Last Answer : (i) [COF4]2_ : Tetrafluorido cobalt (III) ion Coordination number = 4 Shape = Tetrahedral Hybridisation = sp3 Important Questions for Class 12 Chemistry Chapter 9 Coordination Compounds Class 12 Important Questions 7

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Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-

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Last Answer : (3) [Ni (CO)4]

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Description : IUPAC name of complex ion `[CrCl_(2)(ox)_(2)]^(3-)` is

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Description : The IUPAC name of complex `[Cu(en)_(2)(H_(2)O)_(2)]^(22+)`

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Description : IUPAC name of complex `K_(3)[Al(C_(2)O_(4))_(3)]` is

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Description : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) (NH_(3))_(2)] Cl_(3)` is

Last Answer : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) ( ... (III) chloride D. Diamminetetraaquacobalt (III) chloride

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Last Answer : The complex that exhibits Co-ordination isomerism is A. `[Cr(NCS)(H_(2)O)_(5)]^(2+)` B. `[Cr(NH_(3))_(6)] ... ]` D. `[CoCl_(2)(NH_(3))_(4)]Cl.H_(2)O`

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Last Answer : The correct statement on the isomerism associated with the following complex ions , `(a) [Ni(H_( ... a) and (b) show geometrical and optical isomerism

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Last Answer : The pair of coordination complex exhibiting the same kind of isomerism is . A. `[Cr(NH_(3))_(5)Cl]C_(2) and [ ... NO_(3))]Cl and [Pt(NH_(3))_(3)Cl]Br`

Description : Which of the following isomerism is/are shown by the complex `[CoCl_(2)(H_(2)O)_(2)(NH_(3))_(2)]` Br ?

Last Answer : Which of the following isomerism is/are shown by the complex `[CoCl_(2)(H_(2)O)_(2)(NH_(3)) ... ? A. Ionization B. Linkage C. Geometrical D. optical

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