Which of the following statements is false about secondary amines?
(a) They react with chloroform and NaOH to form isocyanides.
(b) They can be prepared by reduction of isocyanides.
(c) They react with acid chlorides to give substituted amides.
(d) They react with ice-cold nitrous acid to give nitrosamine (yellow oil)

1 Answer

Answer :

They react with chloroform and NaOH to form isocyanides.

Related questions

Description : Which of the following statements is false about primary amines? (a) They can be prepared by reduction of nitriles with LiAlH4. (b) They do not form salts with acids (c) They react with ice-cold nitrous acid to form nitrogen gas. (d) They are basic and soluble in water

Last Answer : They do not form salts with acids

Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid

Description : Aliphatic primary amines react with cold nitrous acid to form (a) Alcohols (b) Diazonium salts (c) Nitriles (d) Nitroalkanes

Last Answer : Alcohols

Description : Which of the following does not react with acyl chlorides to form amides : (a) ammonia (b) 1° amine (c) 2° amine (d) 3° amine

Last Answer : 3° amine

Description : Which of the following statements is false about benzylamine? (a) can be prepared by reduction of benzonitrile with LiAlH4. (b) cannot be prepared by reduction of benzamide with LiAlH4. (c) reacts with nitrous acid to give benzyl alcohol. (d) reacts with KMnO4 to give benzoic acid.

Last Answer : cannot be prepared by reduction of benzamide with LiAlH

Description : Alkyl halides react with ammonia in the presence of base to form : (a) primary amines (b) nitrated alkyl halides (c) amides (d) quaternary ammonium salts

Last Answer : primary amines

Description : Which of the following amines react with nitrous acid to form nitrosoamine? (a) Ethylamine (b) Triethylamine (c) Diethylamine (d) Isopropylamine

Last Answer : Diethylamine

Description : The diazonium salts are the reaction products of the reaction of nitrous acid with (a) primary aliphatic amines (b) primary aromatic amines (c) secondary aliphatic amines (d) secondary aromatic amines

Last Answer : primary aromatic amines

Description : Which of the following acid-derivatives are most stable? (a) Acid chlorides (b) Esters (c) Amides (d) Anhydrides

Last Answer : Amides

Description : Esters and amides are most easily made by nucleophilic acyl substitution reactions on : (a) acid anhydrides (b) carboxylates (c) carboxylic acids (d) acid chlorides

Last Answer : acid chlorides

Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form

Last Answer : primary amines form

Description : Which of the following statements is correct about aniline? (a) is weak acid. (b) diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid. (c) can be nitrated with ... p-nitroaniline. (d) gives an intense green color with a suspension of bleaching powder in water

Last Answer : diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid.

Description : When chloroform is heated with aqueous NaOH, it gives (a) Formic acid (b) Sodium formate (c) Acetic acid (d) Sodium acetate

Last Answer : Sodium formate

Description : n-propylamine containing no secondary and tertiary amines as impurities is prepared by

Last Answer : n-propylamine containing no secondary and tertiary amines as impurities is prepared by A. Hoffmann ... n-propylchloride with ammonia D. none of these

Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides

Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides

Description : Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Last Answer : the reduction of nitrobenzene with Sn/HCl

Description : Which is not an anasthetic agent in surgical operations? (1) Chloroform (2) Ether (3) Nitrous oxide (4) Acetone

Last Answer : (4) Acetone Explanation: The currently used inhalational anaesthetic agents are mainly: nitrous oxide, isoflurane, sevoflurane and desflurane. Chloroform, ether, ethylene are other anaesthetic agents. However, they are not widely used in clinical practice today.

Description : The pair of compounds used as anesthetic in medicines – (1) Ether, Ammonia (2) Nitrous oxide, Chloroform (3) Chloroform, Nitrogen dioxide (4) Nitrogen dioxide, ether

Last Answer : (2) Nitrous oxide, Chloroform Explanation: Nitrous oxide is one of the more well-known anesthetic gases, and has been in use for around 200 years. Unlike some other anesthetics, this compound ... than ether. Its use as an anaesthetic decreased with increased experience and knowledge of its dangers.

Description : The pair of compounds used as anaesthetic in medicines : (1) Ether, Ammonia (2) Nitrous oxide, Chloroform (3) Chloroform, Nitrogen dioxide (4) Nitrogen dioxide, ether

Last Answer : Nitrous oxide, Chloroform

Description : Which is not an anasthetic agent in surgical operations? (1) Chloroform (2) Ether (3) Nitrous oxide (4) Acetone

Last Answer : Acetone

Description : Which of the following reactions is suitable for the preparation of α-amino acids? (a) Schmidt reaction (b) Hofmann's degradation of amides (c) Strecker's synthesis (b) Reduction of nitro compounds

Last Answer : Strecker's synthesis

Description : Acid chlorides undergo reduction to the corresponding aldehydes on treatment with hydrogen in the presence of Pd/BaSO4. This reaction is called : (a) Clemmensen reduction (b) Rosenmund reduction (c) Wolf-Kishner reduction (d) None of these

Last Answer : Rosenmund reduction

Description : Which of the following statements is False about acetamide? (a) reacts with Br2/NaOH to form tertiary amine (b) undergoes acid-hydrolysis to form acetic acid (c) undergoes dehydration with P2O5 to form a nitrile (d) is a white crystalline solid, soluble in water

Last Answer : reacts with Br2/NaOH to form tertiary amine

Description : Chlorobenzene can be prepared by treatment of aniline with (a) Cuprous chloride (b) Chlorine in the presence of UV light (c) Nitrous acid followed by treatment with CuCl (d) Chlorine in the presence of FeCl3

Last Answer : Nitrous acid followed by treatment with CuCl

Description : Bromobenzene can be prepared by treating aniline with (a) Conc HBr (b) Br2/FeBr3 (b) CuBr (d) Nitrous acid then CuBr

Last Answer : Nitrous acid then CuBr

Description : State as to why: (a) A solution of Na2CO3 is alkaline? (b)alkali metals are prepared by electrolysis of their fused chlorides ? (c)sodium is found to be more useful than potassium ?

Last Answer : Ans. (a) It undergoes hydrolysis to produce a strong base NaOH . (b) When the aq. Solution of any alkali metal is subjected to electrolysis ,H2 instead of the alkali metal is produced at the ... of sugars and amino acids into the cells. Thus, sodium is found to be more useful than potassium.

Description : Aromatic primary amines are not prepared by gabrial phthalimide synthesis. Why?

Last Answer : Ans:- Because aryl halides donot undergo nucleophilic substitution reaction. 

Description : Which of the following reagents does not react with aniline? (a) Acetyl chloride (b) Acetic anhydride (c) Ammonia (d) Nitrous acid

Last Answer : Ammonia

Description : Amides undergo hydrolysis under acidic conditions to give (a) Carboxylic acid and amine (b) Carboxylic acid and ammonium ion (c) Carboxylate ion and ammonium ion (d) Carboxylate ion and amine

Last Answer : Carboxylic acid and ammonium ion

Description : Which of the following amines will react with cyclohexanone to give enamine?

Last Answer : Which of the following amines will react with cyclohexanone to give enamine? A. `CH_(3)NH_(2)` B. C. D.

Description : Alkaloids are usually purified by extraction with (A) Ether (B) Dil HCl (C) NaOH (D) Chloroform

Last Answer : Answer : B

Description : DDT is prepared by the reaction of chlorobenzene with (in the presence of conc. H2SO4) (a) Chloral (b) Chlorine (c) Chloroform (d) Carbon tetrachloride

Last Answer : Chloral

Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene

Description : Carbylamine test is given by (a) Primary amines (b) Secondary amines (c) Tertiary amines (d) None of these

Last Answer : Primary amines

Description : The compound which on rection with aqueous nirous acid at low temperature produces an oily nitrosamine, is

Last Answer : The compound which on rection with aqueous nirous acid at low temperature produces an oily ... B. methylamine C. dimethylamine D. trimethylamine

Description : A compound undergoes reduction with LiAlH4. It also dissolves in aqueous NaOH from which it can be recovered by addition of HCl. The compound is (a) a carboxylic acid (b) an ester (c) an acid anhydride (d) an alcohol

Last Answer : a carboxylic acid

Description : Which of the following amines cannot be prepared by path-I?

Last Answer : Which of the following amines cannot be prepared by path-I? A. B. C. D.

Description : Which have the maximum density? (1) Water (2) Benzene (3) Ice (4) Chloroform

Last Answer : (1) Water Explanation: Water has its maximum density of 1g/cm3 at 4 degrees Celsius. When the temperature changes from either greater or less than 4 degrees, the density will become less than 1 g/cm3.

Description : Which of the following reagents will react with acetamide to form methylamine? (a) LiAlH4 (b) Br2/NaOH (c) PCl5 (d) H2/Ni

Last Answer : Br2/NaOH

Description : Nitrosamine can deaminate (A) Cytosine to form uracil (B) Adenine to form xanthine (C) Guanine to form hypoxanthine (D) All of these

Last Answer : Answer : A

Description : Acetone undergoes reduction with hydrazine in the presence of NaOH to form propane. This reaction is known as (a) Clemmensen reduction (b) Wolf-Kishner reduction (c) Rosenmund reduction (d) Reformatsky reaction

Last Answer : Wolf-Kishner reduction

Description : Cinnamaldehyde is prepared by the treatment of : (a) benzaldehyde with acetaldehyde in the presence of NaOH (b) benzaldehyde with formaldehyde in the presence of NaOH (c) benzophenone with acetaldehyde in the presence of NaOH (d) benzophenone with formaldehyde in the presence of NaOH

Last Answer : benzaldehyde with acetaldehyde in the presence of NaOH

Description : Iodobenzene can be prepared by (a) treating chlorobenzene with I2 using FeCl3 catalyst. (b) treating phenol with I2 in NaOH solution. (c) treating benzenediazonium chloride with KI (d) treating benzene with CH3I using AlCl3 catalyst

Last Answer : treating benzenediazonium chloride with KI

Description : Which of the following reagents readily react with ethyl methyl ether? (a) NaOH (b) Conc HI (c) KMnO4 (d) H2O

Last Answer : Conc HI

Description : Amino acid synthesis inhibitors a). Sulfonyl ureas b). Amides c). Triazines d). all

Last Answer : a). Sulfonyl ureas

Description : Oil of Wintergreen (Methyl salicylate) is obtained by treating salicylic acid with (a) Methane at 150°C (b) CH3OH and conc. H2SO4 (c) Methyl chloride (d) NaOH and then CH3OH

Last Answer : CH3OH and conc. H2SO4

Description : Mutations can be caused by (A) Nitrosamine (B) Dimethyl sulphate (C) Acridine (D) All of these

Last Answer : Answer : D

Description : For which one of the following is the density maximum? A. Ice B. Water (Answer) C. Benzene D. Chloroform

Last Answer : B. Water (Answer)

Description : Which of the following statements are correct about chloroform? a. Liquid fuel b. Anaesthetic in nature c. Produces phosgene d. Fire extinguisher (1) a, b (2) a, c (3) b, c (4) d, a

Last Answer : b, c

Description : The chlorides of both beryllium and aluminium are Lewis acid Why ?

Last Answer : Ans Incomplete octate.