Alkyl halides react with ammonia in the presence of base to form :
(a) primary amines

(b) nitrated alkyl halides
(c) amides
(d) quaternary ammonium salts

1 Answer

Answer :

primary amines

Related questions

Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form

Last Answer : primary amines form

Description : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is

Last Answer : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in ... reaction D. Reaction with `NH_(3)`

Description : Which of the following statements is false about secondary amines? (a) They react with chloroform and NaOH to form isocyanides. (b) They can be prepared by reduction of isocyanides. (c) They react ... give substituted amides. (d) They react with ice-cold nitrous acid to give nitrosamine (yellow oil)

Last Answer : They react with chloroform and NaOH to form isocyanides.

Description : Why the presence of a base is essential in the ammonolysis of alkyl halides ?

Last Answer : During ammonolysis of alkyl halides, the acid liberated during the reaction combines with the amine formed to form amine salt. To liberate free amine from the amine salt, a base is needed.

Description : Aliphatic primary amines react with cold nitrous acid to form (a) Alcohols (b) Diazonium salts (c) Nitriles (d) Nitroalkanes

Last Answer : Alcohols

Description : Which of the following statements is false about primary amines? (a) They can be prepared by reduction of nitriles with LiAlH4. (b) They do not form salts with acids (c) They react with ice-cold nitrous acid to form nitrogen gas. (d) They are basic and soluble in water

Last Answer : They do not form salts with acids

Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides

Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides

Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F

Last Answer : CH3CH2I

Description : Which of the following does not react with acyl chlorides to form amides : (a) ammonia (b) 1° amine (c) 2° amine (d) 3° amine

Last Answer : 3° amine

Description : The diazonium salts are the reaction products of the reaction of nitrous acid with (a) primary aliphatic amines (b) primary aromatic amines (c) secondary aliphatic amines (d) secondary aromatic amines

Last Answer : primary aromatic amines

Description : Give reasons:--- a. Primary amines are more basic than ammonia. b . Sec. amines are more basic than pr.amines.

Last Answer : Ans— a. In pr. Amines, alkyl group increases electron density on the N-atom making it more basic than ammo b. In sec. amine, there are two alkyl groups increase electron density on N-atom more than N-atom in pr. amines in which there is one alkyl group. 

Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism

Last Answer : Resonance stabilization

Description : Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides

Last Answer : Alkoxyalkanes

Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)

Last Answer : (a) and (b)

Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Last Answer : Nucleophilic substitution reactions

Description : Amides undergo hydrolysis under acidic conditions to give (a) Carboxylic acid and amine (b) Carboxylic acid and ammonium ion (c) Carboxylate ion and ammonium ion (d) Carboxylate ion and amine

Last Answer : Carboxylic acid and ammonium ion

Description : Ammonia is excreted as ammonium salts during metabolic acidosis but the majority is excreted as (A) Phosphates (B) Creatine (C) Uric acid (D) Urea

Last Answer : Answer : D

Description : The unwanted amino acids abstracted from the tissues are either used up by the tissue or in the liver converted into (A) Ammonia (B) Urea (C) Ammonium salts (D) Uric acid

Last Answer : Answer : B

Description : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is :

Last Answer : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is : A. RF > RCl > RBr > ... RBr > RF > RI D. RI > RBr > RCl > RF

Description : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism?

Last Answer : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism? A. `CH_(3)Cl` B. `CH_(3)CH_(2)Cl` ... (2)CH_(2)Cl` D. `(CH_(3))_(3)"CCl"`

Description : Which of the alkyl chlorides listed below undergoes dehydrohalogenation in the presence of a strong base to give 2-pentene as the only alkene product? (a) 1-chloropentane (b) 2-chloropentane (c) 3-chloropentane (d) 1-chloro-2-methylbutane

Last Answer : 3-chloropentane

Description : Which of the alkyl chlorides listed below undergoes dehydrohalogenation in the presence of a strong base to give 2-pentene as the only alkene product? (a) 1-chloropentane (b) 2-chloropentane (c) 3-chloropentane (d) 1-chloro-2-methylbutane

Last Answer : 3-chloropentane

Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene

Description : 2-Methyl-2-butene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide

Last Answer : A secondary alkyl bromide

Description : 2-Methylpropene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide

Last Answer : A primary alkyl bromide

Description : Assuming roughly equivalent molecular weights, which of the following would have the highest boiling point? (a) a tertiary amine (b) a quaternary ammonium salt (c) an alcohol (d) an ether

Last Answer : a quaternary ammonium salt

Description : Fermentation is adversely affected by the (A) Presence of air (B) Absence of air (C) High concentration (D) Presence of ammonium salts

Last Answer : (C) High concentration

Description : Which of the following amines react with nitrous acid to form nitrosoamine? (a) Ethylamine (b) Triethylamine (c) Diethylamine (d) Isopropylamine

Last Answer : Diethylamine

Description : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. Pseudo halogens can acts as ligands

Last Answer : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. ... and C black D. `Na(CN)_2^-`

Description : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. Pseudo halogens can acts as ligands

Last Answer : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. ... NaBr C. (C) NaF D. (D) Nal

Description : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. Pseudo halogens can acts as ligands

Last Answer : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. ... . H_2O` D. (D) None of these

Description : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. Pseudo halogens can acts as ligands

Last Answer : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides ... . `NaCN, NaOCN` D. `HCOONa, NH_3`

Description : What is a quaternary ammonium compound or quaternary ammonium cleaner?

Last Answer : Quaternary ammonium cleaner is the last generation of quaternary ammonium compounds, it is a one-step cleaner which is used against the broad spectrum of bacteria fungus virus etc..

Description : The most potent viricidal properties: (another format of the same question: ‘Indicate which of the following has viricidal properties’) A. Sodium hypochlorite B. Chlorhexidine C. Glutaraldehyde D. Alcohol 70% E. Quaternary ammonium

Last Answer : A. Sodium hypochlorite

Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid

Description : Acetamide is a much weaker base than ammonia. This is because (a) the electron withdrawing effect of the C=O group makes the lone pair of electrons on nitrogen atom less available for protonation. (b) ) ... NH2 group. (d) an H atom from the nitrogen is less easily lost from CH3CONH2 than from NH3.

Last Answer : the electron withdrawing effect of the C=O group makes the lone pair of electrons on nitrogen atom less available for protonation

Description : Which of the following amines will react with cyclohexanone to give enamine?

Last Answer : Which of the following amines will react with cyclohexanone to give enamine? A. `CH_(3)NH_(2)` B. C. D.

Description : Which of the following hydrogen halides react with `AgNO_3` to give a precipitate that dissolves in hypo solution ? (I)HCl (II)HF (III)HI (IV)HBr

Last Answer : Which of the following hydrogen halides react with `AgNO_3` to give a precipitate that dissolves in hypo solution ? (I) ... II),(I) D. (II),(IV),(III)

Description : Aromatic primary amines are not prepared by gabrial phthalimide synthesis. Why?

Last Answer : Ans:- Because aryl halides donot undergo nucleophilic substitution reaction. 

Description : The linear arrangement of amino acid units in proteins is called : (a) primary structure (b) secondary structure (c) tertiary structure (d) quaternary structure

Last Answer : primary structure

Description : Which of the following protein structures does “denaturation” destroy? (a) primary and secondary structures (b) secondary and tertiary structures (c) tertiary and quaternary structures (d) secondary, tertiary, and quaternary structures

Last Answer : secondary, tertiary, and quaternary structures

Description : Carbylamine test is given by (a) Primary amines (b) Secondary amines (c) Tertiary amines (d) None of these

Last Answer : Primary amines

Description : Which type of amine produces N2 when treated with HONO? (a) Primary (b) Secondary (c) Tertiary (d) Quaternary

Last Answer : Primary

Description : Which of the following statements is correct about aniline? (a) is weak acid. (b) diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid. (c) can be nitrated with ... p-nitroaniline. (d) gives an intense green color with a suspension of bleaching powder in water

Last Answer : diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid.

Description : Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Last Answer : can be oxidized with KMnO4 to give benzoic acid

Description : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Last Answer : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii ... (vi) `PCl_(3)` (vii) `AsCl_(3)`

Description : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Last Answer : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii ... (vi) `PCl_(3)` (vii) `AsCl_(3)`

Description : (3) Conversion of ammonia to nitrites Explanation: Nitrification is the biological oxidation of ammonia or ammonium to nitrite followed by the oxidation of the nitrite to nitrate. The oxidation of ammonia ... -oxidizing archaea (AOA). Nitrification is an important step in the nitrogen cycle in soil.

Last Answer : Acid rain is caused due to pollution of atmosphere by – (1) oxides of carbon and nitrogen (2) oxides of nitrogen and sulphur (3) oxides of nitrogen and phosphorous (4) None of these

Description : Which of the following is the main nitrogenous waste in humans ? (1) Ammonia (2) Urea (3) Uric Acid (4) Ammonium Nitrate

Last Answer : Uric Acid

Description : How should CH3CHClCH2CH3 be classified? (a) primary alkyl halide (b) secondary alkyl halide (c) tertiary alkyl halide (d) quarternary alkyl halide

Last Answer : secondary alkyl halide