Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form
Last Answer : primary amines form
Description : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is
Last Answer : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in ... reaction D. Reaction with `NH_(3)`
Description : Which of the following statements is false about secondary amines? (a) They react with chloroform and NaOH to form isocyanides. (b) They can be prepared by reduction of isocyanides. (c) They react ... give substituted amides. (d) They react with ice-cold nitrous acid to give nitrosamine (yellow oil)
Last Answer : They react with chloroform and NaOH to form isocyanides.
Description : Why the presence of a base is essential in the ammonolysis of alkyl halides ?
Last Answer : During ammonolysis of alkyl halides, the acid liberated during the reaction combines with the amine formed to form amine salt. To liberate free amine from the amine salt, a base is needed.
Description : Aliphatic primary amines react with cold nitrous acid to form (a) Alcohols (b) Diazonium salts (c) Nitriles (d) Nitroalkanes
Last Answer : Alcohols
Description : Which of the following statements is false about primary amines? (a) They can be prepared by reduction of nitriles with LiAlH4. (b) They do not form salts with acids (c) They react with ice-cold nitrous acid to form nitrogen gas. (d) They are basic and soluble in water
Last Answer : They do not form salts with acids
Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides
Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides
Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F
Last Answer : CH3CH2I
Description : Which of the following does not react with acyl chlorides to form amides : (a) ammonia (b) 1° amine (c) 2° amine (d) 3° amine
Last Answer : 3° amine
Description : The diazonium salts are the reaction products of the reaction of nitrous acid with (a) primary aliphatic amines (b) primary aromatic amines (c) secondary aliphatic amines (d) secondary aromatic amines
Last Answer : primary aromatic amines
Description : Give reasons:--- a. Primary amines are more basic than ammonia. b . Sec. amines are more basic than pr.amines.
Last Answer : Ans— a. In pr. Amines, alkyl group increases electron density on the N-atom making it more basic than ammo b. In sec. amine, there are two alkyl groups increase electron density on N-atom more than N-atom in pr. amines in which there is one alkyl group.
Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism
Last Answer : Resonance stabilization
Description : Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides
Last Answer : Alkoxyalkanes
Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)
Last Answer : (a) and (b)
Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions
Last Answer : Nucleophilic substitution reactions
Description : Amides undergo hydrolysis under acidic conditions to give (a) Carboxylic acid and amine (b) Carboxylic acid and ammonium ion (c) Carboxylate ion and ammonium ion (d) Carboxylate ion and amine
Last Answer : Carboxylic acid and ammonium ion
Description : Ammonia is excreted as ammonium salts during metabolic acidosis but the majority is excreted as (A) Phosphates (B) Creatine (C) Uric acid (D) Urea
Last Answer : Answer : D
Description : The unwanted amino acids abstracted from the tissues are either used up by the tissue or in the liver converted into (A) Ammonia (B) Urea (C) Ammonium salts (D) Uric acid
Last Answer : Answer : B
Description : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is :
Last Answer : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is : A. RF > RCl > RBr > ... RBr > RF > RI D. RI > RBr > RCl > RF
Description : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism?
Last Answer : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism? A. `CH_(3)Cl` B. `CH_(3)CH_(2)Cl` ... (2)CH_(2)Cl` D. `(CH_(3))_(3)"CCl"`
Description : Which of the alkyl chlorides listed below undergoes dehydrohalogenation in the presence of a strong base to give 2-pentene as the only alkene product? (a) 1-chloropentane (b) 2-chloropentane (c) 3-chloropentane (d) 1-chloro-2-methylbutane
Last Answer : 3-chloropentane
Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.
Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene
Description : 2-Methyl-2-butene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide
Last Answer : A secondary alkyl bromide
Description : 2-Methylpropene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide
Last Answer : A primary alkyl bromide
Description : Assuming roughly equivalent molecular weights, which of the following would have the highest boiling point? (a) a tertiary amine (b) a quaternary ammonium salt (c) an alcohol (d) an ether
Last Answer : a quaternary ammonium salt
Description : Fermentation is adversely affected by the (A) Presence of air (B) Absence of air (C) High concentration (D) Presence of ammonium salts
Last Answer : (C) High concentration
Description : Which of the following amines react with nitrous acid to form nitrosoamine? (a) Ethylamine (b) Triethylamine (c) Diethylamine (d) Isopropylamine
Last Answer : Diethylamine
Description : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. Pseudo halogens can acts as ligands
Last Answer : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. ... and C black D. `Na(CN)_2^-`
Last Answer : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. ... NaBr C. (C) NaF D. (D) Nal
Last Answer : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides. ... . H_2O` D. (D) None of these
Last Answer : Pseudo halides are anions having resemblance with halide ions. Group I metals can form salts with pseudo halides ... . `NaCN, NaOCN` D. `HCOONa, NH_3`
Description : What is a quaternary ammonium compound or quaternary ammonium cleaner?
Last Answer : Quaternary ammonium cleaner is the last generation of quaternary ammonium compounds, it is a one-step cleaner which is used against the broad spectrum of bacteria fungus virus etc..
Description : The most potent viricidal properties: (another format of the same question: ‘Indicate which of the following has viricidal properties’) A. Sodium hypochlorite B. Chlorhexidine C. Glutaraldehyde D. Alcohol 70% E. Quaternary ammonium
Last Answer : A. Sodium hypochlorite
Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl
Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid
Description : Acetamide is a much weaker base than ammonia. This is because (a) the electron withdrawing effect of the C=O group makes the lone pair of electrons on nitrogen atom less available for protonation. (b) ) ... NH2 group. (d) an H atom from the nitrogen is less easily lost from CH3CONH2 than from NH3.
Last Answer : the electron withdrawing effect of the C=O group makes the lone pair of electrons on nitrogen atom less available for protonation
Description : Which of the following amines will react with cyclohexanone to give enamine?
Last Answer : Which of the following amines will react with cyclohexanone to give enamine? A. `CH_(3)NH_(2)` B. C. D.
Description : Which of the following hydrogen halides react with `AgNO_3` to give a precipitate that dissolves in hypo solution ? (I)HCl (II)HF (III)HI (IV)HBr
Last Answer : Which of the following hydrogen halides react with `AgNO_3` to give a precipitate that dissolves in hypo solution ? (I) ... II),(I) D. (II),(IV),(III)
Description : Aromatic primary amines are not prepared by gabrial phthalimide synthesis. Why?
Last Answer : Ans:- Because aryl halides donot undergo nucleophilic substitution reaction.
Description : The linear arrangement of amino acid units in proteins is called : (a) primary structure (b) secondary structure (c) tertiary structure (d) quaternary structure
Last Answer : primary structure
Description : Which of the following protein structures does “denaturation” destroy? (a) primary and secondary structures (b) secondary and tertiary structures (c) tertiary and quaternary structures (d) secondary, tertiary, and quaternary structures
Last Answer : secondary, tertiary, and quaternary structures
Description : Carbylamine test is given by (a) Primary amines (b) Secondary amines (c) Tertiary amines (d) None of these
Last Answer : Primary amines
Description : Which type of amine produces N2 when treated with HONO? (a) Primary (b) Secondary (c) Tertiary (d) Quaternary
Last Answer : Primary
Description : Which of the following statements is correct about aniline? (a) is weak acid. (b) diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid. (c) can be nitrated with ... p-nitroaniline. (d) gives an intense green color with a suspension of bleaching powder in water
Last Answer : diazotizes to benzenediazonium chloride when treated with ice-cold nitrous acid.
Description : Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.
Last Answer : can be oxidized with KMnO4 to give benzoic acid
Description : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC
Last Answer : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii ... (vi) `PCl_(3)` (vii) `AsCl_(3)`
Description : (3) Conversion of ammonia to nitrites Explanation: Nitrification is the biological oxidation of ammonia or ammonium to nitrite followed by the oxidation of the nitrite to nitrate. The oxidation of ammonia ... -oxidizing archaea (AOA). Nitrification is an important step in the nitrogen cycle in soil.
Last Answer : Acid rain is caused due to pollution of atmosphere by – (1) oxides of carbon and nitrogen (2) oxides of nitrogen and sulphur (3) oxides of nitrogen and phosphorous (4) None of these
Description : Which of the following is the main nitrogenous waste in humans ? (1) Ammonia (2) Urea (3) Uric Acid (4) Ammonium Nitrate
Last Answer : Uric Acid
Description : How should CH3CHClCH2CH3 be classified? (a) primary alkyl halide (b) secondary alkyl halide (c) tertiary alkyl halide (d) quarternary alkyl halide
Last Answer : secondary alkyl halide