Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the reaction is practically irreversible in nature (C) The intercept of the Arrhenius plot is called the 'activation energy' (D) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Pick out the wrong statement.
(A) A particular chemical reaction is more temperature sensitive at low
temperatures
(B) A very high value of equilibrium constant, K (K >> 1) indicates that the
reaction is practically irreversible in nature
(C) The intercept of the Arrhenius plot is called the 'activation energy'
(D) Non-ideal flow takes place in reactors due to recycling, channeling or by
creation of stagnant regions
by

1 Answer

Answer :

(C) The intercept of the Arrhenius plot is called the 'activation energy
by

Related questions

Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to iron catalyst in ammonia synthesis reaction (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot

Pick out the wrong statement: (A) Chemical reactions with high activation energy are very temperature sensitive (B) A flat velocity profile exists in a plug flow reactor (C) The residence time for all the elements of fluid in case of a P.F.R. need not be same (D) Half life of a reaction increases with increased initial concentration for reaction orders more than one

Description : Pick out the wrong statement: (A) Chemical reactions with high activation energy are very temperature sensitive (B) A flat velocity profile exists in a plug flow reactor (C) The residence ... D) Half life of a reaction increases with increased initial concentration for reaction orders more than one

Last Answer : (C) The residence time for all the elements of fluid in case of a P.F.R. need not be same

Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by light (D) A chemical reaction occurs when the energy of the reacting molecule is less than the activation energy of the reaction

Description : Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by ... occurs when the energy of the reacting molecule is less than the activation energy of the reaction

Last Answer : (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state

Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For a second order reaction, the slope of the graph/plot between rate and (concentration) is equal to the rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero

Description : Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For ... rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero

Last Answer : (B) The order and molecularity of a complex reaction may not be the same

Pick out the wrong statement. (A) The vessel dispersion number (D/UL) for plug flow and mixed flow approaches zero and infinity respectively (B) Space time in a flow reactor is a measure of its capacity and is equal to the residence time when the density of reaction mixture is constant (C) Mixed reactor is always smaller than the plug flow reactor for all positive reaction orders for a particular duty (D) In an ideal tubular flow reactor, mixing takes place in radial direction and there is no mixing in longitudinal direction

Description : Pick out the wrong statement. (A) The vessel dispersion number (D/UL) for plug flow and mixed flow approaches zero and infinity respectively (B) Space time in a flow reactor is a ... ideal tubular flow reactor, mixing takes place in radial direction and there is no mixing in longitudinal direction

Last Answer : (C) Mixed reactor is always smaller than the plug flow reactor for all positive reaction orders for a particular duty

The minimum energy required to allow a chemical reaction to proceed is termed as the 'threshold energy '. Chemical reactions with low activation energy are: (A) Always irreversible (B) Insensitive to temperature changes (C) Mostly irreversible (D) Highly temperature sensitive

Description : The minimum energy required to allow a chemical reaction to proceed is termed as the 'threshold energy '. Chemical reactions with low activation energy are: (A) Always irreversible (B) Insensitive to temperature changes (C) Mostly irreversible (D) Highly temperature sensitive

Last Answer : (B) Insensitive to temperature changes

Pick out the wrong statement. (A) Catalytic activity of enzyme catalysed reactions which is affected by temperature, pH value & chemical agents, is maximum at a temperature of about 45°C(B) Most of the enzyme catalysed reactions involve at least two substrates (C) Enzymes help in increasing the activation energy of the reaction (D) Equilibrium concentrations in enzyme catalysed reactions can be calculated by using the thermodynamic properties of substrates & prod

Description : Pick out the wrong statement. (A) Catalytic activity of enzyme catalysed reactions which is affected by temperature, pH value & chemical agents, is maximum at a temperature of about 45°C ... in enzyme catalysed reactions can be calculated by using the thermodynamic properties of substrates & prod

Last Answer : (C) Enzymes help in increasing the activation energy of the reaction

Reactions with high activation energy are (A) Very temperature sensitive (B) Temperature insensitive (C) Always irreversible (D) Always reversible

Description : Reactions with high activation energy are (A) Very temperature sensitive (B) Temperature insensitive (C) Always irreversible (D) Always reversible

Last Answer : (A) Very temperature sensitive

Pick out the wrong statement. (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity(B) For an ideal mixed reactor at steady state, the exit stream has the samecomposition as fluid within the reactor and the space time is equivalent toholding time for constant density system(C) Plug flow reactor (PFR) is always smaller than mixed reactor for allpositive reaction orders for a particular duty(D) Reaction rate does not decrease appreciably as the reaction proceeds incase of an autocatalytic reaction

Description : Pick out the wrong statement. (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity(B) For an ideal ... D) Reaction rate does not decrease appreciably as the reaction proceeds in case of an autocatalytic reaction

Last Answer : (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity

. A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two reactors. (A) Both conversion as well as concentration are same (B) Conversion in both will be the same but concentrations will be different (C) Both the conversion as well as concentrations will be different (D) None of these

Description : . A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two ... be different (C) Both the conversion as well as concentrations will be different (D) None of these

Last Answer : (B) Conversion in both will be the same but concentrations will be different

Arrhenius equation represents graphically the variation between the __________ and temperature. (A) Rate of reaction (B) Frequency factor (C) Rate constant (D) Activation energy

Description : Arrhenius equation represents graphically the variation between the __________ and temperature. (A) Rate of reaction (B) Frequency factor (C) Rate constant (D) Activation energy

Last Answer : (C) Rate constant

Arrhenius equation shows the variation of __________ with temperature. (A) Reaction rate (B) Rate constant (C) Energy of activation (D) Frequency factor

Description : Arrhenius equation shows the variation of __________ with temperature. (A) Reaction rate (B) Rate constant (C) Energy of activation (D) Frequency factor

Last Answer : (B) Rate constant

Pick out the wrong statement. (A) In a multistep reaction, the slowest step is the rate determining step (B) In general, the rate of a reaction becomes triple for every 10°C rise in temperature (C) Slow chemical reactions have generally high values of activation energy (D) Molecularity of a reaction cannot be zero but the order of a reaction can be zero

Description : Pick out the wrong statement. (A) In a multistep reaction, the slowest step is the rate determining step (B) In general, the rate of a reaction becomes triple for every 10°C rise in temperature (C ... energy (D) Molecularity of a reaction cannot be zero but the order of a reaction can be zero

Last Answer : (B) In general, the rate of a reaction becomes triple for every 10°C rise in temperature

Pick out the wrong statement. (A) 'Hold back' is defined as the fraction of material that stays longer than the mean residence time (B) Study of non-ideal flow reactor is done experimentally by stimulus￾response technique (C) For studying a chemical reaction, it is desirable to monitor the reactants during initial stages and the products during the final stages of reaction (D) A batch reactor cannot be used to study the kinetics of catalytic reaction

Description : Pick out the wrong statement. (A) 'Hold back' is defined as the fraction of material that stays longer than the mean residence time (B) Study of non-ideal flow reactor is done experimentally ... final stages of reaction (D) A batch reactor cannot be used to study the kinetics of catalytic reaction

Last Answer : (D) A batch reactor cannot be used to study the kinetics of catalytic reaction

At a given value of E/R (ratio of activation energy and gas constant), the ratio of the rate constants at 500°K and 400°K is 2, if Arrhenius law is used. What will be this ratio, if transition state theory is used with the same value of ‘E/R’? (A) 1.6 (B) 2 (C) 2.24 (D) 2.5

Description : At a given value of E/R (ratio of activation energy and gas constant), the ratio of the rate constants at 500°K and 400°K is 2, if Arrhenius law is used. What will be this ratio, if transition state theory is used with the same value of ‘E/R’? (A) 1.6 (B) 2 (C) 2.24 (D) 2.5

Last Answer : (D) 2.5

Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an endothermic reaction (C) The rate constant for a first order reaction does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

Description : Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an ... does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

Last Answer : (C) The rate constant for a first order reaction does not change on changing the concentration units

Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium solubility curve in case of a single component stripper (C) The operating pressure in solvent extraction system should be below vapor pressures of all components (D) The solubility of a particular gas in ideal solution in any solvent is always the same

Description : Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium ... (D) The solubility of a particular gas in ideal solution in any solvent is always the same

Last Answer : (C) The operating pressure in solvent extraction system should be below vapor pressures of all components

The rate expression for a heterogeneous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + KR.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A) (A) E (B) E + ΔHA (C) E + ΔHA - ΔHR ) (D) ΔHA + ΔHR

Description : The rate expression for a heterogeneous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + KR.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR ... R and A) (A) E (B) E + ΔHA (C) E + ΔHA - ΔHR ) (D) ΔHA + ΔHR

Last Answer : (C) E + ΔHA - ΔHR )

Pick out the wrong statement. (A) In a first order reaction, A → products; the reaction becomes slower as it proceeds, because the concentration of A decreases and the rate is proportional to the concentration of A (B) Transition state theory approaches the problem of calculating reaction rates by concentrating on the idea of activated complexes (C) According to the penetration theory, the mass transfer co-efficient decreases, if the exposure time of an eddy to the solute decreases (D) If the rate of an irreversible reaction, A + B → 2C is k.CA .CB , then the reaction is always elementary

Description : Pick out the wrong statement. (A) In a first order reaction, A → products; the reaction becomes slower as it proceeds, because the concentration of A decreases and the rate is proportional to the concentration ... irreversible reaction, A + B → 2C is k.CA .CB , then the reaction is always elementary

Last Answer : (C) According to the penetration theory, the mass transfer co-efficient decreases, if the exposure time of an eddy to the solute decreases

The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction

Description : The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction

Last Answer : (B) Activation energy

Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these

Description : Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these

Last Answer : (A) Activation energy

The catalyst in a first order chemical reaction changes the (A) Equilibrium constant(B) Activation energy(C) Heat of formation of the product(D) Heat of reaction

Description : The catalyst in a first order chemical reaction changes the (A) Equilibrium constant (B) Activation energy (C) Heat of formation of the product (D) Heat of reaction

Last Answer : (B) Activation energy

The unit of frequency factor in Arrhenius equation is (A) Same as that of rate constant (B) Same as that of activation energy (C) Dimensionless (D) None of these

Description : The unit of frequency factor in Arrhenius equation is (A) Same as that of rate constant (B) Same as that of activation energy (C) Dimensionless (D) None of these

Last Answer : (A) Same as that of rate constant

Pick out the correct statement. (A) The available energy in an isolated system for all irreversible (real) processes decreases (B) The efficiency of a Carnot engine increases, if the sink temperature is decreased (C) The reversible work for compression in non-flow process under isothermal condition is the change in Helmholtz free energy (D) All (A), (B) and (C)

Description : Pick out the correct statement. (A) The available energy in an isolated system for all irreversible (real) processes decreases (B) The efficiency of a Carnot engine increases, if the sink temperature is decreased ... condition is the change in Helmholtz free energy (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Pick out the correct statement. (A) A catalyst does not change AH of the reaction (B) A catalyst changes the equilibrium point (C) Law of mass action was suggested by Le-Chatelier (D) The difference between the energy of reactants and that of the products is the activation energy

Description : Pick out the correct statement. (A) A catalyst does not change AH of the reaction (B) A catalyst changes the equilibrium point (C) Law of mass action was suggested by Le-Chatelier (D) The difference between the energy of reactants and that of the products is the activation energy

Last Answer : (A) A catalyst does not change AH of the reaction

Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly efficient catalyst for one or more chemical reactions in a living system. C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.

Description : Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly ... increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.

Last Answer : C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy.

Pick out the wrong statement. (A) Exit age description function (E) and internal age distribution function (I) are related as, E = -(dI/dθ) (B) Chemisorption studies are useful in the determination of catalyst surface area and pore size distribution (C) A higher temperature favours the reaction of higher activation energy (D) A catalyst increases the potential energy barrier over which the reactants must pass to form products

Description : Pick out the wrong statement. (A) Exit age description function (E) and internal age distribution function (I) are related as, E = -(dI/dθ) (B) Chemisorption studies are useful in the ... energy (D) A catalyst increases the potential energy barrier over which the reactants must pass to form products

Last Answer : (D) A catalyst increases the potential energy barrier over which the reactants must pass to form products

According to Arrhenius equation of temperature dependency of rate constant for an elementary reaction (A) k ∝ √T (B) k ∝ e -E/RT (C) k ∝ T e -E/RT (D) None of these

Description : According to Arrhenius equation of temperature dependency of rate constant for an elementary reaction (A) k ∝ √T (B) k ∝ e -E/RT (C) k ∝ T e -E/RT (D) None of these

Last Answer : (B) k ∝ e -E/RT

Pick out the wrong statement. (A) The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction (B) With increase in temperature, the equilibrium constant increases for an exothermic reaction (C) The equilibrium constant of a reaction depends upon temperature only (D) The conversion for a gas phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction

Description : Pick out the wrong statement. (A) The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction (B) With ... phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction

Last Answer : (B) With increase in temperature, the equilibrium constant increases for an exothermic reaction

Pick out the wrong statement: (A) The expansion of a gas in vacuum is an irreversible process (B) An isometric process is a constant pressure process (C) Entropy change for a reversible adiabatic process is zero (D) Free energy change for a spontaneous process is negative

Description : Pick out the wrong statement: (A) The expansion of a gas in vacuum is an irreversible process (B) An isometric process is a constant pressure process (C) Entropy change for a reversible adiabatic process is zero (D) Free energy change for a spontaneous process is negative

Last Answer : (B) An isometric process is a constant pressure process

Higher free energy of activation of a chemical reaction (at a given temperature) implies (A) Slower rate of reaction (B) Higher rate of reaction (C) Higher equilibrium conversion (D) Both (B) and (C)

Description : Higher free energy of activation of a chemical reaction (at a given temperature) implies (A) Slower rate of reaction (B) Higher rate of reaction (C) Higher equilibrium conversion (D) Both (B) and (C)

Last Answer : (A) Slower rate of reaction

Pick out the wrong statement. (A) Momentum transfer in laminar flow results from velocity gradient (B) A fluid in equilibrium is not free from shear stress (C) The viscosity of a non-Newtonian fluid is a function of temperature only (D) Both (B) and (C)

Description : Pick out the wrong statement. (A) Momentum transfer in laminar flow results from velocity gradient (B) A fluid in equilibrium is not free from shear stress (C) The viscosity of a non-Newtonian fluid is a function of temperature only (D) Both (B) and (C)

Last Answer : (D) Both (B) and (C)

Which of the following conditions indicates a short circuited capacitor when checking its condition with an ohmmeter? A. The capacitor shows charging, but the final resistance reading is appreciably less than normal. B. The reading is practically zero and remains there. C. The capacitor shows no charging action, but indicates a very high resistance. D. The pointer moves quickly to the low resistance side of the scale, then slowly recedes toward infinity.

Description : Which of the following conditions indicates a short circuited capacitor when checking its condition with an ohmmeter? A. The capacitor shows charging, but the final resistance reading is appreciably less ... moves quickly to the low resistance side of the scale, then slowly recedes toward infinity.

Last Answer : Answer: B

From Arrhenius law, a plot of loge K versus 1/T gives a straight line with a slope of (-E/R). The unit of E/R is (A) k cal (B) k cal/°K (C) °K (D) k cal. °K

Description : From Arrhenius law, a plot of loge K versus 1/T gives a straight line with a slope of (-E/R). The unit of E/R is (A) k cal (B) k cal/°K (C) °K (D) k cal. °K

Last Answer : (C) °K

The energy of activation of a chemical reaction: (A) Is same as heat of reaction at constant pressure (B) Is the minimum energy which the molecules must have before the reaction can take place (C) Varies as fifth power of the temperature (D) Both (B) and (C)

Description : The energy of activation of a chemical reaction: (A) Is same as heat of reaction at constant pressure (B) Is the minimum energy which the molecules must have before the reaction can take place (C) Varies as fifth power of the temperature (D) Both (B) and (C)

Last Answer : (B) Is the minimum energy which the molecules must have before the reaction can take place

The equilibrium constant for a chemical reaction at two different temperatures is given by (A) Kp2/Kp1 = - (∆H/R) (1/T2- 1/T1) (B) Kp2/Kp1 = (∆H/R) (1/T2- 1/T1) (C) Kp2/Kp1 = ∆H (1/T2- 1/T1) (D) Kp2/Kp1 = - (1/R) (1/T2- 1/T1)

Description : The equilibrium constant for a chemical reaction at two different temperatures is given by (A) Kp2/Kp1 = - (∆H/R) (1/T2- 1/T1) (B) Kp2/Kp1 = (∆H/R) (1/T2- 1/T1) (C) Kp2/Kp1 = ∆H (1/T2- 1/T1) (D) Kp2/Kp1 = - (1/R) (1/T2- 1/T1)

Last Answer : (A) Kp2/Kp1 = - (∆H/R) (1/T2- 1/T1)

Pick out the wrong statemen(A) Autocatalytic reactions are exemplified by microbial fermentation reactions (B) The slowest step has the greatest influence on the overall reaction rate in case of an irreversible series reaction (C) The fractional conversion at any time is same for both the constant as well as the variable volume system in case of an irreversible unimolecular type first order reaction (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction

Description : Pick out the wrong statemen (A) Autocatalytic reactions are exemplified by microbial fermentation reactions (B) The slowest step has the greatest influence on the overall reaction rate in case of an ... reaction (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction

Last Answer : (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction

Pick out the wrong statement. (A) A slight haze at the top of chimney indicates good combustion in the furnace (B) A bag filter incurs very small pressure drop and is very efficient for removal of submicronic dust particles from flue gases at very high temperature (C) Electrostatic precipitator is the most efficient dust collection equipment for removal of submicronic dust particles present in flue gas (D) None of these

Description : Pick out the wrong statement. (A) A slight haze at the top of chimney indicates good combustion in the furnace (B) A bag filter incurs very small pressure drop and is very efficient for ... dust collection equipment for removal of submicronic dust particles present in flue gas (D) None of these

Last Answer : (B) A bag filter incurs very small pressure drop and is very efficient for removal of submicronic dust particles from flue gases at very high temperature

he quantitative effect of temperature on chemical equilibrium is given by the (A) Van’t-Hoff equation (B) Le-Chatelier's principle (C) Arrhenius equation (D) None of these

Description : he quantitative effect of temperature on chemical equilibrium is given by the (A) Van’t-Hoff equation (B) Le-Chatelier's principle (C) Arrhenius equation (D) None of these

Last Answer : (A) Van’t-Hoff equation

Pick out the wrong statement pertaining to space velocity of flow reactors. (A) The unit of space velocity is (time) -1 (B) The space velocity of 3 hr -1 means that three reactor volumes of feed at specified conditions are being fed into the reactor every hour (C) The space velocity of 3 hr -1 means that one third reactor volume of feed at specified conditions are being fed into the reactor (D) None of these

Description : Pick out the wrong statement pertaining to space velocity of flow reactors. (A) The unit of space velocity is (time) -1 (B) The space velocity of 3 hr -1 means that three reactor volumes of ... one third reactor volume of feed at specified conditions are being fed into the reactor (D) None of these

Last Answer : (C) The space velocity of 3 hr -1 means that one third reactor volume of feed at specified conditions are being fed into the reactor

Pick out the wrong statement. (A) Enthalpies of all elements in their standard states are assumed to be zero (B) Combustion reactions are never endothermic in nature (C) Heat of reaction at constant volume is equal to the change in internal energy (D) Clausius-Clapeyron equation is not applicable to melting process

Description : Pick out the wrong statement. (A) Enthalpies of all elements in their standard states are assumed to be zero (B) Combustion reactions are never endothermic in nature (C) Heat of reaction ... to the change in internal energy (D) Clausius-Clapeyron equation is not applicable to melting process

Last Answer : (D) Clausius-Clapeyron equation is not applicable to melting process

Pick out the wrong statement. (A) The net change in entropy in any reversible cycle is always zero (B) The entropy of the system as a whole in an irreversible process increases (C) The entropy of the universe tends to a maximum (D) The entropy of a substance does not remain constant during a reversible adiabatic change

Description : Pick out the wrong statement. (A) The net change in entropy in any reversible cycle is always zero (B) The entropy of the system as a whole in an irreversible process increases (C) The ... to a maximum (D) The entropy of a substance does not remain constant during a reversible adiabatic change

Last Answer : (D) The entropy of a substance does not remain constant during a reversible adiabatic change

Pick out the wrong statement regarding the solubility characteristics of high polymers. (A) Greater the degree of cross-linking in the polymer, lesser is its solubility (B) Polymers having more aliphatic character are more soluble in aliphatic solvents, while those polymers having more aromatic character are more soluble in aromatic solvents (C) Swelling tendency or solubility of polymers in a particular solvent decreases with increase in molecular weight of the solvent (D) High molecular weight polymers on dissolving gives solution of very low viscosity

Description : Pick out the wrong statement regarding the solubility characteristics of high polymers. (A) Greater the degree of cross-linking in the polymer, lesser is its solubility (B) Polymers having more ... of the solvent (D) High molecular weight polymers on dissolving gives solution of very low viscosity

Last Answer : (D) High molecular weight polymers on dissolving gives solution of very low viscosity

The exit age distribution of fluid leaving a vessel is used to know the (A) Activation energies of a reaction (B) Reaction mechanism (C) Extent of non-ideal flow in the vessel (D) None of these

Description : The exit age distribution of fluid leaving a vessel is used to know the (A) Activation energies of a reaction (B) Reaction mechanism (C) Extent of non-ideal flow in the vessel (D) None of these

Last Answer : (C) Extent of non-ideal flow in the vessel

Pick out the wrong statement (A) A horizontal line on the humidity chart indicates the temperature changes at constant molal humidity (B) When water is cooled from 80 to 70°C by exposure to the air with a wet bulb temperature of 60°C, then both the approach & the range would be 10°C (C) For unsaturated air-water vapor mixture at atmospheric conditions, the wet bulb temperature & adiabatic cooling lines are the same (D) Relative saturation of unsaturated mixture of water vapor & air cannot be increased by either reducing the mixture temperature or by increasing the total pressure

Description : Pick out the wrong statement (A) A horizontal line on the humidity chart indicates the temperature changes at constant molal humidity (B) When water is cooled from 80 to 70°C by exposure ... & air cannot be increased by either reducing the mixture temperature or by increasing the total pressure

Last Answer : (D) Relative saturation of unsaturated mixture of water vapor & air cannot be increased by either reducing the mixture temperature or by increasing the total pressure

Pick out the wrong statement. Raoult's law does not apply, when the (A) Size of component molecules are not equal (B) Attractive forces between like and unlike molecules in the solution are approximately equal (C) Component molecules are non-polar (D) Chemical combination or molecular association between unlike molecules takes place in the formation of solution

Description : Pick out the wrong statement. Raoult's law does not apply, when the (A) Size of component molecules are not equal (B) Attractive forces between like and unlike molecules ... D) Chemical combination or molecular association between unlike molecules takes place in the formation of solution

Last Answer : (C) Component molecules are non-polar

Pick out the wrong statement. (A) The binary diffusivity in liquids is of the order of 10 -5 cm2 /sec (B) Molecular diffusion in solid is much faster than that in liquids (C) Particles movement from higher concentration to lower concentration takes place in diffusion process (D) According to Poiseuille's law, the permeability decreases with increase in temperature for flow of a gas through a given capillary

Description : Pick out the wrong statement. (A) The binary diffusivity in liquids is of the order of 10 -5 cm2 /sec (B) Molecular diffusion in solid is much faster than that in liquids ( ... Poiseuille's law, the permeability decreases with increase in temperature for flow of a gas through a given capillary

Last Answer : (B) Molecular diffusion in solid is much faster than that in liquids

Pick out the wrong statement: (A) Absorption factor is constant, when the equilibrium and operating lines are straight (B) In case of a stripper, the equilibrium curve is always below the operating line (C) In case of an absorber, the operating line is always above the equilibrium curve (D) In the absorption of low solubility gases, the liquid film is the controlling resistance

Description : Pick out the wrong statement: (A) Absorption factor is constant, when the equilibrium and operating lines are straight (B) In case of a stripper, the equilibrium curve is always below ... (D) In the absorption of low solubility gases, the liquid film is the controlling resistance

Last Answer : (B) In case of a stripper, the equilibrium curve is always below the operating line

The equilibrium constant ‘K’ of a chemical reaction depends on (A) Temperature only (B) Pressure only (C) Temperature and pressure (D) Ratio of reactants

Description : The equilibrium constant ‘K’ of a chemical reaction depends on (A) Temperature only (B) Pressure only (C) Temperature and pressure (D) Ratio of reactants

Last Answer : (A) Temperature only

Pick out the correct statement. (A) In catalytic reactions, the catalyst reacts with the reactants (B) A catalyst initiates a chemical reaction (C) A catalyst lowers the activation energy of the reacting molecules (D) A catalyst cannot be recovered chemically unchanged at the end of the chemical reaction

Description : Pick out the correct statement. (A) In catalytic reactions, the catalyst reacts with the reactants (B) A catalyst initiates a chemical reaction (C) A catalyst lowers the activation energy of ... molecules (D) A catalyst cannot be recovered chemically unchanged at the end of the chemical reaction

Last Answer : (C) A catalyst lowers the activation energy of the reacting molecules