Description : Threshold energy in a reaction is equal to the (A) Activation energy (B) Normal energy of reactants (C) Sum of (A) & (B) (D) Neither (A) nor (B)
Last Answer : (C) Sum of (A) & (B)
Description : The excess energy of reactants in a chemical reaction required to dissociate into products is termed as the __________ energy. (A) Activation (B) Potential (C) Binding (D) Threshold
Last Answer : (A) Activation
Description : The excess energy of the reactants required to dissociate into products is known as the __________ energy. (A) Thermal (B) Activation (C) Threshold (D) Binding
Last Answer : (B) Activation
Description : For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst ... with the reactant (D) The surface of the catalyst does not play an important role during reaction
Last Answer : (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction
Description : A catalyst (A) Initiates a reaction (B) Lowers the activation energy of reacting molecules (C) Is capable of reacting with any one of the reactants (D) Cannot be recovered chemically unchanged at the end of a chemical reaction
Last Answer : (C) Is capable of reacting with any one of the reactants
Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction
Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot
Description : Pick out the wrong statement. (A) Exit age description function (E) and internal age distribution function (I) are related as, E = -(dI/dθ) (B) Chemisorption studies are useful in the ... energy (D) A catalyst increases the potential energy barrier over which the reactants must pass to form products
Last Answer : (D) A catalyst increases the potential energy barrier over which the reactants must pass to form products
Description : Pick out the correct statement. (A) In catalytic reactions, the catalyst reacts with the reactants (B) A catalyst initiates a chemical reaction (C) A catalyst lowers the activation energy of ... molecules (D) A catalyst cannot be recovered chemically unchanged at the end of the chemical reaction
Last Answer : (C) A catalyst lowers the activation energy of the reacting molecules
Description : If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower (C) Entropy changes (D) Free energy of activation is higher
Last Answer : (D) Free energy of activation is higher
Description : Pick out the correct statement. (A) A catalyst does not change AH of the reaction (B) A catalyst changes the equilibrium point (C) Law of mass action was suggested by Le-Chatelier (D) The difference between the energy of reactants and that of the products is the activation energy
Last Answer : (A) A catalyst does not change AH of the reaction
Description : The minimum energy required to allow a chemical reaction to proceed is termed as the 'threshold energy '. Chemical reactions with low activation energy are: (A) Always irreversible (B) Insensitive to temperature changes (C) Mostly irreversible (D) Highly temperature sensitive
Last Answer : (B) Insensitive to temperature changes
Description : The reaction rate almost gets doubled for 10°C rise in temperature. This is due to the fact that the (A) Increased temperature reduces the activation energy (B) Fraction of molecules having threshold energy increases (C) Collision frequency increases (D) Value of threshold energy decreases
Last Answer : (B) Fraction of molecules having threshold energy increases
Description : What happens when a catalyst is added to a system at equilibrium? A The reaction follows an alternative pathway of lower activation energy. B The heat of reaction decreases. C The potential ... decreases. D The potential energy of the products decreases. E The rate of chemical reaction decreases.
Last Answer : A The reaction follows an alternative pathway of lower activation energy.
Description : The difference between Threshold energy and average energy of the molecules is called activation energy. Ina chemical reaction lowers the rate of reaction the greater will be. The activation energy
Last Answer : How do you define the molecularity of a reaction ?
Description : Burning of Gasoline initially requires heat before it burns spontaneously. Which of the following does not give a good explanation of this phenomenon? a. the initial heat rises the enthalpy of the reactant ... of products. d. The enthalpy of the product is lower than the enthalpy of the reactant
Last Answer : the enthalpy of reactants is lower than the enthalpy of products.
Description : When the reaction occurs in the diffusion controlled region, the apparent activation energy as measured is only __________ the true value. (A) Twice (B) Half (C) Equal (D) None of these
Last Answer : (B) Half
Description : If the pore diffusion controls in a catalytic reaction, the apparent activation energy Ea is equal to (A) The intrinsic activation energy E (B) (E + ED) where ED is activation due to diffusion (C) (E + ED)/2 (D) ED/2
Last Answer : (D) ED/2
Description : The rate expression for a heterogeneous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + KR.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR ... R and A) (A) E (B) E + ΔHA (C) E + ΔHA - ΔHR ) (D) ΔHA + ΔHR
Last Answer : (C) E + ΔHA - ΔHR )
Description : A chemical reaction occurs when the energy of the reacting molecules is __________ the activation energy of the reaction. (A) Less than (B) Equal to (C) More than (D) Equal to or more than
Last Answer : (D) Equal to or more than
Description : A chemical reaction occurs, when the energy of the reacting molecules is __________ the activation energy of reaction. (A) Less than (B) Equal to (C) More than (D) Equal to or more than
Description : Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For ... rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero
Last Answer : (B) The order and molecularity of a complex reaction may not be the same
Description : The order of a chemical reaction is (A) An experimentally determined quantity (B) Always equal to the total stoichiometric number of reactants (C) Never fractional (D) None of these
Last Answer : (A) An experimentally determined quantity
Description : Pick out the correct statement. (A) If an insoluble gas is passed through a volatile liquid placed in a perfectly insulated container, the temperature of the liquid will increase (B) A ... compound is defined as the heat of reaction leading to the formation of the compound from its reactants
Last Answer : (D) The heat of formation of a compound is defined as the heat of reaction leading to the formation of the compound from its reactants
Description : In an exothermic chemical reaction, the reactants compared to the products have (A) Higher temperature (B) More energy (C) Less energy (D) Same energy
Last Answer : (B) More energy
Description : The internal energy of the combustion products is __________compared to that of reactants. (A) More (B) Less (C) Equal (D) More or less; (depends on the state of fuel.)
Last Answer : (B) Less
Description : It is important to balance the chemical equations to satisfy the law of conservation of mass. Which of the following statements of the law is incorrect? (a) The total mass of the elements present in ... the reaction (d) Mass can neither be created nor can it be destroyed in a chemical Reaction.
Last Answer : Answer : (c) The chemical composition of the reactants is the same before and after the reaction
Description : The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction
Last Answer : (B) Activation energy
Description : Pick out the correct statement. (A) A lower temperature favours the reaction of lower activation energy (B) The dispersion number for a reactor/vessel is uL/D (C) The rate controlling step in ... step (D) Pore volume and porosity of a catalyst is measured by BrunauerEmmett-Teller (BET) technique
Last Answer : (A) A lower temperature favours the reaction of lower activation energy
Description : Enzymes (a protein) are catalysts found in organisms. Its efficiency of catalysing a reaction is due to its capacity to lower the activation energy of the reaction. The enzyme ptyalin used for food digestion is present in (A) Blood (B) Saliva (C) Intestine (D) Gland
Last Answer : (B) Saliva
Description : Pick out the wrong statement. (A) In a multistep reaction, the slowest step is the rate determining step (B) In general, the rate of a reaction becomes triple for every 10°C rise in temperature (C ... energy (D) Molecularity of a reaction cannot be zero but the order of a reaction can be zero
Last Answer : (B) In general, the rate of a reaction becomes triple for every 10°C rise in temperature
Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions
Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy
Description : Photochemical reaction rate does not depend significantly on temperature, because (A) It is a reversible reaction (B) It is an exothermic reaction (C) The energy of reacting molecules exceeds the activation energy by absorption of light (D) None of these
Last Answer : (C) The energy of reacting molecules exceeds the activation energy by absorption of light
Description : Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by ... occurs when the energy of the reacting molecule is less than the activation energy of the reaction
Last Answer : (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state
Description : Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these
Last Answer : (A) Activation energy
Description : The reason why a catalyst increases the rate of reaction is that, it (A) Decreases the energy barrier for reaction (B) Increases the activation energy (C) Decreases the molecular collision diameter (D) None of these
Last Answer : (A) Decreases the energy barrier for reaction
Description : Pick out the wrong statement: (A) Chemical reactions with high activation energy are very temperature sensitive (B) A flat velocity profile exists in a plug flow reactor (C) The residence ... D) Half life of a reaction increases with increased initial concentration for reaction orders more than one
Last Answer : (C) The residence time for all the elements of fluid in case of a P.F.R. need not be same
Description : The increase in the rate of reaction with temperature is due to (A) Increase in the number of effective collisions (B) Decrease in activation energy (C) Increase in the average kinetic energy of the reacting molecules (D) None of these
Last Answer : (B) Decrease in activation energy
Description : Pick out the wrong statement. (A) Catalytic activity of enzyme catalysed reactions which is affected by temperature, pH value & chemical agents, is maximum at a temperature of about 45°C ... in enzyme catalysed reactions can be calculated by using the thermodynamic properties of substrates & prod
Last Answer : (C) Enzymes help in increasing the activation energy of the reaction
Description : Higher free energy of activation of a chemical reaction (at a given temperature) implies (A) Slower rate of reaction (B) Higher rate of reaction (C) Higher equilibrium conversion (D) Both (B) and (C)
Last Answer : (A) Slower rate of reaction
Description : The energy of activation of a chemical reaction: (A) Is same as heat of reaction at constant pressure (B) Is the minimum energy which the molecules must have before the reaction can take place (C) Varies as fifth power of the temperature (D) Both (B) and (C)
Last Answer : (B) Is the minimum energy which the molecules must have before the reaction can take place
Description : The catalyst in a first order chemical reaction changes the (A) Equilibrium constant (B) Activation energy (C) Heat of formation of the product (D) Heat of reaction
Description : Arrhenius equation represents graphically the variation between the __________ and temperature. (A) Rate of reaction (B) Frequency factor (C) Rate constant (D) Activation energy
Last Answer : (C) Rate constant
Description : A catalyst in a chemical reaction (A) Decreases the activation energy (B) Alters the reaction mechanism (C) Increases the frequency of collisions of reacting species (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : Arrhenius equation shows the variation of __________ with temperature. (A) Reaction rate (B) Rate constant (C) Energy of activation (D) Frequency factor
Last Answer : (B) Rate constant
Description : The energy of activation of exothermic reaction is (A) Zero (B) Negative (C) Very large compared to that for endothermic reaction (D) Not possible to predict
Last Answer : (D) Not possible to predict
Description : During decomposition, energy is absorbed in the form of heat, light or electricity for breaking down the reactants which is known as: (a) exothermic reaction (b) endothermic reaction (c) reduction reaction (d) oxidation
Last Answer : (b) endothermic reaction
Description : The minimum amount of energy required for the reaction to takes place is called threshold energy.
Last Answer : What is activation energy ?
Description : The free energy change, AG (A) Is directly proportional to the standard free energy change, AG (B) Is equal to zero at equilibrium (C) Can only be calculated when the reactants and products are present at 1mol/1 concentrations (D) Is equal to –RT in keq
Last Answer : B
Description : Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time required to ... Then the order of this reaction is: (A) 0 (B) 1 (C) 2 (D) 3
Last Answer : (B) 1
Description : Reverse reaction in a chemical equilibrium is favoured by the (A) Removal of one of the products regularly (B) Increase in the concentration of one of the products (C) Increase in the concentration of one of the reactants (D) None of these
Last Answer : (B) Increase in the concentration of one of the products