Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time requiredto reduce the concentration of reactant from 100 gm moles/litre to 50 gmmoles/litre is same as that required to reduce it from 2 gm moles/litre to 1gm mole/litre in the same volume. Then the order of this reaction is:(A) 0(B) 1(C) 2(D) 3

Rate constant for a first order reaction does not depend upon reaction
time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time required
to reduce the concentration of reactant from 100 gm moles/litre to 50 gm
moles/litre is same as that required to reduce it from 2 gm moles/litre to 1
gm mole/litre in the same volume. Then the order of this reaction is:
(A) 0
(B) 1
(C) 2
(D) 3
by

1 Answer

Answer :

(B) 1
by

Related questions

In a first order reaction, the time required to reduce the concentration of reactant from 1 mole/litre to 0.5 mole/litre will be __________ that requiredto reduce it from 10 moles/litre to 5 moles/litre in the same volume.(A) More than(B) Less than(C) Same as(D) Data insufficient; can't be predicted

Description : In a first order reaction, the time required to reduce the concentration of reactant from 1 mole/litre to 0.5 mole/litre will be __________ that requiredto reduce it from 10 moles/litre to 5 moles/litre in the ... (A) More than (B) Less than (C) Same as (D) Data insufficient; can't be predicted

Last Answer : (C) Same as

What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second

Description : What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second

Last Answer : (A) Litre/mole.second

Concentration of the limiting reactant (with initial concentration of a moles/litre) after time t is (a-x). Then 't' for a first order reaction is given by (A) k. t = ln a/(a - x) (B) k. t = x/a (a - x) (C) k. t = ln (a - x)/a (D) k. t = ln a (a - x)/x

Description : Concentration of the limiting reactant (with initial concentration of a moles/litre) after time t is (a-x). Then 't' for a first order reaction is given by (A) k. t = ln a/(a - x) (B) k. t = x/a (a - x) (C) k. t = ln (a - x)/a (D) k. t = ln a (a - x)/x

Last Answer : (A) k. t = ln a/(a - x)

The rate constant of a reaction is a function of the (A) Time of reaction (B) Temperature of the system (C) Extent of reaction (D) Initial concentration of the reactants

Description : The rate constant of a reaction is a function of the (A) Time of reaction (B) Temperature of the system (C) Extent of reaction (D) Initial concentration of the reactants

Last Answer : (B) Temperature of the system

The rate constant of a reaction depends on the (A) Initial concentration of reactants (B) Time of reaction (C) Temperature of the system (D) Extent of reaction

Description : The rate constant of a reaction depends on the (A) Initial concentration of reactants (B) Time of reaction (C) Temperature of the system (D) Extent of reaction

Last Answer : All of the carbon atoms are sp hybridized

The rate constant of a reaction depends on the (A) Initial concentration of reactants (B) Time of reaction (C) Temperature of the system (D) Extent of reaction

Description : The rate constant of a reaction depends on the (A) Initial concentration of reactants (B) Time of reaction (C) Temperature of the system (D) Extent of reaction

Last Answer : (C) Temperature of the system

The order of reaction is the number of moles whose concentrations determine the rate of a reaction at a given temperature Give the integrated equation for first order reaction. K = (2.303 / t) * log (a / a-x) Rate equation of first order reaction is. dx/dt = K * (a-x) where ‘a’ is the initial concentration of reactants ‘x’ is the amount reacted in time t seconds

Description : The order of reaction is the number of moles whose concentrations determine the rate of a reaction at a given temperature Give the integrated equation for first order reaction. K = (2.303 / t) * log (a ... a' is the initial concentration of reactants x' is the amount reacted in time t seconds

Last Answer : What is Threshold energy ?

If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower(C) Entropy changes(D) Free energy of activation is higher

Description : If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower (C) Entropy changes (D) Free energy of activation is higher

Last Answer : (D) Free energy of activation is higher

Velocity of a chemical reaction (A) Decreases with increase in temperature (B) Increases with increase of pressure of reactants for all reactions (C) Decreases with increase of reactant concentration (D) None of these

Description : Velocity of a chemical reaction (A) Decreases with increase in temperature (B) Increases with increase of pressure of reactants for all reactions (C) Decreases with increase of reactant concentration (D) None of these

Last Answer : (D) None of these

For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637

Description : For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637

Last Answer : (B) 0.338

In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = 0 (C) Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

Description : In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = ... any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

Last Answer : D) All 'a', 'b' & 'c'

For the reaction as shown in the bellow figure, the rate of formation of Z is 0.2 gm mole/litre.hr. What is the rate of disappearance of X in gm mole/litre.hr? (A) 0.4 (B) 0.1 (C) 0.2 (D) None of these

Description : For the reaction as shown in the bellow figure, the rate of formation of Z is 0.2 gm mole/litre.hr. What is the rate of disappearance of X in gm mole/litre.hr? (A) 0.4 (B) 0.1 (C) 0.2 (D) None of these

Last Answer : (A) 0.4

A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume of the reacting mixture is V and the density of the liquid mixture is constant. The mass balance for A is (A) d(VCA )/dt = -F (CAF - CA ) - kCA 2V (B) d(VCA )/dt = F (CAF - CA ) - kCA 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V

Description : A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume ... 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V

Last Answer : (D) d(VCA )/dt = FCAF - kCA 2V

What is the order of a chemical reaction in which doubling the initial concentration of the reactants doubles the half life time of the reaction? (A) 0 (B) 1 (C) 2 (D) 3

Description : What is the order of a chemical reaction in which doubling the initial concentration of the reactants doubles the half life time of the reaction? (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (A) 0

If the time required to change the concentration of reactant to half its original value is independent of the initial concentration, the order of reaction is: (A) Zero (B) One (C) Two (D) Three

Description : If the time required to change the concentration of reactant to half its original value is independent of the initial concentration, the order of reaction is: (A) Zero (B) One (C) Two (D) Three

Last Answer : (B) One

For a __________ order chemical reaction as shown in the bellow figure, the half life period is independent of the initial concentration of the reactant A(A) Zero(B) First(C) Second(D) Third.

Description : For a __________ order chemical reaction as shown in the bellow figure, the half life period is independent of the initial concentration of the reactant A. (A) Zero (B) First (C) Second (D) Third

Last Answer : (B) First

Equilibrium constant of a reaction varies with the (A) Initial concentration of the reactant (B) Pressure (C) Temperature (D) None of these

Description : Equilibrium constant of a reaction varies with the (A) Initial concentration of the reactant (B) Pressure (C) Temperature (D) None of these

Last Answer : C) Temperature

The rate constant of a first order reaction depends on the (A) Concentration of the reactant (B) Temperature (C) Concentration of the product (D) Time

Description : The rate constant of a first order reaction depends on the (A) Concentration of the reactant (B) Temperature (C) Concentration of the product (D) Time

Last Answer : (B) Temperature

For a zero order chemical reaction, the (A) Half life period is directly proportion to the initial concentration of the reactants (B) Plot of products concentration with time is a straight line through the origin (C) Products concentration increases linearly with time (D) All (A), (B) and (C)

Description : For a zero order chemical reaction, the (A) Half life period is directly proportion to the initial concentration of the reactants (B) Plot of products concentration with time is a straight line through the origin (C) Products concentration increases linearly with time (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

The dimensions of rate constant for reaction 3A → B are (l/gm mole)/min. Therefore the reaction order is (A) 0 (B) 1 (C) 2 (D) 3

Description : The dimensions of rate constant for reaction 3A → B are (l/gm mole)/min. Therefore the reaction order is (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (C) 2

. In a zero order reaction, reactants concentration does not change with time and the (A) Time for half change is half the time taken for completion of the reaction (B) Time for half change is independent of the initial concentration (C) Time for completion of the reaction is independent of the initial concentration (D) Reaction rate is trebled when the initial concentration is trebled

Description : . In a zero order reaction, reactants concentration does not change with time and the (A) Time for half change is half the time taken for completion of the reaction (B) Time for ... is independent of the initial concentration (D) Reaction rate is trebled when the initial concentration is trebled

Last Answer : (A) Time for half change is half the time taken for completion of the reaction

The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction

Description : The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction

Last Answer : (C) Temperature

The rate constant of a chemical reaction increases by increasing the (A) Temperature (B) Pressure (C) Reactant's concentration (D) None of these

Description : The rate constant of a chemical reaction increases by increasing the (A) Temperature (B) Pressure (C) Reactant's concentration (D) None of these

Last Answer : (A) Temperature

For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst can cause the conversion of large amount of reactants which does not mean that catalyst concentration is important (C) The catalyst does not form an intermediate complex with the reactant (D) The surface of the catalyst does not play an important role during reaction

Description : For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst ... with the reactant (D) The surface of the catalyst does not play an important role during reaction

Last Answer : (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction

In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth

Description : In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth

Last Answer : (A) Remain the same

Half-life period for a first order reaction is __________ the initial concentration of the reactant. (A) Directly proportional to (B) Inversely proportional to (C) Independent of(D) None of these

Description : Half-life period for a first order reaction is __________ the initial concentration of the reactant. (A) Directly proportional to (B) Inversely proportional to (C) Independent of (D) None of these

Last Answer : (C) Independent of

According to the 'law of mass action', the rate of reaction is directlyproportional to the (A) Equilibrium constant (B) Volume of the reaction vessel (C) Nature of the reactants (D) Molar concentration of the reactants

Description : According to the 'law of mass action', the rate of reaction is directlyproportional to the (A) Equilibrium constant (B) Volume of the reaction vessel (C) Nature of the reactants (D) Molar concentration of the reactants

Last Answer : (D) Molar concentration of the reactants

Pick out the wrong statement. (A) In a batch reactor, which is exclusively used for liquid phase reactions; temperature pressure and composition may vary with time (B) In a semi-batch reactor, one reactant is charged batch wise, while the other reactant is fed continuously (C) In a continuous flow reactor, uniform concentration cannot be maintained throughout the vessel even in a well agitated system (D) In a continuous flow reactor, both the reactants and the products flow out continuously

Description : Pick out the wrong statement. (A) In a batch reactor, which is exclusively used for liquid phase reactions; temperature pressure and composition may vary with time (B) In a semi-batch reactor, ... system (D) In a continuous flow reactor, both the reactants and the products flow out continuously

Last Answer : (C) In a continuous flow reactor, uniform concentration cannot be maintained throughout the vessel even in a well agitated system

The conversion in a mixed reactor/accomplishing a reaction A → 3R is 50% when gaseous reactant 'A' is introduced at the rate of 1 litre/second and the leaving flow rate is 2 litres/second. The holding time for this operation is __________ second. (A) 0.5 (B) 1 (C) 2(D) 3

Description : The conversion in a mixed reactor/accomplishing a reaction A → 3R is 50% when gaseous reactant 'A' is introduced at the rate of 1 litre/second and the leaving flow rate is 2 litres/second. The holding time for this operation is __________ second. (A) 0.5 (B) 1 (C) 2 (D) 3

Last Answer : (A) 0.5

A gaseous reactant is introduced in a mixed reactor of 3 litres volume at the rate of 1 litre/second. The space time is __________ seconds. (A) 1 (B) 3 (C) 1/3 (D) 32

Description : A gaseous reactant is introduced in a mixed reactor of 3 litres volume at the rate of 1 litre/second. The space time is __________ seconds. (A) 1 (B) 3 (C) 1/3 (D) 32

Last Answer : (B) 3

In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases by a factor of 9 on trebling the concentration of the reactant. Then the rate of the reaction is proportional to(where, CA = concentration of the reactant) (A) CA (B) CA 2 (C) CA 3 (D) CA

Description : In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases ... where, CA = concentration of the reactant) (A) CA (B) CA 2 (C) CA 3 (D) CA

Last Answer : (B) CA 2

Rate of a chemical reaction is independent of the concentration of the reactants for a __________ reaction. (A) Zero order (B) Third order (C) Consecutive (D) None of these

Description : Rate of a chemical reaction is independent of the concentration of the reactants for a __________ reaction. (A) Zero order (B) Third order (C) Consecutive (D) None of these

Last Answer : (A) Zero order

Molarity is defined as the number of gm moles of solute per __________ of solvent. (A) Litre (B) kg (C) gm (D) c.c

Description : Molarity is defined as the number of gm moles of solute per __________ of solvent. (A) Litre (B) kg (C) gm (D) c.c

Last Answer : (A) Litre

Molality is defined as the number of gm moles of solute per __________ of solvent. (A) Litre (B) gm (C) Kg (D) m

Description : Molality is defined as the number of gm moles of solute per __________ of solvent. (A) Litre (B) gm (C) Kg (D) m

Last Answer : (C) Kg

Half life period of a chemical reaction is (A) The time required to reduce the concentration of the reacting substance to half its initial value (B) Half of the space time of a reaction (C) Half of the residence time of a reaction (D) None of these

Description : Half life period of a chemical reaction is (A) The time required to reduce the concentration of the reacting substance to half its initial value (B) Half of the space time of a reaction (C) Half of the residence time of a reaction (D) None of these

Last Answer : (A) The time required to reduce the concentration of the reacting substance to half its initial value

If the time required to complete a definite fraction of reaction varies inversely as the concentration of the reactants, then the order of reaction is (A) 1 (B) 2 (C) 3 (D) 4

Description : If the time required to complete a definite fraction of reaction varies inversely as the concentration of the reactants, then the order of reaction is (A) 1 (B) 2 (C) 3 (D) 4

Last Answer : (B) 2

Rate of a chemical reaction is not influenced by the (A) Catalyst (B) Temperature (C) Reactants concentration (D) Number of molecules of reactants taking part in a reaction

Description : Rate of a chemical reaction is not influenced by the (A) Catalyst (B) Temperature (C) Reactants concentration (D) Number of molecules of reactants taking part in a reaction

Last Answer : (D) Number of molecules of reactants taking part in a reaction

Rate of a chemical reaction is not affected by the (A) Catalyst(B) Temperature (C) Reactant’s concentration (D) Number of molecules of reactants taking part in the reaction

Description : Rate of a chemical reaction is not affected by the (A) Catalyst (B) Temperature (C) Reactant’s concentration (D) Number of molecules of reactants taking part in the reaction

Last Answer : (D) Number of molecules of reactants taking part in the reaction

Which of the following is not a unit of reaction rate? (A) Moles for med/(surface of catalyst) (time) (B) Moles formed/volume of reactor) (time) (C) Mole formed/volume of catalyst) (time) (D) None of these

Description : Which of the following is not a unit of reaction rate? (A) Moles for med/(surface of catalyst) (time) (B) Moles formed/volume of reactor) (time) (C) Mole formed/volume of catalyst) (time) (D) None of these

Last Answer : (D) None of these

Burning of Gasoline initially requires heat before it burns spontaneously. Which of the following does not give a good explanation of this phenomenon?  a. the initial heat rises the enthalpy of the reactant  b. the initial heat lowers the activation of energy of the reactants  c. the enthalpy of reactants is lower than the enthalpy of products.  d. The enthalpy of the product is lower than the enthalpy of the reactant

Description : Burning of Gasoline initially requires heat before it burns spontaneously. Which of the following does not give a good explanation of this phenomenon?  a. the initial heat rises the enthalpy of the reactant ... of products.  d. The enthalpy of the product is lower than the enthalpy of the reactant

Last Answer : the enthalpy of reactants is lower than the enthalpy of products.

FeO (s) + CO (g) = Fe (s) + CO2 (g), k = 0. 435 at 1173E; at equilibrium, what will be the number of moles of CO gas required to reduce one mole of FeO at 1173 K? (A) 1.0 (B) 1.3 (C) 2.3 (D) 3.3

Description : FeO (s) + CO (g) = Fe (s) + CO2 (g), k = 0. 435 at 1173E; at equilibrium, what will be the number of moles of CO gas required to reduce one mole of FeO at 1173 K? (A) 1.0 (B) 1.3 (C) 2.3 (D) 3.3

Last Answer : Option D

first order chemical reaction, the concentration of the reactant decreases __________ with time. (A) Linearly (B) Exponentially (C) Logarithmically (D) Inversely

Description : first order chemical reaction, the concentration of the reactant decreases __________ with time. (A) Linearly (B) Exponentially (C) Logarithmically (D) Inversely

Last Answer : (A) Linearly

Velocity of a reaction depends upon the (A) Nature of the reactants (B) Concentration of the reactants (C) Temperature at which the reaction is carried (D) All (A), (B) and (C)

Description : Velocity of a reaction depends upon the (A) Nature of the reactants (B) Concentration of the reactants (C) Temperature at which the reaction is carried (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

The rate of a chemical reaction can be affected by: w) temperature x) concentration of products y) concentration of reactants z) all of the above

Description : The rate of a chemical reaction can be affected by: w) temperature x) concentration of products y) concentration of reactants z) all of the above

Last Answer : ANSWER: Z -- ALL OF THE ABOVE

In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Description : In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Last Answer : (C) Temperature

A batch adiabatic reactor at an initial temperature of 373°K is being used for the reaction, A → B. Assume the heat of reaction is - 1kJ/mole at 373°K and heat capacity of both A and B to be constant and equal to 50J/mole.K. The temperature rise after a conversion of 0.5 will be: (A) 5°C (B) 10°C (C) 20°C (D) 100°C

Description : A batch adiabatic reactor at an initial temperature of 373°K is being used for the reaction, A → B. Assume the heat of reaction is - 1kJ/mole at 373°K and heat capacity of both A and B to be constant and equal ... rise after a conversion of 0.5 will be: (A) 5°C (B) 10°C (C) 20°C (D) 100°C

Last Answer : (B) 10°C

In an ideal P.F.R. at steady state conditions (A) The composition of reactants remains constant along a flow path (B) The conversion of the reactant varies from point to point along a flow path (C) There is no lateral mixing of fluid (D) There may be diffusion along the flow path

Description : In an ideal P.F.R. at steady state conditions (A) The composition of reactants remains constant along a flow path (B) The conversion of the reactant varies from point to point along a flow path (C) There is no lateral mixing of fluid (D) There may be diffusion along the flow path

Last Answer : (B) The conversion of the reactant varies from point to point along a flow path

If the time required for half change is inversely proportional to the square of initial concentration and the velocity depends on the units in which the concentration term is expressed, then the order of reaction is (A) 0 (B) 1 (C) 2 (D) 3

Description : If the time required for half change is inversely proportional to the square of initial concentration and the velocity depends on the units in which the concentration term is expressed, then the order of reaction is (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (D) 3