Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these

Catalytic action in a catalytic chemical reaction follows from the ability
of catalyst to change the
(A) Activation energy
(B) Equilibrium constant
(C) Heat of reaction
(D) None of these
by

1 Answer

Answer :

(A) Activation energy
by

Related questions

Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to iron catalyst in ammonia synthesis reaction (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot

What happens when a catalyst is added to a system at equilibrium? A The reaction follows an alternative pathway of lower activation energy. B The heat of reaction decreases. C The potential energy of the reactants decreases. D The potential energy of the products decreases. E The rate of chemical reaction decreases.

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Last Answer : A The reaction follows an alternative pathway of lower activation energy.

The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction

Description : The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction

Last Answer : (B) Activation energy

The catalyst in a first order chemical reaction changes the (A) Equilibrium constant(B) Activation energy(C) Heat of formation of the product(D) Heat of reaction

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Pick out the correct statement. (A) A catalyst does not change AH of the reaction (B) A catalyst changes the equilibrium point (C) Law of mass action was suggested by Le-Chatelier (D) The difference between the energy of reactants and that of the products is the activation energy

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Last Answer : (A) A catalyst does not change AH of the reaction

Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly efficient catalyst for one or more chemical reactions in a living system. C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.

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Last Answer : C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy.

Pick out the correct statement. (A) In catalytic reactions, the catalyst reacts with the reactants (B) A catalyst initiates a chemical reaction (C) A catalyst lowers the activation energy of the reacting molecules (D) A catalyst cannot be recovered chemically unchanged at the end of the chemical reaction

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The equilibrium constant of a catalytic chemical reaction __________ due to the presence of a catalyst. (A) Increases (B) Decreases (C) Remain unaffected (D) Unpredictable from the data

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The rate expression for a heterogeneous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + KR.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A) (A) E (B) E + ΔHA (C) E + ΔHA - ΔHR ) (D) ΔHA + ΔHR

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Last Answer : (C) E + ΔHA - ΔHR )

Pick out the wrong statement. (A) Catalytic activity of enzyme catalysed reactions which is affected by temperature, pH value & chemical agents, is maximum at a temperature of about 45°C(B) Most of the enzyme catalysed reactions involve at least two substrates (C) Enzymes help in increasing the activation energy of the reaction (D) Equilibrium concentrations in enzyme catalysed reactions can be calculated by using the thermodynamic properties of substrates & prod

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For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst can cause the conversion of large amount of reactants which does not mean that catalyst concentration is important (C) The catalyst does not form an intermediate complex with the reactant (D) The surface of the catalyst does not play an important role during reaction

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Last Answer : (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction

The catalytic power of enzymes is due to (a) the presence of amino acids in their structures (b) their high molecular weight (c) their ability to lower the activation energy of the reaction (d) their limited solubility in water and other solvents

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Last Answer : Ans:(c)

Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the reaction is practically irreversible in nature (C) The intercept of the Arrhenius plot is called the 'activation energy' (D) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

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A catalyst is a substance which (a) Changes the equilibrium of a reaction so that the concentration of the product increases (b) Increases the rate of reaction and increases the equilibrium concentration of products (c) Hastens the attainment of equilibrium (d) Increases the activation energy

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Last Answer : Ans:(c)

A catalyst (A) Initiates a reaction (B) Lowers the activation energy of reacting molecules (C) Is capable of reacting with any one of the reactants (D) Cannot be recovered chemically unchanged at the end of a chemical reaction

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A catalyst in a chemical reaction (A) Decreases the activation energy (B) Alters the reaction mechanism (C) Increases the frequency of collisions of reacting species (D) All (A), (B) and (C)

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Last Answer : (D) All (A), (B) and (C)

Catalyst is a substance, which __________ chemical reaction. (A) Increases the speed of a (B) Decreases the speed of a (C) Can either increase or decrease the speed of a (D) Alters the value of equilibrium constant in a reversible

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The equilibrium constant of chemical reaction __________ in the presence of catalyst. (A) Increases (B) Decreases (C) Remain unaffected (D) Can either increase or decrease (depends on the type of catalyst)

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Last Answer : (C) Remain unaffected

Enzymes increases the rate of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

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Last Answer : Answer : B

Enzymes increase the rates of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

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Last Answer : Answer : B

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Last Answer : (B) Is the minimum energy which the molecules must have before the reaction can take place

Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by light (D) A chemical reaction occurs when the energy of the reacting molecule is less than the activation energy of the reaction

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Higher free energy of activation of a chemical reaction (at a given temperature) implies (A) Slower rate of reaction (B) Higher rate of reaction (C) Higher equilibrium conversion (D) Both (B) and (C)

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Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

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Last Answer : (C) Pressure changes do not change the equilibrium concentrations

If the pore diffusion controls in a catalytic reaction, the apparent activation energy Ea is equal to (A) The intrinsic activation energy E (B) (E + ED) where ED is activation due to diffusion (C) (E + ED)/2 (D) ED/2

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Last Answer : (D) ED/2

Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an endothermic reaction (C) The rate constant for a first order reaction does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

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Overall rate of reaction in a heterogeneous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of catalyst, if it doesnot entail a chain mechanism.(A) Proportional to(B) Independent of(C) Inversely proportional to(D) Proportional to the square o

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Last Answer : (A) Proportional to

Pick out the correct statement. (A) A lower temperature favours the reaction of lower activation energy (B) The dispersion number for a reactor/vessel is uL/D (C) The rate controlling step in a reaction involving many steps is the fastest step (D) Pore volume and porosity of a catalyst is measured by Brunauer￾Emmett-Teller (BET) technique

Description : Pick out the correct statement. (A) A lower temperature favours the reaction of lower activation energy (B) The dispersion number for a reactor/vessel is uL/D (C) The rate controlling step in ... step (D) Pore volume and porosity of a catalyst is measured by Brunauer￾Emmett-Teller (BET) technique

Last Answer : (A) A lower temperature favours the reaction of lower activation energy

The reason why a catalyst increases the rate of reaction is that, it (A) Decreases the energy barrier for reaction (B) Increases the activation energy (C) Decreases the molecular collision diameter (D) None of these

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Last Answer : (A) Decreases the energy barrier for reaction

Pick out the wrong statement. (A) Exit age description function (E) and internal age distribution function (I) are related as, E = -(dI/dθ) (B) Chemisorption studies are useful in the determination of catalyst surface area and pore size distribution (C) A higher temperature favours the reaction of higher activation energy (D) A catalyst increases the potential energy barrier over which the reactants must pass to form products

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Last Answer : (D) A catalyst increases the potential energy barrier over which the reactants must pass to form products

A Catalyst (A) Increases the equilibrium concentration of the product (B) Changes the equilibrium constant of the reaction (C) Shortens the time to reach the equilibrium (D) None of these

Description : A Catalyst (A) Increases the equilibrium concentration of the product (B) Changes the equilibrium constant of the reaction (C) Shortens the time to reach the equilibrium (D) None of these

Last Answer : (C) Shortens the time to reach the equilibrium

A catalyst is said to be a negative catalyst, if it (A) Retards the rate of reaction (B) Reduces the value of equilibrium constant (C) Does not initiate the reaction (D) All (A), (B) and (C)

Description : A catalyst is said to be a negative catalyst, if it (A) Retards the rate of reaction (B) Reduces the value of equilibrium constant (C) Does not initiate the reaction (D) All (A), (B) and (C)

Last Answer : (A) Retards the rate of reaction

_________ explains the equilibrium constant for any chemical reaction. (A) Henry's law (B) Law of mass action (C) Hess's law (D) None of these

Description : _________ explains the equilibrium constant for any chemical reaction. (A) Henry's law (B) Law of mass action (C) Hess's law (D) None of these

Last Answer : (B) Law of mass action

If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower(C) Entropy changes(D) Free energy of activation is higher

Description : If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower (C) Entropy changes (D) Free energy of activation is higher

Last Answer : (D) Free energy of activation is higher

Promoter (A) Initiates a chemical reaction and is a catalyst by itself (B) Alters the position of equilibrium in a reversible reaction (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals(D) All (A), (B) and (C)

Description : Promoter (A) Initiates a chemical reaction and is a catalyst by itself (B) Alters the position of equilibrium in a reversible reaction (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals (D) All (A), (B) and (C)

Last Answer : (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals

Pick out the wrong statement. (A) A catalyst does not alter the final position of equilibrium in a reversible reaction (B) A catalyst initiates a reaction (C) A catalyst is specific in reaction (D) A catalyst remains unchanged in chemical composition at the end the reaction

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Last Answer : (B) A catalyst initiates a reaction

The free energy change for a chemical reaction is given by (where, K = equilibrium constant) (A) RT ln K (B) -RT ln K (C) -R ln K (D) T ln K

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Last Answer : (B) -RT ln K

Pick out the wrong statement. (A) Lower boiling paraffins have higher octane number than higher paraffins (B) Dehydrogenation of naphthenes to aromatics is a desirable reaction in reforming process (C) The most ideal feedstock for thermal reforming is dearomatised kerosene (D) Catalyst used in catalytic reforming is platinum on silica-alumina base

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Last Answer : (C) The most ideal feedstock for thermal reforming is dearomatised kerosene

Which is a catalyst promoter used in catalytic ammonia synthesis reaction? (A) Al2O3 (B) Cr2O3 (C) K2O (D) MnO

Description : Which is a catalyst promoter used in catalytic ammonia synthesis reaction? (A) Al2O3 (B) Cr2O3 (C) K2O (D) MnO

Last Answer : (C) K2O

A reaction in which one of the products of reaction acts as a catalyst is called a/an __________ reaction. (A) Catalytic (B) Autocatalytic (C) Photochemical

Description : A reaction in which one of the products of reaction acts as a catalyst is called a/an __________ reaction. (A) Catalytic (B) Autocatalytic (C) Photochemical

Last Answer : (C) Photochemical

The reaction in which one of the products of reaction acts as a catalyst is called a/an __________ reaction. (A) Biochemical (B) Photochemical (C) Catalytic (D) Autocatalytic

Description : The reaction in which one of the products of reaction acts as a catalyst is called a/an __________ reaction. (A) Biochemical (B) Photochemical (C) Catalytic (D) Autocatalytic

Last Answer : (D) Autocatalytic

The catalytic activity of enzymes is due to their capacity to lower the __________ energy. (A) Activation (B) Potential (C) Kinetic (D) None of these

Description : The catalytic activity of enzymes is due to their capacity to lower the __________ energy. (A) Activation (B) Potential (C) Kinetic (D) None of these

Last Answer : (A) Activation

An enzyme promotes a chemical reaction by (A) Lowering the energy of activation (B) Causing the release of heat which acts as a primer (C) Increasing molecular motion (D) Changing the free energy difference between substrate and product

Description : An enzyme promotes a chemical reaction by (A) Lowering the energy of activation (B) Causing the release of heat which acts as a primer (C) Increasing molecular motion (D) Changing the free energy difference between substrate and product

Last Answer : Answer : A

The unit of equilibrium constant of a chemical reaction is the same as that of (A) Molar concentration (B) Temperature (C) Internal energy (D) None of these

Description : The unit of equilibrium constant of a chemical reaction is the same as that of (A) Molar concentration (B) Temperature (C) Internal energy (D) None of these

Last Answer : (D) None of these

When a catalyst increases the rate of chemical reaction, the rate constant (A) Decreases (B) Increases (C) Remain constant (D) Become infinite

Description : When a catalyst increases the rate of chemical reaction, the rate constant (A) Decreases (B) Increases (C) Remain constant (D) Become infinite

Last Answer : (B) Increases

A catalyst in a chemical reaction __________ free energy change in the reaction. (A) Increases (B) Decreases (C) Either (A) or (B); depends on the type of catalyst (D) Neither (A) nor (B)

Description : A catalyst in a chemical reaction __________ free energy change in the reaction. (A) Increases (B) Decreases (C) Either (A) or (B); depends on the type of catalyst (D) Neither (A) nor (B)

Last Answer : (C) Either (A) or (B); depends on the type of catalyst

Brunauer, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation? (A) Langmuir's assumption applies to every adsorbed layer (B) There is no dynamic equilibrium between successive layer (C) The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process (D) None of these

Description : Brunauer, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates ... (except the first one) is involved in each of the evaporation process (D) None of these

Last Answer : (B) There is no dynamic equilibrium between successive layer

According to the 'law of mass action', the rate of reaction is directlyproportional to the (A) Equilibrium constant (B) Volume of the reaction vessel (C) Nature of the reactants (D) Molar concentration of the reactants

Description : According to the 'law of mass action', the rate of reaction is directlyproportional to the (A) Equilibrium constant (B) Volume of the reaction vessel (C) Nature of the reactants (D) Molar concentration of the reactants

Last Answer : (D) Molar concentration of the reactants

Arrhenius equation represents graphically the variation between the __________ and temperature. (A) Rate of reaction (B) Frequency factor (C) Rate constant (D) Activation energy

Description : Arrhenius equation represents graphically the variation between the __________ and temperature. (A) Rate of reaction (B) Frequency factor (C) Rate constant (D) Activation energy

Last Answer : (C) Rate constant