Description : Why tert. Amines donot undergo acylation reaction ?
Last Answer : Ans.-- Tert. Amines donot undergo acylation reaction because they donot have Nattached to H- atom.
Description : Carbylamine test is given by (a) Primary amines (b) Secondary amines (c) Tertiary amines (d) None of these
Last Answer : Primary amines
Description : n-propylamine containing no secondary and tertiary amines as impurities is prepared by
Last Answer : n-propylamine containing no secondary and tertiary amines as impurities is prepared by A. Hoffmann ... n-propylchloride with ammonia D. none of these
Description : The nitrogan atom in each of the following tertiary amines may be removed as trimethyl amine by repeated Hoffmann elimination. Which of the following
Last Answer : The nitrogan atom in each of the following tertiary amines may be removed as trimethyl amine by repeated Hoffmann ... to accomplish this? A. B. C. D.
Description : Of the following reactions, how many reaction, are used for the preparation of amines? (a) `R-C-=N overset(LiAIh_(4))rarr` (b) `R-overset(O)overset(||
Last Answer : Of the following reactions, how many reaction, are used for the preparation of amines? (a) `R-C-=N overset( ... R-CH_(2)-NO_(2) overset(H_(2),Ni)rarr`
Description : Only one of the following amines will lose its nitrogen atom as trimethyl amine by repeated Hofmann elimination reactions:
Last Answer : Only one of the following amines will lose its nitrogen atom as trimethyl amine by repeated Hofmann elimination reactions: A. B. C. D.
Description : Tertiary butyl chloride preferably undergo hydrolysis by:
Last Answer : Tertiary butyl chloride preferably undergo hydrolysis by: A. `S_(N^(1))` mechanism B. `S_(N^(2))` mechanism C. and of (a) and (b) D. none of these
Description : Although benzene is highly unsaturated, it does not undergo addition reactions, why?
Last Answer : Ans. Because of extra stability, due to delocalization of π-electrons.
Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?
Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.
Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Description : Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV
Last Answer : I, II, and III
Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)
Last Answer : (a) and (b)
Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions
Last Answer : Nucleophilic substitution reactions
Description : Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds ... fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.
Last Answer : Alkynes are generally more reactive than alkenes.
Description : Basic-hydrolysis of esters is called (a) Acetylation (b) Acidification (c) Esterification (d) Saponification
Last Answer : Saponification
Description : Give reason: Alkanes undergo only substitution reactions but alkenes and alkynes undergo both substitution and addition reactions.
Last Answer : Alkenes and alkynes have double and triple bonds, which on breaking can add hydrogen atoms to satisfy the valency.
Description : Intentionality is the achievement in this sub-stage of the sensorimotor stage. a. Coordination of Secondary circular reactions b. Primary circular reactions c. Tertiary circular reactions d. Secondary circular reactions
Last Answer : a. Coordination of Secondary circular reactions
Description : Sodium phenoxide when heated with `CO_(2)` under pressure at `125^(@) C` yield a product which on acetylation gives product `C`
Last Answer : Sodium phenoxide when heated with `CO_(2)` under pressure at `125^(@) C` yield a product which on acetylation gives product `C` A. B. C. D.
Last Answer : Sodium phenoxide when heated with `CO_(2)` under pressure at `125^(@) C` yield a ... B. salicyladehyde C. sodium benzoate D. sodium salicylate
Description : Pantothenic acid is a constituent of coenzyme involved in (A) Acetylation (B) Decarboxylation (C) Dehydrogenation (D) Oxidation
Last Answer : Answer : A
Description : Pantothenic acid is a constituent of the coenzyme involved in (A) Decarboxylation (B) Dehydrogenation (C) Acetylation (D) Oxidation
Last Answer : Answer : C
Description : Which of the following is not true of sulfonamides ? (a) They are primarily metabolized by acetylation (b) They are more likely to produce crystalluria in alkaline urine in which they are ... in the urinary tract (d) Used alone, they have become therapeutically unreliable for serious infections
Last Answer : Ans: B
Description : Drug called ‘Heroin’ is synthesised by (a) nitration of morphine (b) methylation of morphine (c) acetylation of morphine (d) glycosylation of morphine.
Last Answer : (c) acetylation of morphine
Last Answer : (C) Acetylation
Description : The following is true of sulfonamides except: A. They are more likely to produce crystalluria in alkaline urine in which they are less soluble B. They are primarily metabolized by acetylation ... in the urinary tract D. Used alone, they have become therapeutically unreliable for serious infections
Last Answer : A. They are more likely to produce crystalluria in alkaline urine in which they are less soluble
Description : The following drug metabolizing reaction is entirely nonmicrosomal: A. Glucuronide conjugation B. Acetylation C. Oxidation D. Reduction
Last Answer : B. Acetylation
Description : The most commonly occurring conjugation reaction for drugs and their metabolites is: A. Glucuronidation B. Acetylation C. Methylation D. Glutathione conjugation
Last Answer : A. Glucuronidation
Description : Chemically fats and oils are: (1) Triesters (2) Amines (3) Aldehydes (4) Ketons
Last Answer : (1) Triesters Explanation: Fats and oils are called triglycerides (or triacylcylgerols) because they are esters composed of three fatty acid units joined to glycerol, a trihydroxy alcohol. Fats and oils are composed of molecules known as triglycerides, which are esters.
Description : Aromatic primary amines are not prepared by gabrial phthalimide synthesis. Why?
Last Answer : Ans:- Because aryl halides donot undergo nucleophilic substitution reaction.
Description : Why are amines always less acidic than comparable alcohols?
Last Answer : Ans.--- Amines are less acidic than alcohols because of oxygen higher electronegative & smaller size. Therefore O-H breakes easily than N-H bond.
Description : Give reasons:--- a. Primary amines are more basic than ammonia. b . Sec. amines are more basic than pr.amines.
Last Answer : Ans— a. In pr. Amines, alkyl group increases electron density on the N-atom making it more basic than ammo b. In sec. amine, there are two alkyl groups increase electron density on N-atom more than N-atom in pr. amines in which there is one alkyl group.
Description : The diazonium salts are the reaction products of the reaction of nitrous acid with (a) primary aliphatic amines (b) primary aromatic amines (c) secondary aliphatic amines (d) secondary aromatic amines
Last Answer : primary aromatic amines
Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form
Last Answer : primary amines form
Description : Which of the following amines react with nitrous acid to form nitrosoamine? (a) Ethylamine (b) Triethylamine (c) Diethylamine (d) Isopropylamine
Last Answer : Diethylamine
Description : Aliphatic primary amines react with cold nitrous acid to form (a) Alcohols (b) Diazonium salts (c) Nitriles (d) Nitroalkanes
Last Answer : Alcohols
Description : Alkyl halides react with ammonia in the presence of base to form : (a) primary amines (b) nitrated alkyl halides (c) amides (d) quaternary ammonium salts
Last Answer : primary amines
Description : Amines are generally classified as (a) Weak acids (b) Strong acids (c) Weak bases (d) Strong bases
Last Answer : Weak bases
Description : Which of the following statements is false about secondary amines? (a) They react with chloroform and NaOH to form isocyanides. (b) They can be prepared by reduction of isocyanides. (c) They react ... give substituted amides. (d) They react with ice-cold nitrous acid to give nitrosamine (yellow oil)
Last Answer : They react with chloroform and NaOH to form isocyanides.
Description : Which of the following statements is false about primary amines? (a) They can be prepared by reduction of nitriles with LiAlH4. (b) They do not form salts with acids (c) They react with ice-cold nitrous acid to form nitrogen gas. (d) They are basic and soluble in water
Last Answer : They do not form salts with acids
Description : Lucas test is used to determine the type of (a) alcohols (b) acids (c) amines (d) carbohydrates
Last Answer : alcohols
Description : Phenols do not undergo substitution of the — OH group like alcohols. Explain.
Last Answer : The C — O bond in phenols has some double bond character due to resonance and hence cannot be easily cleaved by a nucleophile. In contrast, the C — O bond in alcohols is a pure single bond and hence can be easily cleaved by a nucleo phile.
Description : How many amines are possible with the molecular formula `C_(4)H_(11)N` (structural isomers only) :-
Last Answer : How many amines are possible with the molecular formula `C_(4)H_(11)N` (structural isomers only) :- A. 6 B. 7 C. 8 D. 9
Description : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is
Last Answer : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in ... reaction D. Reaction with `NH_(3)`
Description : The strongest base in aqueous solution among the following amines is :
Last Answer : The strongest base in aqueous solution among the following amines is : A. N,N- ... N-ethylethanamine C. M-methylmethanamine D. ethanamine
Description : Of the following amines how many can give carbyl amine reaction?
Last Answer : Of the following amines how many can give carbyl amine reaction?
Description : Which of the following amines cannot be prepared by path-I?
Last Answer : Which of the following amines cannot be prepared by path-I? A. B. C. D.
Description : Which of the following amines reacts most rapidly with
Last Answer : Which of the following amines reacts most rapidly with A. B. C. D.
Description : Which of the following amines form `N-` nitroso derivative when treated with `NaNO_(2)` and `HCI`?
Last Answer : Which of the following amines form `N-` nitroso derivative when treated with `NaNO_(2)` and `HCI`? A. `CH_(3)NH_(2)` B. C. D.