Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form
Last Answer : primary amines form
Description : Alkyl halides react with ammonia in the presence of base to form : (a) primary amines (b) nitrated alkyl halides (c) amides (d) quaternary ammonium salts
Last Answer : primary amines
Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides
Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides
Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)
Last Answer : (a) and (b)
Description : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is :
Last Answer : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is : A. RF > RCl > RBr > ... RBr > RF > RI D. RI > RBr > RCl > RF
Description : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism?
Last Answer : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism? A. `CH_(3)Cl` B. `CH_(3)CH_(2)Cl` ... (2)CH_(2)Cl` D. `(CH_(3))_(3)"CCl"`
Description : Why the presence of a base is essential in the ammonolysis of alkyl halides ?
Last Answer : During ammonolysis of alkyl halides, the acid liberated during the reaction combines with the amine formed to form amine salt. To liberate free amine from the amine salt, a base is needed.
Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism
Last Answer : Resonance stabilization
Description : Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides
Last Answer : Alkoxyalkanes
Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F
Last Answer : CH3CH2I
Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions
Last Answer : Nucleophilic substitution reactions
Description : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the carbon chain, the reagent used as sou
Last Answer : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the ... C_(6)H_(4)(CO)_(2)N^(-)K^(+)`
Description : The designation D or Lbefore the name of a monosaccharide (a) indicates the direction of rotation of polarized light. (b) indicates the length of the carbon chain in the carbohydrate. (c) ... the primary alcohol group. (d) indicates the position of the asymmetric carbon atoms in the carbohydrate.
Last Answer : indicates the position of the OH group on the carbon next to the primary alcohol group.
Description : Aromatic primary amines are not prepared by gabrial phthalimide synthesis. Why?
Last Answer : Ans:- Because aryl halides donot undergo nucleophilic substitution reaction.
Description : Give reasons:--- a. Primary amines are more basic than ammonia. b . Sec. amines are more basic than pr.amines.
Last Answer : Ans— a. In pr. Amines, alkyl group increases electron density on the N-atom making it more basic than ammo b. In sec. amine, there are two alkyl groups increase electron density on N-atom more than N-atom in pr. amines in which there is one alkyl group.
Description : The diazonium salts are the reaction products of the reaction of nitrous acid with (a) primary aliphatic amines (b) primary aromatic amines (c) secondary aliphatic amines (d) secondary aromatic amines
Last Answer : primary aromatic amines
Description : Carbylamine test is given by (a) Primary amines (b) Secondary amines (c) Tertiary amines (d) None of these
Last Answer : Primary amines
Description : Aliphatic primary amines react with cold nitrous acid to form (a) Alcohols (b) Diazonium salts (c) Nitriles (d) Nitroalkanes
Last Answer : Alcohols
Description : Which of the following statements is false about primary amines? (a) They can be prepared by reduction of nitriles with LiAlH4. (b) They do not form salts with acids (c) They react with ice-cold nitrous acid to form nitrogen gas. (d) They are basic and soluble in water
Last Answer : They do not form salts with acids
Description : All long chain fatty acids with even number of carbon atoms are oxidized to a pool of _________ by β-oxidation. (A) CO2 (B) Propionic acid (C) Acetic acid (D) Acetyl CoA
Last Answer : Answer : D
Description : In nylon-6, the number 6 represents the total number of (A) Carbon atoms in the ring (B) Carbon atoms in the linear polymer chain (C) Nitrogen atoms in the ring (D) Hydrogen atoms in the ring
Last Answer : (B) Carbon atoms in the linear polymer chain
Description : Choose the correct statement. (A) Octane number of i-octane is zero (B) Octane number of paraffins increases with increasing number of carbon atoms (C) Branched chain paraffins have higher octane ... atoms (D) The aromatics have lower octane number than naphthenes with same number of carbon atoms
Last Answer : (A) Octane number of i-octane is zero
Description : How should CH3CHClCH2CH3 be classified? (a) primary alkyl halide (b) secondary alkyl halide (c) tertiary alkyl halide (d) quarternary alkyl halide
Last Answer : secondary alkyl halide
Description : 2-Methyl-2-butene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide
Last Answer : A secondary alkyl bromide
Description : 2-Methylpropene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide
Last Answer : A primary alkyl bromide
Description : What type of an alkyl group is an isobutyl group? (a) primary (b) secondary (c) tertiary (d) none of these
Last Answer : none of these
Description : Alkyl cyanide on reduction gives….. a. primary amine b. secondary amine c. amide d. carboxylic acid
Last Answer : a. primary amine
Description : In an alkyl halide substitution of hydrogen by deuterium results in slow formation of ion pair. This is known as? a. Ortho effect b. Mesomeric effect c. Secondary kinetic isotope effect d. Primary kinetic isotope effect
Last Answer : c. Secondary kinetic isotope effect
Description : The maximum possible chain length of fatty acids formed in the pathway of de novo synthesis is (A) 16 Carbon atoms (B) 18 Carbon atoms (C) 20 Carbon atoms (D) 24 Carbon atoms
Last Answer : Answer : A
Description : The carbon chain of fatty acids is shortened by 2 carbon atoms at a time. This involves successive reactions catalysed by 4-enzymes. These act the following order: (A) Acetyl CoA dehydrogenase, ... CoA dehydrogenase (D) Enoyl hydrase, β-OH acyl CoA dehydrogenase, acyl CoA dehydrogenase, thiolose,
Last Answer : Answer : B
Description : Fatty acids having chain length of 10 carbon atoms enter the (A) Portal ciruclation (B) Lacteals (C) Systemic circulation (D) Colon
Description : The ability of carbon atoms to link together to from short or long chain by covalent bond is called
Last Answer : catenation.
Description : How many hydrogens are there in the straight chain alkane that has three carbon atoms?
Last Answer : ANSWER: EIGHT
Description : What is the name of the alkane that is composed of a chain of five carbon atoms?
Last Answer : ANSWER: PENTANE
Description : Which of the following best describes the carbon-chlorine bond of an alkyl chloride? (a) nonpolar; no dipole (b) polar; δ+ at carbon and δ– at chlorine (c) polar; δ– at carbon and δ+ at chlorine (d) ionic
Last Answer : polar; δ+ at carbon and δ– at chlorine
Description : Which of the following statements is correct for a saturated alkyl halide? (a) the C-X bond results from overlap of the s orbital of carbon and the p orbital of the halogen (X) (b) the C-X bond ... the C-X bond results from overlap of the sp2 orbital of carbon and the p orbital of the halogen (X)
Last Answer : the C–X bond results from overlap of the sp3 orbital of carbon and the p orbital of the halogen (X)
Description : The major carbon compound formed from the incomplete combustion of a hydrocarbon in air is (a) carbon dioxide (b) carbon monoxide (c) water (d) alkyl chains
Last Answer : carbon monoxide
Description : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC
Last Answer : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii ... (vi) `PCl_(3)` (vii) `AsCl_(3)`
Description : Which of the following is NOT a means of preparing carbon dioxide? w) burning coke in the absence of air x) combustion of methane y) heating certain normal carbonates z) action of acids on carbonates
Last Answer : ANSWER: W -- BURNING COKE IN THE ABSENCE OF AIR
Description : How many amines are possible with the molecular formula `C_(4)H_(11)N` (structural isomers only) :-
Last Answer : How many amines are possible with the molecular formula `C_(4)H_(11)N` (structural isomers only) :- A. 6 B. 7 C. 8 D. 9
Description : n-propylamine containing no secondary and tertiary amines as impurities is prepared by
Last Answer : n-propylamine containing no secondary and tertiary amines as impurities is prepared by A. Hoffmann ... n-propylchloride with ammonia D. none of these
Description : The strongest base in aqueous solution among the following amines is :
Last Answer : The strongest base in aqueous solution among the following amines is : A. N,N- ... N-ethylethanamine C. M-methylmethanamine D. ethanamine
Description : Of the following reactions, how many reaction, are used for the preparation of amines? (a) `R-C-=N overset(LiAIh_(4))rarr` (b) `R-overset(O)overset(||
Last Answer : Of the following reactions, how many reaction, are used for the preparation of amines? (a) `R-C-=N overset( ... R-CH_(2)-NO_(2) overset(H_(2),Ni)rarr`
Description : Of the following amines how many can give carbyl amine reaction?
Last Answer : Of the following amines how many can give carbyl amine reaction?
Description : Which of the following amines cannot be prepared by path-I?
Last Answer : Which of the following amines cannot be prepared by path-I? A. B. C. D.
Description : Which of the following amines reacts most rapidly with
Last Answer : Which of the following amines reacts most rapidly with A. B. C. D.
Description : The nitrogan atom in each of the following tertiary amines may be removed as trimethyl amine by repeated Hoffmann elimination. Which of the following
Last Answer : The nitrogan atom in each of the following tertiary amines may be removed as trimethyl amine by repeated Hoffmann ... to accomplish this? A. B. C. D.
Description : Only one of the following amines will lose its nitrogen atom as trimethyl amine by repeated Hofmann elimination reactions:
Last Answer : Only one of the following amines will lose its nitrogen atom as trimethyl amine by repeated Hofmann elimination reactions: A. B. C. D.
Description : Which of the following amines form `N-` nitroso derivative when treated with `NaNO_(2)` and `HCI`?
Last Answer : Which of the following amines form `N-` nitroso derivative when treated with `NaNO_(2)` and `HCI`? A. `CH_(3)NH_(2)` B. C. D.