Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Alkyl halides undergo
(a) Electrophilic substitution reactions
(b) Electrophilic addition reactions
(c) Nucleophilic substitution reactions
(d) Nucleophilic addition reactions
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1 Answer

Answer :

Nucleophilic substitution reactions
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Related questions

Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.

Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an sp3 hybridized carbon undergo substitution and elimination reactions. (c) The electronegative atom is replaced by another atom or group in substitution reactions. (d) (a) and (b)

Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)

Last Answer : (a) and (b)

Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Last Answer : nucleophilic addition; free radical addition

Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism

Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism

Last Answer : Resonance stabilization

Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F

Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F

Last Answer : CH3CH2I

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Last Answer : nucleophilic substitution

Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition(d) Nucleophilic substitution

Description : Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition (d) Nucleophilic substitution

Last Answer : Nucleophilic addition

Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Description : Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Last Answer : Electrophilic addition

The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Last Answer : a free-radical substitution

Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds of alkynes are higher in energy than the bonds and are thus more reactive. (c) Unlike alkenes, alkynes fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.

Description : Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds ... fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.

Last Answer : Alkynes are generally more reactive than alkenes.

Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV

Description : Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV

Last Answer : I, II, and III

Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the concentration of the alkyl halide. (c) The rate of reaction of a particular alkyl bromide depends on the steric accessibility of the carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides

Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides

Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides

Give reason: Alkanes undergo only substitution reactions but alkenes and alkynes undergo both substitution and addition reactions.

Description : Give reason: Alkanes undergo only substitution reactions but alkenes and alkynes undergo both substitution and addition reactions.

Last Answer : Alkenes and alkynes have double and triple bonds, which on breaking can add hydrogen atoms to satisfy the valency.

Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II Benzyl chloride III n-Propyl chloride IV V

Description : Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II Benzyl chloride III n-Propyl chloride IV V

Last Answer : Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II ... are correct D. I and III are correct

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Anthracene undergoes electrophilic substitution reactions mainly at (a) C-1 (b) C-2 (c) C-9 (d) C-1 and C-2

Description : Anthracene undergoes electrophilic substitution reactions mainly at (a) C-1 (b) C-2 (c) C-9 (d) C-1 and C-2

Last Answer : C-9

Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Description : Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Last Answer : Nitrobenzene

Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Description : Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Last Answer : Benzene + Br2/FeBr3

In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Description : In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Last Answer : is a deactivator and an o,p-director

Esters can be formed by nucleophilic substitution reactions of : (a) carboxylic acids and alcohols ; acid-catalyzed (b) acid chlorides and alcohols (c) both of the above (d) neither of the above

Description : Esters can be formed by nucleophilic substitution reactions of : (a) carboxylic acids and alcohols ; acid-catalyzed (b) acid chlorides and alcohols (c) both of the above (d) neither of the above

Last Answer : both of the above

Esters and amides are most easily made by nucleophilic acyl substitution reactions on : (a) acid anhydrides (b) carboxylates (c) carboxylic acids (d) acid chlorides

Description : Esters and amides are most easily made by nucleophilic acyl substitution reactions on : (a) acid anhydrides (b) carboxylates (c) carboxylic acids (d) acid chlorides

Last Answer : acid chlorides

Explain why nucleophilic substitution reactions are not very common in phenols.

Description : Explain why nucleophilic substitution reactions are not very common in phenols.

Last Answer : Explain why nucleophilic substitution reactions are not very common in phenols.

(A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl chloride is `+I` electron pushing group

Description : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl chloride is `+I` electron pushing group

Last Answer : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl ... A) is incorrect but (R) is correct.

Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds:

Description : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds:

Last Answer : Identify the correct order of reactivity in electrophilic substitution reactions of the following ... C. `IIgtIgtIIIgtIV` D. `IIgtIIIgtIgtIV`

Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds :

Description : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds :

Last Answer : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds : ... ` C. `2gt1gt3gt4` D. `2gt3gt1gt4`

Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : (3) Elimination Explanation: Benzene can not undergo Elimination reaction.

Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : Elimination

Arrange the following carboxyl compounds in increasing order of their reactivity in nucleophilic addition reactions. Explain with proper reasoning : Benzaldehyde. p-tolualdeyde, p-nitrobenzaldehyde, Acetophenone.

Description : Arrange the following carboxyl compounds in increasing order of their reactivity in nucleophilic addition reactions. Explain with proper reasoning : Benzaldehyde. p-tolualdeyde, p-nitrobenzaldehyde, Acetophenone.

Last Answer : Ans. Acetophenone is a ketone while all others are aldehydes, therefore it is least reactive. In p-tolualdehyde, there is methyl group (CH3 ) at para position w.r.t. to the ... overall order of increasing reactivity : acetophenone < p-tolualdehyde < benzaldehyde < p-nitrobenzaldehyde. 

Phenol is an ortho-para director because the hydroxyl group : (a) donates electrons that increase electron density at ortho and para positions favoring nucleophilic attack. (b) donates electrons that increase electron density at ortho and para positions favoring electrophilic attack. (c) donates electrons to the ortho and para positions and attracts electrons away from meta positions favoring nucleophilic attack of the ring. (d) donates electrons to the ortho and para positions and attracts electrons away from meta positions favoring electrophilic attack on the ring.

Description : Phenol is an ortho-para director because the hydroxyl group : (a) donates electrons that increase electron density at ortho and para positions favoring nucleophilic attack. (b) donates ... para positions and attracts electrons away from meta positions favoring electrophilic attack on the ring.

Last Answer : donates electrons that increase electron density at ortho and para positions favoring electrophilic attack.

Why the presence of a base is essential in the ammonolysis of alkyl halides ?

Description : Why the presence of a base is essential in the ammonolysis of alkyl halides ?

Last Answer : During ammonolysis of alkyl halides, the acid liberated during the reaction combines with the amine formed to form amine salt. To liberate free amine from the amine salt, a base is needed.

When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form

Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form

Last Answer : primary amines form

Alkyl halides react with ammonia in the presence of base to form : (a) primary amines(b) nitrated alkyl halides(c) amides(d) quaternary ammonium salts

Description : Alkyl halides react with ammonia in the presence of base to form : (a) primary amines (b) nitrated alkyl halides (c) amides (d) quaternary ammonium salts

Last Answer : primary amines

Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides

Description : Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides

Last Answer : Alkoxyalkanes

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Although benzene is highly unsaturated, it does not undergo addition reactions, why?

Description : Although benzene is highly unsaturated, it does not undergo addition reactions, why?

Last Answer : Ans. Because of extra stability, due to delocalization of π-electrons.

Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is

Description : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is

Last Answer : Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in ... reaction D. Reaction with `NH_(3)`

The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is :

Description : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is :

Last Answer : The order of reactivities of the following alkyl halides for a `S_(N^(2))` reaction is : A. RF > RCl > RBr > ... RBr > RF > RI D. RI > RBr > RCl > RF

Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism?

Description : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism?

Last Answer : Which of the following alkyl halides is hydrolysed by `S_(N^(1))` mechanism? A. `CH_(3)Cl` B. `CH_(3)CH_(2)Cl` ... (2)CH_(2)Cl` D. `(CH_(3))_(3)"CCl"`

How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

Quinoline undergoes nucleophilic substitution on heating with NaNH2 to give (a) 2-Aminoquinoline (b) 4-Aminoquinoline (c) 3-Aminoquinoline (d) 8-Aminoquinoline

Description : Quinoline undergoes nucleophilic substitution on heating with NaNH2 to give (a) 2-Aminoquinoline (b) 4-Aminoquinoline (c) 3-Aminoquinoline (d) 8-Aminoquinoline

Last Answer : 2-Aminoquinoline

Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

Description : Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

Last Answer : 3-Pyridinesulfonic acid

What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Acetyl chloride undergoes nucleophilic substitution at a faster rate than methyl acetate because __________. (a) the ester is more sterically hindered than the acid chloride (b) the acid chloride is more sterically hindered than the ester (c) the methoxide is a better leaving group than chloride (d) chloride is a better leaving group than methoxide

Description : Acetyl chloride undergoes nucleophilic substitution at a faster rate than methyl acetate because __________. (a) the ester is more sterically hindered than the acid chloride (b) the acid chloride is ... is a better leaving group than chloride (d) chloride is a better leaving group than methoxide

Last Answer : chloride is a better leaving group than methoxide

Ethylene is obtained from ethyl bromide by : (a) Simple heating (b) Hydrolysis (c) Dehydrohalogenation (d) Nucleophilic substitution

Description : Ethylene is obtained from ethyl bromide by : (a) Simple heating (b) Hydrolysis (c) Dehydrohalogenation (d) Nucleophilic substitution

Last Answer : Dehydrohalogenation

In an alkyl halide substitution of hydrogen by deuterium results in slow formation of ion pair. This is known as? a. Ortho effect b. Mesomeric effect c. Secondary kinetic isotope effect d. Primary kinetic isotope effect

Description : In an alkyl halide substitution of hydrogen by deuterium results in slow formation of ion pair. This is known as? a. Ortho effect b. Mesomeric effect c. Secondary kinetic isotope effect d. Primary kinetic isotope effect

Last Answer : c. Secondary kinetic isotope effect

Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Description : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Last Answer : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ? A. `A gt B gt ... A` D. `C gt B gt D gt A`