Description : `CH_(2)OHCH_(2)CH_(2)COCH_(3)overset("Reagent")rarr` `CH_(2)OHCH_(2)CH_(2)CH_(2)CH_(3)` Suitable reagent for above reaction is :-
Last Answer : `CH_(2)OHCH_(2)CH_(2)COCH_(3)overset("Reagent")rarr` `CH_(2)OHCH_(2)CH_(2)CH_(2)CH_(3)` Suitable reagent for ... /C_(2)H_(5)ONa` C. Red P + HI D. All
Description : What is the major product obtained from the following reactions ? `CH_(3)COCH_(2)COOH overset("heat")to` product
Last Answer : What is the major product obtained from the following reactions ? `CH_(3)COCH_(2)COOH overset("heat")to` ... -overset(OH)overset(|)(C)=CH_(2)` D.
Description : Arrange the following compounds in decreasing orders of rate of hydration. `(X) C Cl_(3)CHO " " (Y) CH_(3)CHO " " (Z)CH_(3)COCH_(3) " " (W) CF_(3)CHO`
Last Answer : Arrange the following compounds in decreasing orders of rate of hydration. `(X) C Cl_(3)CHO ... . WgtZgtXgtY B. WgtXgtYgtZ C. WgtYgtZgtX D. WgtZgtYgtX
Description : `(CH_(3))_(3)COCH_(3)overset(+HI)rarr(CH_(3))_(3)CI+CH_(3)OH` follows which mechanism ?
Last Answer : `(CH_(3))_(3)COCH_(3)overset(+HI)rarr(CH_(3))_(3)CI+CH_(3)OH` follows which mechanism ? A. `S_(N)1` B. `S_(N)2` C. `E_(1)` D. `E_(2)`
Description : Which of the following statements describes the first step in the mechanism of the aldol condensation? (a) An alpha hydrogen is abstracted by the base to form an enolate anion. (b) A nucleophilic base attacks ... by the base ion. (d) The alpha hydrogen is abstracted by an acid to the enolate anion.
Last Answer : An alpha hydrogen is abstracted by the base to form an enolate anion
Description : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the carbon chain, the reagent used as sou
Last Answer : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the ... C_(6)H_(4)(CO)_(2)N^(-)K^(+)`
Description : Which of the following sequence of reagent is the good mean to furnish the conversion? `R-CH_(2)OHrarr R -CH_(2)NH_(2)`
Last Answer : Which of the following sequence of reagent is the good mean to furnish the conversion? `R-CH_(2)OHrarr R -CH_(2) ... D. `Cu,300^(@)C,NH_(2),LiAiH_(4)`
Description : `CH_(3) - underset(CH_(3))underset(|)(CH) - CH = CH_(2) overset("Reagent R")rarr` Alcohol Which is true about alcohol and R ?
Last Answer : `CH_(3) - underset(CH_(3))underset(|)(CH) - CH = CH_(2) overset("Reagent R")rarr` Alcohol Which is true about ... ) - CH_(2)CH_(3)` dil. `H_(2)SO_(4)`
Description : Which is the best reagent to convert isopropyl alcohol to isopropyl bromide ? `CH_(3)- overset(CH_(3))overset(|)(CH)- OH overset(?)rarr CH_(3) - overs
Last Answer : Which is the best reagent to convert isopropyl alcohol to isopropyl bromide ? `CH_(3)- overset(CH_(3))overset(|)(CH ... )` C. `Br_(2)` D. `CH_(3)MgBr`
Description : Explain why nucleophilic substitution reactions are not very common in phenols.
Last Answer : Explain why nucleophilic substitution reactions are not very common in phenols.
Description : Arrange the following compounds in decreasing order of nucleophilic addition with semicarbazide `NH_(2)NHCONH_(2)` i.e., `ddot(N)H_(2)-ddot(Z)`
Last Answer : Arrange the following compounds in decreasing order of nucleophilic addition with semicarbazide `NH_(2)NHCONH_(2)` i.e., `ddot(N)H_(2)-ddot(Z)`
Description : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl chloride is `+I` electron pushing group
Last Answer : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl ... A) is incorrect but (R) is correct.
Description : Which of the following is an example of nucleophilic addition of acetone?
Last Answer : Which of the following is an example of nucleophilic addition of acetone? A. Ketal formation B ... gas C. Cyanohydrin formation D. Bisulphite additon
Description : Which gives nucleophilic addition reaction?
Last Answer : Which gives nucleophilic addition reaction? A. Methanal B. Ethanal C. Propanone D. Propene
Description : Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II Benzyl chloride III n-Propyl chloride IV V
Last Answer : Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II ... are correct D. I and III are correct
Description : Nucleophilic addition reaction will be most favoured in
Last Answer : Nucleophilic addition reaction will be most favoured in A. `CH_(3)CH_(2)CHO` B. `CH_(3)CHO` C. `CH_(3)CH_(2)CH_(2 ... |)C-CH_(3)` D. `(CH_(3))_(2)C=O`
Description : Arrange the following nucleophiles in the order of their nucleophilic strength.
Last Answer : Arrange the following nucleophiles in the order of their nucleophilic strength. A. `OH^(-)gtCH_(3)COO^(-)gtCH_(3)O^ ... (5)O^(-)ltOH^(-)ltCH_(3)O^(-)`
Description : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` mechanism?
Last Answer : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` ... Isopropyl chloride C. Chlorobenzene D. Benzyl chloride
Description : Which one of the following is most reactive towards nucleophilic substitution reaction ?
Last Answer : Which one of the following is most reactive towards nucleophilic substitution reaction ? A. `H_(2)C=CH-Cl` B. ` ... 3)CH=CHCl` D. `ClCH_(2)-CH=CH_(2)`
Description : Among the following the strongest nucleophilic is
Last Answer : Among the following the strongest nucleophilic is A. `C_(2)H_(5)SH` B. `CH_(3)COO^(-)` C. `CH_(3)NH_(2)` D. `N"CC"H_(2)^(-)`
Description : Which of the following is least reactive in a nucleophilic substitution reaction?
Last Answer : Which of the following is least reactive in a nucleophilic substitution reaction? A. `(CH_(3))_(3)C-Cl` B. `CH_ ... 3)CH_(2)Cl` D. `CH_(2)=CHCH_(2)Cl`
Description : The most nucleophilic nitrogen is in:
Last Answer : The most nucleophilic nitrogen is in: A. B. C. D.
Description : Among the given compounds, the most susceptible to nucleophilic attack at the cabonyl group is:
Last Answer : Among the given compounds, the most susceptible to nucleophilic attack at the cabonyl group is: A. `MeCOCl` B. `MeCHO` C. `MeCOOMe` D. `MeCOOCOMe`
Description : The nucleophilic attack on the esterified carboxyl group of the peptidyl-tRNA occupying the P site and the α-amino group of the new amino acyl tRNA, the number of ATP required by the amino acid on the charged tRNA is (A) Zero (B) One (C) Two (D) Four
Last Answer : Answer : A
Description : The α-amino group of the new amino acyl tRNA in the A site carries out a nucleophilic attack on the esterified carboxyl group of the peptidyl tRNA occupying the P site. This reaction is catalysed by (A) DNA polymerase (B) RNA polymerase (C) Peptidyl transferase (D) DNA ligase
Last Answer : Answer : C
Description : The enzyme amino acyl tRNA synthetase is involved in (A) Dissociation of discharged tRNA from 80S ribosome (B) Charging of tRNA with specific amino acids (C) Termination of protein synthesis (D) Nucleophilic attack on esterified carboxyl group of peptidyl tRNA
Last Answer : Answer : B
Description : What is nucleophilic addition reaction ?
Last Answer : When the attacking species during the addition reaction is Nucleophilic, it is nucleophilic addition reaction. Ex; Acetaldehyde cynohydrin
Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?
Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.
Description : Arrange the following carboxyl compounds in increasing order of their reactivity in nucleophilic addition reactions. Explain with proper reasoning : Benzaldehyde. p-tolualdeyde, p-nitrobenzaldehyde, Acetophenone.
Last Answer : Ans. Acetophenone is a ketone while all others are aldehydes, therefore it is least reactive. In p-tolualdehyde, there is methyl group (CH3 ) at para position w.r.t. to the ... overall order of increasing reactivity : acetophenone < p-tolualdehyde < benzaldehyde < p-nitrobenzaldehyde.
Description : Quinoline undergoes nucleophilic substitution on heating with NaNH2 to give (a) 2-Aminoquinoline (b) 4-Aminoquinoline (c) 3-Aminoquinoline (d) 8-Aminoquinoline
Last Answer : 2-Aminoquinoline
Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism
Last Answer : Resonance stabilization
Description : Phenol is an ortho-para director because the hydroxyl group : (a) donates electrons that increase electron density at ortho and para positions favoring nucleophilic attack. (b) donates ... para positions and attracts electrons away from meta positions favoring electrophilic attack on the ring.
Last Answer : donates electrons that increase electron density at ortho and para positions favoring electrophilic attack.
Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution
Last Answer : Electrophilic substitution
Description : Esters can be formed by nucleophilic substitution reactions of : (a) carboxylic acids and alcohols ; acid-catalyzed (b) acid chlorides and alcohols (c) both of the above (d) neither of the above
Last Answer : both of the above
Description : Esters and amides are most easily made by nucleophilic acyl substitution reactions on : (a) acid anhydrides (b) carboxylates (c) carboxylic acids (d) acid chlorides
Last Answer : acid chlorides
Description : Acetyl chloride undergoes nucleophilic substitution at a faster rate than methyl acetate because __________. (a) the ester is more sterically hindered than the acid chloride (b) the acid chloride is ... is a better leaving group than chloride (d) chloride is a better leaving group than methoxide
Last Answer : chloride is a better leaving group than methoxide
Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution
Last Answer : nucleophilic substitution
Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition
Last Answer : nucleophilic addition; free radical addition
Description : Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition (d) Nucleophilic substitution
Last Answer : Nucleophilic addition
Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F
Last Answer : CH3CH2I
Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions
Last Answer : Nucleophilic substitution reactions
Description : The reaction of 1-butene with bromine, Br2, in aqueous solution gives primarily 1-bromo-2-butanol. Identify the nucleophilic species in the reaction. (a) Br2 (b) Br– (c) H2O (d) HOBr
Last Answer : H2O
Description : Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution
Last Answer : Electrophilic addition
Description : Ethylene is obtained from ethyl bromide by : (a) Simple heating (b) Hydrolysis (c) Dehydrohalogenation (d) Nucleophilic substitution
Last Answer : Dehydrohalogenation
Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution
Last Answer : a free-radical substitution