Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II Benzyl chloride III n-Propyl chloride IV V

Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II Benzyl chloride III n-Propyl chloride IV V
by

1 Answer

Answer :

Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II ... are correct D. I and III are correct
by
selected by

Related questions

Arrange the following free radicals in order of decreasing stability: Methyl(I), Vinly(II), Allyl(III), Benzyl(IV)

Description : Arrange the following free radicals in order of decreasing stability: Methyl(I), Vinly(II), Allyl(III), Benzyl(IV)

Last Answer : Arrange the following free radicals in order of decreasing stability: Methyl(I), Vinly(II), Allyl(III), Benzyl(IV) ... gt III D. IV gt III gt I gt II

Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.

Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Last Answer : Nucleophilic substitution reactions

Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV

Description : Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV

Last Answer : I, II, and III

Propene reacts with HBr in the presence of a peroxide to give (a) n-Propyl bromide (b) Allyl bromide (c) Isopropyl bromide (d) Vinyl bromide

Description : Propene reacts with HBr in the presence of a peroxide to give (a) n-Propyl bromide (b) Allyl bromide (c) Isopropyl bromide (d) Vinyl bromide

Last Answer : n-Propyl bromide

(A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl chloride is `+I` electron pushing group

Description : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl chloride is `+I` electron pushing group

Last Answer : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl ... A) is incorrect but (R) is correct.

Acetyl chloride undergoes nucleophilic substitution at a faster rate than methyl acetate because __________. (a) the ester is more sterically hindered than the acid chloride (b) the acid chloride is more sterically hindered than the ester (c) the methoxide is a better leaving group than chloride (d) chloride is a better leaving group than methoxide

Description : Acetyl chloride undergoes nucleophilic substitution at a faster rate than methyl acetate because __________. (a) the ester is more sterically hindered than the acid chloride (b) the acid chloride is ... is a better leaving group than chloride (d) chloride is a better leaving group than methoxide

Last Answer : chloride is a better leaving group than methoxide

How many of the following compounds would give turbidity with lucas reagent without heating (1) Benzyl alcohol (2) Allyl alcohol (3) Cyclohexanol (4)

Description : How many of the following compounds would give turbidity with lucas reagent without heating (1) Benzyl alcohol (2) Allyl alcohol (3) Cyclohexanol (4)

Last Answer : How many of the following compounds would give turbidity with lucas reagent without heating (1) ... methyl carbionol (9) P-Nitro benzyl alcohol

Pungency in Onion is due to presence of a. Diallyl disulphide b. Isothiocyanate c. Capsaicin d. Allyl propyl disulphide

Description : Pungency in Onion is due to presence of a. Diallyl disulphide b. Isothiocyanate c. Capsaicin d. Allyl propyl disulphide

Last Answer : d. Allyl propyl disulphide

Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` mechanism?

Description : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` mechanism?

Last Answer : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` ... Isopropyl chloride C. Chlorobenzene D. Benzyl chloride

(A) In allylic substitution propene gives allyl bromide. (R) NBS is a selective brominating agent and gives substitution at the alpha carbon with resp

Description : (A) In allylic substitution propene gives allyl bromide. (R) NBS is a selective brominating agent and gives substitution at the alpha carbon with resp

Last Answer : (A) In allylic substitution propene gives allyl bromide. (R) NBS is a selective brominating agent and gives ... (A) is incorrect but (R) is correct.

Which of the following has the highest boiling point? (a) diethyl ether (b) n-Butyraldehyde (c) n-propyl chloride (d) n-Butyl alcohol

Description : Which of the following has the highest boiling point? (a) diethyl ether (b) n-Butyraldehyde (c) n-propyl chloride (d) n-Butyl alcohol

Last Answer : n-Butyl alcohol

Explain why nucleophilic substitution reactions are not very common in phenols.

Description : Explain why nucleophilic substitution reactions are not very common in phenols.

Last Answer : Explain why nucleophilic substitution reactions are not very common in phenols.

Which one of the following is most reactive towards nucleophilic substitution reaction ?

Description : Which one of the following is most reactive towards nucleophilic substitution reaction ?

Last Answer : Which one of the following is most reactive towards nucleophilic substitution reaction ? A. `H_(2)C=CH-Cl` B. ` ... 3)CH=CHCl` D. `ClCH_(2)-CH=CH_(2)`

Which of the following is least reactive in a nucleophilic substitution reaction?

Description : Which of the following is least reactive in a nucleophilic substitution reaction?

Last Answer : Which of the following is least reactive in a nucleophilic substitution reaction? A. `(CH_(3))_(3)C-Cl` B. `CH_ ... 3)CH_(2)Cl` D. `CH_(2)=CHCH_(2)Cl`

Quinoline undergoes nucleophilic substitution on heating with NaNH2 to give (a) 2-Aminoquinoline (b) 4-Aminoquinoline (c) 3-Aminoquinoline (d) 8-Aminoquinoline

Description : Quinoline undergoes nucleophilic substitution on heating with NaNH2 to give (a) 2-Aminoquinoline (b) 4-Aminoquinoline (c) 3-Aminoquinoline (d) 8-Aminoquinoline

Last Answer : 2-Aminoquinoline

Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism

Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism

Last Answer : Resonance stabilization

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Esters can be formed by nucleophilic substitution reactions of : (a) carboxylic acids and alcohols ; acid-catalyzed (b) acid chlorides and alcohols (c) both of the above (d) neither of the above

Description : Esters can be formed by nucleophilic substitution reactions of : (a) carboxylic acids and alcohols ; acid-catalyzed (b) acid chlorides and alcohols (c) both of the above (d) neither of the above

Last Answer : both of the above

Esters and amides are most easily made by nucleophilic acyl substitution reactions on : (a) acid anhydrides (b) carboxylates (c) carboxylic acids (d) acid chlorides

Description : Esters and amides are most easily made by nucleophilic acyl substitution reactions on : (a) acid anhydrides (b) carboxylates (c) carboxylic acids (d) acid chlorides

Last Answer : acid chlorides

The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Last Answer : nucleophilic substitution

Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Last Answer : nucleophilic addition; free radical addition

Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition(d) Nucleophilic substitution

Description : Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition (d) Nucleophilic substitution

Last Answer : Nucleophilic addition

Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F

Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F

Last Answer : CH3CH2I

Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Description : Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Last Answer : Electrophilic addition

Ethylene is obtained from ethyl bromide by : (a) Simple heating (b) Hydrolysis (c) Dehydrohalogenation (d) Nucleophilic substitution

Description : Ethylene is obtained from ethyl bromide by : (a) Simple heating (b) Hydrolysis (c) Dehydrohalogenation (d) Nucleophilic substitution

Last Answer : Dehydrohalogenation

The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Last Answer : a free-radical substitution

What is the validity after supervisors course (TW-3)? (i) Normally, supervisors shall not be required to undergo the course again. However, they may be sent for course on performance basis.* (ii) 2 years (iii) 5 Years (iv) 10 Years

Description : What is the validity after supervisors course (TW-3)? (i) Normally, supervisors shall not be required to undergo the course again. However, they may be sent for course on performance basis.* (ii) 2 years (iii) 5 Years (iv) 10 Years

Last Answer : (i) Normally, supervisors shall not be required to undergo the course again. However, they may be sent for course on performance basis.*

Orlon is prepared by the polymerisation of (a) Vinyl cyanide (b) Allyl alcohol (c) Vinyl chloride (d) Allyl chloride

Description : Orlon is prepared by the polymerisation of (a) Vinyl cyanide (b) Allyl alcohol (c) Vinyl chloride (d) Allyl chloride

Last Answer : Vinyl cyanide

Which of the following reagents can be used to distinguish between chlorobenzene and allyl chloride? (a) H2/Ni(b) Br2 in CCl4(c) Zn/HCl(d) NH2NH2

Description : Which of the following reagents can be used to distinguish between chlorobenzene and allyl chloride? (a) H2/Ni (b) Br2 in CCl4 (c) Zn/HCl (d) NH2NH2

Last Answer : Br2 in CCl4

Which of the following compounds will give a white precipitate with alcoholic AgNO3? (a) Vinylbenzene (b) Chlorobenzene (c) Vinyl chloride (d) Allyl chloride

Description : Which of the following compounds will give a white precipitate with alcoholic AgNO3? (a) Vinylbenzene (b) Chlorobenzene (c) Vinyl chloride (d) Allyl chloride

Last Answer : Allyl chloride

Which of the following are the components of loamy soils? 1. Red soil 2. Clay soil 3. Alluvial soil 4. Silt soil 5. Sandy soil In d i a n So i l , Se a s o n s a n d N a t u r a l Ve g e t a t i o n (a) I and II (b) I, III and IV (c) II and V (d) II, III and V

Description : Which of the following are the components of loamy soils? 1. Red soil 2. Clay soil 3. Alluvial soil 4. Silt soil 5. Sandy soil In d i a n So i l , Se a s o n s a n d N a t u r a l Ve g e t a t i o n (a) I and II (b) I, III and IV (c) II and V (d) II, III and V

Last Answer : Ans: (c)

Which of the following does not give benzoic acid on hydrolysis? (1) phenyl cyanide (2) benzoyl chloride (3) benzyl chloride (4) methyl benzoate

Description : Which of the following does not give benzoic acid on hydrolysis? (1) phenyl cyanide (2) benzoyl chloride (3) benzyl chloride (4) methyl benzoate

Last Answer : (3) benzyl chloride Explanation: Hydrolysis is any chemical reaction in which a molecule of water ruptures one or more chemical bonds.

Benzoyl chloride reacts with hydrogen in the presence of palladium and barium sulfate to give : (a) Benzyl alcohol (b) Benzaldehyde (c) Cinnamic acid (d) Benzophenone

Description : Benzoyl chloride reacts with hydrogen in the presence of palladium and barium sulfate to give : (a) Benzyl alcohol (b) Benzaldehyde (c) Cinnamic acid (d) Benzophenone

Last Answer : Benzaldehyde

Which of the following reagents can be used to distinguish between chlorobenzene and benzyl chloride? (a) alcoholic AgNO3 (b) Br2 in CCl4 (c) KCN (d) Br2 in H2O

Description : Which of the following reagents can be used to distinguish between chlorobenzene and benzyl chloride? (a) alcoholic AgNO3 (b) Br2 in CCl4 (c) KCN (d) Br2 in H2O

Last Answer : alcoholic AgNO3

Hydrolysis of benzal chloride gives (a) Phenol (b) Benzaldehyde (c) Benzyl alcohol(d) Benzoyl chloride

Description : Hydrolysis of benzal chloride gives (a) Phenol (b) Benzaldehyde (c) Benzyl alcohol (d) Benzoyl chloride

Last Answer : (d) Benzoyl chloride

Benzene reacts with benzoyl chloride in the presence of anhydrous aluminium chloride to form (a) Benzyl chloride (b) Benzaldehyde (c) Benzal chloride(d) Benzophenone

Description : Benzene reacts with benzoyl chloride in the presence of anhydrous aluminium chloride to form (a) Benzyl chloride (b) Benzaldehyde (c) Benzal chloride (d) Benzophenone

Last Answer : Benzophenone

Benzene reacts with chlorine in the presence of FeCl3 catalyst to form (a) Hexachlorobenzene (b) Chlorobenzene (c) Hexachlorocyclohexane (d) Benzyl chloride

Description : Benzene reacts with chlorine in the presence of FeCl3 catalyst to form (a) Hexachlorobenzene (b) Chlorobenzene (c) Hexachlorocyclohexane (d) Benzyl chloride

Last Answer : Chlorobenzene

Which of the following compounds will give an iodoform test? (a) Benzoic acid (b) Ethanol (c) Benzyl chloride (d) Methanol

Description : Which of the following compounds will give an iodoform test? (a) Benzoic acid (b) Ethanol (c) Benzyl chloride (d) Methanol

Last Answer : Ethanol

The given graph/data I, II, III and IV represent general trends observed for different physisorption and chemisorption processes under mild conditions

Description : The given graph/data I, II, III and IV represent general trends observed for different physisorption and chemisorption processes under mild conditions

Last Answer : The given graph/data I, II, III and IV represent general trends observed for different ... D. IV is chemisorption and III is chemisorption

Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Description : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Last Answer : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii ... (vi) `PCl_(3)` (vii) `AsCl_(3)`

Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Description : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii) `BCl_(3)` (iii) `NCl_(3)` (iv) `AlC

Last Answer : Number of halides undergoing complete reaction in presence of water under normal conditions is : (i) `BF_(3)` (ii ... (vi) `PCl_(3)` (vii) `AsCl_(3)`

Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : (3) Elimination Explanation: Benzene can not undergo Elimination reaction.

Phenols do not undergo substitution of the — OH group like alcohols. Explain.

Description : Phenols do not undergo substitution of the — OH group like alcohols. Explain.

Last Answer : The C — O bond in phenols has some double bond character due to resonance and hence cannot be easily cleaved by a nucleophile. In contrast, the C — O bond in alcohols is a pure single bond and hence can be easily cleaved by a nucleo phile.

Give reason: Alkanes undergo only substitution reactions but alkenes and alkynes undergo both substitution and addition reactions.

Description : Give reason: Alkanes undergo only substitution reactions but alkenes and alkynes undergo both substitution and addition reactions.

Last Answer : Alkenes and alkynes have double and triple bonds, which on breaking can add hydrogen atoms to satisfy the valency.

Which of the following will undergo substitution in the ortho and para positions rather than in the meta position? (a) Nitrobenzene (b) Benzoic acid (c) Acetanilide (d) Benzaldehyde

Description : Which of the following will undergo substitution in the ortho and para positions rather than in the meta position? (a) Nitrobenzene (b) Benzoic acid (c) Acetanilide (d) Benzaldehyde

Last Answer : Acetanilide

Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an sp3 hybridized carbon undergo substitution and elimination reactions. (c) The electronegative atom is replaced by another atom or group in substitution reactions. (d) (a) and (b)

Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)

Last Answer : (a) and (b)

Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : Elimination