Description : Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH
Last Answer : Benzene + Br2/FeBr3
Description : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl chloride is `+I` electron pushing group
Last Answer : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl ... A) is incorrect but (R) is correct.
Description : Quinoline undergoes nucleophilic substitution on heating with NaNH2 to give (a) 2-Aminoquinoline (b) 4-Aminoquinoline (c) 3-Aminoquinoline (d) 8-Aminoquinoline
Last Answer : 2-Aminoquinoline
Description : Ethylene oxide reacts with HBr to give (a) 1-Bromoethanol (b) Ethyl bromide (c) 2-Bromoethanol (c) Ethylene glycol
Last Answer : 2-Bromoethanol
Description : Ethylene oxide undergoes acid-hydrolysis to form (a) Ethylene glycol (b) Formic acid (c) Ethyl alcohol (d) Acetic acid
Last Answer : Ethylene glycol
Description : Which of the following compounds will react with methylmagnesium iodide followed by acid-hydrolysis to give ethyl alcohol? (a) Ethylene (b) Acetaldehyde (c) Formaldehyde (d) Acetone
Last Answer : Formaldehyde
Description : Ethyl alcohol cannot be produced (A) From waste sulphite substrate of paper mills (B) By Esterification and hydrolysis of ethylene (C) From molasses (D) None of these
Last Answer : (D) None of these
Description : Ethanol on heating with concentrated H2SO4 at 170°C gives (a) ethylene (b) ethyl hydrogen sulfate (c) diethyl ether (d) diethyl sulfate
Last Answer : ethylene
Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?
Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.
Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism
Last Answer : Resonance stabilization
Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution
Last Answer : Electrophilic substitution
Description : Esters can be formed by nucleophilic substitution reactions of : (a) carboxylic acids and alcohols ; acid-catalyzed (b) acid chlorides and alcohols (c) both of the above (d) neither of the above
Last Answer : both of the above
Description : Esters and amides are most easily made by nucleophilic acyl substitution reactions on : (a) acid anhydrides (b) carboxylates (c) carboxylic acids (d) acid chlorides
Last Answer : acid chlorides
Description : Acetyl chloride undergoes nucleophilic substitution at a faster rate than methyl acetate because __________. (a) the ester is more sterically hindered than the acid chloride (b) the acid chloride is ... is a better leaving group than chloride (d) chloride is a better leaving group than methoxide
Last Answer : chloride is a better leaving group than methoxide
Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution
Last Answer : nucleophilic substitution
Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition
Last Answer : nucleophilic addition; free radical addition
Description : Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition (d) Nucleophilic substitution
Last Answer : Nucleophilic addition
Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F
Last Answer : CH3CH2I
Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions
Last Answer : Nucleophilic substitution reactions
Description : Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution
Last Answer : Electrophilic addition
Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution
Last Answer : a free-radical substitution
Description : Explain why nucleophilic substitution reactions are not very common in phenols.
Last Answer : Explain why nucleophilic substitution reactions are not very common in phenols.
Description : Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II Benzyl chloride III n-Propyl chloride IV V
Last Answer : Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II ... are correct D. I and III are correct
Description : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` mechanism?
Last Answer : Which of the following undergoes nucleophilic substitution exclusively by `S_(N^(1))` ... Isopropyl chloride C. Chlorobenzene D. Benzyl chloride
Description : Which one of the following is most reactive towards nucleophilic substitution reaction ?
Last Answer : Which one of the following is most reactive towards nucleophilic substitution reaction ? A. `H_(2)C=CH-Cl` B. ` ... 3)CH=CHCl` D. `ClCH_(2)-CH=CH_(2)`
Description : Which of the following is least reactive in a nucleophilic substitution reaction?
Last Answer : Which of the following is least reactive in a nucleophilic substitution reaction? A. `(CH_(3))_(3)C-Cl` B. `CH_ ... 3)CH_(2)Cl` D. `CH_(2)=CHCH_(2)Cl`
Description : Phenylmagnesium bromide reacts with CO2 followed by acid-hydrolysis to form : (a) Phenol (b) Benzoic acid (c) Bromobenzene (d) Acetophenone
Last Answer : Benzoic acid
Description : Phenylmagnesium bromide reacts with acetaldehyde to form an addition product which undergoes acid-hydrolysis to give (a) Diphenylcarbinol (b) Benzyl alcohol (c) Methylphenylcarbinol (d) Benzoic acid
Last Answer : Methylphenylcarbinol
Description : n-Propylmagnesium bromide on treatment with carbon dioxide and further hydrolysis gives : (a) Acetic acid (b) Propanoic acid (c) Butanoic acid (d) Formic acid
Last Answer : Butanoic acid
Description : The pH of water will be decreased to below pH 7 by the hydrolysis of which of the following? w) sodium carbonate x) sodium chloride y) ammonium chloride z) potassium bromide
Last Answer : ANSWER: C -- AMMONIUM CHLORIDE
Description : Ethyl bromide reacts with sodium methoxide to form (a) Diethyl ether (b) Ethyl methyl ether (c) Dimethyl ether (d) n-Propyl alcohol
Last Answer : Ethyl methyl ether
Description : Which of the following compounds will not give a white precipitate with alcoholic AgNO3. (a) Bromobenzene (b) 1-Bromopropane (c) Ethyl bromide (d) 2-Bromopropane
Last Answer : Bromobenzene
Description : Which of the following is ozone depleting pesticide? (1) D.D.T. (2) Benzene (3) Methyl bromide (4) Ethylene ozonide
Last Answer : (3) Methyl bromide Explanation: Methyl bromide- is considered to be a significant ozone depleting substance (ODS) by atmospheric scientists. While methyl bromide is a natural substance, the additional methyl ... impact not only to human health and the environment, but to agricultural crops as well.
Description : Which of the following is ozone depleting pesticide ? (1) D.D.T. (2) Benzene (3) Methyl bromide (4) Ethylene ozonide
Last Answer : Methyl bromide
Description : (A) In allylic substitution propene gives allyl bromide. (R) NBS is a selective brominating agent and gives substitution at the alpha carbon with resp
Last Answer : (A) In allylic substitution propene gives allyl bromide. (R) NBS is a selective brominating agent and gives ... (A) is incorrect but (R) is correct.
Description : Benzoyl chloride on basic-hydrolysis (NaOH/H2O) gives : (a) Benzoic acid (b) Methyl benzoate (c) Sodium benzoate (d) Ethyl benzoate
Last Answer : Sodium benzoate
Description : When ethyl acetoacetate is subjected to ketonic hydrolysis, the ketone obtained is (a) Dimethyl ketone (b) Methyl ethyl ketone (c) Diethyl ketone (d) Methyl n-propyl ketone
Last Answer : Diethyl ketone
Description : The ethyl derivative of acetoacetic ester on basic-hydrolysis gives (a) Acetic acid (b) Acetic acid and propionic acid (c) Propionic acid (d) Acetic acid and n-butyric acid
Last Answer : Acetic acid
Description : Ethyl acetoacetate undergoes acid-hydrolysis with dilute HCl to form (a) Acetoacetic acid (b) Succinic acid (c) Acetic acid (d) Adipic acid
Last Answer : Acetoacetic acid
Description : Which of the following will give acetic acid on acid-hydrolysis? (a) Ethyl acetate (b) Acetone (c) Methyl propionate (d) Lactic acid
Last Answer : Ethyl acetate
Description : Acid-catalyzed hydrolysis of ethylene oxide yields (a) CH3CH2OH (b) HOCH2CH2OH (c) CH3CH2CH2OH (d) HOCH2CH2CH2OH
Last Answer : HOCH2CH2OH
Description : During fermentation of sugar, the compound which is always formed is – (1) Methyl Alcohol (2) Ethyl Alcohol (3) Acetic Acid (4) Ethylene
Last Answer : (2) Ethyl Alcohol Explanation: Fermentation is the conversion of sugar into car-bon dioxide has (CO2) and ethyl alcohol. This process is carried out by yeast cells using a range of enzymes.
Description : Reduction of acetaldehyde with H2/Ni gives (a) Ethyl alcohol (b) Acetic acid (c) Ethylene (d) Ethane
Last Answer : Ethyl alcohol
Description : Ethylene reacts with oxygen in the presence of silver catalyst at 300°C to form (a) Diethyl ether (b) Ethylene glycol (c) Ethyl alcohol (d) Ethylene oxide
Last Answer : Ethylene oxide
Description : Which of the following statements is false? (a) Diethyl ether has been used as a general anesthetic (b) Ethyl alcohol is present in all alcoholic beverages (c) Methyl alcohol is produced by fermentation of sugars (d) Ethylene glycol is a common antifreeze for automobiles
Last Answer : Methyl alcohol is produced by fermentation of sugars
Description : Ethyl alcohol reacts with concentrated H2SO4 at 140°C to form (a) Acetone (b) Ethylene (c) Diethyl ether (d) Acetic acid
Last Answer : Diethyl ether
Description : Which of the following compounds is least soluble in water? (a) Glycerol (b) Ethyl alcohol (c) Ethylene glycol (d) Ethyl chloride
Last Answer : Ethyl chloride
Description : 1,2-Ethanediol reacts with anhydrous zinc chloride to form (a) Ethylene (b) Acetaldehyde (c) Acetylene (d) Ethyl chloride
Last Answer : Acetaldehyde