Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Benzene reacts with concentrated HNO3 in the presence of concentrated
H2SO4 to give nitrobenzene. This reaction is an example of
(a) Electrophilic addition
(b) Nucleophilic addition
(c) Electrophilic substitution
(d) Nucleophilic substitution
by

1 Answer

Answer :

Electrophilic substitution
by

Related questions

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition(d) Nucleophilic substitution

Description : Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition (d) Nucleophilic substitution

Last Answer : Nucleophilic addition

Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Description : Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Last Answer : Electrophilic addition

The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Last Answer : a free-radical substitution

The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Last Answer : nucleophilic substitution

Which of the following compounds reacts most rapidly with HNO3/H2SO4? (a) toluene (b) anisole (c) nitrobenzene(d) benzonitrile

Description : Which of the following compounds reacts most rapidly with HNO3/H2SO4? (a) toluene (b) anisole (c) nitrobenzene (d) benzonitrile

Last Answer : anisole

Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Description : Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Last Answer : Nitrobenzene

Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.

Which of the following agents is used in order to make benzene react with concentrated nitric acid to give nitrobenzene? (a) Concentrated H2SO4 (b) FeCl3 catalyst (c) Lindlar's catalyst (d) Ultraviolet light

Description : Which of the following agents is used in order to make benzene react with concentrated nitric acid to give nitrobenzene? (a) Concentrated H2SO4 (b) FeCl3 catalyst (c) Lindlar's catalyst (d) Ultraviolet light

Last Answer : Concentrated H2SO4

Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

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Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Last Answer : nucleophilic addition; free radical addition

Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

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Last Answer : Nucleophilic substitution reactions

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Description : Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Last Answer : (2) Substitution reaction Explanation: The reaction between benzene and chlorine in the presence of a catalyst such as aluminium chloride gives Chlorobenzene. This reaction is an example of electrophilic substitution ... since one of the hydrogen atoms on the ring is replaced by a chlorine atom.

Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Description : Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Last Answer : Substitution reaction

Nitration of nitrobenzene with HNO3/H2SO4 gives : (a) m-dinitrobenzene (b) o-dinitrobenzene (c) p-dinitrobenzene (d) m-nitrobenzenesulfonic acid

Description : Nitration of nitrobenzene with HNO3/H2SO4 gives : (a) m-dinitrobenzene (b) o-dinitrobenzene (c) p-dinitrobenzene (d) m-nitrobenzenesulfonic acid

Last Answer : m-dinitrobenzene

40. Among the fo the one that is most reactive towards electrophilic nitration is: (1) Benzene (2) Benzoic acid (3) Nitrobenzene (4) Toluene

Description : 40. Among the following compounds the one that is most reactive towards electrophilic nitration is: (1) Benzene (2) Benzoic acid (3) Nitrobenzene (4) Toluene

Last Answer : Toluene

Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with acidic KMnO4 solution. (c) on refluxing with concentrated H2SO4 gives a mixture of ortho and para toluenesulfonic acid. (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene

What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

Description : Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

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Benzene reacts with propene in the presence of H2SO4 catalyst to give (a) n-Propylbenzene (b) Benzophenone (c) Cumene (d) Nothing happens

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A compound reacts with steam in the presence of concentrated H2SO4 to give isopropyl alcohol. The compound could be (a) Alkane (b) Alkyne (c) Alkene (d) Allene

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Last Answer : Alkene

BHC (Benzene hexachloride) is made by the chlorination of benzene (A) Which is an addition reaction (B) Which is a substitution reaction (C) In absolute dark (D) In presence of sunlight

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Last Answer : (A) Which is an addition reaction

Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

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Last Answer : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the ... D. A is incorrect but R is correct

How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

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Last Answer : Benzene + Br2/FeBr3

When glycerol is treated with a mixture of concentrated HNO3 + H2SO4, it forms (a) Nitroethane (b) 1-Nitropropane (c) Nitroglycerine (d) 2-Nitropropane

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Last Answer : Nitroglycerine

Benzene undergoes Friedel-Crafts reaction with isopropyl alcohol in the presence of H2SO4 catalyst to give (a) n-Propylbenzene (b) Benzophenone (c) Isopropylbenzene (d) Nothing happens

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Last Answer : Isopropylbenzene

Nitrobenzene reacts with Br2 in the presence of FeCl3 to give(a) o-chloronitrobenzene(b) o-bromonitrobenzene(c) m-chloronitrobenzene(d) m-bromonitrobenzene

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Last Answer : m-bromonitrobenzene

Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

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Last Answer : there is delocalization of electrons

Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Description : Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Last Answer : there is delocalization of electrons

Give the example for electrophilic substitution reaction ?

Description : Give the example for electrophilic substitution reaction ?

Last Answer : The species, which accepts the electrons, are called Electrophilles (or) Electrophilic reagents. When the atom (or) group of atoms present in the organic compound is replaced by another atom (or) group of atoms (electrophilic) is called electrophilic substitution reaction.

2-Propanol reacts with KBr and concentrated H2SO4 to give (a) 1-Bromopropane (b) 1,2-Dibromopropane (c) 2-Bromopropane (d) 2,2-Dibromopropane

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Last Answer : 2-Bromopropane

Benzene reacts with H2 at 150°C at 30 atm in the presence of Ni catalyst to give (a) Cyclohexane (b) Cyclohexene (c) n-Hexane (d) No reaction occurs

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Last Answer : Cyclohexane

Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds of alkynes are higher in energy than the bonds and are thus more reactive. (c) Unlike alkenes, alkynes fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.

Description : Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds ... fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.

Last Answer : Alkynes are generally more reactive than alkenes.

For the COD test of sewage, organic matter is oxidised by K2Cr2O7 in the presence of A. H2SO4 B. HNO3 C. HCl D. None of these

Description : For the COD test of sewage, organic matter is oxidised by K2Cr2O7 in the presence of A. H2SO4 B. HNO3 C. HCl D. None of these

Last Answer : ANS: A

Ethyl alcohol reacts with concentrated H2SO4 at 140°C to form (a) Acetone (b) Ethylene (c) Diethyl ether (d) Acetic acid

Description : Ethyl alcohol reacts with concentrated H2SO4 at 140°C to form (a) Acetone (b) Ethylene (c) Diethyl ether (d) Acetic acid

Last Answer : Diethyl ether

Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Description : Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Last Answer : the reduction of nitrobenzene with Sn/HCl

Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : (3) Elimination Explanation: Benzene can not undergo Elimination reaction.

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : Elimination

Phenol is an ortho-para director because the hydroxyl group : (a) donates electrons that increase electron density at ortho and para positions favoring nucleophilic attack. (b) donates electrons that increase electron density at ortho and para positions favoring electrophilic attack. (c) donates electrons to the ortho and para positions and attracts electrons away from meta positions favoring nucleophilic attack of the ring. (d) donates electrons to the ortho and para positions and attracts electrons away from meta positions favoring electrophilic attack on the ring.

Description : Phenol is an ortho-para director because the hydroxyl group : (a) donates electrons that increase electron density at ortho and para positions favoring nucleophilic attack. (b) donates ... para positions and attracts electrons away from meta positions favoring electrophilic attack on the ring.

Last Answer : donates electrons that increase electron density at ortho and para positions favoring electrophilic attack.

Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Description : Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Last Answer : can be oxidized with KMnO4 to give benzoic acid

Naphthalene undergoes nitration with HNO3/H2SO4 at 60°C to give mainly (a) 1-Nitronaphthalene (b) 1,2-Dinitronaphthalene (c) 2-Nitronaphthalene (d) 1,5-Dinitronaphthalene

Description : Naphthalene undergoes nitration with HNO3/H2SO4 at 60°C to give mainly (a) 1-Nitronaphthalene (b) 1,2-Dinitronaphthalene (c) 2-Nitronaphthalene (d) 1,5-Dinitronaphthalene

Last Answer : 1-Nitronaphthalene

Quinoline undergoes nucleophilic substitution on heating with NaNH2 to give (a) 2-Aminoquinoline (b) 4-Aminoquinoline (c) 3-Aminoquinoline (d) 8-Aminoquinoline

Description : Quinoline undergoes nucleophilic substitution on heating with NaNH2 to give (a) 2-Aminoquinoline (b) 4-Aminoquinoline (c) 3-Aminoquinoline (d) 8-Aminoquinoline

Last Answer : 2-Aminoquinoline

In the following compounds, anisole (I), benzene (II) and nitrobenzene (III), the ease of reaction with electrophiles is:

Description : In the following compounds, anisole (I), benzene (II) and nitrobenzene (III), the ease of reaction with electrophiles is:

Last Answer : In the following compounds, anisole (I), benzene (II) and nitrobenzene (III), the ease of reaction ... . `IIIgtIIgtI` C. `IIgtIgtIII` D. `IgtIIgtIII`

Which of the following will undergo substitution in the ortho and para positions rather than in the meta position? (a) Nitrobenzene (b) Benzoic acid (c) Acetanilide (d) Benzaldehyde

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Last Answer : Acetanilide

A compound, C4H6, reacts with bromine and forms a white precipitate with ammoniacal silver nitrate solution. It reacts with dilute H2SO4 in the presence of mercuric sulfate to form 2-butanone. The compound could be (a) 1-Butyne (b) 1-Butene (c) 2-Butyne (d) 2-Butene

Description : A compound, C4H6, reacts with bromine and forms a white precipitate with ammoniacal silver nitrate solution. It reacts with dilute H2SO4 in the presence of mercuric sulfate to form 2-butanone. The compound could be (a) 1-Butyne (b) 1-Butene (c) 2-Butyne (d) 2-Butene

Last Answer : 1-Butyne

Propyne reacts with aqueous H2SO4 in the presence of HgSO4 to form (a) acetone (b) 1-propanol (c) acetaldehyde (d) 2-propanol

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Last Answer : acetone