Which of the following equations is used for the prediction of activity co-efficient from experiments? (A) Van Laar equation (B) Margules equation (C) Wilson's equation (D) All (A), (B) and (C)

Which of the following equations is used for the prediction of activity co-efficient from experiments?
(A) Van Laar equation
(B) Margules equation
(C) Wilson's equation
(D) All (A), (B) and (C)
by

1 Answer

Answer :

(D) All (A), (B) and (C)
by

Related questions

________ Equation predicts the activity co-efficient from experimental data. (A) Lewis-Randall (B) Margules (C) Van Laar (D) Both (B) & (C)

Description : ________ Equation predicts the activity co-efficient from experimental data. (A) Lewis-Randall (B) Margules (C) Van Laar (D) Both (B) & (C)

Last Answer : (D) Both (B) & (C)

The relation connecting the fugacities of various components in a solution with one another and to composition at constant temperature and pressure is called the __________ equation. (A) Gibbs-Duhem (B) Van Laar (C) Gibbs-Helmholtz (D) Margules

Description : The relation connecting the fugacities of various components in a solution with one another and to composition at constant temperature and pressure is called the __________ equation. (A) Gibbs-Duhem (B) Van Laar (C) Gibbs-Helmholtz (D) Margules

Last Answer : (A) Gibbs-Duhem

Van Laar equation deals with the activity co-efficients in (A) Binary solutions (B) Ternary solutions (C) Azeotropic mixture only (D) None of these

Description : Van Laar equation deals with the activity co-efficients in (A) Binary solutions (B) Ternary solutions (C) Azeotropic mixture only (D) None of these

Last Answer : (A) Binary solutions

If the vapour pressure at two temperatures of a solid phase in equilibrium with its liquid phase are known, then the latent heat of fusion can be calculated by the (A) Maxwell's equation (B) Clausius-Clapeyron Equation (C) Van Laar equation (D) Nernst Heat Theorem

Description : If the vapour pressure at two temperatures of a solid phase in equilibrium with its liquid phase are known, then the latent heat of fusion can be calculated by the (A) Maxwell's equation (B) Clausius-Clapeyron Equation (C) Van Laar equation (D) Nernst Heat Theorem

Last Answer : B) Clausius-Clapeyron Equation

A solute distributes itself between two non-miscible solvents in contact with each other in such a way that, at a constant temperature, the ratio of its concentrations in two layers is constant, irrespective of its total amount". This is (A) The distribution law (B) Followed from Margules equation (C) A corollary of Henry's law (D) None of these

Description : A solute distributes itself between two non-miscible solvents in contact with each other in such a way that, at a constant temperature, the ratio of its concentrations in two layers is constant, irrespective of ... B) Followed from Margules equation (C) A corollary of Henry's law (D) None of these

Last Answer : (A) The distribution law

Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Description : Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Last Answer : (D) All (A), (B), and (C)

The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12

Description : The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12

Last Answer : (A) A . x22

Which of the following equations as suggested by Colebrook and White gives the increase in roughness of a new surface (ε0 ) with age/time (t) (where, ε = roughness of the surface after time't'. α = a co-efficient to be experimentally determined)? (A) ε = ε0 + α.t (B) ε = ε0 + α.t 2 (C) ε = ε0 + α.t 3 (D) ε = ε0 + α.t

Description : Which of the following equations as suggested by Colebrook and White gives the increase in roughness of a new surface (ε0 ) with age/time (t) (where, ε = roughness of the surface after time't'. α = a co-efficient to be experimentally determined ... ε = ε0 + α.t 2 (C) ε = ε0 + α.t 3 (D) ε = ε0 + α.t

Last Answer : (A) ε = ε0 + α.t

Which of the following is true for Virial equation of state? (A) Virial co-efficients are universal constants (B) Virial co-efficients 'B' represents three body interactions (C) Virial co-efficients are function of temperature only (D) For some gases, Virial equations and ideal gas equations are the same

Description : Which of the following is true for Virial equation of state? (A) Virial co-efficients are universal constants (B) Virial co-efficients 'B' represents three body interactions (C) Virial co-efficients ... of temperature only (D) For some gases, Virial equations and ideal gas equations are the same

Last Answer : (C) Virial co-efficients are function of temperature only

What is the value of ln y (where y = activity co-efficient) for ideal gases? (A) Zero (B) Unity (C) Infinity (D) Negative

Description : What is the value of ln y (where y = activity co-efficient) for ideal gases? (A) Zero (B) Unity (C) Infinity (D) Negative

Last Answer : (A) Zero

For an ideal solution, the value of activity co-efficient is (A) 0 (B) 1 (C) < 1 (D) > 1

Description : For an ideal solution, the value of activity co-efficient is (A) 0 (B) 1 (C) < 1 (D) > 1

Last Answer : (B) 1

Partial molar free energy of an element A in solution is same as its (A) Chemical potential (B) Activity (C) Fugacity (D) Activity co-efficient

Description : Partial molar free energy of an element A in solution is same as its (A) Chemical potential (B) Activity (C) Fugacity (D) Activity co-efficient

Last Answer : (A) Chemical potential

Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature. (A) Decreases (B) Increases (C) Remains constant

Description : Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature. (A) Decreases (B) Increases (C) Remains constant

Last Answer : (B) Increases

At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is (A) 1.572 (B) 1.9398 (C) 3.389

Description : At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole ... respectively. Activity co-efficient of methanol is (A) 1.572 (B) 1.9398 (C) 3.389

Last Answer : (A) 1.572

For an ideal gas, the activity co-efficient is (A) Directly proportional to pressure (B) Inversely proportional to pressure (C) Unity at all pressures (D) None of these

Description : For an ideal gas, the activity co-efficient is (A) Directly proportional to pressure (B) Inversely proportional to pressure (C) Unity at all pressures (D) None of these

Last Answer : (C) Unity at all pressures

In a homogeneous solution, the activity co-efficient of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Description : In a homogeneous solution, the activity co-efficient of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

For an ideal liquid solution, which of the following is unity? (A) Activity (B) Fugacity (C) Activity co-efficient (D) Fugacity co-efficient

Description : For an ideal liquid solution, which of the following is unity? (A) Activity (B) Fugacity (C) Activity co-efficient (D) Fugacity co-efficient

Last Answer : (C) Activity co-efficient

Which of the following is not affected by temperature changes? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) None of these

Description : Which of the following is not affected by temperature changes? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) None of these

Last Answer : (D) None of these

Pick out the wrong statement. (A) Activity co-efficient is dimensionless. (B) In case of an ideal gas, the fugacity is equal to its pressure. (C) In a mixture of ideal gases, the fugacity of a component is equal to the partial pressure of the component. (D) The fugacity co-efficient is zero for an ideal gas

Description : Pick out the wrong statement. (A) Activity co-efficient is dimensionless. (B) In case of an ideal gas, the fugacity is equal to its pressure. (C) In a mixture of ideal gases, the fugacity of ... equal to the partial pressure of the component. (D) The fugacity co-efficient is zero for an ideal gas

Last Answer : (D) The fugacity co-efficient is zero for an ideal gas

A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of (A) Temperature only (B) Temperature and pressure only (C) Temperature, pressure and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Last Answer : (C) Temperature, pressure and liquid composition xi only

Which of the following is affected by the temperature? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) All (A), (B) & (C)

Description : Which of the following is affected by the temperature? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) All (A), (B) & (C)

Last Answer : (D) All (A), (B) & (C)

Activity co-efficient is a measure of the (A) Departure from ideal solution behaviour (B) Departure of gas phase from ideal gas law (C) Vapour pressure of liquid (D) None of these

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The activity co-efficient of the solute in a dilute solution (A) Decreases with the increase of concentration of the solute (B) Increases with the increase of concentration of the solute (C) Remains constant (D) Is unity at infinite dilution

Description : The activity co-efficient of the solute in a dilute solution (A) Decreases with the increase of concentration of the solute (B) Increases with the increase of concentration of the solute (C) Remains constant (D) Is unity at infinite dilution

Last Answer : (C) Remains constant

Dephosphorization of molten pig iron is favoured by (A) Oxidising and basic slag (B) Reducing and basic slag (C) High activity co-efficient of phosphorous in metal (D) Oxidising and neutral slag

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Heat transfer co-efficient equation for forced convection, Nu = 0.023 Re 0.8 . Pr n , is not valid, if the value of (A) n = 0.4 is used for heating (B) n = 0.3 is used for cooling (C) Reynolds number for the flow involved is > 10000 (D) Reynolds number for the flow involved is < 2100

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Last Answer : (D) Reynolds number for the flow involved is < 2100

Pick out the wrong statement. (A) The shear stress at the pipe (dia = D, length = L) wall in case of laminar flow of Newtonian fluids is (D/4L). ∆p (B) In the equation, T. gc = k. (du/dy) n the value of 'n' for pseudoplastic and Dilatant fluid are < 1 and >1 respectively (C) Shear stress for Newtonian fluid is proportional to the rate of shear in the direction perpendicular to motion (D) With increase in the Mach number >0.6, the drag co-efficient decreases in case of compressible fluids

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Internal energy of a gas obeying Van-Der-Waals equation of state, [p + (a/v2)] (V - b) = RT, depends upon its (A) Pressure & temperature (B) Pressure & specific volume (C) Temperature & specific volume (D) Temperature only

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Last Answer : (i) If we substitute x = 4, we get L.H.S = x + 4 = 4 + 4 = 8 and R.H.S = 2x = 2 x 4 = 8 ∴ L.H.S = R.H.S. Hence, 4 is a solution of x + 4 = 2x. (ii) If we substitute y = 3, we get L.H.S = y - 7 = 3 - ... S = 2u + 7 = 2(5) + 7 = 10 + 7 = 17 ∴ L.H.S = R.H.S. Hence , 5 is a solution of 3u + 2 = 2u + 7

In the following equations , verify whether the given value of the variable is a solution of the equation : -Maths 9th

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Last Answer : (i) f we substitute x = √2, we get L.H.S. = 2x - 3 = 2(√2) - 3 = 2√2 - 3 and R.H.S = x / 2 - 2 = √2 / 2 - 2 ∴ L.H.S. ≠ R.H.S . Hence, √2 is not a solution of 2x - 3 = x / 2 - 2 (ii) If we substitute ... = 7 ∴ L.H.S. ≠ R.H.S . Hence , -1 is not a solution of 24 - 3 (u - 2) = u + 8

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Last Answer : (i) If we substitute x = 4, we get L.H.S = x + 4 = 4 + 4 = 8 and R.H.S = 2x = 2 x 4 = 8 ∴ L.H.S = R.H.S. Hence, 4 is a solution of x + 4 = 2x. (ii) If we substitute y = 3, we get L.H.S = y - 7 = 3 - ... S = 2u + 7 = 2(5) + 7 = 10 + 7 = 17 ∴ L.H.S = R.H.S. Hence , 5 is a solution of 3u + 2 = 2u + 7

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