For an ideal liquid solution, which of the following is unity? (A) Activity (B) Fugacity (C) Activity co-efficient (D) Fugacity co-efficient

For an ideal liquid solution, which of the following is unity? (A) Activity
(B) Fugacity
(C) Activity co-efficient
(D) Fugacity co-efficient
by

1 Answer

Answer :

(C) Activity co-efficient
by

Related questions

Pick out the wrong statement. (A) Activity co-efficient is dimensionless. (B) In case of an ideal gas, the fugacity is equal to its pressure. (C) In a mixture of ideal gases, the fugacity of a component is equal to the partial pressure of the component. (D) The fugacity co-efficient is zero for an ideal gas

Description : Pick out the wrong statement. (A) Activity co-efficient is dimensionless. (B) In case of an ideal gas, the fugacity is equal to its pressure. (C) In a mixture of ideal gases, the fugacity of ... equal to the partial pressure of the component. (D) The fugacity co-efficient is zero for an ideal gas

Last Answer : (D) The fugacity co-efficient is zero for an ideal gas

A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of (A) Temperature only (B) Temperature and pressure only (C) Temperature, pressure and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Last Answer : (C) Temperature, pressure and liquid composition xi only

Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Description : Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Last Answer : (D) All (A), (B), and (C)

Partial molar free energy of an element A in solution is same as its (A) Chemical potential (B) Activity (C) Fugacity (D) Activity co-efficient

Description : Partial molar free energy of an element A in solution is same as its (A) Chemical potential (B) Activity (C) Fugacity (D) Activity co-efficient

Last Answer : (A) Chemical potential

What is the value of ln y (where y = activity co-efficient) for ideal gases? (A) Zero (B) Unity (C) Infinity (D) Negative

Description : What is the value of ln y (where y = activity co-efficient) for ideal gases? (A) Zero (B) Unity (C) Infinity (D) Negative

Last Answer : (A) Zero

For an ideal gas, the activity co-efficient is (A) Directly proportional to pressure (B) Inversely proportional to pressure (C) Unity at all pressures (D) None of these

Description : For an ideal gas, the activity co-efficient is (A) Directly proportional to pressure (B) Inversely proportional to pressure (C) Unity at all pressures (D) None of these

Last Answer : (C) Unity at all pressures

Activity co-efficient is a measure of the (A) Departure from ideal solution behaviour (B) Departure of gas phase from ideal gas law (C) Vapour pressure of liquid (D) None of these

Description : Activity co-efficient is a measure of the (A) Departure from ideal solution behaviour (B) Departure of gas phase from ideal gas law (C) Vapour pressure of liquid (D) None of these

Last Answer : (A) Departure from ideal solution behaviour

Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature. (A) Decreases (B) Increases (C) Remains constant

Description : Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature. (A) Decreases (B) Increases (C) Remains constant

Last Answer : (B) Increases

Which of the following is not affected by temperature changes? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) None of these

Description : Which of the following is not affected by temperature changes? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) None of these

Last Answer : (D) None of these

Which of the following is affected by the temperature? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) All (A), (B) & (C)

Description : Which of the following is affected by the temperature? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) All (A), (B) & (C)

Last Answer : (D) All (A), (B) & (C)

The activity co-efficient of the solute in a dilute solution (A) Decreases with the increase of concentration of the solute (B) Increases with the increase of concentration of the solute (C) Remains constant (D) Is unity at infinite dilution

Description : The activity co-efficient of the solute in a dilute solution (A) Decreases with the increase of concentration of the solute (B) Increases with the increase of concentration of the solute (C) Remains constant (D) Is unity at infinite dilution

Last Answer : (C) Remains constant

In an ideal solution, the activity of a component equals its (A) Mole fraction (B) Fugacity at the same temperature and pressure (C) Partial pressure (D) None of these

Description : In an ideal solution, the activity of a component equals its (A) Mole fraction (B) Fugacity at the same temperature and pressure (C) Partial pressure (D) None of these

Last Answer : (A) Mole fraction

The standard state of a gas (at a given temperature) is the state in which fugacity is equal to (A) Unity (B) Activity (C) Both (A) & (B) (D) Neither (A) nor (B)

Description : The standard state of a gas (at a given temperature) is the state in which fugacity is equal to (A) Unity (B) Activity (C) Both (A) & (B) (D) Neither (A) nor (B)

Last Answer : (C) Both (A) & (B)

For an ideal solution, the value of activity co-efficient is (A) 0 (B) 1 (C) < 1 (D) > 1

Description : For an ideal solution, the value of activity co-efficient is (A) 0 (B) 1 (C) < 1 (D) > 1

Last Answer : (B) 1

With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure (A) Increases (B) Decreases (C) Remain same (D) Decreases linearly

Description : With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure (A) Increases (B) Decreases (C) Remain same (D) Decreases linearly

Last Answer : (A) Increases

At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is (A) 1.572 (B) 1.9398 (C) 3.389

Description : At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole ... respectively. Activity co-efficient of methanol is (A) 1.572 (B) 1.9398 (C) 3.389

Last Answer : (A) 1.572

Pick out the wrong statement. (A) In the McCabe-Thiele diagram for binary distillation, vertical feed line represents saturated liquid feed and horizontal feed line represents saturated vapour feed (B) In small columns, local efficiency is larger than Murphree efficiency; in large columns local efficiency is smaller than Murphree efficiency (C) For Laminar flow over a plate of length L, the local mass transfer co￾efficient at a distance L from the leading edge is 1.5 × 10 -2m/s. Then the average mass transfer co-efficient for the plate is 2 × 10 -2m/s (D) The concentration and hydrodynamic boundary layers over a flat plate are of equal thickness, if Schmidt number is equal to unity

Description : Pick out the wrong statement. (A) In the McCabe-Thiele diagram for binary distillation, vertical feed line represents saturated liquid feed and horizontal feed line represents saturated vapour feed (B) In ... layers over a flat plate are of equal thickness, if Schmidt number is equal to unity

Last Answer : (C) For Laminar flow over a plate of length L, the local mass transfer co￾efficient at a distance L from the leading edge is 1.5 × 10 -2m/s. Then the average mass transfer co-efficient for the plate is 2 × 10 -2m/s

Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature __________ as its mole fraction increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant

Description : Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and ... increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant

Last Answer : (C) Increases

The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12

Description : The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12

Last Answer : (A) A . x22

In a homogeneous solution, the activity co-efficient of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Description : In a homogeneous solution, the activity co-efficient of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Pick out the correct statement pertaining to Venturimeter. (A) A Venturimeter with a fixed pressure drop discharges more, when the flow is vertically downward, than when the flow is vertically upward (B) The co-efficient of contraction of a Venturimeter is always unity (C) For a fixed pressure drop, the discharge of a gas through a Venturimeter is greater, when compressibility is taken into account, than when it is neglected (D) None of these

Description : Pick out the correct statement pertaining to Venturimeter. (A) A Venturimeter with a fixed pressure drop discharges more, when the flow is vertically downward, than when the flow is vertically upward (B ... , when compressibility is taken into account, than when it is neglected (D) None of these

Last Answer : (D) None of these

In an ideal gas mixture, fugacity of a species is equal to its (A) Vapor pressure (B) Partial pressure (C) Chemical potential (D) None of these

Description : In an ideal gas mixture, fugacity of a species is equal to its (A) Vapor pressure (B) Partial pressure (C) Chemical potential (D) None of these

Last Answer : (B) Partial pressure

Fugacity is a measure of the (A) Escaping tendencies of the same substance in different phases of a system (B) Relative volatility of a mixture of two miscible liquids (C) Behaviour of ideal gases (D) None of these

Description : Fugacity is a measure of the (A) Escaping tendencies of the same substance in different phases of a system (B) Relative volatility of a mixture of two miscible liquids (C) Behaviour of ideal gases (D) None of these

Last Answer : (A) Escaping tendencies of the same substance in different phases of a system

Fugacity and pressure are numerically not equal for the gases (A) At low temperature and high pressure (B) At standard state (C) Both (A) and (B) (D) In ideal state

Description : Fugacity and pressure are numerically not equal for the gases (A) At low temperature and high pressure (B) At standard state (C) Both (A) and (B) (D) In ideal state

Last Answer : (C) Both (A) and (B)

Fugacity and pressure are numerically equal, when the gas is (A) In standard state (B) At high pressure (C) At low temperature (D) In ideal state

Description : Fugacity and pressure are numerically equal, when the gas is (A) In standard state (B) At high pressure (C) At low temperature (D) In ideal state

Last Answer : (D) In ideal state

The overall mass transfer co-efficient for the absorption of SO2 in air with dilute NaOH solution can be increased substantially by (A) Increasing the gas film co-efficient(B) Increasing the liquid film co-efficient(C) Increasing the total pressure(D) Decreasing the total pressure

Description : The overall mass transfer co-efficient for the absorption of SO2 in air with dilute NaOH solution can be increased substantially by (A) Increasing the gas film co-efficient (B) Increasing the liquid film co-efficient (C) Increasing the total pressure (D) Decreasing the total pressure

Last Answer : (A) Increasing the gas film co-efficient

For a given substance at a specified temperature, activity is __________ to fugacity. (A) Directly proportional (B) Inversely proportional (C) Equal (D) None of these

Description : For a given substance at a specified temperature, activity is __________ to fugacity. (A) Directly proportional (B) Inversely proportional (C) Equal (D) None of these

Last Answer : (A) Directly proportional

The reflection co-efficient at the open circuited end of a transmission line. (a) zero (b) infinity (c) unity (d) none of the above

Description : The reflection co-efficient at the open circuited end of a transmission line. (a) zero (b) infinity (c) unity (d) none of the above

Last Answer : (c) unity

For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be (A) 6738.9 (B) 6753.5 (C) 7058.3 (D) 9000

Description : For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be (A) 6738.9 (B) 6753.5 (C) 7058.3 (D) 9000

Last Answer : (B) 6753.5

In a homogeneous solution, the fugacity of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Description : In a homogeneous solution, the fugacity of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

An ideal coolant for a nuclear reactor should (A) Be a good absorber of neutrons (B) Be capable of attaining high temperature, only when it is pressurised (C) Have high density, but low heat transfer co-efficient (D) Be free from radiation damage and non-corrosive

Description : An ideal coolant for a nuclear reactor should (A) Be a good absorber of neutrons (B) Be capable of attaining high temperature, only when it is pressurised (C) Have high density, but low heat transfer co-efficient (D) Be free from radiation damage and non-corrosive

Last Answer : (D) Be free from radiation damage and non-corrosive

The expression, nCv(T2- T1), is for the __________ of an ideal gas. (A) Work done under adiabatic condition (B) Co-efficient of thermal expansion (C) Compressibility (D) None of these

Description : The expression, nCv(T2- T1), is for the __________ of an ideal gas. (A) Work done under adiabatic condition (B) Co-efficient of thermal expansion (C) Compressibility (D) None of these

Last Answer : (A) Work done under adiabatic condition

What is the value of Joule-Thomson co-efficient for an ideal gas? (A) +ve (B) -ve (C) 0 (D) ∞

Description : What is the value of Joule-Thomson co-efficient for an ideal gas? (A) +ve (B) -ve (C) 0 (D) ∞

Last Answer : (C) 0

The expression, nRT ln(P1/P2), is for the __________of an ideal gas. (A) Compressibility (B) Work done under adiabatic condition (C) Work done under isothermal condition (D) Co-efficient of thermal expansion

Description : The expression, nRT ln(P1/P2), is for the __________of an ideal gas. (A) Compressibility (B) Work done under adiabatic condition (C) Work done under isothermal condition (D) Co-efficient of thermal expansion

Last Answer : C) Work done under isothermal condition

While dissolving a gas into a liquid at a constant temperature, the ratio of the concentration of the gas in the solution phase and in the gaseous phase is (A) Infinity (B) Unity (C) Constant (D) Negative

Description : While dissolving a gas into a liquid at a constant temperature, the ratio of the concentration of the gas in the solution phase and in the gaseous phase is (A) Infinity (B) Unity (C) Constant (D) Negative

Last Answer : (C) Constant

________ Equation predicts the activity co-efficient from experimental data. (A) Lewis-Randall (B) Margules (C) Van Laar (D) Both (B) & (C)

Description : ________ Equation predicts the activity co-efficient from experimental data. (A) Lewis-Randall (B) Margules (C) Van Laar (D) Both (B) & (C)

Last Answer : (D) Both (B) & (C)

Which of the following equations is used for the prediction of activity co-efficient from experiments? (A) Van Laar equation (B) Margules equation (C) Wilson's equation (D) All (A), (B) and (C)

Description : Which of the following equations is used for the prediction of activity co-efficient from experiments? (A) Van Laar equation (B) Margules equation (C) Wilson's equation (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Dephosphorization of molten pig iron is favoured by (A) Oxidising and basic slag (B) Reducing and basic slag (C) High activity co-efficient of phosphorous in metal (D) Oxidising and neutral slag

Description : Dephosphorization of molten pig iron is favoured by (A) Oxidising and basic slag (B) Reducing and basic slag (C) High activity co-efficient of phosphorous in metal (D) Oxidising and neutral slag

Last Answer : Option B

The wetted wall tower is used to determine (A) Individual mass transfer co-efficient (M.T.C.) in gaseous system (B) M.T.C. of individual components in a liquid-liquid system (C) M.T.C. of liquid in liquid-gas system (D) The overall M.T.C. of the system

Description : The wetted wall tower is used to determine (A) Individual mass transfer co-efficient (M.T.C.) in gaseous system (B) M.T.C. of individual components in a liquid-liquid system (C) M.T.C. of liquid in liquid-gas system (D) The overall M.T.C. of the system

Last Answer : (A) Individual mass transfer co-efficient (M.T.C.) in gaseous system

For absorbing a sparingly soluble gas in a liquid (A) Gas side mass transfer co-efficient should be increased (B) Liquid side mass transfer co-efficient should be increased (C) Liquid side mass transfer co-efficient should be decreased (D) Mass transfer co-efficient must be kept constant

Description : For absorbing a sparingly soluble gas in a liquid (A) Gas side mass transfer co-efficient should be increased (B) Liquid side mass transfer co-efficient should be increased (C) Liquid side mass transfer co-efficient should be decreased (D) Mass transfer co-efficient must be kept constant

Last Answer : (B) Liquid side mass transfer co-efficient should be increased

Mass transfer co-efficient of liquid is (A) Affected more by temperature than that for gases (B) Affected much less by temperature than that for gases

Description : Mass transfer co-efficient of liquid is (A) Affected more by temperature than that for gases (B) Affected much less by temperature than that for gases

Last Answer : (A) Affected more by temperature than that for gases

The solvent used in liquid-liquid extraction should have __________ less than one. (A) Selectivity (B) Distribution co-efficient(C) Both (A) and (B)(D) Neither (A) nor (B)

Description : The solvent used in liquid-liquid extraction should have __________ less than one. (A) Selectivity (B) Distribution co-efficient (C) Both (A) and (B) (D) Neither (A) nor (B)

Last Answer : (D) Neither (A) nor (B)

The diffusion co-efficient in m2 /s. of acetic acid in benzene (liquid in liquid) is (A) 2.09 × 10 -4 (B) 2.09 × 10 -5 (C) 2.09 × 10 -9 (D) 2.09 × 10 -12

Description : The diffusion co-efficient in m2 /s. of acetic acid in benzene (liquid in liquid) is (A) 2.09 × 10 -4 (B) 2.09 × 10 -5 (C) 2.09 × 10 -9 (D) 2.09 × 10 -12

Last Answer : (A) 2.09 × 10 -4 (B) 2.09 × 10 -5

Pick out the wrong statement. (A) Mass transfer co-efficient does not account for gas-liquid diffusion (B) Diffusion co-efficient and mass transfer co-efficient are not same in any mass transfer operation

Description : Pick out the wrong statement. (A) Mass transfer co-efficient does not account for gas-liquid diffusion (B) Diffusion co-efficient and mass transfer co-efficient are not same in any mass transfer operation

Last Answer : (A) Mass transfer co-efficient does not account for gas-liquid diffusion

In a vapor-liquid contacting equipment, the overall gas phase mass transfer co-efficient (M.T.C), KG is related to individual co-efficients (KG and KL ) as (A) KG = 1/KG + m/KL (B) 1/KG = 1/KG + m/KL (C) 1/KG = 1/KL + m/KG (D) KG = 1/KL + m/KG

Description : In a vapor-liquid contacting equipment, the overall gas phase mass transfer co-efficient (M.T.C), KG is related to individual co-efficients (KG and KL ) as (A) KG = 1/KG + m/KL (B) 1/KG = 1/KG + m/KL (C) 1/KG = 1/KL + m/KG (D) KG = 1/KL + m/KG

Last Answer : (B) 1/KG = 1/KG + m/KL

The Reynolds number of the liquid was increased 100 fold for a laminar falling film used for gas-liquid contacting. Assuming penetrating theory is applicable, the fold increase in the mass transfer co-efficient (Kc ) for the same system is(A) 100(B) 10(C) 5(D) 1.

Description : The Reynolds number of the liquid was increased 100 fold for a laminar falling film used for gas-liquid contacting. Assuming penetrating theory is applicable, the fold increase in the mass transfer co-efficient (Kc ) for the same system is. (A) 100 (B) 10 (C) 5 (D) 1

Last Answer : (B) 10

For absorbing a sparingly soluble gas in a liquid, the (A) Gas side co-efficient should be increased(B) Liquid side coefficient should be increased(C) Gas side co-efficient should be decreased(D) Liquid side co-efficient should be decreased

Description : For absorbing a sparingly soluble gas in a liquid, the (A) Gas side co-efficient should be increased (B) Liquid side coefficient should be increased (C) Gas side co-efficient should be decreased (D) Liquid side co-efficient should be decreased

Last Answer : (B) Liquid side coefficient should be increased

The mass transfer co-efficient for a solid sphere of radius 'a' dissolving in a large volume of quiescent liquid, in which ‘D’ is the diffusivity of solute, is (A) D/a (B) D/2a (C) Proportional to √D (D) Dependent on the Reynolds number

Description : The mass transfer co-efficient for a solid sphere of radius 'a' dissolving in a large volume of quiescent liquid, in which ‘D’ is the diffusivity of solute, is (A) D/a (B) D/2a (C) Proportional to √D (D) Dependent on the Reynolds number

Last Answer : (D) Dependent on the Reynolds number

Pick out the wrong statement. (A) The condensing film co-efficient is about 3 times lower for vertical condenser as compared to the equivalent horizontal condenser for identical situation (B) Film co-efficient for vaporisation decreases as a result of vapor binding (C) In industrial practice, sub-cooling of condensate is required, when thecondensate is a volatile liquid and is to be transferred for storage(D) Overall heat transfer co-efficient in a heat exchanger is controlled by thevalue of the film co-efficient, which is higher

Description : Pick out the wrong statement. (A) The condensing film co-efficient is about 3 times lower for vertical condenser as compared to the equivalent horizontal condenser for identical situation ( ... in a heat exchanger is controlled by the value of the film co-efficient, which is higher

Last Answer : (D) Overall heat transfer co-efficient in a heat exchanger is controlled by the value of the film co-efficient, which is higher

Double pipe heat exchangers are preferably useful, when (A) High viscosity liquid is to be cooled (B) Requirement of heat transfer area is low (C) Overall heat transfer co-efficient is very high (D) A corrosive liquid is to be heated

Description : Double pipe heat exchangers are preferably useful, when (A) High viscosity liquid is to be cooled (B) Requirement of heat transfer area is low (C) Overall heat transfer co-efficient is very high (D) A corrosive liquid is to be heated

Last Answer : (B) Requirement of heat transfer area is low