Which of the following is not a nucleophile? (a) NH3 (b) HSO3– (c) AlCl3 (d) HO–

Which of the following is not a nucleophile?
(a) NH3
(b) HSO3–
(c) AlCl3
(d) HO–
by

1 Answer

Answer :

AlCl3
by

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Description : What is Ca(HSO3)2?

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Out of (a) 1 M CaCl2 (b) 1 M AlCl3 which aqueous soln. will show max. vapour pressure at 300 K ?

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Last Answer : (a) 1 M CaCl3 , if we assume 100% dissociation, i for CaCl2 = 3 and AlCl3 = 4 and relative lowering of V. P. is directly proportional to i.

Iodobenzene can be prepared by (a) treating chlorobenzene with I2 using FeCl3 catalyst. (b) treating phenol with I2 in NaOH solution. (c) treating benzenediazonium chloride with KI (d) treating benzene with CH3I using AlCl3 catalyst

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Toluene reacts with chlorine in the presence of AlCl3 to give (a) o-Chlorotoluene (b) o- plus p-Chlorotoluene (c) m-Chlorotoluene (d) o- plus m-Chlorotoluene

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Last Answer : Chlorine in the presence of uv light

Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with acidic KMnO4 solution. (c) on refluxing with concentrated H2SO4 gives a mixture of ortho and para toluenesulfonic acid. (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

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Why cyanide ion act as ambident nucleophile ?

Description : Why cyanide ion act as ambident nucleophile ?

Last Answer : Ans.---- Cyanide ion can link through either carbon or nitrogen, therefore it is an ambident nuclophile.

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

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Last Answer : The addition product is a frequently observed minor product.

Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

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Which of the following factors has no effect on the rate of SN1 reactions? (a) the nature of the alkyl halide (b) the nature of the leaving group (c) the concentration of the alkyl halide (d) the concentration of the nucleophile

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Which of the following is the rate law for SN1 mechanisms? (a) Rate = k[Alkyl Halide] [Nucleophile] (b) Rate = k[Nucleophile] (c) Rate = k[Alkyl Halide](d) Rate = k1[Alkyl Halide] + k2[Nucleophile]

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