Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction
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(2) Substitution reaction Explanation: The reaction between benzene and chlorine in the presence of a catalyst such as aluminium chloride gives Chlorobenzene. This reaction is an example of electrophilic substitution reaction since one of the hydrogen atoms on the ring is replaced by a chlorine atom.
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Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Description : Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Last Answer : Substitution reaction

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : (3) Elimination Explanation: Benzene can not undergo Elimination reaction.

Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo : (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : Elimination

What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

BHC (Benzene hexachloride) is made by the chlorination of benzene (A) Which is an addition reaction (B) Which is a substitution reaction (C) In absolute dark (D) In presence of sunlight

Description : BHC (Benzene hexachloride) is made by the chlorination of benzene (A) Which is an addition reaction (B) Which is a substitution reaction (C) In absolute dark (D) In presence of sunlight

Last Answer : (A) Which is an addition reaction

What is the major organic product of the reaction between benzene and isobutyl chloride in the presence of AlCl3? (a) tert-butylbenzene (b) isobutylbenzene (c) n-butylbenzene (d) chlorobenzene

Description : What is the major organic product of the reaction between benzene and isobutyl chloride in the presence of AlCl3? (a) tert-butylbenzene (b) isobutylbenzene (c) n-butylbenzene (d) chlorobenzene

Last Answer : tert-butylbenzene

Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Description : Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Last Answer : there is delocalization of electrons

Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Description : Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Last Answer : there is delocalization of electrons

Benzene reacts with acetic anhydride in the presence of AlCl3 to form (a) Acetophenone (b) Benzophenone (c) Phenylacetic acid (d) Phenyl acetate

Description : Benzene reacts with acetic anhydride in the presence of AlCl3 to form (a) Acetophenone (b) Benzophenone (c) Phenylacetic acid (d) Phenyl acetate

Last Answer : Acetophenone

Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with acidic KMnO4 solution. (c) on refluxing with concentrated H2SO4 gives a mixture of ortho and para toluenesulfonic acid. (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Iodobenzene can be prepared by (a) treating chlorobenzene with I2 using FeCl3 catalyst. (b) treating phenol with I2 in NaOH solution. (c) treating benzenediazonium chloride with KI (d) treating benzene with CH3I using AlCl3 catalyst

Description : Iodobenzene can be prepared by (a) treating chlorobenzene with I2 using FeCl3 catalyst. (b) treating phenol with I2 in NaOH solution. (c) treating benzenediazonium chloride with KI (d) treating benzene with CH3I using AlCl3 catalyst

Last Answer : treating benzenediazonium chloride with KI

Which of the following agents is used in order to make benzene react with acetyl chloride to give acetophenone?(a) Ultraviolet light (b) AlCl3 catalyst (c) Platinum catalyst (d) Al2O3 catalyst

Description : Which of the following agents is used in order to make benzene react with acetyl chloride to give acetophenone? (a) Ultraviolet light (b) AlCl3 catalyst (c) Platinum catalyst (d) Al2O3 catalyst

Last Answer : AlCl3 catalyst

Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an sp3 hybridized carbon undergo substitution and elimination reactions. (c) The electronegative atom is replaced by another atom or group in substitution reactions. (d) (a) and (b)

Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)

Last Answer : (a) and (b)

During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Description : During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Last Answer : During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Description : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Last Answer : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the ... D. A is incorrect but R is correct

The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Last Answer : nucleophilic substitution

Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition(d) Nucleophilic substitution

Description : Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition (d) Nucleophilic substitution

Last Answer : Nucleophilic addition

Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Description : Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Last Answer : Electrophilic addition

The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Last Answer : a free-radical substitution

Toluene reacts with chlorine in the presence of AlCl3 to give (a) o-Chlorotoluene (b) o- plus p-Chlorotoluene (c) m-Chlorotoluene (d) o- plus m-Chlorotoluene

Description : Toluene reacts with chlorine in the presence of AlCl3 to give (a) o-Chlorotoluene (b) o- plus p-Chlorotoluene (c) m-Chlorotoluene (d) o- plus m-Chlorotoluene

Last Answer : o- plus p-Chlorotoluene

Which of the following reagents will react with methyl group rather than thebenzene ring in methylbenzene?(a) Chlorine in the presence of uv light(b) CH3Cl in the presence of AlCl3(c) CH3COCl in the presence of AlCl3(d) Hydrogen in the presence of nickel

Description : Which of the following reagents will react with methyl group rather than the benzene ring in methylbenzene? (a) Chlorine in the presence of uv light (b) CH3Cl in the presence of AlCl3 (c) CH3COCl in the presence of AlCl3 (d) Hydrogen in the presence of nickel

Last Answer : Chlorine in the presence of uv light

Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.

How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Description : Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Last Answer : Benzene + Br2/FeBr3

Benzene undergoes Friedel-Crafts reaction with isopropyl alcohol in the presence of H2SO4 catalyst to give (a) n-Propylbenzene (b) Benzophenone (c) Isopropylbenzene (d) Nothing happens

Description : Benzene undergoes Friedel-Crafts reaction with isopropyl alcohol in the presence of H2SO4 catalyst to give (a) n-Propylbenzene (b) Benzophenone (c) Isopropylbenzene (d) Nothing happens

Last Answer : Isopropylbenzene

Benzene reacts with H2 at 150°C at 30 atm in the presence of Ni catalyst to give (a) Cyclohexane (b) Cyclohexene (c) n-Hexane (d) No reaction occurs

Description : Benzene reacts with H2 at 150°C at 30 atm in the presence of Ni catalyst to give (a) Cyclohexane (b) Cyclohexene (c) n-Hexane (d) No reaction occurs

Last Answer : Cyclohexane

Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will (A) Decrease on addition of Cl2 (B) Increase on addition of an inert gas at constant pressure (C) Decrease on increasing the pressure of the system (D) None of these

Description : Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will (A) Decrease on addition of Cl2 (B) Increase on addition of ... at constant pressure (C) Decrease on increasing the pressure of the system (D) None of these

Last Answer : (D) None of thes

Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Last Answer : nucleophilic addition; free radical addition

Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV

Description : Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV

Last Answer : I, II, and III

Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Last Answer : Nucleophilic substitution reactions

'Chlorination' is 1. A process of converting chlorides into chlorine 2. Adding small amounts of chlorine to impure water 3. A chemical reaction in which chlorine is formed 4. An addition reaction of ethylene and chlorine The correct statements are: (a) 1 and 4 (b) 2 and 4 (c) 3 and 4 (d) 1 and 2

Description : 'Chlorination' is 1. A process of converting chlorides into chlorine 2. Adding small amounts of chlorine to impure water 3. A chemical reaction in which chlorine is formed 4. An addition reaction of ethylene and chlorine The correct statements are: (a) 1 and 4 (b) 2 and 4 (c) 3 and 4 (d) 1 and 2

Last Answer : Ans:(b)

Pick out the wrong statement. (A) DDT is manufactured by the condensation of chlorobenzene with chloral at 30°C in presence of oleum, which is a highly exothermic reaction (B) Chloral is obtained by the chlorination of ethyl alcohol (C) Insecticides acting on the insects through the respiratory system are called fumigants (D) Benzene hexachloride is not a contact insecticide

Description : Pick out the wrong statement. (A) DDT is manufactured by the condensation of chlorobenzene with chloral at 30°C in presence of oleum, which is a highly exothermic reaction (B) Chloral ... through the respiratory system are called fumigants (D) Benzene hexachloride is not a contact insecticide

Last Answer : (D) Benzene hexachloride is not a contact insecticide

Although benzene is highly unsaturated, it does not undergo addition reactions, why?

Description : Although benzene is highly unsaturated, it does not undergo addition reactions, why?

Last Answer : Ans. Because of extra stability, due to delocalization of π-electrons.

The elimination of the scum of yeasts in the brine during the fermentation include A.agitation of the surface B.addition of the mustard oil C.addition of the sorbic acid D.all of these

Description : The elimination of the scum of yeasts in the brine during the fermentation include A.agitation of the surface B.addition of the mustard oil C.addition of the sorbic acid D.all of these

Last Answer : D.all of these

Pick out the wrong statement. (A) Alkylation produces a larger iso-paraffin (having higher octane number) from the reaction of an olefin with smaller iso-paraffin (B) Catalytic alkylation processes use HF, AlCl3 & H2SO4 as Catalysts (C) All the alkylation processes use very high temperature (> 1000°C) (D) Gasoline having an octane number of 90 can be produced by alkylation process

Description : Pick out the wrong statement. (A) Alkylation produces a larger iso-paraffin (having higher octane number) from the reaction of an olefin with smaller iso-paraffin (B) Catalytic alkylation processes use HF ... (> 1000°C) (D) Gasoline having an octane number of 90 can be produced by alkylation process

Last Answer : (C) All the alkylation processes use very high temperature (> 1000°C)

Give reason: Alkanes undergo only substitution reactions but alkenes and alkynes undergo both substitution and addition reactions.

Description : Give reason: Alkanes undergo only substitution reactions but alkenes and alkynes undergo both substitution and addition reactions.

Last Answer : Alkenes and alkynes have double and triple bonds, which on breaking can add hydrogen atoms to satisfy the valency.

Which one of the following could NOT cause a change in the mRNA ―reading frame‖? a. Insertion Sequence b. Base-Pair Substitution c. Base Addition d. Base Deletion

Description : Which one of the following could NOT cause a change in the mRNA ―reading frame‖? a. Insertion Sequence b. Base-Pair Substitution c. Base Addition d. Base Deletion

Last Answer : b. Base-Pair Substitution

Which of the following reagents is most suitable for preparing chlorobenzene from benzene? (a) Aqueous chlorine (b) Chlorine in the presence of ultraviolet light (c) Chlorine in acetic acid (d) Chlorine in the presence of FeCl3

Description : Which of the following reagents is most suitable for preparing chlorobenzene from benzene? (a) Aqueous chlorine (b) Chlorine in the presence of ultraviolet light (c) Chlorine in acetic acid (d) Chlorine in the presence of FeCl3

Last Answer : Chlorine in the presence of FeCl3

Benzene reacts with propene in the presence of H2SO4 catalyst to give (a) n-Propylbenzene (b) Benzophenone (c) Cumene (d) Nothing happens

Description : Benzene reacts with propene in the presence of H2SO4 catalyst to give (a) n-Propylbenzene (b) Benzophenone (c) Cumene (d) Nothing happens

Last Answer : Cumene

Benzene reacts with benzoyl chloride in the presence of anhydrous aluminium chloride to form (a) Benzyl chloride (b) Benzaldehyde (c) Benzal chloride(d) Benzophenone

Description : Benzene reacts with benzoyl chloride in the presence of anhydrous aluminium chloride to form (a) Benzyl chloride (b) Benzaldehyde (c) Benzal chloride (d) Benzophenone

Last Answer : Benzophenone

Benzene reacts with chlorine in the presence of FeCl3 catalyst to form (a) Hexachlorobenzene (b) Chlorobenzene (c) Hexachlorocyclohexane (d) Benzyl chloride

Description : Benzene reacts with chlorine in the presence of FeCl3 catalyst to form (a) Hexachlorobenzene (b) Chlorobenzene (c) Hexachlorocyclohexane (d) Benzyl chloride

Last Answer : Chlorobenzene

Which of the following can be made by the action of CH3Cl on benzene in the presence of aluminium chloride? (a) Ethylbenzene (b) o-Xylene (c) Chlorobenzene (d) m-Xylene

Description : Which of the following can be made by the action of CH3Cl on benzene in the presence of aluminium chloride? (a) Ethylbenzene (b) o-Xylene (c) Chlorobenzene (d) m-Xylene

Last Answer : o-Xylene

Which of the following statements are false about benzene? (a) It is a planar molecule with bond angles 120°(b) It is immiscible with water forming the lower layer. (c) It can be converted into cyclohexane by hydrogenation at 200°C in the presence of Ni catalyst. (d) It reacts with ethyl chloride in the presence of aluminium chloride to form ethylbenzene..

Description : Which of the following statements are false about benzene? (a) It is a planar molecule with bond angles 120°. (b) It is immiscible with water forming the lower layer. (c) It can be ... Ni catalyst. (d) It reacts with ethyl chloride in the presence of aluminium chloride to form ethylbenzene.

Last Answer : It is immiscible with water forming the lower layer

Give the example for electrophilic substitution reaction ?

Description : Give the example for electrophilic substitution reaction ?

Last Answer : The species, which accepts the electrons, are called Electrophilles (or) Electrophilic reagents. When the atom (or) group of atoms present in the organic compound is replaced by another atom (or) group of atoms (electrophilic) is called electrophilic substitution reaction.