Pick out the wrong statement. (A) Alkylation produces a larger iso-paraffin (having higher octane number) from the reaction of an olefin with smaller iso-paraffin (B) Catalytic alkylation processes use HF, AlCl3 & H2SO4 as Catalysts (C) All the alkylation processes use very high temperature (> 1000°C) (D) Gasoline having an octane number of 90 can be produced by alkylation process

Pick out the wrong statement.
(A) Alkylation produces a larger iso-paraffin (having higher octane number)
from the reaction of an olefin with smaller iso-paraffin
(B) Catalytic alkylation processes use HF, AlCl3 & H2SO4 as Catalysts
(C) All the alkylation processes use very high temperature (> 1000°C)
(D) Gasoline having an octane number of 90 can be produced by alkylation
process
by

1 Answer

Answer :

(C) All the alkylation processes use very high temperature (> 1000°C)
by

Related questions

In catalytic alkylation, higher iso-butane to olefin ratio gives (A) Low final boiling point product (B) Higher yield (C) Both (A) and (B) (D) Neither (A) nor (B

Description : In catalytic alkylation, higher iso-butane to olefin ratio gives (A) Low final boiling point product (B) Higher yield (C) Both (A) and (B) (D) Neither (A) nor (B

Last Answer : (A) Low final boiling point product

Alkylation (A) Causes olefins to combine with each other(B) Causes olefins to combine with iso-paraffins(C) Converts iso-paraffin into olefin(D) Converts olefin into paraffin

Description : Alkylation (A) Causes olefins to combine with each other (B) Causes olefins to combine with iso-paraffins (C) Converts iso-paraffin into olefin (D) Converts olefin into paraffin

Last Answer : (B) Causes olefins to combine with iso-paraffins

Pick out the correct statement. (A) Paraffins have higher octane number than corresponding iso-paraffin (B) Paraffins have lower smoke point than aromatics

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Last Answer : (B) In H2SO4 polymerisation, H3PO4 is always used with 2% steam to prevent meta & ortho H3PO4 formation, which are inactive

Catalyst used in catalytic polymerisation which produces polymergasoline is(A) H2SO4(B) H3PO4(C) Both (A) and (B)(D) AlCl3

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Last Answer : (C) Both (A) and (B)

In catalytic cracking, the (A) Gasoline obtained has a very low octane number (B) Pressure & temperature is very high (C) Gasoline obtained has very high aromatic content (D) Gasoline obtained has very high amount of gum forming compounds

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Pick out the correct statement pertaining to catalytic cracking. (A) With increase in the reactor pressure, octane number of gasoline decreases (B) With increase in the reactor temperature, gasoline yield decreases for a given conversion (C) Percentage conversion increases with increase in the catalyst to oil ratio (D) All (A), (B) and (C)

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Catalyst used in isomerisation process is (A) H2SO4 (B) H3PO4 (C) HF(D) AlCl3

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Paraffin base crude oil as compared to asphalt base crude gives (A) Higher yield of straight run gasoline (B) Higher octane number gasoline (C) Lower viscosity index lube oil (D) Poorer yield of lube oil

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Last Answer : (A) Higher yield of straight run gasoline

Octane number of gasoline produced by two stage fluidised catalytic cracking process is (A) 80 (B) 87 (C) 92 (D) 97

Description : Octane number of gasoline produced by two stage fluidised catalytic cracking process is (A) 80 (B) 87 (C) 92 (D) 97

Last Answer : (D) 97

Higher pressure in the reforming reactor (A) Increases coke formation (B) Increases the rate of reaction(C) Produces high octane number gasoline(D) None of these

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Concentration of H2SO4 catalyst in alkylation is kept between 90-98%, because H2SO4 having concentration. (A) Less than 90% promotes polymerisation (B) More than 98% promotes cracking (C) Both (A) and (B) (D) Neither (A) nor (B)

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Last Answer : (C) Both (A) and (B)

Pick out the wrong statement. (A) Higher temperature is employed in visbreaking than in thermal cracking (B) Pyrolysis is a mild thermal cracking process (C) Lead susceptibility of petrol produced by catalytic process is more than that produced by thermal cracking (D) Operating pressure and temperature in thermal cracking process is more than that in catalytic cracking process

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Which among the following is used as a catalyst in the production of high octane fuels? (1) HNO3 (2) H2SO4 (3) HCl (4) HF

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Pick out the wrong statement. (A) Catalytic hydrogenation of carbon monoxide produces methyl alcohol (B) In nylon-6, the number 6 represents the total number of carbon atoms in the ring (C) Raw materials for DDT manufacture are benzene and chlorine (D) Ethanolamines are produced by using ammonia and ethylene oxide as raw material

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Name the hydrocarbon having the poorest oxidation stability. (A) Naphthene (B) Olefin (C) Paraffin (D) Aromatics

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Straight run naphtha is converted into high octane number petrol (gasoline) by catalytic (A) Cracking (B) Polymerisation (C) Reforming (D) Isomerisation

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Gum formation in stored gasoline is mainly due to the (A) Alkylation of unsaturated (B) Presence of sulphur (C) Oxidation & polymerisation of unsaturated (D) Higher aromatic content

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Octane number (unleaded) of gasoline produced by isomerisation of butane may be about (A) 45 (B) 55 (C) 70 (D) 90

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Which one of the following processes aims at producing higher yield of gaseous unsaturated hydrocarbons and aromatics like benzene & toluene? (A) Reforming (B) Pyrolysis (C) Alkylation (D) Hydrocracking

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Calorific value of (A) Light paraffinic fuel oils is equal to that of equivalent olefins (B) n-paraffin is lower than that of iso-paraffins of the same compounds (C) Light paraffinic fuel oils is higher than that of equivalent olefins (D) Light paraffinic fuel oils is lower than that of equivalent olefins

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Last Answer : (C) Light paraffinic fuel oils is higher than that of equivalent olefins

In petroleum refining, the process used for conversion of hydrocarbons to aromatics is (A) Catalytic cracking (B) Catalytic reforming (C) Hydrotreating (D) Alkylation

Description : In petroleum refining, the process used for conversion of hydrocarbons to aromatics is (A) Catalytic cracking (B) Catalytic reforming (C) Hydrotreating (D) Alkylation

Last Answer : (B) Catalytic reforming

Octane number (unleaded) of reformed gasoline may be upto (A) 60 (B) 70 (C) 80 (D) 90

Description : Octane number (unleaded) of reformed gasoline may be upto (A) 60 (B) 70 (C) 80 (D) 90

Last Answer : (D) 90

Pick out the wrong statement. (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity(B) For an ideal mixed reactor at steady state, the exit stream has the samecomposition as fluid within the reactor and the space time is equivalent toholding time for constant density system(C) Plug flow reactor (PFR) is always smaller than mixed reactor for allpositive reaction orders for a particular duty(D) Reaction rate does not decrease appreciably as the reaction proceeds incase of an autocatalytic reaction

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Last Answer : (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity

__________ determination is not a very significant and important test for gasoline. (A) Gum & sulphur content (B) Viscosity (C) Octane number (D) Reid vapor pressure

Description : __________ determination is not a very significant and important test for gasoline. (A) Gum & sulphur content (B) Viscosity (C) Octane number (D) Reid vapor pressure

Last Answer : (B) Viscosity

Pick out the wrong statement. (A) In the McCabe-Thiele diagram for binary distillation, vertical feed line represents saturated liquid feed and horizontal feed line represents saturated vapour feed (B) In small columns, local efficiency is larger than Murphree efficiency; in large columns local efficiency is smaller than Murphree efficiency (C) For Laminar flow over a plate of length L, the local mass transfer co￾efficient at a distance L from the leading edge is 1.5 × 10 -2m/s. Then the average mass transfer co-efficient for the plate is 2 × 10 -2m/s (D) The concentration and hydrodynamic boundary layers over a flat plate are of equal thickness, if Schmidt number is equal to unity

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Though increased pressure has a retarding effect on cracking reaction, yet in actual process, a positive pressure of 10-15 kgf/cm2 is maintained during cracking mainly to (A) Increase the yield of light distillates (B) Suppress coke formation (C) Enhance the octane number of gasoline (D) Reduce gum content in gasoline

Description : Though increased pressure has a retarding effect on cracking reaction, yet in actual process, a positive pressure of 10-15 kgf/cm2 is maintained during cracking mainly to (A) Increase the yield of ... coke formation (C) Enhance the octane number of gasoline (D) Reduce gum content in gasoline

Last Answer : (B) Suppress coke formation

Catalytic cracking compared to thermal cracking of residue of vacuum distillation of crude oil (A) Gives higher yield of petrol (B) Lower octane number of petrol (C) Higher sulphur content in the product (D) Higher gum forming material in petro

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Last Answer : (A) Gives higher yield of petrol

Pick out the wrong statement about cavitation. (A) Sudden reduction of pressure in a fluid flow system caused by flow separation, vortex formation or abrupt closing of valve leads to cavitation (B) Cavitation may be caused due to boiling of liquid by decreasing the pressure resulting in formation & collapse of vapor cavities (C) Cavitation begins at higher static pressure and lower velocity in larger diameter pipelines resulting in audible noise(D) Large scale cavitation cannot damage pipeline, restrict fluid flow anddamage steam turbine blades

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Last Answer : (D) Large scale cavitation cannot damage pipeline, restrict fluid flow and damage steam turbine blades

Gasoline with an octane number of 90 is equivalent in knocking characteristics to a mixture of heptane and isooctane of the following composition : (a) 20% heptane + 80% isooctane (b) 90% heptane + 10% isooctane (c) 80% heptane + 20% isooctane (d) 10% heptane + 90% isooctane

Description : Gasoline with an octane number of 90 is equivalent in knocking characteristics to a mixture of heptane and isooctane of the following composition : (a) 20% heptane + 80% isooctane (b) 90% heptane + 10% isooctane (c) 80% heptane + 20% isooctane (d) 10% heptane + 90% isooctane

Last Answer : 10% heptane + 90% isooctane

Choose the correct statement regarding thermal cracking. (A) Moderate changes in operating temperature does not change the depth of cracking (B) Increased residence time results in the decreased severity of cracking (C) At low pressure, the yield of lighter hydrocarbons are more (D) Greater depth of cracking gives lower octane number gasoline

Description : Choose the correct statement regarding thermal cracking. (A) Moderate changes in operating temperature does not change the depth of cracking (B) Increased residence time results in the decreased ... of lighter hydrocarbons are more (D) Greater depth of cracking gives lower octane number gasoline

Last Answer : (D) Greater depth of cracking gives lower octane number gasoline

Vinyl chloride (CH2 = CH.Cl) is produced by the thermal pyrolysis of ethylene dichloride at a pressure & temperature of (A) 4 kgf/cm2 & 500°C (B) 10 kgf/cm2 & 1000°C (C) 40 kg/cm2 & 200°C (D) 100 kgf/cm2 & 500°C

Description : Vinyl chloride (CH2 = CH.Cl) is produced by the thermal pyrolysis of ethylene dichloride at a pressure & temperature of (A) 4 kgf/cm2 & 500°C (B) 10 kgf/cm2 & 1000°C (C) 40 kg/cm2 & 200°C (D) 100 kgf/cm2 & 500°C

Last Answer : (A) 4 kgf/cm2 & 500°C

Pick out the wrong statement. (A) 'Hold back' is defined as the fraction of material that stays longer than the mean residence time (B) Study of non-ideal flow reactor is done experimentally by stimulus￾response technique (C) For studying a chemical reaction, it is desirable to monitor the reactants during initial stages and the products during the final stages of reaction (D) A batch reactor cannot be used to study the kinetics of catalytic reaction

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Last Answer : (D) A batch reactor cannot be used to study the kinetics of catalytic reaction

Pick out the wrong statement. (A) Chamber process of sulphuric acid manufacture produces pure acid of concentration < 80% (B) Contact process of sulphuric acid manufacture produces pure acid of concentration ≥ 98% (C) 75% oleum can be produced by distillation of 20% oleum (D) Contact process of sulphuric acid manufacture uses nickel as the catalyst

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Last Answer : (D) Contact process of sulphuric acid manufacture uses nickel as the catalyst

Pick out the wrong statement. (A) The integral method of analysing kinetic data is used when the data is scattered (B) The differential method of analysing kinetic data requires more accurate or larger amounts of data (C) When the reaction rate is independent of temperature, the reaction is said to be of zero order (D) The ratio of volumes of plug flow reactor to that of mixed reactor is always less than one for identical feed composition, flow rate, conversion and for all positive reaction orders

Description : Pick out the wrong statement. (A) The integral method of analysing kinetic data is used when the data is scattered (B) The differential method of analysing kinetic data requires more accurate ... less than one for identical feed composition, flow rate, conversion and for all positive reaction orders

Last Answer : (C) When the reaction rate is independent of temperature, the reaction is said to be of zero order

Pick out the wrong statement. (A) In drying a solid containing moisture above the critical moisture content the number of degrees of freedom is 2 (B) Sherwood number in mass transfer corresponds to Nusselt number in heat transfer and Schmidt number to Prandtl number (C) Forced convection is relatively more effective in increasing the rate of mass transfer, if Schmidt number is larger (D) Hot gases at moderate pressure are usually in the shell side of shell and tube heat exchangers. At higher pressure, however, it is customary to put gas in the tube side

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Last Answer : (C) Forced convection is relatively more effective in increasing the rate of mass transfer, if Schmidt number is larger

The chamber process is (A) Preferred over contact process for producing 98 to 100% H2SO4 and various oleums (B) Non-catalytic and operates only on pyrites (C) A batch process for directly producing high strength (98 to 100%) H2SO4 (D) None of these

Description : The chamber process is (A) Preferred over contact process for producing 98 to 100% H2SO4 and various oleums (B) Non-catalytic and operates only on pyrites (C) A batch process for directly producing high strength (98 to 100%) H2SO4 (D) None of these

Last Answer : (D) None of these

Catalytic desulphurisation process used for sweetening of straight run gasoline and kerosene uses __________ as catalyst. (A) Bauxite (B) Fuller’s earth (C) Activated clay(D) All (A), (B) & (C)

Description : Catalytic desulphurisation process used for sweetening of straight run gasoline and kerosene uses __________ as catalyst. (A) Bauxite (B) Fuller’s earth (C) Activated clay (D) All (A), (B) & (C)

Last Answer : (D) All (A), (B) & (C)

Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with acidic KMnO4 solution. (c) on refluxing with concentrated H2SO4 gives a mixture of ortho and para toluenesulfonic acid. (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene

Visbreaking process is used mainly for making (A) High cetane diesel (B) High octane gasoline (C) Fuel oil (D) Smoke free kerosene

Description : Visbreaking process is used mainly for making (A) High cetane diesel (B) High octane gasoline (C) Fuel oil (D) Smoke free kerosene

Last Answer : (C) Fuel oil