Description : Which of the following is not a nucleophile? (a) FeBr3 (b) Br– (c) NH3 (d) CH3OCH3
Last Answer : CH3OCH3
Description : Which of the following is not a nucleophile? (a) NH3 (b) HSO3– (c) AlCl3 (d) HO–
Last Answer : AlCl3
Description : Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent? (a) CH3CH2NH2 (b) (CH3CH2)2NH (c) (CH3CH2)3N (d) (CH3)3N
Last Answer : CH3CH2NH2
Description : What type of intermolecular interactions does (CH3CH2)2NH undergo? (a) induced dipole-induced dipole (b) dipole-dipole (c) hydrogen bonding (d) all of these
Last Answer : all of these
Description : Triethylamine [(CH3CH2)3N] is a molecule in which the nitrogen atom is __________ hybridized and the CNC bond angle is __________. (a) sp2; >109.5° (b) sp2; 109.5° (d) sp3;
Last Answer : sp3;
Description : Which of the following compounds does not form a salt with dilute HCl? (a) CH3CH2CONH2 (b) (CH3CH2)2NH (c) CH3CH2NH2 (d) (CH3CH2)3N
Last Answer : CH3CH2CONH2
Description : Diethyl ether reacts with excess of hot concentrated HI to form (a) CH3CH2I + CH3CH2OH (b) Only CH3CH2OH (c) CH3CH2OH + CH2=CH2 (d) Only CH3CH2
Last Answer : Only CH3CH2
Description : Why does the boiling point of CH3NH2 less than HCOOH?
Last Answer : Ans:- HCOOH is associated with intermolecular H-bonding in greater extent then CH3NH2 and therefore HCOOH has higher boiling point than CH3NH2 .
Description : What is the hybridization of the carbon atom in CH3NH2? (a) 3sp3 (b) sp (c) sp2 (d) sp3
Last Answer : sp3
Description : What is the hybridization of the nitrogen atom in CH3NH2? (a) sp (b) sp2 (c) sp3 (d) s-sp3
Description : Which of the following has the greatest solubility in CH3CH2CH2CH3? (a) CH3OH (b) CH3NH2 (c) CH3OCH3 (d) (CH3)3CH
Last Answer : (CH3)3CH
Description : What is the conjugate base of CH3NH2? (a) CH3NH3+ (b) CH3NH– (c) NH4+ (d) NH2–
Last Answer : CH3NH–
Description : What is the conjugate acid of CH3NH2? (a) CH3NH3+ (b) CH3NH– (c) NH4+ (d) NH2–
Last Answer : CH3NH3+
Description : Impurities present in brine is normally removed by treatment with (A) NH3 and CO2 (B) Lime and soda ash (C) Lime, ammonia and carbon (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : Is CH3NH2 inorganic or organic?
Last Answer : CH3NH2 is methyl amine, and it is ORGANIC.
Description : Why cyanide ion act as ambident nucleophile ?
Last Answer : Ans.---- Cyanide ion can link through either carbon or nitrogen, therefore it is an ambident nuclophile.
Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.
Last Answer : The addition product is a frequently observed minor product.
Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic
Description : Which of the following factors has no effect on the rate of SN1 reactions? (a) the nature of the alkyl halide (b) the nature of the leaving group (c) the concentration of the alkyl halide (d) the concentration of the nucleophile
Last Answer : the concentration of the nucleophile
Description : Which of the following is the rate law for SN1 mechanisms? (a) Rate = k[Alkyl Halide] [Nucleophile] (b) Rate = k[Nucleophile] (c) Rate = k[Alkyl Halide] (d) Rate = k1[Alkyl Halide] + k2[Nucleophile]
Last Answer : Rate = k[Alkyl Halide]
Description : Which of the following is the best nucleophile in water? (a) I– (b) CH3SCH3 (c) CH3OCH3 (d) Cl–
Last Answer : I–
Description : Which of the following is the strongest nucleophile in an aqueous solution? (a) HO– (b) Cl– (c) Br– (d) I
Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides
Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides
Description : Which of the following factors influence whether a reaction will proceed by an SN1, SN2, E1, or E2 mechanism? (a) Structure of the alkyl halide (b) Solvent (c) Concentration of reagents (d) Nature of the nucleophile (e) All of these
Last Answer : All of these
Description : Which of the following is not a possible reaction of a carbocation? (a) addition of a nucleophile (b) rearrangement to a more stable carbocation (c) addition of a proton to form an alkane (d) loss of a β-hydrogen to form an alkene
Last Answer : addition of a proton to form an alkane
Description : Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds ... fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.
Last Answer : Alkynes are generally more reactive than alkenes.
Description : Why does a H+ ion attacking a carbon-carbon double bond add to the carbon with the least number of substituents? (a) the reaction is resonance stabilized. (b) the hybrid geometry favors this ... tends to attack stable centers of negative charge. (d) a more stable carbonium ion is generated.
Last Answer : a more stable carbonium ion is generated.
Description : In the reaction of propene with HCl, H+ ion acts as the : (a) electrophile (b) carbonium ion (c) nucleophile (d) carbanion
Last Answer : electrophile
Description : Which of the following statements is incorrect? (a) Electrons move toward positively charged locations. (b) An electron-rich atom is called an electrophile. (c) An electrophile is electron loving. (d) A nucleophile has a a pair of electrons it can share
Last Answer : An electron-rich atom is called an electrophile.
Description : A nucleophile acts as a __________ when it reacts with an electrophile. (a) Bronsted-Lowry acid (b) Arrhenius base (c) Lewis acid (d) Lewis base
Last Answer : Lewis base
Description : An electrophile acts as a __________ when it reacts with a nucleophile. (a) Bronsted-Lowry base (b) Arrhenius base (c) Lewis acid (d) Lewis base
Last Answer : Lewis acid
Description : Which of the following is a nucleophile? (a) AlCl3 (b) H3O+ (c) BF3 (d) CN–
Last Answer : CN–
Description : When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one nitrogen atom of semicarbazide acts as a nucleophile and attack
Last Answer : When semicarbazide reacts with a ketone (or aldehyde) to form semicarbazone. Only one ... atoms of semicarbazide are relatively non nucleophilic ?
Description : Which of the following is not a nucleophile ?
Last Answer : Which of the following is not a nucleophile ? A. `H_(2)` B. `CH_(3)OH` C. `H_(2)O` D. `NH_(3)`
Description : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)=CH_(2))" "underset("(2)")(CH_(2)=
Last Answer : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)= ... and (4) D. (2), (3) and (4)
Description : `NH_(3) + NaOCl overset("golatin or " EDTA^(+))rarr` products The number of moles of `N - H` bonds present in one mole of the strongest nucleophile pr
Last Answer : `NH_(3) + NaOCl overset("golatin or " EDTA^(+))rarr` products The number of moles of ... mole of the strongest nucleophile present in the product is:
Description : Which of the following are nucleophile?
Last Answer : Which of the following are nucleophile? A. `NH_(3)` B. `OH^(-)` C. `R-O-R` D. `AlCl_(3)`
Description : A nucleophile must have :
Last Answer : A nucleophile must have : A. a negative charge B. a positive charge C. a lone pair of electron D. an electron deficient centre
Description : Which one of the following behaves both as a nucleophile and an electrophile ?
Last Answer : Which one of the following behaves both as a nucleophile and an electrophile ? A. `CH_(3)NH_(2)` B. `CH_(3)OH` C. `CH_(3)CN` D. `CH_(3)Cl`
Description : A nucleophile is:
Last Answer : A nucleophile is: A. electron-rich species B. electron-deficient species C. a Lewis base D. positively charged species
Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.
Description : (i) Write down the IUPAC name of the following complex : [CO(NH3)5Cl]2+ (ii) Write the formula for the following complex : Potassium tetrachloridonickelate (II) -Chemistry
Last Answer : i) [CO(NH3)5Cl]2+ IUPAC name : Pentaammine chlorido cobalt (III) ion (ii) Formula of the complex potassium tetrachloridonickelate (II) K2[NiCl4]
Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry
Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+
Description : Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit? -Chemistry
Last Answer : IUPAC name : Tetraamine dichlorido chromium (III) ion. It exhibits geometrical isomerism.
Description : Explain why [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex. (At. no. Co = 27, Ni = 28) -Chemistry
Last Answer : In [Co(NH3)6]3+, the d-electrons of Co3+ ([Ar]3d6 45°) get paired leaving behind two empty d-orbital and undergo d2sp3 hybridization and hence inner orbital complex, while in [Ni(NH3)6]2+ ... of Ni2+([Ar]3d8 45°) do not pair up and use outer 4d subshell hence outer orbital complex.
Description : Describe the shape and magnetic behaviour of following complexes : (i) [CO(NH3)6]3+ (ii) [Ni(CN)4]2- (At. No. Co = 27, Ni = 28) -Chemistry
Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-
Description : Name the following coordination compounds according to IUPAC system of nomenclature :(i) [Co(NH3)4 (H2O)Cl]Cl2 (ii) [CrCl2(en)2]Cl, (en = ethane – 1, 2 – diamine) -Chemistry
Last Answer : (i) [CO(NH3)4 (H2O)Cl]Cl2 Tetraammine aquachlorido cobalt (III) chloride (ii) [CrCl2(en)2]Cl Dichlorobis (ethane-1, 2-diamine) chromium (III) chloride